CN103213416B - Gold stamping method for improving mirror surface effect, ultraviolet (UV) intermediate coat and UV finishing coat - Google Patents

Gold stamping method for improving mirror surface effect, ultraviolet (UV) intermediate coat and UV finishing coat Download PDF

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Publication number
CN103213416B
CN103213416B CN201310133618.0A CN201310133618A CN103213416B CN 103213416 B CN103213416 B CN 103213416B CN 201310133618 A CN201310133618 A CN 201310133618A CN 103213416 B CN103213416 B CN 103213416B
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paint
ester
gold stamping
methylpropanol
ipdi
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CN103213416A (en
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廖肇敏
钟传森
陈武
胡建丁
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Dongguan Chitwing Technology Co Ltd
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Dongguan Chitwing Technology Co Ltd
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Abstract

The invention discloses a gold stamping method for improving a mirror surface effect, an ultraviolet (UV) intermediate coat and a UV finishing coat, wherein the gold stamping method comprises the following steps: applying a base coat on a base material surface; spraying the UV intermediate coat on a base coat surface, and semi-solidifying to form a film; gold stamping in the UV intermediate coat; and spraying the UV finishing coat on the base material surface, and completely solidifying to obtain the film. According to the gold stamping method provided by the invention, a UV intermediate coat spraying step is added before a gold stamping process, so that a gold stamping joining layer is smooth, the glossiness of a gold stamping logo is greatly increased, and a mirror effect of the gold stamping logo is better.

