TW201801711A - Antiperspirant or deodorant cosmetic - Google Patents

Antiperspirant or deodorant cosmetic Download PDF

Info

Publication number
TW201801711A
TW201801711A TW106118491A TW106118491A TW201801711A TW 201801711 A TW201801711 A TW 201801711A TW 106118491 A TW106118491 A TW 106118491A TW 106118491 A TW106118491 A TW 106118491A TW 201801711 A TW201801711 A TW 201801711A
Authority
TW
Taiwan
Prior art keywords
sweat
mass
group
alcohol
oil
Prior art date
Application number
TW106118491A
Other languages
Chinese (zh)
Inventor
大村孝之
Original Assignee
資生堂股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 資生堂股份有限公司 filed Critical 資生堂股份有限公司
Publication of TW201801711A publication Critical patent/TW201801711A/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

To provide an antiperspirant or deodorant cosmetic comprising an oil-in-alcohol/water type emulsion composition, said antiperspirant or deodorant cosmetic having a high emulsion stability, offering no stickiness upon application and giving a pleasant refreshing feeling and dry touch. An antiperspirant or deodorant cosmetic comprising an oil-in-alcohol/water type emulsion composition, said oil-in-alcohol/water type emulsion composition containing: (a) 1 mass% or less of an oily component containing a highly polymerized silicone; (b) an emulsifier comprising one or more kinds of polyether-denatured silicones; (c) 50 mass% or more of a lower alcohol; and (d) water.

Description

制汗或除臭化妝料Sweat or deodorant cosmetics

本發明係關於一種無須於使用前搖晃之無粉末之制汗或除臭化妝料。更詳細而言，係關於一種化妝料，其包含利用特定之聚醚改性矽酮使包含高聚合矽酮之油分乳化之醇/水中油型乳化組合物，且即便不含粉末成分亦發揮良好之制汗及除臭效果。The present invention relates to a powder-free sweat-making or deodorizing cosmetic that does not need to be shaken before use. More specifically, the present invention relates to a cosmetic material containing an alcohol / oil-in-water emulsified composition that emulsifies an oil component containing a high-polymerized silicone with a specific polyether-modified silicone, and performs well even without a powder component. The sweat and deodorant effect.

作為用於減輕由汗水引起之肌膚之黏膩、或由該黏膩而產生之不快感的化妝料，使用有制汗除臭劑。對於該制汗劑化妝料，使用者除期望調配制汗成分而有發汗抑制或收斂作用以外，亦強烈要求於塗抹於皮膚時可獲得涼爽之清涼感或爽快感、或塗抹後之乾爽感。 作為先前之制汗劑化妝料，多市售以抑制黏膩且獲得乾爽感為目的而調配有粉末成分之商品。然而，有粉末之制汗劑於靜置時由於粉體於容器內沈澱，故而於使用時必須藉由搖晃使粉體充分再分散。於該再分散不充分之情形時，不僅無法獲得由粉末成分帶來之良好之使用感，而且於霧狀地噴霧之噴霧型或噴射型之制汗劑中有發生堵塞之問題。又，亦擔心因粉末成分導致塗抹後之皮膚變白。 專利文獻1中揭示有一種制汗劑組合物，其調配有制汗成分(粉末成分)、交聯型甲基聚矽氧烷及交聯型甲基苯基聚矽氧烷化合物之至少任一者、交聯型聚醚改性矽酮、及低級醇，其藉由提高粉末之分散性而防止粉末成分之結晶化，改善乾燥後之使用感(外觀)。然而，由於依然包含粉末成分，故而於使用前必須藉由搖晃使粉末再分散，此外，外觀雖然有所改善，但有塗抹後之皮膚產生泛白之傾向。 因此，強烈要求一種無塗抹時之黏膩，可獲得充分之清涼感及乾爽感之無粉末之制汗或除臭化妝料。 另一方面，於毛髮化妝料之領域中，已知有藉由調配聚醚改性矽酮作為乳化劑，而將包含高聚合矽酮等毛髮處理成分之油分穩定地乳化於醇中之醇中油型乳化組合物，該醇中油型乳化組合物係用於護髮劑或造型劑等(專利文獻2)。然而，尚未知將該醇中油型乳化組合物用於制汗或除臭化妝料之例。 先前技術文獻 專利文獻 專利文獻1：日本專利特開平5-229925號公報 專利文獻2：日本專利第3417567號公報As a cosmetic material for reducing the stickiness of the skin caused by sweat or the unpleasant feeling caused by the stickiness, a sweat deodorant is used. With regard to this sweat-preventing cosmetic material, in addition to expecting that the sweat component is formulated to have a sweat-suppressing or astringent effect, users also strongly demand that they can obtain a cool refreshing feeling or refreshing feeling when applied to the skin, or a dry feeling after application. As a conventional sweat-making cosmetic, there are many commercially available products prepared with powder components for the purpose of suppressing stickiness and obtaining a dry feeling. However, powder-based sweat-making agents have powders that settle in the container when they are left to stand, so they must be fully redispersed by shaking during use. When the redispersion is insufficient, not only a good feeling of use due to the powder component cannot be obtained, but also a problem of clogging in a spray type or spray type sweat suppressant sprayed in a mist form. In addition, there is also concern that the skin after application may turn white due to the powder component. Patent Document 1 discloses a sweat-producing composition which is formulated with at least any one of a sweat-producing component (powder component), a cross-linked methyl polysiloxane, and a cross-linked methyl phenyl polysiloxane compound. , Cross-linked polyether-modified silicone, and lower alcohols, which improve the dispersibility of the powder, prevent the crystallization of the powder component, and improve the use feeling (appearance) after drying. However, since the powder component is still contained, it is necessary to re-disperse the powder by shaking before use. In addition, although the appearance is improved, the skin tends to become white after application. Therefore, there is a strong demand for a powder-free sweat-making or deodorizing cosmetic that is non-sticky when applied, and can obtain sufficient cooling and dryness. On the other hand, in the field of hair cosmetics, it is known to stably emulsify an oil component containing a hair-treating component such as a high-polymerized silicone into an alcohol-in-oil by blending polyether-modified silicone as an emulsifier. Type emulsified composition which is used for a hair conditioner or a styling agent (Patent Document 2). However, there is no known example of using this oil-in-alcohol type emulsified composition for a sweat or deodorant cosmetic. Prior Art Literature Patent Literature Patent Literature 1: Japanese Patent Laid-Open No. 5-229925 Patent Literature 2: Japanese Patent No. 3417567

