CN109321129A - A kind of silicone resin frost flower paint film and preparation method thereof - Google Patents

A kind of silicone resin frost flower paint film and preparation method thereof Download PDF

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Publication number
CN109321129A
CN109321129A CN201810969349.4A CN201810969349A CN109321129A CN 109321129 A CN109321129 A CN 109321129A CN 201810969349 A CN201810969349 A CN 201810969349A CN 109321129 A CN109321129 A CN 109321129A
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CN
China
Prior art keywords
parts
preparation
paint film
paint
frost flower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810969349.4A
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Chinese (zh)
Inventor
卢世仑
沈大伟
金振斗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinhua Darong Coatings Co Ltd
Original Assignee
Jinhua Darong Coatings Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinhua Darong Coatings Co Ltd filed Critical Jinhua Darong Coatings Co Ltd
Priority to CN201810969349.4A priority Critical patent/CN109321129A/en
Publication of CN109321129A publication Critical patent/CN109321129A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers

Abstract

The invention discloses a kind of silicone resin frost flower paint films and preparation method thereof, frost flower paint film includes priming paint and finishing coat, specific preparation method the following steps are included: (1) priming paint preparation: the various raw materials for including by priming paint are by dispersion stirring, grinding, it is uniformly mixed, forms primer base;(2) preparation of finishing coat: the various raw materials for including by finishing coat are ground by dispersion stirring, are uniformly mixed, and topcoat paint is formed;(3) preparation of frost flower paint film: primer base is sprayed on required workpiece, 10min is dried at a temperature of 150 DEG C, after being cooled to room temperature, again by topcoat paint even application on primer base surface, continuation dries 10min at a temperature of 150 DEG C, solidify 10min at a temperature of being then placed within 280 DEG C, be cooled to room temperature, that is, forms frost flower paint film.Silicone resin frost flower paint film of the invention, containing the colored varnish that can be sprayed one of various pigments with cross-linking reaction in paint, is made molding paint film have clearly ice flower pattern, enhances the aesthetics of paint film because its unsaturated-resin ingredient is more.

