CN109310617A - Hidroschesis or deodorant cosmetics - Google Patents
Hidroschesis or deodorant cosmetics Download PDFInfo
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- CN109310617A CN109310617A CN201780035946.3A CN201780035946A CN109310617A CN 109310617 A CN109310617 A CN 109310617A CN 201780035946 A CN201780035946 A CN 201780035946A CN 109310617 A CN109310617 A CN 109310617A
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- hidroschesis
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
That the object of the present invention is to provide emulsion stabilities is good, without coating when it is sticky, with good refrigerant sense and dry feeling include alcohol/O/W emulsion composition hidroschesis or deodorant cosmetics.The present invention relates to a kind of hidroschesis or deodorant cosmetics, it includes alcohol/O/W emulsion compositions, alcohol/the O/W emulsion composition contains: (a) including the oil of 1 mass % high polymerizing silicone below, (b) emulsifier comprising one or more kinds of polyether modified silicones, (c) lower alcohol of 50 mass % or more, and (d) water.
Description
Technical field
The present invention relates to the hidroschesis or deodorant cosmetics without powder without rocking before use.More specifically, it is related to
Include alcohol/oil-in-water type emulsion group obtained from making the oil emulsification comprising high polymerizing silicone using specific polyether modified silicone
It closes object and plays the cosmetics of good hidroschesis and deodorizing effect being free of powdered ingredients.
Background technique
As the cosmetics of the sense of discomfort generated for mitigating the sticky, sticky by this of the skin as caused by sweat, use
There are Antiperspirants and Deodorants.For the antiperspirant cosmetics, user has sweating inhibition, astriction except compounding hidroschesis ingredient is expected
In addition, it is strongly required that the dry feeling after nice and cool refrigerant sense, frank sense, coating can be obtained when being coated on skin.
It is mostly commercially available for the purpose of inhibiting sticky, obtain dry feeling and compounded with powder as previous antiperspirant cosmetics
The commodity of last ingredient.However, joined the antiperspirant of powder when standing since powder is deposited in container, needed when using
To make powder more fully redisperse by rocking.In the case that the redisperse is insufficient, not only it is unable to get by powdered ingredients
The good use feeling of bring, and asked in the spraying antiperspirant for misty aerosol type or ejection-type in the presence of what is blocked
Topic.In addition, also worrying to lead to the whiteness of skin after coating because of powdered ingredients.
It is disclosed in patent document 1, compounded with hidroschesis ingredient (powdered ingredients), cross-linking type methyl polysiloxane and cross-linking type
Methyl phenyl silicone compound at least any one, the antiperspirant combination of crosslinked polyether modified silicone and lower alcohol
Object, the dispersibility by improving powder prevent the crystallization of powdered ingredients, improve the use feeling (appearance) after drying.So
And due to still including powdered ingredients, therefore powder redisperse must be made by rocking before, although appearance has in addition to this
Improved, but has the tendency that the skin after coating generates whiting.
Therefore, be strongly required it is a kind of without coating when it is sticky, can obtain sufficient refrigerant sense and dry feeling without powder
Hidroschesis or deodorant cosmetics.
On the other hand, in the field of hair cosmetic composition, it is known to by compounding polyether modified silicone as emulsifier, from
And the oil comprising the hair treatments ingredient such as high polymerizing silicone is steadily emulsifiable in the alcohol oil-in emulsification composition in alcohol, it should
Alcohol oil-in emulsification composition is for (patent documents 2) such as hair conditioner, hair styling agents.However, not known by the alcohol packet
Oil type emulsification composition is used in the example of hidroschesis or deodorant cosmetics.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 5-229925 bulletin
Patent document 2: No. 3417567 bulletins of Japanese Patent No.
Summary of the invention
Problems to be solved by the invention
Problem of the present invention is that a kind of cosmetics of no powder are obtained, even if not being compounded powdered ingredients (antiperspirant),
The dry feeling after refrigerant sense and coating when also with use required by hidroschesis or deodorant cosmetics.
The solution to the problem
The inventors of the present invention in order to solve aforementioned problems, repeatedly further investigation as a result, it has been found that, in the past be used for hair conditioner, hair
Send out setting agent in alcohol oil-in emulsification composition in, by the compounding amount of high polymerizing silicone is set as 1 mass % hereinafter, even if
It is not compounded previous hidroschesis ingredient, dry feeling can also be assigned when being coated with skin, so far complete the present invention.