[發明所欲解決之問題] 本發明之課題在於獲得一種無粉末之化妝料，其即便不調配粉末成分(制汗劑)，亦具有對制汗或除臭化妝料要求之使用時之清涼感及塗抹後之乾爽感。 [解決問題之技術手段] 本發明者等人為解決上述問題而反覆進行努力研究，結果發現先前護髮劑或造型劑所使用之醇中油型乳化組合物中，藉由將高聚合矽酮之調配量設為1質量%以下，即便不調配先前之制汗成分，亦能夠於塗抹於肌膚時賦予乾爽感，從而完成本發明。 即，本發明提供一種制汗或除臭化妝料，其包含醇/水中油型乳化組合物，上述醇/水中油型乳化組合物含有：(a)包含1質量%以下之高聚合矽酮之油分、(b)包含具有特定結構之聚醚改性矽酮之乳化劑、(c)50質量%以上之低級醇、及(d)水。 [發明之效果] 本發明由於未實質調配粉末成分，故而無須於使用前藉由搖晃而使粉末成分再分散，亦不產生塗抹後之肌膚之泛白。又，藉由設為上述構成，而無塗抹於肌膚時之黏膩，可於塗抹時及乾燥後獲得清涼感及乾爽感。又，藉由調配具有特定結構之聚醚改性矽酮作為乳化劑，而可將油分穩定地乳化於醇中，故而經時性穩定性亦優異，亦無調配成分析出而使噴霧容器發生堵塞之情況。[Problems to be Solved by the Invention] The object of the present invention is to obtain a powder-free cosmetic material which has a refreshing feeling when used without requiring powder ingredients (sweat-making agents) for use in making sweat or deodorizing cosmetics. And dry feeling after application. [Technical means to solve the problem] The present inventors have made repeated efforts to solve the above-mentioned problems, and as a result, have found that the alcohol-in-oil type emulsification composition previously used in hair conditioners or styling agents is formulated by blending highly polymerized silicone The amount is set to 1% by mass or less, and the present invention can be imparted with a dry feeling when applied to the skin even if the previous sweat-making ingredients are not blended. That is, the present invention provides a sweat-making or deodorizing cosmetic comprising an alcohol / oil-in-water emulsified composition, and the alcohol / oil-in-water emulsified composition contains: (a) 1% by mass or less of a highly polymerized silicone; The oil component, (b) an emulsifier containing polyether-modified silicone having a specific structure, (c) a lower alcohol of 50% by mass or more, and (d) water. [Effects of the Invention] Since the present invention does not substantially mix the powder component, it is not necessary to re-disperse the powder component by shaking before use, nor does it cause whitening of the skin after application. In addition, by adopting the above configuration, there is no stickiness when applied to the skin, and a cool feeling and a dry feeling can be obtained during application and after drying. In addition, by blending a polyether-modified silicone with a specific structure as an emulsifier, the oil can be stably emulsified in an alcohol, so it is also excellent in stability over time, and it is not formulated to analyze and cause a spray container to occur. Blocking situation.

其次，對構成本發明之化妝料之各成分進行詳細敍述。 ＜(a)包含高聚合矽酮之油分＞ 本發明中所使用之(a)包含高聚合矽酮之油分(以下，有時簡稱為「(a)成分」)係包含膠狀(例如30℃下之黏度約為1,000,000 mPa・s以上)之選自高聚合矽酮及胺基改性或銨改性高聚合矽酮之一種或兩種以上(亦有時稱為矽酮膠)的油分。 作為本發明中之高聚合矽酮，可例示下述通式(I)所表示之高聚合聚矽氧烷或高聚合聚二甲基矽氧烷醇。 [化1]

