CN109354553A - One kind is with juice production humic acid water-soluble fertilizer and preparation method thereof - Google Patents
One kind is with juice production humic acid water-soluble fertilizer and preparation method thereof Download PDFInfo
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- CN109354553A CN109354553A CN201811571914.8A CN201811571914A CN109354553A CN 109354553 A CN109354553 A CN 109354553A CN 201811571914 A CN201811571914 A CN 201811571914A CN 109354553 A CN109354553 A CN 109354553A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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Abstract
The present invention relates to Water soluble fertilizer technical fields, more specifically, it is related to one kind with juice production humic acid water-soluble fertilizer and preparation method thereof, choose the fruit that market has the residual generaI investigation verification of conformity of agriculture, crushing is taken to squeeze, enzymatic hydrolysis, the fermented juice that biofermentation mode produces is carrier, add metal-chelator, function additive, microelement, pass through two times of ultrafiltration, the humic acid trace element water-soluble fertilizer of production, outside its index for containing humic acid trace element requirement, its another microelement has chelating properties, rich in reproducibility sugar source, thallus, product has antisolvent precipitation and flocculation, dissolubility is high, crop easily absorbs, nutrition easily accumulates the characteristics of converting by crop, after applying product of the invention, crops, upgrading, obvious effect of increasing production.
Description
Technical field
The present invention relates to Water soluble fertilizer technical fields, more specifically, be related to it is a kind of with juice production humic acid water-soluble fertilizer and
Preparation method.
Background technique
Domestic a large amount of for a long time or excessive application chemical fertilizer, because utilization rate of fertilizer is low, nutrient is unbalanced, blindly applies fertilizer, makes
At soil hardening, a series of environmental problems such as soil microbial community mistake, environmental pollution, nutrition accumulation, chemical fertilizer exists in recent years
Up to 100,000,000,000 yuan of bring loss in terms of environmental pollution.In agricultural production in recent years simultaneously, the shortage of microelement is increasingly tight
Weight, all there is the deficiency disease of microelement in many crops, such as corn, rice zinc-deficiency, Chlorosis in Fruit trees, boron deficiency, rape boron etc..
Fruit tree has the characteristics that fix even technology year ground growth more than ten years compared with annual field crop, micro in soil
Depletion of element seems more prominent than field crop, so it is relatively sensitive to microelement, whole life cycle is to micro
The demand of element is also relatively large.Low productive soil is easy to appear shortage microelement, improves soil, continuous with yield level
It improves, demand of the crop to microelement also can accordingly increase.Simultaneously with the raising of multiple crop index, yield increases year by year, nitrogen,
The application of phosphorus, potash fertilizer is consequently increased, so that the consumption of effective trace elements in soil is exacerbated, so that nutrient supply is lacked of proper care,
Because plan requires supplementation with certain microelement, could further play chemical fertilizer yield potential, per acre total output of grain can obtain compared with
High level.
Patent CN201510401005.X discloses a kind of Water soluble fertilizer made using liquid molasses fermentation as carrier, in liquid molasses
Sugar fertilizer be mainly that sucrose and glucose need to be converted into fruit after absorbing for being similar to for the fruit such as apple, peach
Sugar storage is needed by fermenting three times, the equipment and complex process needed.It introduces and utilizes in patent CN201710497143.1
Buckwheat shell makes humic acid water-soluble fertilizer, and raw material has limitation.201510209299.6 introducing benefit with 201410525077.0
It is raw material with humic acid potassium, sodium humate, configures other auxiliary material production humic acid water-soluble fertilizer, characteristic is mainly hard water resistance and heavy
It forms sediment.The humic acid water-soluble fertilizer of non-mineral source method production is described in patent CN201310290566.8 and 201210491270.8,
Its main humic acid material is fermentation liquid such as biogas slurry, livestock manure fermented liquid.Patent CN201110250221.0,
It is raw material through making a living that CN201110224852.5, CN201010124606.8 etc., which are described using furfural dregs, humic acid, weathered coal liquid,
Change production humic acid water-soluble fertilizer method, the humic-acid kind of the method production is similar to mineral sources humic acid potassium and sodium humate.To sum up
Described, the raw material that humic acid water-soluble fertilizer is made in existing publication has compared comprehensively, and function is also enriched, but its composition of raw materials
Single, production humic acid water-soluble fertilizer-plant absorption rate is low, is easy to be adsorbed by soil particle in the soil, cause in soil
Oxidation-reduction potential is higher, causes the imbalance cost of material of Soil Microorganism more expensive, is confined to conventional humic acid water-soluble fertilizer
Technical standard and raw material will be in limiting the Innovative Development and commercial applications of humic acid fertilizer.Last existing humic acid water-soluble
There is precipitating in fertilizer and flocculation problems are relatively difficult to resolve certainly, and it is mostly that plant directly provides nutrition, and is not planted by improving that effect, which embodies,
It is required that the microenvironment of object growth provides plant nutrient indirectly.
