CN108034337A - A kind of transparent powder paint - Google Patents

A kind of transparent powder paint Download PDF

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Publication number
CN108034337A
CN108034337A CN201711251661.1A CN201711251661A CN108034337A CN 108034337 A CN108034337 A CN 108034337A CN 201711251661 A CN201711251661 A CN 201711251661A CN 108034337 A CN108034337 A CN 108034337A
Authority
CN
China
Prior art keywords
transparent powder
powder paint
agent
good
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711251661.1A
Other languages
Chinese (zh)
Inventor
王雯琪
李论
张光红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Xinda Macromolecule Material Co Ltd
Original Assignee
Chengdu Xinda Macromolecule Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Xinda Macromolecule Material Co Ltd filed Critical Chengdu Xinda Macromolecule Material Co Ltd
Priority to CN201711251661.1A priority Critical patent/CN108034337A/en
Publication of CN108034337A publication Critical patent/CN108034337A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/20Carboxylic acid amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • C08K5/34924Triazines containing cyanurate groups; Tautomers thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of transparent powder paint, the transparent powder powdery paints includes:75 95 parts of polyester resin, 0.9 10 parts of curing agent, 0.2~2 part of levelling agent, 0.2~1.5 part of wetting agent, 0.2~1 part of defoamer, 0~1 part of stearic acid, 0.001~3 part of dyestuff, 0~7 part of delustering agent.The transparent powder paint of the present invention has the advantages that high glaze, high rigidity, the transparency is good, resistance to chemical corrosion is good, anti-yellowing property is good, good decorative property, is that one kind is widely used in various metal works Lacquer finish transparent powder paints.

Description

A kind of transparent powder paint
Technical field
The present invention relates to paint field, and in particular to a kind of transparent powder paint.
Background technology
Powdery paints be it is a kind of prolong born Novel environment-friendlymaterial material based on petrochemical materials, mainly by low molecule Resin, auxiliary agent, filler etc. are measured, prepared under certain conditions, spray, toasted and formed with certain appearance, gloss, face Color, and play the film of anti-corrosion and decoration function in object surface.Powdery paints in actual application, such as outdoor gate, Balcony guardrail etc..After a period of time, film will occur to change to a certain degree, such as gloss decline, colour-darkening or cool white, painting There is rust spot, crackle etc. in layer surface.
Powdery paints practitioner is in lifting powdery paints weatherability at present, mainly using following several method:1st, select Suitable polyester resin is selected, fully list is synthesized from weatherability angle, design molecular structure, selection in the building-up process of polyester Body.2nd, it is modified using different resin alloys, such as Organic fluoride, the cold spelling blending and modifying of organosilicon.3rd, inorganic filler selects, such as organic The technological means such as the titanium dioxide of silicon coating lift coating weatherability.4th, auxiliary agent is added, UV absorbents is such as added and absorbs 295-350nm The ultraviolet light of wave band.But these current means are concentrated mainly on the single film in surface.Meanwhile add auxiliary agent or cold spelling There is certain limitation etc. means, be exposed to the sun in Florida experimentally, migration can be produced, final decay is very big.
The content of the invention
The object of the present invention is to provide a kind of transparent powder paint, transparent powder paint of the invention has high glaze, height The advantages that hardness, good, resistance to chemical corrosion is good, anti-yellowing property is good, good decorative property transparency, it is various to be that one kind is widely used in Metal works Lacquer finish transparent powder paint.
The present invention provides a kind of transparent powder paint, and the powdery paints includes following components by weight percent raw material:
Further, the polyester resin is high transparency polyester resin.
Further, the curing agent is TGIC or HAA.
Further, the levelling agent is 486 levelling agent of Troy, and wetting agent is 520 wetting agent of Troy, and defoamer is Troy defoamer.
Further, the stearic acid is stearic acid 1895.
Further, the dyestuff is high temperature resistant Weather-proof dye.
Further, the delustering agent is acrylic matting agent.
Technical solution of the present invention also provides a kind of preparation method of above-mentioned transparent powder paint, comprises the following steps:
Above-mentioned each raw material is mixed in proportion, by mixing extrusion in extruder, after then tabletting crushes, then by micro mist Broken machine crushes, sieving, up to the transparent powder paint.
Technical solution of the present invention also provides a kind of application of above-mentioned transparent powder paint, by above-mentioned coating applied metal work Part.
Further, the coating is sprayed by corona electrostatic.
Transparent powder paint provided by the invention uses high transparency polyester resin as main ingredient, and with good resistance to Hot, weatherability TGIC or HAA is as curing agent so that transparent powder paint has excellent weatherability, adhesive force and soft Toughness;4 kinds of auxiliary agents such as levelling agent, wetting agent, defoamer, stearic acid are with the addition of, the addition of above-mentioned auxiliary agent significantly improves polyester The levelability of resin, wetability so that coating has the advantages that flowing flow leveling, the transparency, the adhesive force of brilliance;It with the addition of High temperature resistant Weather-proof dye, can recall the transparent powder paint of a variety of colors, be sprayed on various metal hardware workpiece surfaces;This Outside, acrylic matting agent is also added, the extinction effect of delustering agent is good, can obtain 1-
60% any gloss.The dosage of filler and pigment is reduced in otherwise see-through powdery paints to the greatest extent, has improved as far as possible Resin ratio shared in transparent powder paint, be conducive to improve the high transparency effect of transparent powder paint, impact resistance, Pliability and adhesive force.
Compared with prior art, the present invention have the beneficial effect that:
1st, transparent powder paint provided by the invention uses high transparency polyester resin as main ingredient, and with good Heat resistance, the TGIC of weatherability or HAA are as curing agent so that transparent powder paint have excellent weatherability, adhesive force and Pliability.
2nd, transparent powder paint provided by the invention is suitable for industrial continuous spraying and application, wide with application range Advantage, there is provided diversified decorative product.
3rd, product of the invention due to be 100% solid part, without any solvent, not only accumulating is convenient, but also can recycle Reuse, utilization rate is up to more than 95%.Overcome solvent-borne type luminous paint, due to there is a solvent flashing, a part is waved during use Hair falls, and a part is attached on coating equipment, and utilization rate only has the shortcomings of 30-40%.
4th, transparent powder paint of the invention has high glaze, high rigidity, the transparency is good, resistance to chemical corrosion is good, resistance to The advantages that xanthochromia performance is good, good decorative property, is that one kind is widely used in various metal works Lacquer finish transparent powder paints.
Embodiment
A kind of preparation of 1 transparent powder paint of embodiment
A kind of transparent powder paint, the powdery paints include following components by weight percent raw material:
Above-mentioned each raw material is mixed in proportion, by mixing extrusion in extruder, after then tabletting crushes, then by micro mist Broken machine crushes, sieving, up to the transparent powder paint.
Embodiment two:A kind of application of transparent powder paint, is used for various metal works by above-mentioned powdery paints.
(1) pre-treatment:In actual application, according to substrate material and the difference in concrete application place, the pre-treatment Process it is also different, be adjusted according to different actual applications for above-mentioned pretreatment process.
(2) spray
The coating sprays to the surface of metal works by corona electrostatic, and the cure parameter in spraying process is 200 DEG C, 10min, the appearance of coating is plane bloom, wherein it is gloss more than 80% that 60 degree of glossometers, which measure bloom,.
(3) coating is tested
The yellow chromaking aluminium sheet based on 0.7mm thickness is tested in laboratory.By construction technology and such environmental effects, actual product Specific performance, such as gloss, effect and appearance may be different with laboratory detection result.
Table one
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair The limitation of the present invention, protection scope of the present invention should be subject to claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Protection scope of the present invention is also should be regarded as into retouching.

