CN103316830B - Coating process on impregnated and presseure-adheriing laminate flooring - Google Patents

Coating process on impregnated and presseure-adheriing laminate flooring Download PDF

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CN103316830B
CN103316830B CN201310265820.9A CN201310265820A CN103316830B CN 103316830 B CN103316830 B CN 103316830B CN 201310265820 A CN201310265820 A CN 201310265820A CN 103316830 B CN103316830 B CN 103316830B
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mixture
coating
resin
acrylic resin
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CN103316830A (en
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江益新
唐基红
陈明贵
吴志飞
江科
常红言
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JIANGSU HIMONIA TECHNOLOGY Co Ltd
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Abstract

The invention discloses a coating process on impregnated and pressure-adhering laminate flooring. Since three kinds of UV (ultraviolet) coatings are adopted, work efficiency can be improved, space can be saved, emission can be reduced, surface properties of the impregnated and pressure-adhering laminate flooring by adopting the coatings can be more excellent, and the impregnated and pressure-adhering laminated flooring can be prevented from being delaminated after being boiled for three hours at the constant temperature of 70 DEG C and dried for three hours at the constant temperature of 70 DEG C. The three kinds of UV coatings refer to a UV-water-resistant high-adhesion base coating, a UV-toughness sanding base coating and a UV-flexible curtaining soft-light finishing coating. The coating process includes impregnating and pressure-adhering reinforcing base materials on laminate flooring to obtain a base material layer; coating the UV-water-resistant high-adhesion base coating, the UV-toughness sanding base coating and the UV-flexible curtaining soft-light finishing coating on the base material layer in sequence. By modifying coating formulas, the laminate flooring coated with modified coatings has good flexibility, fullness, adhesive force and comprehensive water resistance, and has special effects of moisture, soft light and glossiness. Besides, the glossiness of a coating film is above 75 degrees.