Summary of the invention
The purpose of the present invention is to provide a kind of humic acid water-soluble fertilizer and preparation method thereof produced using fruit juice as raw material.
In order to achieve the above objectives, technical solution provided by the invention are as follows:
One kind is composed of the following raw materials by weight with juice production humic acid water-soluble fertilizer: 70-85 parts of fermented juice, metal-chelating
2-8 parts of agent, 0.1-0.6 parts of function additive, 3-5 parts of manganese sulfate, 4-6 parts of ferrous sulfate, 0.5-1.5 parts of copper sulphate, boric acid
2.5-3 parts, 0.8-1.2 parts of ammonium molybdate, 1.5-2 parts of zinc sulfate.
Further, the metal-chelator is disodium ethylene diamine tetraacetate, diethylenetriamine pentacarboxylic acid salt, gluconic acid
One or more mixtures in sodium and Oxyethylethylenediaminetriacetic acid.
Further, the function additive be it is a kind of in polyglutamic acid, poly-aspartate, chitin and sodium alginate or
A variety of mixtures.
A kind of preparation method with juice production humic acid water-soluble fertilizer, comprising the following steps:
S1, fruit juice fermentation: the fruit of screening decayed fruit rate < 5% is broken for the pulp and juice mixture of 3-6mm grade with crusher,
Complex enzyme is added, controls 50-70 DEG C of temperature, mixing speed controls 20-30rad/min, digests 2 hours；By the substance after enzymatic hydrolysis
30-35 DEG C of temperature, revolving speed 50rad/min, adjusting pH of control is 6-7, is added after carrying out fermentation 24 hours beneficial to composite flora, and
Plate compression is taken to obtain filtrate as fermented juice by 0.25mm net；
S2, material dissolution: being 70-85 parts of fermented juice, 2-8 parts of metal-chelator, 0.1-0.6 parts of function by parts by weight
Additive sequentially adds in reaction kettle, stirring to whole dissolutions；
It is S3, trace element chelated: to be 3-5 parts of manganese sulfate, 4-6 parts of ferrous sulfate, 0.5-1.5 parts of sulfuric acid by parts by weight
Stirring to whole in S2 in reaction kettle is added in copper, 2.5-3 parts of boric acid, 0.8-1.2 parts of ammonium molybdate, 1.5-2 parts of zinc sulfate
Dissolution；
S4, ultrafiltration disinfection: by the solution being uniformly mixed in S2 by 150 mesh net filtrations, filtrate being placed in reaction kettle and is sterilized,
Uniformly mixed liquid is then imported into storage tank, is stored 12 hours, is humic acid microelement after taking supernatant detection qualified
Water soluble fertilizer.
Further, the fruit has the residual generaI investigation verification of conformity of agriculture.
Further, pulp enzyme, cellulase, hemicellulase, lignin peroxidase, matter in the complex enzyme
Amount ratio is 1:0.5:0.3:0.1, and the mass ratio of complex enzyme and pulp and juice mixture is 2000:1；The beneficial composite flora
Middle Trichoderma, muscardine, bacillus subtilis, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；
It is 1000:1 beneficial to the mass ratio of composite flora and pulp and juice mixture.