Description

For improving paint and UV finish paint in the bronzing method of mirror effect and UV
Technical field
The present invention relates to technical field of surface, particularly relating to a kind of bronzing method for improving mirror effect and for paint and UV finish paint in the UV in this bronzing method.
Background technology
In recent years, along with people are to the raising of electronic product overall styling and quality requirement, printing technology and post-press finishing technology achieve vigorous growth especially, and electrochemical aluminium thermoprinting is as a part for printing technology, and this change in several years is huge especially.The continuous appearance that new technology, new technology and multiple technologies are combined, makes printed matter in glossiness, metal sense, all achieve good effect after thermoprint, makes product seem high-grade exquisite.But, adopt the product that existing gilding technology obtains, though its gold stamping logo has stronger metal sense, because the flatness of logo is not high, therefore its gloss and mirror effect poor.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, the object of the present invention is to provide paint and UV finish paint in a kind of bronzing method for improving mirror effect and UV, the flatness being intended to solve the logo that existing surface gilding technique obtains is not high, gloss and the poor problem of mirror effect.
Technical scheme of the present invention is as follows:
For improving a bronzing method for mirror effect, wherein, comprise the following steps:
At PC, PC+ABS, ABS, PC+GF or PMMA substrate surface priming;
Paint in primed surface spraying UV, semi-solid preparation film forming, paints in described UV according to weight percent meter, comprises following component: modified polyester acrylate ester 43.8-53.6%; Acrylic monomers 10-14%; Benzoin dimethylether 2-6%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.1-0.5%; Ethyl ester 6-10%; 2-methylpropanol 10-14%; Butyl ester 5-9%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 2-6%;
In UV, coating surface carries out gold stamping;
At substrate surface spraying UV finish paint, complete film-forming.
The described bronzing method for improving mirror effect, wherein, described UV finish paint, according to weight percent meter, comprises following component:
Modified polyester acrylate ester 40-50%; Acrylic monomers 8-14%; Benzoin dimethylether 1-2%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.05-0.15%; Ethyl ester 8-12%; 2-methylpropanol 12-16%; Butyl ester 10-14%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 0-4%.
The described bronzing method for improving mirror effect, wherein, in described UV, paint is first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 500-700mj/cm 2lower irradiation is solidified; Described UV finish paint first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 1000-1200mj/cm 2lower irradiation is solidified.
The described bronzing method for improving mirror effect, wherein, paints in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.
The described bronzing method for improving mirror effect, wherein, described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.
A kind of for painting in the UV in bronzing method as above, wherein, paint in described UV and be sprayed at substrate surface before carrying out gold stamping operation; Paint in described UV according to weight percent meter, comprise following component:
Modified polyester acrylate ester 43.8-53.6%; Acrylic monomers 10-14%; Benzoin dimethylether 2-6%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.1-0.5%; Ethyl ester 6-10%; 2-methylpropanol 10-14%; Butyl ester 5-9%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 2-6%.
Paint in described UV, wherein, paint in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.
For the UV finish paint in bronzing method as above, wherein, paint in described UV finish paint and UV as above and support the use, described UV finish paint is sprayed at substrate surface after completing gold stamping operation; Described UV finish paint, according to weight percent meter, comprises following component:
Modified polyester acrylate ester 40-50%; Acrylic monomers 8-14%; Benzoin dimethylether 1-2%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.05-0.15%; Ethyl ester 8-12%; 2-methylpropanol 12-16%; Butyl ester 10-14%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 0-4%.
Described UV finish paint, wherein, described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.
Beneficial effect: the bronzing method for improving mirror effect provided by the present invention, by adding the step painted in spraying UV before gold stamping operation, make thermoprint accept the flat smooth of layer change, greatly strengthen the glossiness of gold stamping logo and make gold stamping rear logo effect mirror effect better.
Detailed description of the invention
The invention provides paint and UV finish paint in a kind of bronzing method for improving mirror effect and UV, for making object of the present invention, technical scheme and effect clearly, clearly, the present invention is described in more detail below.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Traditional gilding technology comprises priming, gold stamping, upper finish paint, and provided by the present invention newly for improving in the bronzing method of mirror effect, for strengthening glossiness and the mirror effect of gold stamping logo, before gold stamping operation, add the step painted in spraying UV, make thermoprint accept the flat smooth of layer change.
Particularly, the bronzing method for improving mirror effect provided by the present invention comprises the following steps:
Priming paint on substrate surface;
Paint in primed surface spraying UV, semi-solid preparation film forming;
In UV, coating surface carries out gold stamping;
At substrate surface spraying UV finish paint, complete film-forming.