Description

A kind ofly overlay the coating process on consolidated floor at dipping
Technical field
The present invention relates to a kind of coating process of UV coating, is respectively a kind ofly to overlay the coating process on consolidated floor at dipping specifically.
Background technology
UV is the english abbreviation of Ultraviolet (ultraviolet ray), and UV paint is ultraviolet-cured paint.Existing traditional consolidated floor substantially all adopts dipping intensified letterweight to paste containing the melamine mould of alundum (Al2O3) and pastes and form, although but this series products wearability is good, the melamine film overlaying is thinner, price is high, make the wood grain that overlays on floor lack stereovision, and cost is higher.Or some factory has been used UV coating, on consolidated floor base material, overlay dipping woodgrained paper after application UV coating, a lot of coating can well be carried out adhesive force on this base material, and the scraping performance of anti-coin also can be done finely, but almost there is no to be coated with the floor that installs UV coating by 3 hours constant temperature poach of 70 degree, 70 3 hours constant temperature dryings of degree and delamination does not appear in paint film.
Summary of the invention
The object of this invention is to provide and a kind ofly overlay the coating process on consolidated floor at dipping, this construction technology adopts three kinds of UV coating, can enhance productivity, save place, reduce discharge, can allow to use the dipping of this coating to overlay consolidated floor surface property more outstanding, well within 3 hours, dry and not delamination by 3 hours poach of 70 degree constant temperature and 70 degree constant temperature.Three kinds of UV coating are respectively a kind of UV-water boiling resistance high adhesion force priming paint, a kind of UV-toughness sanding priming paint, a kind of flexible showering sheen finish paint.
The object of the invention is to be achieved through the following technical solutions:
Overlay the coating process on consolidated floor at dipping, it is characterized in that this technique comprises: dipping overlays strengthening base material on consolidated floor, obtains substrate layer; On substrate layer, apply successively UV-water boiling resistance high adhesion force priming paint, UV-toughness sanding priming paint and flexible showering sheen finish paint.Specific as follows:
1) dipping overlays consolidated floor dedusting;
2) the UV-high adhesion force priming paint roller coat of use water boiling resistance, consumption 15 ~ 20g/m2,220mj/cm2UV solidifies;
3) the UV-high adhesion force priming paint roller coat of use water boiling resistance, consumption 15 ~ 20g/m2,220mj/cm2UV solidifies;
4) with the flexible sanding priming paint of UV-roller coat, consumption 15 ~ 20g/m2,90mj/cm2UV solidifies;
5) with the flexible sanding priming paint of UV-roller coat, after UV-toughness showering sheen finish paint, use 320# sand paper light weight sand;
6) use dust removal machine dedusting;
7) with toughness showering sheen finish paint roller coat, consumption 5 ~ 8g/m2, does not solidify, only wetting;
8) with the showering of toughness showering sheen finish paint; Consumption 95 ~ 110g/m2,300mj/cm2UV solidifies.
In the present invention, component and the weight proportion thereof of described UV-water boiling resistance high adhesion force priming paint are: 100% UV cured resin 30% ~ 50%; Defoamer 0.1 ~ 0.3%; Adhesion promoter 0.1% ~ 5%; Dispersant 0.5 ~ 1.5%; Thixotropic agent 0.5% ~ 1%; Light trigger 4% ~ 8%; Filler 10% ~ 30%; Surplus is monomer; Described 100% UV-resin is epoxy acrylic resin or modified epoxy acrylate resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture with acidic-group; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class.
Component and the weight proportion thereof of the flexible sanding priming paint of described UV-are: 100% UV cured resin 40% ~ 60%; Defoamer 0.1 ~ 1%; Levelling 0.1% ~ 0.5%; Dispersant 0.5 ~ 1.5%; Anti-settling agent 0.2% ~ 1%; Light trigger 4% ~ 8%; Filler 10% ~ 20%; Surplus is monomer.Described 100% UV-resin is aliphatic epoxy acrylic resin or fatty acid modified epoxy acrylic resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class.
Component and the weight proportion thereof of described flexible showering sheen finish paint are: 100% UV cured resin 30% ~ 50%; Defoamer 1 ~ 3%; Levelling 0.1% ~ 0.5%; Dispersant 0.5 ~ 1.5%; Anti-settling agent 0.2% ~ 1%; Light trigger 4% ~ 8%; Filler 3% ~ 8%; Surplus is monomer.Described 100% UV-resin is epoxy acrylic resin or modified epoxy acrylate resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class.
Described defoamer is non-silicon base polymer solution, polyacrylic acid high polymer or their mixture; Adhesion promoter is phosphate modified acrylate compound or their mixture; Levelling agent is organosilicon polymer solution, polyacrylic acid high polymer or their mixture; Dispersant is high molecular weight block copolymer solution, modified acroleic acid block copolymer solution or their mixture; Anti-settling agent is organic matter modified gas aerosil class, aerosil or the mixture made with high molecular weight block copolymer solution, modified acroleic acid block copolymer solution; Light trigger is fragrant ketone, benzoin and derivative thereof or their mixture; Filler is the inorganic transparent powder classes such as talcum powder, silica flour; Delustering agent is organic matter modified gas aerosil class, aerosil, delustring wax slurry class or their mixture.
Compared with prior art; the present invention is by improving formulation for coating material and construction method; adopt continuous productive process, improved production efficiency, improved the utilization rate in place; reduce discharge; reduce coating consumption, improved water boiling resistance performance and the toughness of product, and lacquer painting third dimension is strong, feel is cunning; can obtain excellent visual effect and sense of touch, greatly improve the aesthetics and the protective value that has strengthened product of product.
The specific embodiment
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1
The coating process overlaying on consolidated floor at dipping comprises: on consolidated floor, dipping overlays a strengthening base material, obtains substrate layer; On substrate layer, apply successively UV-water boiling resistance high adhesion force priming paint, UV-toughness sanding priming paint and flexible showering sheen finish paint.
Component and the weight proportion thereof of the UV-high adhesion force priming paint of the water boiling resistance of the present embodiment are: 100% UV cured resin 45%; Defoamer 0.1%; Adhesion promoter 2.5%; Dispersant 0.5%; Thixotropic agent 0.5%; Light trigger 7%; Inserts 20%; Surplus is monomer.
Component and the weight proportion thereof of the flexible sanding priming paint of UV-of the present embodiment are: 100% UV cured resin 70%; Defoamer 0.1%; Levelling agent 0.05%; Dispersant 1%; Anti-settling agent 0.4%; Light trigger 4%; Inserts 10%; Surplus is monomer.