I.e. the present invention provides a kind of hidroschesis or deodorant cosmetics, it includes alcohol/O/W emulsion composition, the alcohol/
O/W emulsion composition contains: (a) including the oil of 1 mass % high polymerizing silicone below, (b) comprising having specific knot
The emulsifier of the polyether modified silicone of structure, (c) lower alcohol of 50 mass % or more, and (d) water.
The effect of invention
The present invention due to not being compounded powdered ingredients substantially, there is no need to rocked before use make powdered ingredients redisperse,
Also the whiting of the skin after not generating coating.In addition, by forming above-mentioned composition, when without sticky, coating when being applied to skin
With refrigerant sense and dry feeling are obtained after drying.In addition, have the polyether modified silicone of specific structure as emulsifier by compounding,
Oil can be made steadily to be emulsifiable in alcohol, thus through when stability it is also excellent, there will not be compounding ingredients be precipitated and block
The case where automiser spray.
Specific embodiment
Then, it is described in detail for each ingredient for constituting cosmetics of the invention.
< (a) includes the oil > of high polymerizing silicone
(a) used in the present invention include high polymerizing silicone oil (hereinafter sometimes referred to simply as " (a) ingredient ") be comprising
Gluey (such as the viscosity at 30 DEG C is about 1,000,000mPas or more), be selected from high polymerizing silicone and amino modified or ammonium
The oil of the one or more (otherwise referred to as silicone adhesive (silicone gum)) of modified high polymerizing silicone.
As high polymerizing silicone of the invention, high polysiloxanes shown in the following general formula (I) or high poly- can be exemplified
Close dimethiconol.
In formula, R1Indicate methyl or phenyl (wherein, R1Will not all phenyl), R2Indicate methyl or hydroxyl.In addition, n table
Show 3000~20000 integer.
It, can example as the modified high polymerizing silicone (being also referred to as amino modified silicone sometimes) of amino modified or ammonium of the invention
Substance shown in the following general formula (II) is shown.
In formula, R1It indicates methyl or a part is phenyl, R2With R3Identical or expression methyl or hydroxyl.R3Expression R4Z{R4
Indicate that the alkylidene with the divalent of 3 to 6 carbon atoms, Z are indicated selected from by-NR5 2、-N+R5 3A-、-NR5(CH2)aNR5 2、-NR5
(CH2)aN+R5 3A-With-NR5(CH2)aN(R5) C=O (R6)(R5Indicate hydrogen or alkyl with 1 to 4 carbon atoms, R6Indicate tool
There is the alkyl of 1 to 4 carbon atom, A indicates Cl, Br or I, the integer that a is 2~6.) composition group in 1 valence group.Shown in
Substituent group with amino or ammonium, m and n are respectively the integer that positive integer and m+n indicate 3000~20000, n/m 1/500
~1/10000.
Wherein, preferred aminopropylmethylsiloxane dimethylsiloxane copolymer (aminopropyl polydimethylsiloxanes
Alkane).
The compounding amount of the high polymerizing silicone (silicone adhesive) of cosmetics of the invention is contained with the reality relative to cosmetics total amount
Meter needs for 1.0 mass % or less.Compounding amount generated when being coated with when being more than 1.0 mass % it is sticky and be unable to get it is dry after
Refrigerant sense.The lower limit value of the compounding amount of high polymerizing silicone is not particularly limited, and is 0.01 matter usually relative to cosmetics total amount
Measure % or more, preferably 0.05 mass % or more, more preferable 0.1 mass % or more.The compounding amount of i.e. high polymerizing silicone (silicone adhesive)
By based on the actual content of cosmetics total amount, be 1.0 mass % or less, preferably 0.01~1.0 mass %, more preferable 0.05
~1.0 mass %, most preferably 0.1~1.0 mass %.
As (a) ingredient of the invention, the commercially available product comprising high polymerizing silicone and oil above-mentioned can be used.
