CN109321627A - A kind of preparation method of biological humic acid - Google Patents
A kind of preparation method of biological humic acid Download PDFInfo
- Publication number
- CN109321627A CN109321627A CN201811277207.8A CN201811277207A CN109321627A CN 109321627 A CN109321627 A CN 109321627A CN 201811277207 A CN201811277207 A CN 201811277207A CN 109321627 A CN109321627 A CN 109321627A
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- China
- Prior art keywords
- humic acid
- fermentation
- added
- preparation
- biological humic
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P39/00—Processes involving microorganisms of different genera in the same process, simultaneously
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/12—Animal feeding-stuffs obtained by microbiological or biochemical processes by fermentation of natural products, e.g. of vegetable material, animal waste material or biomass
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/16—Addition of microorganisms or extracts thereof, e.g. single-cell proteins, to feeding-stuff compositions
- A23K10/18—Addition of microorganisms or extracts thereof, e.g. single-cell proteins, to feeding-stuff compositions of live microorganisms
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
- A23K10/37—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material
- A23K10/38—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material from distillers' or brewers' waste
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K35/00—Medicinal preparations containing materials or reaction products thereof with undetermined constitution
- A61K35/02—Medicinal preparations containing materials or reaction products thereof with undetermined constitution from inanimate materials
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
- Y02P60/87—Re-use of by-products of food processing for fodder production
Abstract
The invention belongs to humic acid technical fields, specifically disclose a kind of preparation method of biological humic acid, when preparing biological humic acid, the waste pomace generated using the still residue and fruit process engineering that generate in generated waste yeast in fruit wine process, fruit distillate liquor production process is raw material, microbial fermentation strain is added, it ferments, the rear mixture using phthalic acid and ethyl alcohol help mentioning, and is remarkably improved the production efficiency of biological humic acid；Gained biological humic acid has been effectively retained the macro-nutrients such as the soluble sugar contained in still residue and pomace, protein and vitamin C, vitamin B, carrotene and other microelements, such as potassium element, calcium constituent, ferro element and Zn-ef ficiency microelement；The biological humic acid has preferable bioactivity, it is made to can be widely used for the fields such as agricultural, health care or chemical industry.
Description
Technical field
The invention belongs to humic acid technical fields, and in particular to a kind of preparation method of biological humic acid.
Background technique
In the process of the fruit downstream product such as fruit juice, fruit vinegar, fruit wine, a large amount of pomace, still residue can be generated,
The by-products such as a large amount of waste yeast mud can be generated in the fermented clear process of fruit wine, these by-products do not have special use,
Common processing method is discarding or compost or is used as feed, or as offal treatment, it is difficult to it is decomposed and removes by natural environment,
It can contaminated soil and environment.Still residue is usually raw material remaining waste residue or useless after fermentation and distillation in fruit wine production
Liquid, the substances such as amino acid abundant, organic acid, flavonoids, Polyphenols remain wherein substantially in fruit, full of nutrition, but
Often direct emission can be processed as waste liquid in processing, not only can serious polluted water resources and soil, also result in greatly
The wasting of resources.
Humic acid is animals and plants remains, mainly the remains of plant, by the decomposition and conversion of microorganism and the earth
A kind of organic substance that a series of processes of chemistry are caused and accumulated, is widely used in agriculture, woods, herds, petroleum, chemical industry, builds
The every field such as material, medical and health, environmental protection especially advocate ecological agriculture construction, pollution-less agriculture production, green food now
Product, pollution-free environmental protection etc., more make " humic acid " by high praise.Industrial production humic acid common at present is mainly with chemical synthesis
Based on, obtained humic acid liquid is by being dried to obtain humic acid powder product, and the time, long energy consumption was high, and gained humic acid biology
Activity is lower.
Summary of the invention
The present invention is with more than the distillation that generates in generated waste yeast in fruit wine process, fruit distillate liquor production process
The waste pomace that liquid and fruit process engineering generate is raw material, prepares a kind of biological humic acid, solves still residue, gives up
It abandons yeast paste and pomace is taken as the problem of environment and waste of resource are polluted in offal treatment, preparation gained biological humic acid activity
Higher, preparation process is simple, solves that existing industrial technology preparation gained humic acid bioactivity is low, and highly energy-consuming low efficiency is asked
Topic.