Further, whipping temp is 40 DEG C -50 DEG C in the S2, and mixing time is 1-2 hours.
Further, whipping temp is 60 DEG C -70 DEG C in the S3, and mixing time is 2-4 hours.
Further, concrete operations are sterilized in the S3 are as follows: control 75 DEG C of temperature using pasteurization, keep 30min.
Further, decayed fruit rate >=5% detection is used as underproof decayed fruit in fruit S3 in the S1, by decayed fruit, pressure in S1
After filter in filter residue and S4 filtered filtration residue as organic fertilizer production raw material.
Compared with prior art, the advantageous effect of present invention is that:
The present invention provides one kind with juice production humic acid water-soluble fertilizer and preparation method thereof, and choosing market, there is the residual generaI investigation of agriculture to close
The fruit that lattice prove, the fermented juice for taking crushing squeezing, enzymatic hydrolysis, biofermentation mode to produce are carrier, add metal-chelating
Agent, function additive, microelement, by two times of ultrafiltration, the humic acid trace element water-soluble fertilizer of production is micro- containing humic acid
Outside the index that secondary element requires, its another microelement has chelating properties, is rich in reproducibility sugar source, thallus, and product has antisolvent precipitation
It is easily absorbed with flocculation, dissolubility height, crop, nutrition easily accumulates the characteristics of converting, after applying product of the invention, farming by crop
Object, upgrading, obvious effect of increasing production.For humic acid water-soluble fertilizer provided by the invention using fruit as raw material, raw material type is from a wealth of sources,
It is not single, there is the place of fruit that can produce this fertilizer；Using the fructose in fruit juice as carrier, fully demonstrates and come from plant
The theory gone in plant；Carbonizable substance in the present invention is that fructose and mycoprotein can provide carbon source for edaphon, also can be straight
Connect supply plant growth needed for, have facilitate production by adjust plant demand Trace Elements, by fruit juice application by
Traditional field of food is applied on the new-type fertilizer of agriculture field, has increased production liquid humic acid trace element water-soluble fertilizer newly
Fruit juice is more made full use of, improves its commercial value by type of feed.What the present invention took is enzymatic hydrolysis, biofermentation legal system
Standby humic acid water-soluble fertilizer, humic acid generate after enzymatic hydrolysis and biofermentation, have it is hard water resistance, without flocculating, dissolve fast characteristic.
To sum up, humic acid water-soluble fertilizer of the invention has that antisolvent precipitation and flocculation, dissolubility is high, crop easily absorbs, nutrition is easily accumulated by crop
The characteristics of tired conversion, after applying product of the invention, crops are taking root, are proposing seedling, upgrading, obvious effect of increasing production.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
One, the preparation of fermented juice: choosing the fruit with the residual generaI investigation verification of conformity of agriculture, in the present invention fruit definition include but not
It is limited to the fruit such as apple, peach, pears, plum, apricot, Kiwi berry, orange, pineapple, filters out the fruit of decayed fruit rate < 5%, decayed fruit rate >=
5% fruit detection is used as rejected product decayed fruit.Qualified product fruit is broken for the pulp and juice of 3-6mm grade using crusher
Complex enzyme is added in mixture, controls 50-70 DEG C of temperature, and mixing speed controls 20-30rad/min, digests 2 hours.After digesting
Substance control 30-35 DEG C of temperature, revolving speed 50rad/min, adjust pH 6-7, be added beneficial to composite flora carry out fermentation 24 hours
Afterwards, and plate compression is taken to pass through 0.25mm net for qualified product fermented juice.
Filter residue is mixed with unified collect of rejected product decayed fruit after pressure filter, can be used as because it contains beneficial to composite flora
Zymophyte in organic fertilizer fermentation.