As the commercially available product comprising high polymerizing silicone and oil shown in above-mentioned logical formula (I), can enumerate for example: SHIN-ETSU HANTOTAI
The dimethicone blend for learning Industrial Co., Ltd has KF-9008 (height polymerization dimethyl silicone polymer 20% as an example
With the mixture of ring five dimethyl silicone polymer 80%), KF-9011 (height polymerization dimethyl silicone polymer 10% and ring five poly- two
The mixture of methylsiloxane 90%), KF-9013 (height polymerization dimethyl silicone polymer 15% and low viscosity polydimethylsiloxanes
The mixture of alkane 85%), KF-9014 (height polymerization dimethyl silicone polymer 15% and ring five dimethyl silicone polymer 85% it is mixed
Close object), the MK-15H mixture of dimethyl silicone polymer 20% and low viscosity dimethyl silicone polymer 80% (height polymerization), X-
21-5495 (mixture of height polymerization dimethyl silicone polymer 15% and ring five dimethyl silicone polymer 85%), KF-9028 are (high
Polymerize the mixture of dimethyl silicone polymer 20% and ring five dimethyl silicone polymer 80%), (height polymerize poly- diformazan to KF-9030
The mixture of radical siloxane 20% and low viscosity dimethyl silicone polymer 80%)；Height polymerization dimethiconol, as example
Son have the X-21-5613 mixture of dimethiconol 20% and low viscosity dimethyl silicone polymer 80% (height polymerization),
X-21-5666 (mixture of height polymerization dimethiconol 30% and ring five dimethyl silicone polymer 70%), X-21-
5847 (height polymerization dimethiconols), X-21-5849 (height polymerization dimethiconol)；Dow Corning
The high polymerization dimethyl silscone of Toray, there is BY11-007 (height polymerization dimethyl silicone polymer 10% and poly- diformazan as an example
The mixture of radical siloxane 90%), BY11-014 (height polymerization dimethyl silicone polymer 15% and dimethyl silicone polymer 85%
Mixture), the BY11-026 mixture of dimethyl silicone polymer 30% and dimethyl silicone polymer 70% (height polymerization) etc..
As the commercially available product comprising amino modified high polymerizing silicone and oil shown in above-mentioned logical formula (II), example can be enumerated
Such as: high polymerization ammonia base oil blend (amino glue (amino gum)) of Shin-Etsu Chemial Co., Ltd has as an example
KF-8017 (mixture of aminopropyl dimethyl silicone polymer 10% and dimethyl silicone polymer 90%), KF-8018 (amino
The mixture of propyl dimethyl silicone polymer 10% and ring five dimethyl silicone polymer 90%), KF-8020 (aminopropyl poly- two
The mixture of methylsiloxane 20% and dimethyl silicone polymer 80%) etc..
The oil other than high polymerizing silicone in (a) ingredient of the invention except various oils contained by aforementioned commercially available product with
Outside, it is also selected from oil usually workable in the cosmetics for skin comprising hidroschesis or deodorant cosmetics.It can enumerate for example
The vegetable oil such as the hydrocarbon ils such as atoleine, saualane, ester oil, avocado oil, palm oil, SIMMONDSIA CHINENSIS SEED OIL, silicone oil etc..
The compounding amount of (a) ingredient in cosmetics of the invention is not particularly limited, and is usually relative to cosmetics total amount
0.1~30 mass %, preferably 0.5~25 mass %, more preferable 0.5~20 mass %.(a) compounding amount of ingredient is more than 30 matter
The stability of emulsion reduces sometimes when measuring %.
< (b) polyether modified silicone >
In the present invention, be characterized in that compounding (b) include the polyether modified silicone with specific structure it is one or two kinds of with
On emulsifier (hereinafter sometimes referred to simply as " (b) ingredient ").
Polyether modified silicone used in the present invention ((b) ingredient) is polyether-modified shown in the following general formula (III)
The one or more of silicone.
In formula, R indicates methyl or phenyl.A is general formula :-C3H6O(C2H4O)a(C3H6O)b(in formula, R ' is selected from by hydrogen to-R '
Atom, acyl group and carbon number 1~4 alkyl composition group in group, and a be 5~50 integer, b be 5~50 integer) institute
The polyoxy alkylidene shown.As the acyl group of R ', specifically, formoxyl, acetyl group, propiono, bytyry, propylene can be exemplified
Acyl group, benzoyl, toluyl etc., as the alkyl of carbon number 1~4, specifically, methyl, ethyl, isopropyl can be exemplified
Base, n-propyl, tert-butyl, normal-butyl etc..