In order to achieve the above objectives, technical solution of the present invention is as follows:
A kind of preparation method of biological humic acid, it is characterised in that: comprise the steps of:
(1) yeast paste that generated still residue and wine fermentation generate after clarifying in fruit distillate liquor production process is collected,
Pomace is added, stirs evenly, obtains fermentation raw material；
(2) fermenting microbe is added in the fermentation raw material, ferments 10 ~ 15 days at 28 ~ 38 DEG C, obtains fermentation liquid；
(3) mixture of phthalic acid and ethyl alcohol is added in the fermentation liquid, controls broth temperature at 20 ~ 28 DEG C, even
After 0.5 ~ 0.8h of continuous stirring, after staticly settling 15 ~ 30min, it is separated by solid-liquid separation, obtains humic acid solution and fermentation residue；
(4) after using clear water rinsing step (3) described fermentation residue 2 ~ 3 times, dries pulverizing crosses 300 ~ 370 meshes, obtains yeast powder
Body；
(5) fermentation powder obtained by step (4) is added in humic acid solution obtained by step (3), then by gained liquid humic acid at
After changing 7 ~ 9h, refined biometric humic acid is obtained.
Preferably, the additional amount of yeast paste described in step (1) is added by the volume ratio of the still residue volume 3 ~ 5%
Enter.
Preferably, the additional amount of pomace described in step (1) is added in the ratio of the still residue volume ratio 35 ~ 50%
Enter.
Preferably, the additional amount of fermenting microbe described in step (2) is added in the ratio of fermentation raw material volume ratio 1 ~ 3%.
Preferably, fermenting microbe described in step (2) is geotrichum candidum, aspergillus niger, bacillus pumilus, Trichoderma viride, wine
Any two kinds in brewer yeast, bacillus subtilis and pseudomonad are compounded in the ratio mixing of 2:3.
Preferably, the additional amount of the mixture of phthalic acid described in step (3) and ethyl alcohol is the volume by fermentation liquid
Ratio than biology 0.5 ~ 0.8 ‰ is added.
Preferably, phthalic acid described in step (3) and ethyl alcohol are mixed in the ratio of 1:3, the concentration of the ethyl alcohol
It is 85%.
Pomace described in fermentation raw material of the present invention is Calophyllum Inophyllum L slag, apple pomace, grape fruit residue, granatum pomace or other fruit
Generated pomace in processing industry production process.
Gained refined biometric humic acid of the present invention in actual application can be as needed to the pH of humic acid
It is adjusted.
Refined biometric humic acid of the present invention can be used as clarifying agent, foliar fertilizer, drug and prepare raw material needed for drug, move
Object high protein feed can also be used as other purposes.
The invention has the advantages that:
(1) it when the present invention prepares biological humic acid, is produced after being clarified with the still residue, the wine fermentation that are generated in fruit distillation process
The pomace generated in raw yeast paste and fruit process industry is raw material, access geotrichum candidum, aspergillus niger, bacillus pumilus, green
Fermenting microbe made of any two kinds of strains mixing compounding in color trichoderma, saccharomyces cerevisiae, bacillus subtilis and pseudomonad,
It ferments, it can be effectively by macro-nutrients such as organic acid, flavonoids, Polyphenols, polysaccharide and amino acid in raw material
It is dissolved in fermentation liquid, so that the later period obtains humic acid and can have significant bioactivity；Phthalic acid and ethyl alcohol are used afterwards
Mixture help mentioning, be remarkably improved the production efficiency of biological humic acid；Gained biological humic acid has been effectively retained distillation
The macro-nutrients such as the soluble sugar, protein, amino acid and the Polyphenols that contain in extraction raffinate and pomace and flavonoids, are also wrapped
It is micro containing vitamin C, vitamin B, carrotene and other microelements, such as potassium element, calcium constituent, ferro element and Zn-ef ficiency
Element；The biological humic acid bioactivity with higher makes it can be widely used for the neck such as agricultural, health care or chemical industry
Domain；
(2) method that the present invention prepares biological humic acid, simple process, low power consuming is high-efficient, solves and produces in fruit process industry
The problem of raw pomace pollutes environment waste of resource by waste treatment；It is effectively utilized and generates in fruit distillate liquor production process
The yeast paste that generates after still residue and fruit wine clarifying treatment, solving these by-products, contaminated soil is asked again by serious waste
Topic；It is low to solve existing industrial technology preparation gained humic acid bioactivity simultaneously, the problem of highly energy-consuming low efficiency.