Pulp enzyme, cellulase, hemicellulase, lignin peroxidase in complex enzyme, mass ratio 1:
The mass ratio of 0.5:0.3:0.1, complex enzyme and pulp and juice mixture is 2000:1；Trichoderma in the beneficial composite flora,
Muscardine, bacillus subtilis, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；Beneficial to compound
The mass ratio of flora and pulp and juice mixture is 1000:1.
Two, with the preparation of juice production humic acid water-soluble fertilizer: (1) material dissolution: by parts by weight be 76 parts fermented juice,
5 parts of disodium ethylene diamine tetraacetate, 0.3 part of polyglutamic acid proportionally sequentially add in reaction kettle, and temperature is controlled at 50 DEG C,
Mixing time is 2 hours to whole dissolutions.(2) trace element chelated: by parts by weight be 5 parts manganese sulfate, 6 parts of sulfuric acid it is sub-
Iron, 1.5 parts of copper sulphate, 3 parts of boric acid, 1.2 parts of ammonium molybdate, 2 parts of zinc sulfate sequentially add in reaction kettle among the above,
At 70 DEG C, mixing time is 4 hours for temperature control, until solution all dissolves.(3) ultrafiltration sterilizes: by uniformly mixed solution mistake
150 mesh screens, for filter residue as organic fertilizer production raw material, filtrate, which is placed in reaction kettle, controls temperature 75 using pasteurization
DEG C, it is kept for 30 minutes, is then imported uniformly mixed liquid storage tank 12 hours, the near room temperature of temperature, supernatant detection is taken to close
It is humic acid trace element water-soluble fertilizer after lattice.
Embodiment 2
One, the preparation of fermented juice: choosing the fruit with the residual generaI investigation verification of conformity of agriculture, in the present invention fruit definition include but not
It is limited to the fruit such as apple, peach, pears, plum, apricot, Kiwi berry, orange, pineapple, filters out 5% qualified product fruit of decayed fruit rate <, decayed fruit
The fruit detection of rate >=5% is used as rejected product decayed fruit.Qualified product fruit is broken for the pulp of 3-6mm grade using crusher
Complex enzyme is added in fruit juice mixt, controls 50-70 DEG C of temperature, and mixing speed controls 20-30rad/min, digests 2 hours.By enzyme
Substance after solution controls 30-35 DEG C of temperature, revolving speed 50rad/min, adjusts pH 6-7, is added and carries out fermentation 24 beneficial to composite flora
After hour, and taking plate compression to pass through 0.25mm net is qualified product fermented juice.
Filter residue is mixed with unified collect of rejected product decayed fruit after pressure filter, can be used as because it contains beneficial to composite flora
Zymophyte in organic fertilizer fermentation.
Pulp enzyme, cellulase, hemicellulase, lignin peroxidase in complex enzyme, mass ratio 1:
The mass ratio of 0.5:0.3:0.1, complex enzyme and pulp and juice mixture is 2000:1；Trichoderma in the beneficial composite flora,
Muscardine, bacillus subtilis, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；Beneficial to compound
The mass ratio of flora and pulp and juice mixture is 1000:1.
Two, with the preparation of juice production humic acid water-soluble fertilizer: (1) being 83 parts of fermented juice, 6 parts of diethyl by parts by weight
Alkene triamine pentacarboxylic acid salt, 0.2 sodium alginate proportionally sequentially add in reaction kettle, temperature control is at 40 DEG C, mixing time
To be 1 hour to whole dissolutions.(2) trace element chelated: to be 3 parts of manganese sulfate, 4 parts of ferrous sulfate, 0.5 part by parts by weight
Copper sulphate, 2.5 parts of boric acid, 0.8 part of ammonium molybdate, 1.5 parts of zinc sulfate sequentially add in reaction kettle among the above, temperature
At 65 DEG C, mixing time is 2 hours for control, until solution all dissolves.(3) ultrafiltration sterilizes: uniformly mixed solution is crossed 150 mesh
Sieve, for filter residue as organic fertilizer production raw material, filtrate, which is placed in reaction kettle, controls 75 DEG C of temperature using pasteurization, keeps
30 minutes, then uniformly mixed liquid is imported storage tank 12 hours, the near room temperature of temperature, is after taking supernatant detection qualified
Humic acid trace element water-soluble fertilizer.