Wherein, provided by the present invention is the conventional primer of usual spray for improving the priming paint adopted in the bronzing method of mirror effect, and technological parameter and traditional gilding technology do not have difference.The effect of painting in the UV adopted is for follow-up gold stamping operation provides smooth face of undertaking the printing of, and makes gold stamping rear logo effect mirror effect better.
Wherein, paint in described UV according to weight percent meter, comprise following component:
Modified polyester acrylate ester 43.8-53.6%; Acrylic monomers 10-14%; Benzoin dimethylether 2-6%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.1-0.5%; Ethyl ester 6-10%; 2-methylpropanol 10-14%; Butyl ester 5-9%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 2-6%.
Paint in described UV at UV energy 500-700mj/cm 2second film-forming of condition.Particularly, in described UV, paint is first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 500-700mj/cm 2lower irradiation is solidified.
Also provide preferred technical scheme in the present invention, paint in described UV according to weight percent meter, composed of the following components:
Modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.
Paint in described UV finish paint and described UV and support the use, UV finish paint provided by the present invention can with described UV in paint and adhere to, common UV finish paint can not be sprayed on UV lacquer painting.Described UV finish paint, according to weight percent meter, comprises following component:
Modified polyester acrylate ester 40-50%; Acrylic monomers 8-14%; Benzoin dimethylether 1-2%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.05-0.15%; Ethyl ester 8-12%; 2-methylpropanol 12-16%; Butyl ester 10-14%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 0-4%.
Described UV finish paint is at UV energy 1000-1200mj/cm 2under condition, complete film-forming, meets the requirement of outward appearance and aspect of performance.Particularly, described UV finish paint first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 1000-1200mj/cm 2lower irradiation is solidified.
Also provide preferred technical scheme in the present invention, described UV finish paint is according to weight percent meter, composed of the following components:
Modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.
Surface gilding method provided by the present invention is applicable to carry out gold stamping at substrate surfaces such as PC (Merlon), PC (Merlon)+ABS (polyacrylonitrile), ABS (polyacrylonitrile), PC (Merlon)+GF (glass), PMMA (polymethyl methacrylate).The gold stamping logo outward appearance aspect flatness adopting the present invention to obtain for the bronzing method improving mirror effect is better, and clear-cut, has more aesthetic feeling, can meet the test request of electronic product.
Further illustrate surface gilding method of the present invention with example below, described example should not be construed as limiting the invention.
Embodiment 1
At PC substrate surface priming; Paint in PC substrate surface spraying UV, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 500-700mj/cm 2lower irradiation semi-solid preparation film forming; Carry out gold stamping at PC substrate surface; At PC substrate surface spraying UV finish paint, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 1000-1200mj/cm 2the complete film-forming of lower irradiation.Paint in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 43.8%; Acrylic monomers 14%; Benzoin dimethylether 2%; IPDI 0.5%; Dibutyl tin laurate 0.1%; Ethyl ester 6%; 2-methylpropanol 14%; Butyl ester 9%; Polyether-modified dimethyl silicone polymer 4.6%; Flatting silica 6%.Described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 50%; Acrylic monomers 8.35%; Benzoin dimethylether 1%; IPDI 1.5%; Dibutyl tin laurate 0.15%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 14%; Polyether-modified dimethyl silicone polymer 5%.In the present embodiment, the gold stamping logo outward appearance aspect flatness on PC substrate surface is good, glossiness and mirror effect good, clear-cut.
Embodiment 2
At PC+ABS substrate surface priming; Paint in PC+ABS substrate surface spraying UV, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 500-700mj/cm 2lower irradiation semi-solid preparation film forming; Carry out gold stamping at PC+ABS substrate surface; At PC+ABS substrate surface spraying UV finish paint, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 1000-1200mj/cm 2the complete film-forming of lower irradiation.Paint in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 53.6%; Acrylic monomers 10%; Benzoin dimethylether 6%; IPDI 1.5%; Dibutyl tin laurate 0.5%; Ethyl ester 10%; 2-methylpropanol 10%; Butyl ester 5%; Polyether-modified dimethyl silicone polymer 1.4%; Flatting silica 2%.Described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 40.4%; Acrylic monomers 14%; Benzoin dimethylether 2%; IPDI 0.55%; Dibutyl tin laurate 0.05%; Ethyl ester 12%; 2-methylpropanol 16%; Butyl ester 10%; Polyether-modified dimethyl silicone polymer 1%; Flatting silica 4%.In the present embodiment, the gold stamping logo outward appearance aspect flatness on PC+ABS substrate surface is good, glossiness and mirror effect good, clear-cut.
Embodiment 3
At PMMA substrate surface priming; Paint in PMMA substrate surface spraying UV, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 500-700mj/cm 2lower irradiation semi-solid preparation film forming; Carry out gold stamping at PMMA substrate surface; At PMMA substrate surface spraying UV finish paint, in temperature 60 ± 5 DEG C baking after 4-6 minute, then use UV lamp at UV energy 1000-1200mj/cm 2the complete film-forming of lower irradiation.Paint in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.Described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.In the present embodiment, the gold stamping logo outward appearance aspect flatness on PMMA substrate surface is best, glossiness and mirror effect best, clear-cut.
Should be understood that, application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.