It should be noted that polyether modified silicone does not show sufficient table when a or b are less than 5 in aforementioned polyoxy alkylidene
Face active effect, obtained composition has sticky sense when in addition a or b is more than 50.
The amount of polyoxy alkylidene in the molecule is not particularly limited, and the amount of polyoxy alkylidene it is expected in total molecule
More than 20 mass % in amount.This is because, polyethers changes when the amount of polyoxy alkylidene is 20 mass % or less in total molecular weight
Property silicone thickening effect significantly reduce.
In addition, the integer that m is 50~1000, the integer that n is 1~40.This is because, m less than 50, n less than 1 when, lack
Emulsion stability, when in addition m is more than that 1000, n is more than 40, obtained composition generates sticky sense.In addition, the preferred 200:1 of m:n
~5:1, particularly preferred 60:1~15:1.
The molecular weight of polyether modified silicone used in the present invention is not particularly limited, and viscosity is not particularly limited, special
Not from the point of view of forming lotion with stability, there is dry feeling, it may be desirable to by polyether modified silicone formation four silicon of prestox
The range that the viscosity at 25 DEG C when 50 mass % solution of oxygen alkane or isoparaffin is 1000~100000mPas.
Polyether modified silicone used in the present invention, can be used commercially available product.As commercially available product, can enumerate for example
BY11-030 (the poly- diformazan of PEG/PPG-19/19 comprising 50 mass % of Dow Corning Toray Silicone corporation
The ring five dimethyl silicone polymer of radical siloxane and 50 mass %.PEG/PPG-19/19 dimethyl silicone polymer refers to above-mentioned logical
The polyether modified silicone of the molecular weight 55000 of m=400, n=10, a=19, b=19 in formula；HLB (Si)=7), BY25-337
((hydrogenation is poly- for the light liquid isoparaffin of the PEG/PPG-19/19 dimethyl silicone polymer comprising 50 mass % and 50 mass %
Isobutene)) etc..
The compounding amount of polyether modified silicone used in the present invention is not particularly limited, preferably with respect to cosmetics total amount,
0.1~5.0 mass %, preferably 0.3~4.0 mass %, more preferable 0.4~3.0 mass %, most preferably are calculated as with actual content
0.5~2.5 mass %.In composition of the invention, the compounding amount of polyether modified silicone is in terms of actual content less than 0.1 mass %
When, it is difficult to it steadily emulsifies, in addition, composition has sticky sense sometimes when more than 5.0 mass %.
< (c) lower alcohol >
(c) lower alcohol used in the present invention (hereinafter sometimes referred to simply as " (c) ingredient ") generally refers to can be used for medicine, change
The alcohol of the carbon atom number 1~6 in cosmetic field etc., preferably carbon atom number 1~4, specifically, methanol, ethyl alcohol, third can be enumerated
Alcohol, butanol, amylalcohol, hexanol etc., wherein particularly preferably using ethyl alcohol.
It should be noted that the You Yu such as isopropanol, normal propyl alcohol, the tert-butyl alcohol, sec-butyl alcohol Shu is aqueous too strong and is difficult to emulsify, because
This expectation is used with ethanol composition.
The compounding amount of lower alcohol used in the present invention ((c) ingredient) relative to cosmetics total amount be 50 mass % or more,
It is preferred that 60 mass % or more.In addition, the compounding amount of lower alcohol is 3 times or more preferably with respect to the compounding amount of the water in composition
(mass ratio).When the amount of lower alcohol is less than 3 times, it is difficult to refrigerant sense and dry feeling after being sufficiently coated with.
< (d) water >
The compounding amount of (d) water (being also referred to as " (d) ingredient " sometimes below) in the present invention is excellent relative to cosmetics total amount
Select 15 mass % or less, more preferable 12 mass % or less.When the compounding amount of water is more than 15 mass %, when coating, generates sticky, nothing
Method obtains dry feeling.