Embodiment 3
One, the preparation of fermented juice: choosing the fruit with the residual generaI investigation verification of conformity of agriculture, in the present invention fruit definition include but not
It is limited to the fruit such as apple, peach, pears, plum, apricot, Kiwi berry, orange, pineapple, filters out 5% qualified product fruit of decayed fruit rate <, decayed fruit
The fruit detection of rate >=5% is used as rejected product decayed fruit.Qualified product fruit is broken for the pulp of 3-6mm grade using crusher
Complex enzyme is added in fruit juice mixt, controls 50-70 DEG C of temperature, and mixing speed controls 20-30rad/min, digests 2 hours.By enzyme
Substance after solution controls 30-35 DEG C of temperature, revolving speed 50rad/min, adjusts pH 6-7, is added and carries out fermentation 24 beneficial to composite flora
After hour, and taking plate compression to pass through 0.25mm net is qualified product fermented juice.
Filter residue is mixed with unified collect of rejected product decayed fruit after pressure filter, can be used as because it contains beneficial to composite flora
Zymophyte in organic fertilizer fermentation.
Pulp enzyme, cellulase, hemicellulase, lignin peroxidase in complex enzyme, mass ratio 1:
The mass ratio of 0.5:0.3:0.1, complex enzyme and pulp and juice mixture is 2000:1；Trichoderma in the beneficial composite flora,
Muscardine, bacillus subtilis, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；Beneficial to compound
The mass ratio of flora and pulp and juice mixture is 1000:1.
Two, with the preparation of juice production humic acid water-soluble fertilizer: (1) being 79 parts of fermented juice, 5 parts of grape by parts by weight
Sodium saccharate, 0.5 poly-aspartate proportionally sequentially add in reaction kettle, temperature control at 50 DEG C, mixing time is 2 small
Up to whole dissolutions.(2) trace element chelated: by parts by weight be 4 parts of manganese sulfate, 5 parts of ferrous sulfate, 1 part of copper sulphate,
2.5 parts of boric acid, 1 part of ammonium molybdate, 2 parts of zinc sulfate sequentially add in reaction kettle among the above, and temperature is controlled at 70 DEG C, stir
Mixing the time is 3 hours, until solution all dissolves.(3) ultrafiltration sterilizes: uniformly mixed solution is crossed 150 mesh screens, filter residue conduct
Organic fertilizer production raw material, filtrate, which is placed in reaction kettle, controls 75 DEG C of temperature using pasteurization, is kept for 30 minutes, then will
It is uniformly mixed liquid to import storage tank 12 hours, the near room temperature of temperature, is the micro member of humic acid after taking supernatant detection qualified
Plain Water soluble fertilizer.
Embodiment 4
One, the preparation of fermented juice: choosing the fruit with the residual generaI investigation verification of conformity of agriculture, in the present invention fruit definition include but not
It is limited to the fruit such as apple, peach, pears, plum, apricot, Kiwi berry, orange, pineapple, filters out 5% qualified product fruit of decayed fruit rate <, decayed fruit
The fruit detection of rate >=5% is used as rejected product decayed fruit.Qualified product fruit is broken for the pulp of 3-6mm grade using crusher
Complex enzyme is added in fruit juice mixt, controls 50-70 DEG C of temperature, and mixing speed controls 20-30rad/min, digests 2 hours.By enzyme
Substance after solution controls 30-35 DEG C of temperature, revolving speed 50rad/min, adjusts pH 6-7, is added and carries out fermentation 24 beneficial to composite flora
After hour, and taking plate compression to pass through 0.25mm net is qualified product fermented juice.
Filter residue is mixed with unified collect of rejected product decayed fruit after pressure filter, can be used as because it contains beneficial to composite flora
Zymophyte in organic fertilizer fermentation.