Figure TW201801711AD00001
式中，R1 表示甲基或苯基(其中，R1 不會全部為苯基)，R2 表示甲基或羥基。又，n表示3,000～20,000之整數。 作為本發明之胺基改性或銨改性高聚合矽酮(亦有時簡稱為胺基改性矽酮)，可例示下述通式(II)所表示者。 [化2]
Figure TW201801711AD00002
式中，R1 表示甲基或一部分為苯基，R2 與R3 相同或表示甲基或羥基。R3 表示式R4 Z{R4 表示具有3～6個碳原子之二價伸烷基，Z表示選自由-NR5 2 、-N+ R5 3 A- 、-NR5 (CH2 )a NR5 2 、-NR5 (CH2 )a N+ R5 3 A- 及-NR5 (CH2 )a N(R5 )C=O(R6 )(R5 表示氫或具有1～4個碳原子之烷基，R6 表示具有1～4個碳原子之烷基，A表示Cl、Br或I，a為2～6之整數)所組成之群中之一價基}所表示之具有胺基或銨基之取代基，m及n分別為正整數且m+n表示3,000～20,000之整數，n/m為1/500～1/10,000。 其中，較佳為胺基丙基甲基矽氧烷·二甲基矽氧烷共聚物(胺基丙基聚二甲基矽氧烷)。 本發明之化妝料中之高聚合矽酮(矽酮膠)之調配量必須以相對於化妝料總量之實際含量計為1.0質量%以下。若調配量超過1.0質量%，則於塗抹時產生黏膩，而且無法獲得乾燥後之清涼感。高聚合矽酮之調配量之下限值無特別限定，通常相對於化妝料總量為0.01質量%以上，較佳為0.05質量%以上，更佳為0.1質量%以上。即，高聚合矽酮(矽酮膠)之調配量以相對於化妝料總量之實際含量計為1.0質量%以下，較佳為0.01～1.0質量%，更佳為0.05～1.0質量%，最佳為0.1～1.0質量%。 作為本發明之(a)成分，可使用包含上述高聚合矽酮及油分之市售品。 作為包含上述通式(I)所表示之高聚合矽酮及油分之市售品，例如可列舉信越化學工業公司製造之二甲基矽酮油摻合物：例如KF-9008(高聚合聚二甲基矽氧烷20%與環五矽氧烷80%之混合物)、KF-9011(高聚合聚二甲基矽氧烷10%與環五矽氧烷90%之混合物)、KF-9013(高聚合聚二甲基矽氧烷15%與低黏度聚二甲基矽氧烷85%之混合物)、KF-9014(高聚合聚二甲基矽氧烷15%與環五矽氧烷85%之混合物)、MK-15H(高聚合聚二甲基矽氧烷20%與低黏度聚二甲基矽氧烷80%之混合物)、X-21-5495(高聚合聚二甲基矽氧烷15%與環五矽氧烷85%之混合物)、KF-9028(高聚合聚二甲基矽氧烷20%與環五矽氧烷80%之混合物)、KF-9030(高聚合聚二甲基矽氧烷20%與低黏度聚二甲基矽氧烷80%之混合物)，高聚合聚二甲基矽氧烷醇：例如X-21-5613(高聚合聚二甲基矽氧烷醇20%與低黏度聚二甲基矽氧烷80%之混合物)、X-21-5666(高聚合聚二甲基矽氧烷醇30%與環五矽氧烷70%之混合物)、X-21-5847(高聚合聚二甲基矽氧烷醇)、X-21-5849(高聚合聚二甲基矽氧烷醇)；Dow Corning Toray公司製造之高聚合二甲基矽酮：例如BY11-007(高聚合聚二甲基矽氧烷10%與聚二甲基矽氧烷90%之混合物)、BY11-014(高聚合聚二甲基矽氧烷15%與聚二甲基矽氧烷85%之混合物)、BY11-026(高聚合聚二甲基矽氧烷30%與聚二甲基矽氧烷70%之混合物)等。 作為包含上述通式(II)所表示之胺基改性高聚合矽酮及油分之市售品，例如可列舉信越化學工業公司製造之高聚合胺油摻合物(胺基膠)：例如KF-8017(胺基丙基聚二甲基矽氧烷10%與聚二甲基矽氧烷90%之混合物)、KF-8018(胺基丙基聚二甲基矽氧烷10%與環五矽氧烷90%之混合物)、KF-8020(胺基丙基聚二甲基矽氧烷20%與聚二甲基矽氧烷80%之混合物)等。 本發明之(a)成分中之高聚合矽酮以外之油分除上述市售品中所含之各種油分外，亦自包含制汗或除臭化妝料之皮膚化妝料中通常可使用之油分中選擇。例如可列舉液態石蠟、角鯊烷等烴油；酯油；萼梨油、棕櫚油、荷荷芭油等植物油；矽酮油等。 本發明之化妝料中之(a)成分之調配量無特別限定，通常相對於化妝料總量為0.1～30質量%，較佳為0.5～25質量%，更佳為0.5～20質量%。若(a)成分之調配量超過30質量%，則有乳化物之穩定性降低之情形。 ＜(b)聚醚改性矽酮＞ 本發明之特徵在於調配(b)包含一種或兩種以上具有特定結構之聚醚改性矽酮之乳化劑(以下，有時簡稱為「(b)成分」)。 本發明中所使用之聚醚改性矽酮((b)成分)係選自下述通式(III)所表示之聚醚改性矽酮之一種或兩種以上。 [化3]
Figure TW201801711AD00003
式中，R為甲基或苯基。A為通式：-C3 H6 O(C2 H4 O)a (C3 H6 O)b -R'(式中，R'為選自由氫原子、醯基及碳數1～4之烷基所組成之群中之基，又，a為5～50之整數，b為5～50之整數)所表示之聚氧伸烷基。作為R'之醯基，具體而言，可例示甲醯基、乙醯基、丙醯基、丁醯基、丙烯醯基、苯甲醯基、甲苯醯基等，作為碳數1～4之烷基，具體而言，可例示甲基、乙基、異丙基、正丙基、第三丁基、正丁基等。 再者，關於上述聚氧伸烷基，於a或b未達5之情形時，聚醚改性矽酮無法表現充分之界面活性效果，又，於a或b超過50之情形時，所獲得之組合物變得具有黏膩感。 聚氧伸烷基於分子中之含量無特別限定，較理想為聚氧伸烷基之含量於總分子量中超過20質量%者。其原因在於：在聚氧伸烷基之含量於總分子量中為20質量%以下之情形時，聚醚改性矽酮之增黏效果顯著降低。 又，m為50～1,000之整數，n為1～40之整數。其原因在於：在m未達50且n未達1之情形時，缺乏乳化穩定性，又，於m超過1,000且n超過40之情形時，所獲得之組合物產生黏膩感。又，m：n較佳為200：1～5：1，特佳為60：1～15：1。 本發明中所使用之聚醚改性矽酮之分子量無特別限定，又，黏度無特別限定，尤其就形成具有穩定性之乳液並具有乾爽感之方面而言，較理想為將聚醚改性矽酮製成八甲基四矽氧烷或異構石蠟之50質量%溶液時於25℃下之黏度為1,000～100,000 mPa・s之範圍。 作為本發明中所使用之聚醚改性矽酮，可使用市售品。作為市售品，例如可列舉Dow Corning Toray Silicone公司製造之BY11-030(包含50質量%之PEG/PPG-19/19聚二甲基矽氧烷及50質量%之環五矽氧烷；所謂PEG/PPG-19/19聚二甲基矽氧烷係指於上述通式中m=400、n=10、a=19、b=19之分子量55000之聚醚改性矽酮；HLB(Si)=7)、BY25-337(包含50質量%之PEG/PPG-19/19聚二甲基矽氧烷及50質量%之輕質液態異構石蠟(氫化聚異丁烯))等。 本發明中所使用之聚醚改性矽酮之調配量無特別限定，較佳為相對於化妝料總量以實際含量計為0.1～5.0質量%，較佳為0.3～4.0質量%，更佳為0.4～3.0質量%，最佳為0.5～2.5質量%。於本發明之組合物中，若聚醚改性矽酮之調配量以實際含量計未達0.1質量%，則難以進行穩定之乳化，又，若超過5.0質量%，則有組合物變得具有黏膩感之情形。 ＜(c)低級醇＞ 本發明中所使用之(c)低級醇(以下，有時簡稱為「(c)成分」)一般意指能夠於醫藥、化妝品領域等中使用之碳原子數1～6、較佳為碳原子數1～4之醇，具體而言，可列舉甲醇、乙醇、丙醇、丁醇、戊醇、己醇等，其中，可尤佳地使用乙醇。 再者，異丙醇、正丙醇、第三丁醇、第二丁醇等由於疏水性過強而難以乳化，故而較理想為與乙醇併用。 本發明中所使用之低級醇((c)成分)之調配量相對於化妝料總量為50質量%以上，較佳為60質量%以上。又，低級醇之調配量較佳為相對於組合物中之水之調配量為3倍以上(質量比)。若低級醇之量未達3倍，則難以充分獲得塗抹後之清涼感及乾爽感。 ＜(d)水＞ 本發明中之(d)水(以下，有時簡稱為「(d)成分」)之調配量相對於化妝料總量較佳為15質量%以下，更佳為12質量%以下。若水之調配量超過15質量%，則於塗抹時產生黏膩，從而無法獲得乾爽感。 本發明之制汗劑化妝料藉由如上所述調配(a)～(d)成分，而成為穩定性較高之醇/水中油型乳化組合物，即便不調配先前之制汗成分(粉末成分)亦可獲得使用時之清涼感及乾爽感。該效果係無法從先前技術預測之令人震驚之效果，但該事實並不意味著排除於本發明之化妝料中進而調配先前之制汗劑化妝料中所調配之制汗成分、抗菌劑、防臭成分。但，其調配量限於無損本發明之效果之範圍內。 作為可調配之制汗成分，例如可列舉對苯酚磺酸鋅(磺基石碳酸鋅)、檸檬酸、各種鋁化合物等收斂、制汗劑；三氯沙、氯化苄烷銨、苄索氯銨、鹽酸洛赫西定、葡萄糖酸洛赫西定、鹵卡班等抗菌劑；氧化鋅、類黃酮、葉綠素等除臭劑；薄荷腦、乳酸䓝酯等冷感劑；各種掩蔽劑等。 本發明之制汗或除臭化妝料中除上述制汗成分外，亦可於無損本發明之效果之範圍內調配化妝料中通常可調配之其他成分，例如保濕劑、防腐劑、香料、螯合劑、抗氧化劑、紫外線吸收劑、凝膠化劑、增黏劑等。 本發明之制汗或除臭化妝料之製品形態無特別限制，例如可以制汗劑、身體乳液、化妝水、美容液等形態提供。本發明之化妝料由於可不調配粉末狀之制汗成分，故而尤其適合以收容於分配器等噴霧容器之噴霧用或與噴射劑一併收容之噴射用之形態提供，不會發生噴嘴之堵塞。 實施例 以下，列舉實施例對本發明進行更具體之說明，但本發明並不受該等限定。再者，只要無特別說明，則調配量表示相對於總量之質量%。 製備本發明之制汗/除臭化妝料，並對使用感進行評價。 (實施例1～16及比較例1～3) 實施例1～16及比較例1～3中所示之化妝料係藉由將以下表1～3中所示之成分中之除離子交換水及氯化苄烷銨液以外之成分均勻地溶解並利用攪拌處理而乳化後，添加離子交換水及氯化苄烷銨液而製備。 (比較例4～6) 比較例4～6中所示之化妝料係藉由將含有低級醇之水相成分及粉末成分混合，其次利用攪拌處理使溶解有界面活性劑之油相成分乳化而製備。 將藉由上述方法而製備之化妝料樣品塗抹於10名專業官能檢查員，基於以下評分及評價基準對塗抹後之黏膩之有無、塗抹時之清涼感、塗抹乾燥後之清涼感、乾爽感進行評價。 +3分：非常良好。 +2分：良好。 +1分：略良好。 0分：普通。 -1分：略差。 -2分：差。 -3分：非常差。 基於上述評分之平均分，依據以下評價基準進行判定。 A：平均分為+2分以上。 B：平均分為+1分以上且未達+2分。 C：平均分為0分以上且未達+1分。 D：平均分為-1分以上且未達0分。 E：平均分為-2分以上且未達-1分。 F：平均分未達-2分。 [表1]
Figure TW201801711AD00004
 [表2]
Figure TW201801711AD00005
 [表3]
Figure TW201801711AD00006