Description

A kind of silicone resin frost flower paint film and preparation method thereof
Technical field
The present invention relates to paint field, in particular to a kind of silicone resin frost flower paint film and preparation method thereof.
Background technique
Silicon resin coating is one of most widely used non-viscous paint on cooker, electric elements, plays the role of decoration. But with constantly bringing forth new ideas for technology, the demand of client is no longer satisfied now, color diversification only, in fierce market Do not have advantage that can say in competition yet.For above-mentioned status, under the premise of color is diversified, changes its appearance, silicon can be made Coating industry is more flourishing, can also improve the market competitiveness of coatings enterprises.
Summary of the invention
That the technical problem to be solved in the present invention is to provide a kind of metal adhesions is good, hardness is high, scratch resistance is good, application property Adaptable, aesthetic conceptions enhancing, the easy-operating silicone resin frost flower paint film of simple process and preparation method thereof.
In order to solve the above-mentioned technical problem, the invention is realized by the following technical scheme:
A kind of silicone resin frost flower paint film and preparation method thereof, the frost flower paint film include priming paint and finishing coat, the priming paint Raw material and its parts by weight are as follows:
The raw material and its parts by weight of the finishing coat are as follows:
60-85 parts of acrylic resin
14-38 parts of organic solvent
0.3-2 parts of auxiliary agent
Specific preparation method the following steps are included:
(1) preparation of priming paint: the various raw materials for including by priming paint are ground by dispersion stirring, are uniformly mixed, and priming paint is formed Coating;
(2) preparation of finishing coat: the various raw materials for including by finishing coat are ground by dispersion stirring, are uniformly mixed, and finishing coat is formed Coating;
(3) preparation of frost flower paint film: primer base is sprayed on required workpiece, dries 10min at a temperature of 150 DEG C, cold But to after room temperature, then by topcoat paint even application on primer base surface, continuation dries 10min at a temperature of 150 DEG C, then Solidify 10min at a temperature of being placed on 280 DEG C, be cooled to room temperature, that is, forms frost flower paint film.
Preferably, the raw material and its parts by weight of priming paint described above are as follows: 57 parts of modified organic silicone resin, reinforced resin 2 Part, 7 parts of high temperature resistant organic pigment, 30 parts of organic solvent, 2 parts of auxiliary agent, 2 parts of filler material;The raw material and its parts by weight of the finishing coat Are as follows: 75 parts of acrylic resin, 24 parts of organic solvent, 1 part of auxiliary agent.
Preferably, acrylic resin described above is methacrylic resin or ethyl propylene acid resin.
Preferably, organic solvent described above is butyl acetate or dimethylbenzene or dibasic acid ester or propylene glycol monomethyl ether acetic acid One or both of ester and combination of the above.
Preferably, auxiliary agent described above is that levelling agent or dispersing agent or defoaming agent or surface active agent or adhesive force promote One or both of agent and combination of the above.
The beneficial effects of the present invention are: silicone resin frost flower paint film of the invention, preparation process is simple to operation, passes through priming paint With the collective effect of finishing coat, keep frost flower hardness of paint film high, scratch resistance is good, and metal adhesion is strong, because acrylic resin is unsaturation Resin makes to make molding paint film have clearly ice containing the colored varnish that can spray one of various pigments with cross-linking reaction in paint Flower decorative pattern, enhances the aesthetic effect of paint film.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A kind of silicone resin frost flower paint film and preparation method thereof, frost flower paint film include priming paint and finishing coat, the raw material of priming paint and its Parts by weight are as follows: 57 parts of modified organic silicone resin, 2 parts of epoxy resin, 7 parts of high temperature resistant organic pigment, 30 parts of organic solvent, levelling agent 1 part, 1 part of dispersing agent, 2 parts of filler material;The raw material and its parts by weight of finishing coat are as follows: 75 parts of acrylic resin, 24 parts of organic solvent, attached 0.7 part of adhesion promoter, 0.3 part of levelling agent, specific preparation method the following steps are included:
(1) preparation of priming paint: the various raw materials for including by priming paint are ground by dispersion stirring, are uniformly mixed, and priming paint is formed Coating;
(2) preparation of finishing coat: the various raw materials for including by finishing coat are ground by dispersion stirring, are uniformly mixed, and finishing coat is formed Coating;
(3) preparation of frost flower paint film: primer base is sprayed on required workpiece, dries 10min at a temperature of 150 DEG C, cold But to after room temperature, then by topcoat paint even application on primer base surface, continuation dries 10min at a temperature of 150 DEG C, then Solidify 10min at a temperature of being placed on 280 DEG C, be cooled to room temperature, that is, forms frost flower paint film.
Embodiment 2
With the manufacturing step of embodiment 1, wherein 51 parts of modified organic silicone resin, 5 parts of epoxy resin, high temperature resistant organic pigment 3 parts, 35 parts of organic solvent, 1 part of defoaming agent, 5 parts of filler material;The raw material and its parts by weight of finishing coat are as follows: 60 parts of acrylic resin, have 38 parts of solvent, 0.7 part of surface active agent, 0.3 part of levelling agent.
Embodiment 3
With the manufacturing step of embodiment 1, wherein 50 parts of modified organic silicone resin, 5 parts of epoxy resin, high temperature resistant organic pigment 4 parts, 35 parts of organic solvent, 0.3 part of levelling agent, 0.7 part of dispersing agent, 5 parts of filler material;The raw material and its parts by weight of finishing coat are as follows: third 70 parts of olefin(e) acid resin, 29.7 parts of organic solvent, 0.3 part of levelling agent.
Embodiment 4
With the manufacturing step of embodiment 1, wherein 70 parts of modified organic silicone resin, 1 part of epoxy resin, high temperature resistant organic pigment 10 parts, 15 parts of organic solvent, 1.5 parts of levelling agent, 1.5 parts of dispersing agent, 1 part of filler material;The raw material and its parts by weight of finishing coat are as follows: third 85 parts of olefin(e) acid resin, 14 parts of organic solvent, 0.3 part of levelling agent, 0.7 part of defoaming agent.
Preferably, in above-described embodiment 1-4, acrylic resin is methacrylic resin or ethyl propylene acid resin, It can choose the AA-9003A (liquid, solid part 35%) or Mitsubishi BR113 (solid) or Degussa P24N of green field chemical industry (solid).
Preferably, organic solvent is butyl acetate or dimethylbenzene or dibasic acid ester or propylene glycol in above-described embodiment 1-4 One or both of methyl ether acetate and combination of the above.
Preferably, auxiliary agent is levelling agent or dispersing agent or defoaming agent or surface active agent or attached in above-described embodiment 1-4 One or both of adhesion promoter and combination of the above.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more Kind change, modification, replacement and modification, still fall in protection scope of the present invention.