Antiperspirant cosmetics of the invention are compounded (a)~(d) ingredient as described above and become the high alcohol/oil-in-water of stability
Type emulsification composition, obtained not being compounded previous hidroschesis ingredient (powdered ingredients) using when refrigerant sense and dry feeling.
The effect is the surprising effect that can not be predicted from the prior art, but the fact is not precluded in cosmetics of the invention into one
Step is compounded hidroschesis ingredient, antibacterial agent, the deodorization ingredient that previous antiperspirant cosmetics are compounded.But its compounding amount is limited to not damage
The range of effect of the invention.
As the hidroschesis ingredient that can be compounded, such as P-phenol zinc sulfonate (ZINC P-PHENOLSULFONATE), citric acid, various aluminium can be enumerated
Compound etc. restrains antiperspirant；Triclosan, benzalkonium chloride, benzethonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, halogen card
The antibacterial agents such as class；The deodorants such as zinc oxide, flavonoids, chlorophyll；The cold feeling agents such as menthol, menthyl lactate；Various screening agents
Deng.
In hidroschesis or deodorant cosmetics of the invention, in addition to above-mentioned hidroschesis ingredient, do not impairing the effect of the present invention
In the range of can be compounded the other compositions that can be usually compounded in cosmetics, such as moisturizer, preservative, fragrance, chelating agent, anti-
Oxidant, ultraviolet absorbing agent, gelling agent, thickener etc..
The product form of hidroschesis or deodorant cosmetics of the invention is not particularly limited, such as can be with antiperspirant, body
The forms such as lotion, toner, beautifying liquid provide.Cosmetics of the invention can not be compounded powdered hidroschesis ingredient, therefore special
Not Shi He by be contained in the automiser sprays such as distributor it is spraying used with or with injection that stock solution accommodates together in the form of provide, no
The blocking of nozzle can occur.
Embodiment
It is exemplified below embodiment to be more specifically illustrated the present invention, but the present invention is not limited to these.It needs to illustrate
It is that unless otherwise specified, compounding amount indicates the quality % relative to total amount.
Antiperspirant deodorant cosmetics of the invention are prepared, use feeling is evaluated.
(embodiment 1~16 and comparative example 1~3)
Cosmetics shown in embodiment 1~16 and comparative example 1~3 are by by removing in ingredient shown in following table 1~3
Other than ion exchange water and benzalkonium chloride liquid uniform component dissolution, stir process and emulsify, then add ion exchange water and
Benzalkonium chloride liquid, to prepare.
(comparative example 4~6)
Cosmetics shown in comparative example 4~6 are by mixing the water-phase component containing lower alcohol and powdered ingredients, then
Emulsify the oil-phase component for having dissolved surfactant using stir process, to prepare.
The cosmetic sample prepared by the above method is coated on 10 panellists, based on evaluation point below
And evaluation criteria, refrigerant sense, dry feeling after refrigerant sense, coating when the presence or absence of sticky, coating after determining coating are dry.
+ 3 points: very good.
+ 2 points: good.
+ 1 point: slightly good.
0 point: common.
- 1 point: slightly worse.
- 2 points: poor.
- 3 points: excessively poor.
Based on the average mark of above-mentioned evaluation point, determined according to evaluation criteria below.
A :+2 points or more are equally divided into.
B :+1 point or more and+2 points of deficiency are equally divided into.
C: 0 point or more and+1 point of deficiency are equally divided into.
D: being equally divided into -1 point or more and divides less than 0.
E: -2 points or more and -1 point of deficiency are equally divided into.
F: average mark is -2 points insufficient.
[table 1]
[table 2]
[table 3]
By the result of Tables 1 and 2 it is found that for antiperspirant cosmetics of the invention, although not being compounded refrigerant in order to obtain
Sense and dry feeling and usually with the powdered ingredients that are mixed in antiperspirant, also without coating when it is sticky, it is also available after the drying
Refrigerant sense and dry feeling.
On the other hand, as illustrated by the result of table 3, by high polymerizing silicone more than 1 matter in terms of silicone adhesive actual content
Amount % and in the case where being compounded (comparative example 1 and comparative example 2), when coating generate it is sticky, be unable to get sufficient refrigerant sense.Separately
Outside, in the case that the compounding amount of lower alcohol is less than 50 mass (comparative example 3), when coating generate it is sticky, be unable to get it is adequately dry
Refreshing sense.