 根據表1及表2之結果，可知本發明之制汗劑化妝料即便不調配為了獲得清涼感及乾爽感而通常調配於制汗劑中之粉末成分，亦無塗抹時之黏膩，且於乾燥後亦可獲得清涼感及乾爽感。 另一方面，如表3之結果所示，於以矽酮膠實際含量計超過1質量%調配高聚合矽酮之情形時(比較例1及比較例2)，在塗抹時產生黏膩，且無法獲得充分之清涼感。又，於將低級醇之調配量設為未達50質量之情形時(比較例3)，在塗抹時產生黏膩，而無法獲得乾爽感。 又，如表1及表2所示，本案發明係藉由(a)成分及(b)成分而可獲得清涼感及乾爽感者。於調配先前為了獲得清涼感及乾爽感而調配之粉末成分代替本案發明之(a)及(b)成分之情形時(比較例4～6)，即便將乙醇含量自50質量%增加至80質量%，亦無法獲得作為制汗劑之良好之使用感。又，即便將粉末成分與制汗成分(氯化羥鋁)組合(比較例6)，亦於塗抹時產生黏膩，而無法獲得乾爽感。 其次，製備本發明之乳化物，對溫度不同之環境下之經時性穩定性進行評價。 具體而言，藉由與上述實施例同樣之方法製備具有下述表4中所列舉之組成的乳化物，將所製備之各乳化物於0℃、室溫、50℃下放置4週後，基於以下基準並藉由目視觀察進行穩定性之評價。將結果示於表4。 ＜評價基準＞ A：無變化。 B：產生少許乳油上浮。 C：產生顯著之乳油上浮。 D：分離。 [表4]
Figure TW201801711AD00007
 如表4之結果所示，任一乳化物均具有良好之乳化穩定性。Next, each component constituting the cosmetic of the present invention will be described in detail. <(A) Oil component containing high-polymerized silicone> (a) The oil component containing high-polymerized silicone (hereinafter, sometimes referred to as "(a) component") is gelatinous (for example, 30 ° C) The viscosity below 1,000,000 mPa · s or more) is selected from one or two or more (also sometimes referred to as silicone rubber) oils selected from the group consisting of highly polymerized silicone and amine-modified or ammonium-modified high polymer silicone. Examples of the high-polymerized silicone in the present invention include a high-polymerized polysiloxane and a high-polymerized polydimethylsiloxane represented by the following general formula (I). [Chemical 1]
Figure TW201801711AD00001
In the formula, R 1 represents a methyl group or a phenyl group (wherein R 1 is not all phenyl groups), and R 2 represents a methyl group or a hydroxyl group. In addition, n represents an integer of 3,000 to 20,000. Examples of the amine-modified or ammonium-modified high-polymerized silicone of the present invention (also sometimes referred to simply as amine-modified silicone) include those represented by the following general formula (II). [Chemical 2]
Figure TW201801711AD00002
In the formula, R 1 represents a methyl group or a part thereof is a phenyl group, and R 2 is the same as R 3 or represents a methyl group or a hydroxyl group. Represented by the formula R 3 R 4 Z {R 4 represents a divalent 3-6 carbon atoms alkylene group, Z represents a selected from the group consisting of -NR 5 2, -N + R 5 3 A -, -NR 5 (CH 2) a NR 5 2 , -NR 5 (CH 2 ) a N + R 5 3 A - and -NR 5 (CH 2 ) a N (R 5 ) C = O (R 6 ) (R 5 represents hydrogen or has 1 ～ An alkyl group of 4 carbon atoms, R 6 represents an alkyl group of 1 to 4 carbon atoms, A represents Cl, Br or I, and a is an integer of 2 to 6) is represented by a valence group} A substituent having an amine group or an ammonium group, m and n are positive integers respectively, m + n represents an integer of 3,000 to 20,000, and n / m is 1/500 to 1 / 10,000. Among them, an aminopropylmethylsiloxane / dimethylsiloxane copolymer (aminopropylpolydimethylsiloxane) is preferred. The compounding amount of the highly polymerized silicone (silicone gum) in the cosmetic of the present invention must be 1.0% by mass or less based on the actual content relative to the total amount of the cosmetic. If the blending amount exceeds 1.0% by mass, stickiness is generated during application, and a cool feeling after drying cannot be obtained. The lower limit of the blending amount of the high-polymerized silicone is not particularly limited, but it is usually 0.01 mass% or more, preferably 0.05 mass% or more, and more preferably 0.1 mass% or more with respect to the total amount of the cosmetic. That is, the blending amount of the highly polymerized silicone (silicone gum) is 1.0% by mass or less, preferably 0.01 to 1.0% by mass, and more preferably 0.05 to 1.0% by mass based on the actual content of the total amount of the cosmetic. It is preferably 0.1 to 1.0% by mass. As the (a) component of the present invention, a commercially available product containing the above-mentioned highly polymerized silicone and an oil component can be used. Examples of commercially available products containing the highly polymerized silicone and oil component represented by the general formula (I) include a dimethyl silicone oil blend manufactured by Shin-Etsu Chemical Industry Co., Ltd .: for example, KF-9008 Mixture of 20% of methylsiloxane and 80% of cyclopentasiloxane), KF-9011 (mixture of 10% of high polymer polydimethylsiloxane and 90% of cyclopentasiloxane), KF-9013 ( Mixture of 15% of high polymer polydimethylsiloxane and 85% of low viscosity polydimethylsiloxane), KF-9014 (15% of high polymer polydimethylsiloxane and 85% cyclopentasiloxane) Mixture), MK-15H (mixture of 20% of high polymer polydimethylsiloxane and 80% of low viscosity polydimethylsiloxane), X-21-5495 (high polymer polydimethylsiloxane 15% mixture with cyclopentasiloxane 85%), KF-9028 (mixture of 20% high polymer polydimethylsiloxane and 80% cyclopentasiloxane), KF-9030 (high polymer