Pulp enzyme, cellulase, hemicellulase, lignin peroxidase in complex enzyme, mass ratio 1:
The mass ratio of 0.5:0.3:0.1, complex enzyme and pulp and juice mixture is 2000:1；Trichoderma in the beneficial composite flora,
Muscardine, bacillus subtilis, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；Beneficial to compound
The mass ratio of flora and pulp and juice mixture is 1000:1.
Two, with the preparation of juice production humic acid water-soluble fertilizer: (1) being 84 parts of fermented juice, 2 parts of hydroxyl by parts by weight
Ethyl-3-acetic acid ethylenediamine, 0.5 chitin proportionally sequentially add in reaction kettle, temperature control is at 40 DEG C, mixing time
To be 1 hour to whole dissolutions.(2) trace element chelated: to be 3 parts of manganese sulfate, 4 parts of ferrous sulfate, 0.5 part by parts by weight
Copper sulphate, 3 parts of boric acid, 1 part of ammonium molybdate, 2 parts of zinc sulfate sequentially add in reaction kettle among the above, temperature control exists
65 DEG C, mixing time is 3 hours, until solution all dissolves.(3) ultrafiltration sterilizes: uniformly mixed solution is crossed into 150 mesh screens,
For filter residue as organic fertilizer production raw material, filtrate, which is placed in reaction kettle, controls 75 DEG C of temperature using pasteurization, is kept for 30 points
Clock then imports uniformly mixed liquid storage tank 12 hours, the near room temperature of temperature, is humic after taking supernatant detection qualified
Sour trace element water-soluble fertilizer.
In above-described embodiment, the preferred manganese sulfate monohydrate of manganese sulfate, the preferred ferrous sulfate heptahydrate of ferrous sulfate, copper sulphate are preferred
The preferred white vitriol of cupric sulfate pentahydrate, zinc sulfate.
Content of humic acid in Water soluble fertilizer is surveyed referring to the requirement of " NY 1106-2010 contains humic acid water-soluble fertilizer "
It is fixed；It is micro in requirement Water soluble fertilizer referring to " measurement of NY/T 1974-2010 water-soluble fertilizer copper, iron, manganese, zinc, boron, molybdenum content "
Constituent content is measured；Referring to " measurement of NY/T 197-2010 liquid fertilizer density " requirement to the density of Water soluble fertilizer into
Row measurement；PH of the requirement of reference " measurement of NY/T 1973-2010 water-soluble fertilizer water insoluble matter content and pH " to Water soluble fertilizer
It is measured.Embodiment 1 and liquid humic acid trace element water-soluble fertilizer index result in embodiment 2 are as described in Table 1.Wherein humic
Acid derives from fermented juice, humic acid >=30g/L in the fermented juice.In liquid humic acid trace element water-soluble fertilizer, humic
Acid >=30g/L, Zn >=2.3g/L, Mn >=7.8g/L, Fe >=8g/L, Cu >=1.2g/L, B >=4.3g/L, Mo >=3.9g/L.
The liquid humic acid trace element water-soluble fertilizer density is 1.1-1.8g/mL, preferably 1.25 g/mL
Table 1: the quality testing of liquid humic acid trace element water-soluble fertilizer
The field fertilizer efficiency of liquid humic acid trace element water-soluble fertilizer
1. being influenced on Quality and biomass of vegetables
The humic acid trace element water-soluble fertilizer that test is prepared using embodiment 1 and embodiment 2, with commercially available humic acid microelement water
Molten fertilizer (humic acid >=3%, Cu+Zn+B >=6.0%) foliar fertilizer is (big in cucumber (excellent 616 kind of saliva), tomato as control fertilizer
Red No.1 kind) with carry out manure trial on 3 main vegetables crops of eggplant (circle eggplant).Test is divided into 4 processing groups, every processing
3 repetitions, it is each to repeat 25m2: the humic acid of humic acid trace element water-soluble fertilizer group, the preparation of embodiment 2 prepared by embodiment 1
Trace element water-soluble fertilizer group, control liquid humic acid trace element water-soluble fertilizer group, clear water are blank control group: cucumber method of application
For foliage-spray, fertilizer amount is 50g/ mus, and mu water consumption is 50kg；Tomato is to apply with water punching with eggplant fertilization mode, fertilizer
Dosage is 5kg/ mus；Control fertilizer according to illustrate recommended dose apply；Other farming operations are identical.Test result is shown in Table 2.