Claims (5)

1. a kind of silicone resin frost flower paint film and preparation method thereof, it is characterised in that: the frost flower paint film includes priming paint and finishing coat, institute State the raw material and its parts by weight of priming paint are as follows:
The raw material and its parts by weight of the finishing coat are as follows:
60-85 parts of acrylic resin
14-38 parts of organic solvent
0.3-2 parts of auxiliary agent
Specific preparation method the following steps are included:
(1) preparation of priming paint: the various raw materials for including by priming paint are ground by dispersion stirring, are uniformly mixed, and are formed priming paint and are applied Material;
(2) preparation of finishing coat: the various raw materials for including by finishing coat are ground by dispersion stirring, are uniformly mixed, and are formed finishing coat and are applied Material;
(3) preparation of frost flower paint film: primer base is sprayed on required workpiece, is dried 10min at a temperature of 150 DEG C, is cooled to After room temperature, then by topcoat paint even application on primer base surface, continuation dries 10min at a temperature of 150 DEG C, then places Solidify 10min at a temperature of 280 DEG C, be cooled to room temperature, that is, forms frost flower paint film.
2. a kind of silicone resin frost flower paint film according to claim 1 and preparation method thereof, it is characterised in that: the priming paint Raw material and its parts by weight are as follows: 57 parts of modified organic silicone resin, 2 parts of reinforced resin, 7 parts of high temperature resistant organic pigment, organic solvent 30 Part, 2 parts of auxiliary agent, 2 parts of filler material;The raw material and its parts by weight of the finishing coat are as follows: 75 parts of acrylic resin, 24 parts of organic solvent, 1 part of auxiliary agent.
3. a kind of silicone resin frost flower paint film according to claim 1 and preparation method thereof, it is characterised in that: the acrylic acid Resin is methacrylic resin or ethyl propylene acid resin.
4. a kind of silicone resin frost flower paint film according to claim 1 and preparation method thereof, it is characterised in that: described organic molten Agent is butyl acetate or dimethylbenzene or one or both of dibasic acid ester or propylene glycol methyl ether acetate and combination of the above.
5. a kind of silicone resin frost flower paint film according to claim 1 and preparation method thereof, it is characterised in that: the auxiliary agent is Levelling agent or dispersing agent or defoaming agent or one or both of surface active agent or adhesion promoter and combination of the above.
CN201810969349.4A 2018-08-23 2018-08-23 A kind of silicone resin frost flower paint film and preparation method thereof Pending CN109321129A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810969349.4A CN109321129A (en) 2018-08-23 2018-08-23 A kind of silicone resin frost flower paint film and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810969349.4A CN109321129A (en) 2018-08-23 2018-08-23 A kind of silicone resin frost flower paint film and preparation method thereof

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CN109321129A true CN109321129A (en) 2019-02-12

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110338634A (en) * 2019-07-17 2019-10-18 应黎达 A kind of non-stick pan and its processing technology with stereoscopic effect
CN111645371A (en) * 2020-06-12 2020-09-11 安徽名士达新材料有限公司 High-wear-resistance water-based paint film and preparation method thereof
CN113185916A (en) * 2021-06-08 2021-07-30 浙江宝晟铁路新材料科技有限公司 Anti-corrosion composite coating for steel rail fastener elastic strip and bolt spike, and preparation method and coating method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876181A (en) * 2011-07-13 2013-01-16 上海大通高科技材料有限责任公司 Ultrathin metal plate heat-insulation reflection coating and its preparation method
CN106893385A (en) * 2015-12-17 2017-06-27 天津瑀作科技有限公司 A kind of heat resistance paint
CN106947355A (en) * 2017-02-24 2017-07-14 宁波柯乐芙家居科技股份有限公司 Environmentally friendly baking vanish door-plate and its manufacturing process with sterilizing function
CN107523217A (en) * 2016-06-21 2017-12-29 天津市统业家俱工贸有限公司 A kind of heat resistance paint formula

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876181A (en) * 2011-07-13 2013-01-16 上海大通高科技材料有限责任公司 Ultrathin metal plate heat-insulation reflection coating and its preparation method
CN106893385A (en) * 2015-12-17 2017-06-27 天津瑀作科技有限公司 A kind of heat resistance paint
CN107523217A (en) * 2016-06-21 2017-12-29 天津市统业家俱工贸有限公司 A kind of heat resistance paint formula
CN106947355A (en) * 2017-02-24 2017-07-14 宁波柯乐芙家居科技股份有限公司 Environmentally friendly baking vanish door-plate and its manufacturing process with sterilizing function

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110338634A (en) * 2019-07-17 2019-10-18 应黎达 A kind of non-stick pan and its processing technology with stereoscopic effect
CN111645371A (en) * 2020-06-12 2020-09-11 安徽名士达新材料有限公司 High-wear-resistance water-based paint film and preparation method thereof
CN113185916A (en) * 2021-06-08 2021-07-30 浙江宝晟铁路新材料科技有限公司 Anti-corrosion composite coating for steel rail fastener elastic strip and bolt spike, and preparation method and coating method thereof

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Application publication date: 20190212