Specific embodiment
Below by specific embodiment, technical solution of the present invention is further illustrated.
Embodiment 1
A kind of preparation method of biological humic acid comprising the steps of:
(1) yeast paste that generated still residue and wine fermentation generate after clarifying in fruit distillate liquor production process is collected,
Pomace is added, stirs evenly, obtains fermentation raw material；
(2) in the fermentation raw material, fermenting microbe is added in 1% ratio of fermentation raw material volume ratio, ferments 15 at 28 DEG C
It, obtains fermentation liquid；The fermenting microbe is geotrichum candidum, aspergillus niger is mixed in the ratio of 2:3；
(3) the ratio addition phthalic acid of volume ratio biology 0.5 ‰ and mixing for ethyl alcohol in the fermentation liquid, in fermentation liquid
Object is closed, broth temperature is controlled at 20 DEG C, after continuously stirring 0.5h, after staticly settling 15min, is separated by solid-liquid separation, obtains humic
Acid solution and fermentation residue；The phthalic acid and ethyl alcohol are mixed in the ratio of 1:3, and the concentration of the ethyl alcohol is 85%；
(4) after using clear water rinsing step (3) described fermentation residue 2 times, dries pulverizing crosses 300 meshes, obtains fermentation powder；
(5) fermentation powder obtained by step (4) is added in humic acid solution obtained by step (3), then by gained liquid humic acid at
After changing 7h, refined biometric humic acid is obtained.
Embodiment 2
A kind of preparation method of biological humic acid comprising the steps of:
(1) yeast paste that generated still residue and wine fermentation generate after clarifying in fruit distillate liquor production process is collected,
Pomace is added, stirs evenly, obtains fermentation raw material；
(2) in the fermentation raw material, fermenting microbe is added in 3% ratio of fermentation raw material volume ratio, ferments 10 at 38 DEG C
It, obtains fermentation liquid；The fermenting microbe is that bacillus pumilus and pseudomonad are mixed in the ratio of 2:3；
(3) the ratio addition phthalic acid of volume ratio biology 0.8 ‰ and mixing for ethyl alcohol in the fermentation liquid, in fermentation liquid
Object is closed, broth temperature is controlled at 28 DEG C, after continuously stirring 0.8h, after staticly settling 30min, is separated by solid-liquid separation, obtains humic
Acid solution and fermentation residue；The phthalic acid and ethyl alcohol are mixed in the ratio of 1:3, and the concentration of the ethyl alcohol is 85%；
(4) after using clear water rinsing step (3) described fermentation residue 3 times, dries pulverizing crosses 370 meshes, obtains fermentation powder；
(5) fermentation powder obtained by step (4) is added in humic acid solution obtained by step (3), then by gained liquid humic acid at
After changing 9h, refined biometric humic acid is obtained.
Embodiment 3
A kind of preparation method of biological humic acid comprising the steps of:
(1) yeast paste that generated still residue and wine fermentation generate after clarifying in fruit distillate liquor production process is collected,
Pomace is added, stirs evenly, obtains fermentation raw material；
(2) in the fermentation raw material, fermenting microbe is added in 2% ratio of fermentation raw material volume ratio, ferments 13 at 35 DEG C
It, obtains fermentation liquid；The fermenting microbe is that saccharomyces cerevisiae and bacillus subtilis are mixed in 3: 2 ratio；
(3) the ratio addition phthalic acid of volume ratio biology 0.6 ‰ and mixing for ethyl alcohol in the fermentation liquid, in fermentation liquid
Object is closed, broth temperature is controlled at 25 DEG C, after continuously stirring 0.6h, after staticly settling 25min, is separated by solid-liquid separation, obtains humic
Acid solution and fermentation residue；The phthalic acid and ethyl alcohol are mixed in the ratio of 1:3, and the concentration of the ethyl alcohol is 85%
(4) after using clear water rinsing step (3) described fermentation residue 2 ~ 3 times, dries pulverizing crosses 340 meshes, obtains fermentation powder；
(5) fermentation powder obtained by step (4) is added in humic acid solution obtained by step (3), then by gained liquid humic acid at
After changing 8h, refined biometric humic acid is obtained.