Obtained in addition, as illustrated by Tables 1 and 2, in the present invention due to (a) ingredient and (b) ingredient refrigerant sense and
Dry feeling.Instead of (a) and (b) ingredient of the invention, and be compounded refrigerant sense and dry feeling were compounded in the past in order to obtain powder at
In the case where point (comparative example 4~6), it is unable to get ethanol content is increased to 80 mass % from 50 mass % as only
The good use feeling of sweat agent.In addition, even if combining hidroschesis ingredient (chloro hydroxy Al) (comparative example 6) in powdered ingredients,
Coating when generate it is sticky, be unable to get dry feeling.
Then, emulsion of the invention is prepared, the ageing stability under the environment different to temperature is evaluated.
Specifically, the emulsion for the composition enumerated with following table 4 is utilized method system same as above-described embodiment
It is standby, to each emulsion prepared, after being placed at 0 DEG C, room temperature, 50 DEG C 4 weeks, based on following benchmark, by visual observation observe into
The evaluation of row stability.As a result it is shown in table 4.
< evaluation criteria >
A: unchanged.
B: slightly generation creaming.
C: significant creaming is generated.
D: separation.
[table 4]
As shown in the result of table 4, whole emulsions all have good emulsion stability.
Claims (4)
1. a kind of hidroschesis or deodorant cosmetics, which is characterized in that include alcohol/O/W emulsion composition, the alcohol/oil-in-water
Type emulsification composition contains:
(a) include 1 mass % high polymerizing silicone below oil,
(b) emulsifiers of the one or more comprising polyether modified silicone shown in the following general formula (III),
Wherein, A is general formula-C in formula3H6O(C2H4O)a(C3H6O)bPolyoxy alkylidene shown in-R', R ' is selected from by hydrogen original in formula
Group in the group of the alkyl composition of son, acyl group and carbon number 1~4, and the integer that a is 5~50, the integer that b is 5~50, R is first
Base or phenyl, and the integer that m is 50~1,000, the integer that n is 1~40,
(c) lower alcohol of 50 mass % or more, and
(d) water.
2. hidroschesis according to claim 1 or deodorant cosmetics, which is characterized in that the compounding amount of (c) lower alcohol is
3 times or more of the compounding amount of (d) water.
3. hidroschesis according to claim 1 or 2 or deodorant cosmetics, which is characterized in that also contain hidroschesis ingredient.
4. a kind of aerosol type hidroschesis or deodorant cosmetics, which is characterized in that its be cosmetics described in claim 1 are filled to
It distributes made of type container.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-116600 | 2016-06-10 | ||
| JP2016116600A JP6692703B2 (en) | 2016-06-10 | 2016-06-10 | Antiperspirant or deodorant cosmetics |
| PCT/JP2017/019954 WO2017212973A1 (en) | 2016-06-10 | 2017-05-29 | Antiperspirant or deodorant cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109310617A true CN109310617A (en) | 2019-02-05 |
| CN109310617B CN109310617B (en) | 2021-10-12 |
Family
ID=60579021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780035946.3A Active CN109310617B (en) | 2016-06-10 | 2017-05-29 | Antiperspirant or deodorant cosmetic |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6692703B2 (en) |
| KR (1) | KR20190016951A (en) |
| CN (1) | CN109310617B (en) |
| SG (1) | SG11201809819QA (en) |
| TW (1) | TW201801711A (en) |
| WO (1) | WO2017212973A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112752565A (en) * | 2018-09-28 | 2021-05-04 | 花王株式会社 | External preparation composition |
| JP7240857B2 (en) * | 2018-11-15 | 2023-03-16 | ポーラ化成工業株式会社 | Water-in-oil emulsion composition |