Component and the weight proportion thereof of the toughness showering sheen finish paint of the present embodiment are: 100% UV cured resin 50%; Defoamer 1%; Levelling agent 0.3%; Dispersant 1%; Anti-settling agent 0.6%; Light trigger 5%; Inserts 3%; Delustering agent 2%; Surplus is monomer.
Embodiment 2
The coating process overlaying on consolidated floor at dipping comprises: on consolidated floor, dipping overlays a strengthening base material, obtains substrate layer; On substrate layer, apply successively UV-water boiling resistance high adhesion force priming paint, UV-toughness sanding priming paint and flexible showering sheen finish paint.
Component and the weight proportion thereof of the UV-high adhesion force priming paint of a kind of water boiling resistance of the present embodiment are: 100% UV cured resin 40%; Defoamer 0.1%; Adhesion promoter 1%; Dispersant 0.5%; Thixotropic agent 1%; Light trigger 7%; Inserts 25%; Surplus is monomer.
Component and the weight proportion thereof of the flexible sanding priming paint of UV-of the present embodiment are: 100% UV cured resin 75%; Defoamer 0.2%; Levelling agent 0.05%; Dispersant 0.5%; Anti-settling agent 0.5%; Light trigger 5%; Inserts 5%; Surplus is monomer.
The toughness showering sheen finish paint of the present embodiment is high gloss finish, and the component of this sheen finish paint and weight proportion thereof are: 100% UV cured resin 45%; Defoamer 1.5%; Levelling agent 0.5%; Wetting agent 0.5%; Light trigger 5%; Inserts 2%; Surplus is monomer.
In the component of above-described embodiment: 100% UV cured resin is aliphatic epoxy acrylic resin or fatty acid modified epoxy acrylic resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture, epoxy resin, aliphatic or aromatic urethane resin, mylar etc. or their mixture produced as Changxing, Taiwan company, Qing Te company of the U.S., Sartomer company of the U.S., Jiangsu San Mu company etc.; Described monomer is esters of acrylic acid, modification acrylate class or their mixture, monomer or their mixture such as TPGDA, TMPTA, HDDA produced as Changxing, Taiwan company, Qing Te company of the U.S., Sartomer company of the U.S., Jiangsu San Mu company, Jiangsu Li Tian company, Tianjin proud son of heaven company etc.; Described defoamer is non-silicon base polymer solution, polyacrylic acid high polymer or their mixture, as the TEGO-910 of the BYK-055 of German Bi Ke company, German Di Gao company, 1286 etc. or their mixture; Described adhesion promoter is phosphate modified acrylate compound or their mixture, as helped chemical UV-7424/7426 etc. or their mixture in the CD-9051 of Sartomer company of the U.S., the EM-39 of Changxing, Taiwan company, middle mountain thousand; Described dispersant is high molecular weight block copolymer solution, modified acroleic acid block copolymer solution or their mixture, as BYK-204, BYK-164, the EFKA-4010 of BASF Aktiengesellschaft etc. of German Bi Ke company or their mixture; Levelling agent is non-silicon base polymer solution, polyacrylic acid high polymer or their mixture, as the BYK-358 of German Bi Ke company, hamming this DC-495, prosperous MAS too gram etc. or their mixture; Anti-settling agent is the hydrophobic aerosil class of organic matter modification, aerosil or the mixture made with high molecular weight block copolymer solution, modified acroleic acid block copolymer solution, as the A-972 of German Chuan Ying company, BYK-103, the EFKA-5028 of BASF Aktiengesellschaft etc. of German Bi Ke company or their mixture; Described thixotropic agent is organic matter modified gas aerosil class, aerosil or the mixture made with high molecular weight block copolymer solution, modified acroleic acid block copolymer solution, as the M-5 of the A-200 of German Chuan Ying company, Cabot Co.,Ltd of the U.S., BYK-110, BYK-410, the EFKA-4010 of BASF Aktiengesellschaft etc. of German Bi Ke company or their mixture; Described light trigger is fragrant ketone, benzoin and derivative thereof or their mixture, as BASF Aktiengesellschaft, Changsha company of Sunyu, Beijing Ying Li company etc. produced 1173,184, benzophenone etc. or their mixture; Described inserts is the inorganic transparent powder classes such as talcum powder, silica flour, talcum powder, the transparent filler etc. that company as wide in Guangxi, Belgian silicon bit company etc. produces or their mixture; Described delustering agent is organic matter modified gas aerosil class, aerosil, delustring wax slurry class or their mixture, and flatting silica is as 2105 of the OK-500 of the UV-55C of Ineos company of Britain, German Chuan Ying company, W. R. Grace & Co of the U.S. etc.; BYK-601, the FA-2120 of this company of hamming etc. of delustring slurry as German Bi Ke company or similarly mixture.
When coating is produced in preparation, by even to 100% UV cured resin, monomer and light trigger mixed dissolution, then add successively defoamer, levelling agent, adhesion promoter, dispersant etc. to stir, control temperature, can not exceed 50 degree; According to the difference of product function, material also has difference; Dropping into successively filler, anti-settling agent, delustering agent stirs again.When coating decoration, can add appropriate monomer or control coating temperature according to actual conditions to regulate the required viscosity of construction, the UV-high adhesion force priming paint of water boiling resistance adopts the rubber rollers roller application that hardness of rubber roll is 40; The flexible sanding priming paint of UV-adopts the rubber rollers roller application that hardness of rubber roll is 45; UV-toughness showering sheen finish paint adopts episodic curtain coater in 40 degree left and right temperature constant state constructions; The refluxing opening place of painting in work progress puts individual layer silk stocking and sneaks in paint bath to reduce foam and impurity.
(0023) after testing, use the technical indicator of substrate of application of the present invention as following table 1:
Table 1
Figure 285229DEST_PATH_IMAGE002
Production technology while adopting three kinds of UV coating material production sheet material of the present invention is as follows:
1, dipping overlays consolidated floor dedusting;
2, with the UV-high adhesion force priming paint roller coat of water boiling resistance, consumption 15 ~ 20g/m2,220mj/cm2UV solidifies;
3, with the UV-high adhesion force priming paint roller coat of water boiling resistance, consumption 15 ~ 20g/m2,220mj/cm2UV solidifies;
4, with the flexible sanding priming paint of UV-roller coat, consumption 15 ~ 20g/m2,90mj/cm2UV solidifies;
5, with the flexible sanding priming paint of UV-roller coat, after UV-toughness showering sheen finish paint, use 320# sand paper light weight sand;
6, use dust removal machine dedusting;
7, with UV-toughness showering sheen finish paint roller coat, consumption 5 ~ 8g/m2, does not solidify, only wetting;
8, with the showering of UV-toughness showering sheen finish paint; Consumption 95 ~ 110g/m2,300mj/cm2UV solidifies.