polydimethylsiloxane Mixture of 20% polysiloxane and low viscosity polydimethylsiloxane (80%), high polymer polydimethylsiloxane: for example X-21-5613 (high polymer polydimethylsiloxane Mixture of 20% and low viscosity polydimethylsiloxane (80%), X-21-5666 (high polymer polydimethylsiloxane Mixture of 30% siloxyalkanol and 70% cyclopentasiloxane; X-21-5847 (high polymer polydimethylsiloxane), X-21-5849 (high polymer polydimethylsiloxane) Oxyalkanol); Highly polymerized dimethyl silicone manufactured by Dow Corning Toray: for example, BY11-007 (mixture of 10% of high polymerized polydimethylsiloxane and 90% of polydimethylsiloxane), BY11 -014 (mixture of 15% high polymer polydimethylsiloxane and 85% polydimethylsiloxane), BY11-026 (30% high polymer polydimethylsiloxane and polydimethylsiloxane 70% mixture of alkanes) and so on. As a commercially available product containing the amine-modified high-polymerized silicone represented by the general formula (II) and an oil component, for example, a high-polymer amine oil blend (amine-based rubber) manufactured by Shin-Etsu Chemical Industry Co., Ltd. may be mentioned: for example, KF -8017 (mixture of 10% of aminopropyl polydimethylsiloxane and 90% of polydimethylsiloxane), KF-8018 (10% of aminopropyl polydimethylsiloxane and cyclopentane 90% mixture of silicone), KF-8020 (20% mixture of aminopropyl polydimethylsiloxane and 80% polydimethylsiloxane), etc. The oils other than the highly polymerized silicone in the component (a) of the present invention are in addition to various oils contained in the above-mentioned commercially available products, and are also included in oils generally used in skin cosmetics containing sweat-making or deodorizing cosmetics. select. Examples thereof include hydrocarbon oils such as liquid paraffin and squalane; ester oils; vegetable oils such as argan oil, palm oil, jojoba oil; and silicone oils. The compounding amount of the component (a) in the cosmetic of the present invention is not particularly limited, but is generally 0.1 to 30% by mass, preferably 0.5 to 25% by mass, and more preferably 0.5 to 20% by mass with respect to the total amount of the cosmetic. When the compounding quantity of (a) component exceeds 30 mass%, the stability of an emulsion may fall. <(B) Polyether-modified silicone> The present invention is characterized by blending (b) an emulsifier containing one or two or more polyether-modified silicones having a specific structure (hereinafter, sometimes referred to as "(b) ingredient"). The polyether-modified silicone (component (b)) used in the present invention is one or two or more selected from the polyether-modified silicones represented by the following general formula (III). [Chemical 3]
Figure TW201801711AD00003
In the formula, R is methyl or phenyl. A is a general formula: -C 3 H 6 O (C 2 H 4 O) a (C 3 H 6 O) b -R '(where R' is selected from the group consisting of a hydrogen atom, a fluorenyl group, and a carbon number of 1 to 4 The group in the group consisting of an alkyl group is a polyoxyalkylene group represented by a in the range of 5 to 50 and b in the range of 5 to 50). Specific examples of the fluorenyl group of R ′ include methyl fluorenyl, ethyl fluorenyl, propyl fluorenyl, butyl fluorenyl, acryl fluorenyl, benzyl fluorenyl, tolyl fluorenyl, etc., and alkyl groups having 1 to 4 carbon atoms Specific examples include methyl, ethyl, isopropyl, n-propyl, third butyl, and n-butyl. Furthermore, regarding the above-mentioned polyoxyalkylene, when a or b is less than 5, polyether-modified silicone cannot exhibit a sufficient interfacial activity effect, and when a or b exceeds 50, the obtained The composition became sticky. The content of polyoxyalkylene in the molecule is not particularly limited, and it is more preferable that the content of polyoxyalkylene exceeds 20% by mass in the total molecular weight. The reason is that when the content of polyoxyalkylene is 20% by mass or less in the total molecular weight, the viscosity-increasing effect of the polyether-modified silicone is significantly reduced. In addition, m is an integer of 50 to 1,000, and n is an integer of 1 to 40. The reason is that when m is less than 50 and n is less than 1, emulsification stability is lacking, and when m is more than 1,000 and n is more than 40, the obtained composition has a sticky feeling. In addition, m: n is preferably 200: 1 to 5: 1, and particularly preferably 60: 1 to 15: 1. The molecular weight of the polyether-modified silicone used in the present invention is not particularly limited, and the viscosity is not particularly limited. In terms of forming a stable emulsion and having a dry feeling, it is desirable to modify the polyether. When