Table 2: embodiment 1, embodiment 2 and compare fertilizer preparation humic acid trace element water-soluble fertilizer to cucumber, tomato, eggplant
Sub- manure trial result
2. pair fruits output and qualitative effects
The humic acid trace element water-soluble fertilizer that test is prepared using embodiment 3 and embodiment 4, with commercially available humic acid microelement water
Molten fertilizer (humic acid >=3%, Fe+Mn+Zn+B+Mo >=6.0%) foliar fertilizer is as control fertilizer, muskmelon (green rich special No. 5 kinds) examination
It tests place and is located at the Xiaxian County of Shanxi Province town the Pei Jie village Chen Qiao, apple (No. 3 kinds of cigarette richness) test is located at the Shanxi Province Linyi County town Niu Du
The village Yang Zhong.Test is divided into 4 processing groups, and 3 repetitions of every processing, muskmelon is each to repeat 25m2, 10 plants of the every repetition of apple trees: implement
3 groups of example, 3 groups of embodiment, control liquid humic acid trace element water-soluble fertilizer group, clear water are blank control group: muskmelon method of application
For foliage-spray, fertilizer amount is 50g/ mus, and mu water consumption is 50kg；Fertilization for apple mode is to apply with water punching, and fertilizer amount is
5kg/ mus；Control fertilizer according to illustrate recommended dose apply；Other farming operations are identical.Test result is shown in Table 3.
Table 3: embodiment 3, embodiment 4 and compare fertilizer preparation humic acid trace element water-soluble fertilizer to muskmelon and apple fertilizer
Imitate test result
By table 2 and 3 data of table, compared with the humic acid trace element water-soluble fertilizer of market routine, the control prepared in embodiment is fertile
The humic acid trace element water-soluble fertilizer of material preparation can make tomato production promoting 7.9-15.03%, Vc improve 0.64-0.96%；Cucumber production promoting
6.84-17.3%；Eggplant increases production 5.80-9.89%.Muskmelon pol improves 5.17-6.9%, apple under same kind and fertilizer application condition
Pol improves 6.41-9.29%.
Only presently preferred embodiments of the present invention is explained in detail above, but the present invention is not limited to above-described embodiment,
Within the knowledge of a person skilled in the art, it can also make without departing from the purpose of the present invention each
Kind variation, various change should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of with juice production humic acid water-soluble fertilizer, which is characterized in that be composed of the following raw materials by weight: fermented juice 70-
85 parts, 2-8 parts of metal-chelator, 0.1-0.6 parts of function additive, 3-5 parts of manganese sulfate, 4-6 parts of ferrous sulfate, copper sulphate 0.5-
1.5 parts, 2.5-3 parts of boric acid, 0.8-1.2 parts of ammonium molybdate, 1.5-2 parts of zinc sulfate.
2. according to claim 1 a kind of with juice production humic acid water-soluble fertilizer, it is characterised in that: the metal-chelator
It is a kind of in disodium ethylene diamine tetraacetate, diethylenetriamine pentacarboxylic acid salt, sodium gluconate and Oxyethylethylenediaminetriacetic acid
Or a variety of mixtures.
3. according to claim 1 a kind of with juice production humic acid water-soluble fertilizer, it is characterised in that: the function additive
For one or more mixtures in polyglutamic acid, poly-aspartate, chitin and sodium alginate.