Claims (2)

1. overlay the coating process on consolidated floor at dipping, it is characterized in that this technique comprises: dipping overlays strengthening base material on consolidated floor, obtains substrate layer; On substrate layer, apply successively UV-water boiling resistance high adhesion force priming paint, UV-toughness sanding priming paint and flexible showering sheen finish paint; Specific as follows:
1) dipping overlays consolidated floor dedusting;
2) the UV-high adhesion force priming paint roller coat of use water boiling resistance, consumption 15~20g/m2,220mj/cm2UV solidifies; Component and the weight proportion thereof of UV-high adhesion force priming paint are: 100% UV cured resin 30%~50%; Defoamer 0.1~0.3%; Adhesion promoter 0.1%~5%; Dispersant 0.5~1.5%; Thixotropic agent 0.5%~1%; Light trigger 4%~8%; Filler 10%~30%; Surplus is monomer; Described 100% UV-resin is epoxy acrylic resin or modified epoxy acrylate resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture with acidic-group; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class;
3) the UV-high adhesion force priming paint roller coat of use water boiling resistance, consumption 15~20g/m2,220mj/cm2UV solidifies;
4) with the flexible sanding priming paint of UV-roller coat, consumption 15~20g/m2,90mj/cm2UV solidifies; Component and the weight proportion thereof of the flexible sanding priming paint of described UV-are: 100% UV cured resin 40%~60%; Defoamer 0.1~1%; Levelling 0.1%~0.5%; Dispersant 0.5~1.5%; Anti-settling agent 0.2%~1%; Light trigger 4%~8%; Filler 10%~20%; Surplus is monomer.Described 100% UV-resin is aliphatic epoxy acrylic resin or fatty acid modified epoxy acrylic resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class;
5) with the flexible sanding priming paint of UV-roller coat, after UV-toughness showering sheen finish paint roller coat, use 320# sand paper light weight sand;
6) use dust removal machine dedusting;
7) with toughness showering sheen finish paint roller coat, consumption 5~8g/m2, does not solidify, only wetting; Component and the weight proportion thereof of described flexible showering sheen finish paint are: 100% UV cured resin 30%~50%; Defoamer 1~3%; Levelling 0.1%~0.5%; Dispersant 0.5~1.5%; Anti-settling agent 0.2%~1%; Light trigger 4%~8%; Filler 3%~8%; Surplus is monomer.Described 100% UV-resin is epoxy acrylic resin or modified epoxy acrylate resin, modified polyurethane acrylic resin, unsaturated polyester (UP) acrylic resin or their mixture; Described monomer is esters of acrylic acid, modification acrylate class or their mixture; Described filler is inorganic powder class.
8) with the showering of toughness showering sheen finish paint; Consumption 95~110g/m2,300mj/cm2UV solidifies.
2. according to claim 1ly overlay the coating process on consolidated floor at dipping, it is characterized in that: described defoamer is non-silicon base polymer solution, polyacrylic acid high polymer or their mixture; Adhesion promoter is phosphate modified acrylate compound or their mixture; Levelling agent is organosilicon polymer solution, polyacrylic acid high polymer or their mixture; Dispersant is high molecular weight block copolymer solution, modified acroleic acid block copolymer solution or their mixture; Anti-settling agent is organic matter modified gas aerosil class, aerosil or the mixture made with high molecular weight block copolymer solution, modified acroleic acid block copolymer solution; Light trigger is fragrant ketone, benzoin and derivative thereof or their mixture; Filler is the inorganic transparent powder classes such as talcum powder, silica flour; Delustering agent is organic matter modified gas aerosil class, aerosil, delustring wax slurry class or their mixture.
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