silicone is used as a 50% by mass solution of octamethyltetrasiloxane or isoparaffin, the viscosity at 25 ° C is in the range of 1,000 to 100,000 mPa · s. As the polyether-modified silicone used in the present invention, a commercially available product can be used. Examples of commercially available products include BY11-030 (containing 50% by mass of PEG / PPG-19 / 19 polydimethylsiloxane and 50% by mass of cyclopentasiloxane; manufactured by Dow Corning Toray Silicone; so-called PEG / PPG-19 / 19 polydimethylsiloxane refers to a polyether-modified silicone with a molecular weight of 55,000 in the above formula, m = 400, n = 10, a = 19, b = 19; HLB (Si ) = 7), BY25-337 (including 50% by mass of PEG / PPG-19 / 19 polydimethylsiloxane and 50% by mass of light liquid isoparaffin (hydrogenated polyisobutylene)) and the like. The blending amount of the polyether-modified silicone used in the present invention is not particularly limited, and it is preferably 0.1 to 5.0% by mass, more preferably 0.3 to 4.0% by mass, and more preferably relative to the total amount of the cosmetic. It is 0.4 to 3.0% by mass, and most preferably 0.5 to 2.5% by mass. In the composition of the present invention, if the blending amount of the polyether-modified silicone is less than 0.1% by mass based on the actual content, it is difficult to perform stable emulsification, and if it exceeds 5.0% by mass, the composition becomes The case of stickiness. <(C) Lower alcohol> The (c) lower alcohol (hereinafter, sometimes simply referred to as "(c) component") used in the present invention generally means that the number of carbon atoms that can be used in the fields of medicine and cosmetics is 1 to 6. An alcohol having 1 to 4 carbon atoms is preferred, and specifically, methanol, ethanol, propanol, butanol, pentanol, hexanol, and the like can be mentioned. Among them, ethanol can be particularly preferably used. Furthermore, isopropyl alcohol, n-propanol, third butanol, second butanol, etc. are too hydrophobic and difficult to emulsify. Therefore, it is preferable to use them in combination with ethanol. The blending amount of the lower alcohol ((c) component) used in the present invention is 50% by mass or more, and preferably 60% by mass or more, relative to the total amount of the cosmetic. The blending amount of the lower alcohol is preferably 3 times or more (mass ratio) with respect to the blending amount of water in the composition. If the amount of the lower alcohol is less than 3 times, it is difficult to sufficiently obtain a cool feeling and a dry feeling after application. <(D) water> The blending amount of (d) water (hereinafter sometimes referred to as "(d) component") in the present invention is preferably 15% by mass or less, more preferably 12% by mass, relative to the total amount of the cosmetic. %the following. If the blending amount of water exceeds 15% by mass, stickiness occurs during application, and a dry feeling cannot be obtained. The sweat-making cosmetic material of the present invention is formulated into an alcohol / oil-in-water emulsified composition with higher stability by blending the components (a) to (d) as described above, even if the previous sweat-making component (powder component is not blended). ) You can also get a cool and dry feeling when using. This effect is a shocking effect that cannot be predicted from the prior art, but this fact does not mean that it is excluded from the cosmetics of the present invention and then the sweat-producing ingredients, antibacterial agents, Deodorant composition. However, the blending amount is limited to the range that does not impair the effect of the present invention. Examples of the sweat-producing ingredients that can be blended include, for example, zinc p-phenol sulfonate (zinc sulfocarbonate), citric acid, and various aluminum compounds, such as astringent and sweat-producing agents; triclosan, benzyl ammonium chloride, and benzethonium chloride , Antibacterial agents such as lochsetin hydrochloride, lochsetin gluconate, and halobamban; deodorants such as zinc oxide, flavonoids, and chlorophyll; cooling agents such as menthol and lactate; and various masking agents. In addition to the above-mentioned sweat-making ingredients, the sweat-making or deodorizing cosmetic materials of the present invention can also be formulated with other ingredients usually adjusted in the cosmetic materials within a range that does not impair the effect of the present invention, such as moisturizers, preservatives, fragrances, chelate Mixtures, antioxidants, UV absorbers, gelling agents, tackifiers, etc. The form of the sweat-making or deodorizing cosmetic product of the present invention is not