Claims (9)

1. for improving a bronzing method for mirror effect, it is characterized in that, comprising the following steps:
At PC, PC+ABS, ABS, PC+GF or PMMA substrate surface priming;
Paint in primed surface spraying UV, semi-solid preparation film forming, paints in described UV according to weight percent meter, comprises following component: modified polyester acrylate ester 43.8-53.6%; Acrylic monomers 10-14%; Benzoin dimethylether 2-6%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.1-0.5%; Ethyl ester 6-10%; 2-methylpropanol 10-14%; Butyl ester 5-9%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 2-6%;
In UV, coating surface carries out gold stamping;
At substrate surface spraying UV finish paint, complete film-forming.
2. the bronzing method for improving mirror effect according to claim 1, is characterized in that, described UV finish paint, according to weight percent meter, comprises following component:
Modified polyester acrylate ester 40-50%; Acrylic monomers 8-14%; Benzoin dimethylether 1-2%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.05-0.15%; Ethyl ester 8-12%; 2-methylpropanol 12-16%; Butyl ester 10-14%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 0-4%.
3. the bronzing method for improving mirror effect according to claim 1, is characterized in that, in described UV, paint is first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 500-700mj/cm 2lower irradiation is solidified; Described UV finish paint first after temperature 60 ± 5 DEG C toasts 4-6 minute, then uses UV lamp at UV energy 1000-1200mj/cm 2lower irradiation is solidified.
4. the bronzing method for improving mirror effect according to claim 1, is characterized in that, paints according to weight percent meter in described UV, composed of the following components: modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.
5. the bronzing method for improving mirror effect according to claim 1, is characterized in that, described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.
6. one kind for painting in the UV in bronzing method as claimed in claim 1, it is characterized in that, paint and be sprayed at substrate surface in described UV before carrying out gold stamping operation; Paint in described UV according to weight percent meter, comprise following component:
Modified polyester acrylate ester 43.8-53.6%; Acrylic monomers 10-14%; Benzoin dimethylether 2-6%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.1-0.5%; Ethyl ester 6-10%; 2-methylpropanol 10-14%; Butyl ester 5-9%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 2-6%.
7. paint in UV according to claim 6, it is characterized in that, paint in described UV according to weight percent meter, composed of the following components: modified polyester acrylate ester 48.7%; Acrylic monomers 12%; Benzoin dimethylether 4%; IPDI 1%; Dibutyl tin laurate 0.3%; Ethyl ester 8%; 2-methylpropanol 12%; Butyl ester 7%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 4%.
8. the UV finish paint in bronzing method as claimed in claim 1, is characterized in that, paint in described UV finish paint and UV as claimed in claim 4 and support the use, described UV finish paint is sprayed at substrate surface after completing gold stamping operation; Described UV finish paint, according to weight percent meter, comprises following component:
Modified polyester acrylate ester 40-50%; Acrylic monomers 8-14%; Benzoin dimethylether 1-2%; IPDI 0.5-1.5%; Dibutyl tin laurate 0.05-0.15%; Ethyl ester 8-12%; 2-methylpropanol 12-16%; Butyl ester 10-14%; Polyether-modified dimethyl silicone polymer 1-5%; Flatting silica 0-4%.
9. UV finish paint according to claim 8, is characterized in that, described UV finish paint is according to weight percent meter, composed of the following components: modified polyester acrylate ester 45%; Acrylic monomers 11.4%; Benzoin dimethylether 1.5%; IPDI 1%; Dibutyl tin laurate 0.1%; Ethyl ester 10%; 2-methylpropanol 14%; Butyl ester 12%; Polyether-modified dimethyl silicone polymer 3%; Flatting silica 2%.
CN201310133618.0A 2013-04-17 2013-04-17 Gold stamping method for improving mirror surface effect, ultraviolet (UV) intermediate coat and UV finishing coat Active CN103213416B (en)

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CN104626778B (en) * 2015-03-16 2017-03-29 苏州印刷总厂有限公司 A kind of process for realizing leaflet local surfaces high metal luster effect
CN112140760A (en) * 2020-08-18 2020-12-29 泸州启航科技有限公司 Silk sleeve ironing production method
CN114347683A (en) * 2022-01-07 2022-04-15 东莞市广正模具塑胶有限公司 Gold stamping process for mobile phone battery cover plate

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