Claims (10)

1. a kind of transparent powder paint, it is characterised in that including following components by weight percent raw material:
2. transparent powder paint as claimed in claim 1, it is characterised in that the polyester resin is high transparency polyester resin.
3. transparent powder paint as claimed in claim 1, it is characterised in that the curing agent is TGIC or HAA.
4. transparent powder paint as claimed in claim 1, it is characterised in that the levelling agent is 486 levelling agent of Troy, profit Humectant is 520 wetting agent of Troy, and defoamer is Troy defoamer.
5. transparent powder paint as claimed in claim 1, it is characterised in that the stearic acid is stearic acid 1895.
6. transparent powder paint as claimed in claim 1, it is characterised in that the dyestuff is high temperature resistant Weather-proof dye.
7. transparent powder paint as claimed in claim 1, it is characterised in that the delustering agent is acrylic matting agent.
8. a kind of preparation method of transparent powder paint as claimed in claim 1, it is characterised in that comprise the following steps:
Above-mentioned each raw material is mixed in proportion, by mixing extrusion in extruder, after then tabletting crushes, then by atomizer Crush, sieving, up to the transparent powder paint.
9. the application of a kind of transparent powder paint as any one of claim 1-7, it is characterised in that by above-mentioned coating Applied to metal works.
10. the application of transparent powder paint as claimed in claim 9, it is characterised in that the coating is sprayed by corona electrostatic Apply spraying.
CN201711251661.1A 2017-12-01 2017-12-01 A kind of transparent powder paint Pending CN108034337A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711251661.1A CN108034337A (en) 2017-12-01 2017-12-01 A kind of transparent powder paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711251661.1A CN108034337A (en) 2017-12-01 2017-12-01 A kind of transparent powder paint

Publications (1)

Publication Number Publication Date
CN108034337A true CN108034337A (en) 2018-05-15

Family

ID=62095273

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711251661.1A Pending CN108034337A (en) 2017-12-01 2017-12-01 A kind of transparent powder paint

Country Status (1)

Country Link
CN (1) CN108034337A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110964412A (en) * 2019-12-26 2020-04-07 忠旺(辽阳)铝模板制造有限公司 Transparent powder coating for aluminum template and preparation method and application thereof
CN114410196A (en) * 2021-12-20 2022-04-29 江南载福粉末涂料(张家港)有限公司 Boiling-resistant powder coating and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059275A (en) * 2012-12-28 2013-04-24 广州擎天材料科技有限公司 A polyester resin used for TGIC cured transparent powder coatings
CN105694683A (en) * 2016-04-28 2016-06-22 佛山市恒学科技服务有限公司 Transparent powdery coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059275A (en) * 2012-12-28 2013-04-24 广州擎天材料科技有限公司 A polyester resin used for TGIC cured transparent powder coatings
CN105694683A (en) * 2016-04-28 2016-06-22 佛山市恒学科技服务有限公司 Transparent powdery coating

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张学敏 等: "《涂料与涂装技术》", 31 January 2006, 化学工业出版社 *
杨成德: "《涂料开发与试验》", 28 February 2015, 科学技术文献出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110964412A (en) * 2019-12-26 2020-04-07 忠旺(辽阳)铝模板制造有限公司 Transparent powder coating for aluminum template and preparation method and application thereof
CN114410196A (en) * 2021-12-20 2022-04-29 江南载福粉末涂料(张家港)有限公司 Boiling-resistant powder coating and preparation method and application thereof

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Application publication date: 20180515

RJ01 Rejection of invention patent application after publication