particularly limited, and may be provided in the form of a sweat-making agent, a body lotion, a lotion, a cosmetic lotion, and the like. Since the cosmetic material of the present invention does not need to mix powdery sweat-making ingredients, it is particularly suitable to be provided in the form of spray for storage in a spray container such as a dispenser or spray for storage with a spray agent without clogging of the nozzle. EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited thereto. In addition, unless otherwise stated, the blended amount represents the mass% relative to the total amount. A sweat-making / deodorizing cosmetic of the present invention was prepared and evaluated for use. (Examples 1 to 16 and Comparative Examples 1 to 3) The cosmetics shown in Examples 1 to 16 and Comparative Examples 1 to 3 were obtained by deionizing water in the components shown in Tables 1 to 3 below. After the components other than the benzyl ammonium chloride solution are uniformly dissolved and emulsified by the stirring treatment, ion exchange water and the benzyl ammonium chloride solution are added to prepare it. (Comparative Examples 4 to 6) The cosmetic materials shown in Comparative Examples 4 to 6 were obtained by mixing a water phase component containing a lower alcohol and a powder component, and then emulsifying the oil phase component in which the surfactant was dissolved by stirring. preparation. The cosmetic samples prepared by the above method were applied to 10 professional functional inspectors. Based on the following ratings and evaluation criteria, the presence or absence of stickiness after application, the cooling sensation during application, the cooling sensation after application, and the dry feeling Evaluate. +3 points: Very good. +2 points: Good. +1 point: Slightly good. 0 points: Normal. -1 point: Slightly worse. -2 points: Poor. -3 points: Very poor. Based on the average score of the above scores, judgments were made based on the following evaluation criteria. A: The average score is +2 or more. B: The average score is +1 or more and less than +2. C: The average score is 0 or more and less than +1. D: The average score is -1 or more and less than 0. E: The average score is -2 points or more and less than -1 points. F: The average score is less than -2 points. [Table 1]
Figure TW201801711AD00004
 [Table 2]
Figure TW201801711AD00005
 [table 3]
Figure TW201801711AD00006
 According to the results of Tables 1 and 2, it can be seen that even if the powdery ingredients usually formulated in the sweat-generating agent of the present invention for the sweat-making cosmetic material are not blended to obtain a cool and dry feeling, there is no stickiness during application and You can also get a cool and dry feeling after drying. On the other hand, as shown in the results of Table 3, when the highly polymerized silicone was blended in excess of 1% by mass based on the actual content of the silicone rubber (Comparative Examples 1 and 2), stickiness occurred during application, and Unable to obtain a sufficient cooling sensation. Moreover, when the compounding quantity of a lower alcohol is less than 50 masses (comparative example 3), it becomes sticky at the time of application, and a dry feeling cannot be obtained. As shown in Tables 1 and 2, the present invention is one in which a cool feeling and a dry feeling can be obtained by using the components (a) and (b). In the case where a powder component previously prepared to obtain a cool feeling and a dry feeling is substituted for the components (a) and (b) of the present invention (Comparative Examples 4 to 6), even if the ethanol content is increased from 50% to 80% %, It is also impossible to obtain a good feeling of use as a sweat suppressant. In addition, even if a powder component was combined with a sweat-producing component (aluminum hydroxychloride) (Comparative Example 6), stickiness occurred during application, and a dry feeling could not be obtained. Next, the emulsion of the present invention is prepared, and the stability over time of the environment with different temperatures is evaluated. Specifically, an emulsion having the composition listed in Table 4 below was prepared by the same method as the above-mentioned Example, and each prepared emulsion was left at 0 ° C, room temperature, and 50 ° C for 4 weeks. The stability was evaluated by visual observation based on the following criteria. The results are shown in Table 4. <Evaluation criteria> A: No change. B: A little creamer floats. C: Significant creamer rise. D: separation. [Table 4]
Figure TW201801711AD00007
 As shown in the results of Table 4, each of the emulsions had good emulsification stability.