Claims (7)
1. a kind of preparation method of biological humic acid, it is characterised in that: comprise the steps of:
(1) yeast paste that generated still residue and wine fermentation generate after clarifying in fruit distillate liquor production process is collected,
Pomace is added, stirs evenly, obtains fermentation raw material；
(2) fermenting microbe is added in the fermentation raw material, ferments 10 ~ 15 days at 28 ~ 38 DEG C, obtains fermentation liquid；
(3) mixture of phthalic acid and ethyl alcohol is added in the fermentation liquid, controls broth temperature at 20 ~ 28 DEG C, even
After 0.5 ~ 0.8h of continuous stirring, after staticly settling 15 ~ 30min, it is separated by solid-liquid separation, obtains humic acid solution and fermentation residue；
(4) after using clear water rinsing step (3) described fermentation residue 2 ~ 3 times, dries pulverizing crosses 300 ~ 370 meshes, obtains yeast powder
Body；
(5) fermentation powder obtained by step (4) is added in humic acid solution obtained by step (3), then by gained liquid humic acid at
After changing 7 ~ 9h, refined biometric humic acid is obtained.
2. the preparation method of biological humic acid according to claim 1, it is characterised in that: yeast paste described in step (1)
Additional amount is added by the volume ratio of the still residue volume 3 ~ 5%.
3. the preparation method of biological humic acid according to claim 2, it is characterised in that: pomace described in step (1) adds
Entering amount is added in the ratio of the still residue volume ratio 35 ~ 50%.
4. the preparation method of biological humic acid according to claim 2, it is characterised in that: fermenting microbe described in step (2)
Additional amount be in fermentation raw material volume ratio 1 ~ 3% ratio be added.
5. the preparation method of biological humic acid according to claim 2, it is characterised in that: fermenting microbe described in step (2)
For appointing in geotrichum candidum, aspergillus niger, bacillus pumilus, Trichoderma viride, saccharomyces cerevisiae, bacillus subtilis and pseudomonad
Two kinds of meaning are compounded in the ratio mixing of 2:3.
6. the preparation method of biological humic acid according to claim 4, it is characterised in that: O-phthalic described in step (3)
The additional amount of the mixture of acid and ethyl alcohol is added in the ratio of volume ratio biology 0.5 ~ 0.8 ‰ of fermentation liquid.
7. the preparation method of biological humic acid according to claim 5, it is characterised in that: O-phthalic described in step (3)
Acid and ethyl alcohol are mixed in the ratio of 1:3, and the concentration of the ethyl alcohol is 85%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811277207.8A CN109321627A (en) | 2018-10-30 | 2018-10-30 | A kind of preparation method of biological humic acid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811277207.8A CN109321627A (en) | 2018-10-30 | 2018-10-30 | A kind of preparation method of biological humic acid |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128214A (en) * | 2019-06-19 | 2019-08-16 | 乐斯福(明光)有限公司 | A method of it is produced using yeast thick slurry waste liquid containing humic acid water-soluble fertilizer |
| CN110128213A (en) * | 2019-06-19 | 2019-08-16 | 乐斯福(明光)有限公司 | A method of liquid fertilizer is produced using beer waste yeast |
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2018
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128214A (en) * | 2019-06-19 | 2019-08-16 | 乐斯福(明光)有限公司 | A method of it is produced using yeast thick slurry waste liquid containing humic acid water-soluble fertilizer |
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Application publication date: 20190212 |