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| CN1030698A (en) * | 1987-06-27 | 1989-02-01 | 贺曼萍 | The compound method that axil reveals |
| CN1045700A (en) * | 1989-03-14 | 1990-10-03 | 普罗格特-甘布尔公司 | Low residue antiperspirant sticks |
| JP2006509736A (en) * | 2002-10-21 | 2006-03-23 | ロレアル | Method for dissolving lipophilic compound in aqueous solution using amphiphilic block copolymer, and cosmetic composition |
| JP2010528090A (en) * | 2007-05-29 | 2010-08-19 | シャネル パフュームズ ビューテ | Cosmetic composition comprising an active agent capable of stimulating tensin 1 expression |
| US20100329999A1 (en) * | 2004-01-30 | 2010-12-30 | Scott Edward Smith | Antiperspirant Aerosol Composition |
| CN104136499A (en) * | 2011-12-27 | 2014-11-05 | 道康宁东丽株式会社 | Novel co-modified organopolysiloxane, and treatment agent and external use preparation comprising the same |
| JP2015117239A (en) * | 2013-11-14 | 2015-06-25 | ライオン株式会社 | Antiperspirant composition |
| CN104769015A (en) * | 2012-10-02 | 2015-07-08 | 道康宁东丽株式会社 | Novel co-modified organopolysiloxane, powder processing agent comprising same, and powder composition |
| WO2016052277A1 (en) * | 2014-09-30 | 2016-04-07 | 株式会社マンダム | Emulsified deodorant composition and deodorant |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8914905D0 (en) * | 1989-06-29 | 1989-08-23 | Unilever Plc | Cosmetic composition |
| JPH05229925A (en) * | 1992-02-19 | 1993-09-07 | Shiseido Co Ltd | Liquid antiperspirant composition |
| KR100406345B1 (en) | 1995-07-12 | 2004-02-18 | 가부시키가이샤 시세이도 | Oil-in-alcohol emulsion composition |
| JP4949550B2 (en) * | 2000-12-11 | 2012-06-13 | 信越化学工業株式会社 | Cosmetics |
| US9238786B2 (en) * | 2011-05-04 | 2016-01-19 | Shiseido Company, Ltd. | Translucent fragrance composition |
-
2016
- 2016-06-10 JP JP2016116600A patent/JP6692703B2/en active Active
-
2017
- 2017-05-29 CN CN201780035946.3A patent/CN109310617B/en active Active
- 2017-05-29 SG SG11201809819QA patent/SG11201809819QA/en unknown
- 2017-05-29 WO PCT/JP2017/019954 patent/WO2017212973A1/en active Application Filing
- 2017-05-29 KR KR1020187034631A patent/KR20190016951A/en not_active Application Discontinuation
- 2017-06-05 TW TW106118491A patent/TW201801711A/en unknown
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030698A (en) * | 1987-06-27 | 1989-02-01 | 贺曼萍 | The compound method that axil reveals |
| CN1045700A (en) * | 1989-03-14 | 1990-10-03 | 普罗格特-甘布尔公司 | Low residue antiperspirant sticks |
| JP2006509736A (en) * | 2002-10-21 | 2006-03-23 | ロレアル | Method for dissolving lipophilic compound in aqueous solution using amphiphilic block copolymer, and cosmetic composition |
| US20100329999A1 (en) * | 2004-01-30 | 2010-12-30 | Scott Edward Smith | Antiperspirant Aerosol Composition |
| JP2010528090A (en) * | 2007-05-29 | 2010-08-19 | シャネル パフュームズ ビューテ | Cosmetic composition comprising an active agent capable of stimulating tensin 1 expression |
| CN104136499A (en) * | 2011-12-27 | 2014-11-05 | 道康宁东丽株式会社 | Novel co-modified organopolysiloxane, and treatment agent and external use preparation comprising the same |
| CN104769015A (en) * | 2012-10-02 | 2015-07-08 | 道康宁东丽株式会社 | Novel co-modified organopolysiloxane, powder processing agent comprising same, and powder composition |
| JP2015117239A (en) * | 2013-11-14 | 2015-06-25 | ライオン株式会社 | Antiperspirant composition |
| WO2016052277A1 (en) * | 2014-09-30 | 2016-04-07 | 株式会社マンダム | Emulsified deodorant composition and deodorant |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6692703B2 (en) | 2020-05-13 |
| JP2017218440A (en) | 2017-12-14 |
| WO2017212973A1 (en) | 2017-12-14 |
| KR20190016951A (en) | 2019-02-19 |
| CN109310617B (en) | 2021-10-12 |
| TW201801711A (en) | 2018-01-16 |
| SG11201809819QA (en) | 2018-12-28 |
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