4. a kind of preparation method with juice production humic acid water-soluble fertilizer, which comprises the following steps:
S1, fruit juice fermentation: the fruit of screening decayed fruit rate < 5% is broken for the pulp and juice mixture of 3-6mm grade with crusher,
Complex enzyme is added, controls 50-70 DEG C of temperature, mixing speed controls 20-30rad/min, digests 2 hours；By the substance after enzymatic hydrolysis
30-35 DEG C of temperature, revolving speed 50rad/min, adjusting pH of control is 6-7, is added after carrying out fermentation 24 hours beneficial to composite flora, and
Plate compression is taken to obtain filtrate as fermented juice by 0.25mm net；
S2, material dissolution: being 70-85 parts of fermented juice, 2-8 parts of metal-chelator, 0.1-0.6 parts of function by parts by weight
Additive sequentially adds in reaction kettle, stirring to whole dissolutions；
It is S3, trace element chelated: to be 3-5 parts of manganese sulfate, 4-6 parts of ferrous sulfate, 0.5-1.5 parts of sulfuric acid by parts by weight
Stirring to whole in S2 in reaction kettle is added in copper, 2.5-3 parts of boric acid, 0.8-1.2 parts of ammonium molybdate, 1.5-2 parts of zinc sulfate
Dissolution；
S4, ultrafiltration disinfection: by the solution being uniformly mixed in S2 by 150 mesh net filtrations, filtrate being placed in reaction kettle and is sterilized,
Uniformly mixed liquid is then imported into storage tank, is stored 12 hours, is humic acid microelement after taking supernatant detection qualified
Water soluble fertilizer.
5. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, which is characterized in that described
Fruit has the residual generaI investigation verification of conformity of agriculture.
6. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, it is characterised in that: described
Pulp enzyme, cellulase, hemicellulase, lignin peroxidase in complex enzyme, mass ratio 1:0.5:0.3:
0.1, the mass ratio of complex enzyme and pulp and juice mixture is 2000:1；It is Trichoderma in the beneficial composite flora, muscardine, withered
Careless bacillus, black-koji mould, aspergillus oryzae, mass ratio 1:0.2:1.5:0.3:0.1；Beneficial to composite flora and pulp
The mass ratio of fruit juice mixt is 1000:1.
7. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, it is characterised in that: described
Whipping temp is 40 DEG C -50 DEG C in S2, and mixing time is 1-2 hours.
8. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, it is characterised in that: described
Whipping temp is 60 DEG C -70 DEG C in S3, and mixing time is 2-4 hours.
9. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, which is characterized in that described
Concrete operations are sterilized in S3 are as follows: control 75 DEG C of temperature using pasteurization, keep 30min.
10. a kind of preparation method with juice production humic acid water-soluble fertilizer according to claim 4, it is characterised in that: institute
It states in S1 decayed fruit rate in fruit S3 >=5% detection and is used as underproof decayed fruit, will be filtered in filter residue after decayed fruit, filters pressing in S1 and S4
Filter residue is as organic fertilizer production raw material afterwards.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130702A (en) * | 2015-08-18 | 2015-12-09 | 宁夏共享生物化工有限公司 | Method used for preparing solid composite chelated water-soluble fertilizer containing humic acid from furfural residue |
| CN105541422A (en) * | 2015-12-22 | 2016-05-04 | 成都新柯力化工科技有限公司 | Humic fertilizer and preparation method thereof |
| CN106316693A (en) * | 2016-08-26 | 2017-01-11 | 山东农业大学 | Biological humic acid fertilizer and preparing method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130702A (en) * | 2015-08-18 | 2015-12-09 | 宁夏共享生物化工有限公司 | Method used for preparing solid composite chelated water-soluble fertilizer containing humic acid from furfural residue |
| CN105541422A (en) * | 2015-12-22 | 2016-05-04 | 成都新柯力化工科技有限公司 | Humic fertilizer and preparation method thereof |
| CN106316693A (en) * | 2016-08-26 | 2017-01-11 | 山东农业大学 | Biological humic acid fertilizer and preparing method thereof |
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