無no

Claims (4)

一種制汗或除臭化妝料，其特徵在於包含醇/水中油型乳化組合物，上述醇/水中油型乳化組合物含有： (a)包含1質量%以下之高聚合矽酮之油分、 (b)包含一種或兩種以上之下述通式(III)：
Figure TW201801711AC00001
[其中，式中A為通式：-C3 H6 O(C2 H4 O)a (C3 H6 O)b -R'(式中，R'為選自由氫原子、醯基及碳數1～4之烷基所組成之群中之基，又，a為5～50之整數，b為5～50之整數)所表示之聚氧伸烷基，R為甲基或苯基，又，m為50～1,000之整數，n為1～40之整數] 所表示之聚醚改性矽酮之乳化劑、 (c)50質量%以上之低級醇、及 (d)水。A sweat-making or deodorizing cosmetic material, comprising an alcohol / oil-in-water emulsified composition, the alcohol / oil-in-water emulsified composition contains: b) contains one or two or more of the following general formula (III):
Figure TW201801711AC00001
[Wherein A is a general formula: -C 3 H 6 O (C 2 H 4 O) a (C 3 H 6 O) b -R '(wherein R' is selected from the group consisting of a hydrogen atom, a fluorenyl group, and A group in a group consisting of an alkyl group having 1 to 4 carbon atoms, and a is an integer of 5 to 50 and b is an integer of 5 to 50), and R is a methyl group or a phenyl group In addition, m is an integer of 50 to 1,000, n is an integer of 1 to 40], an emulsifier of polyether-modified silicone represented by (c) a lower alcohol of 50% by mass or more, and (d) water. 如請求項1之制汗或除臭化妝料，其中上述(c)低級醇之調配量為上述(d)水之調配量之3倍以上。For example, the sweat-making or deodorizing cosmetic according to claim 1, wherein the compounding amount of the lower alcohol (c) is more than three times the compounding amount of the water (d). 如請求項1或2之制汗或除臭化妝料，其進而含有制汗成分。The sweat-making or deodorizing cosmetic according to claim 1 or 2, further comprising a sweat-making ingredient. 一種噴霧型制汗或除臭化妝料，其係將如請求項1之化妝料填充至分配器型容器而成。A spray-type sweat-making or deodorizing cosmetic material is prepared by filling a dispenser-type container with the cosmetic material according to claim 1.
TW106118491A 2016-06-10 2017-06-05 Antiperspirant or deodorant cosmetic TW201801711A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP??2016-116600 2016-06-10
JP2016116600A JP6692703B2 (en) 2016-06-10 2016-06-10 Antiperspirant or deodorant cosmetics

Publications (1)

Publication Number Publication Date
TW201801711A true TW201801711A (en) 2018-01-16

Family

ID=60579021

Family Applications (1)

Application Number Title Priority Date Filing Date
TW106118491A TW201801711A (en) 2016-06-10 2017-06-05 Antiperspirant or deodorant cosmetic

Country Status (6)

Country Link
JP (1) JP6692703B2 (en)
KR (1) KR20190016951A (en)
CN (1) CN109310617B (en)
SG (1) SG11201809819QA (en)
TW (1) TW201801711A (en)
WO (1) WO2017212973A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112752565A (en) * 2018-09-28 2021-05-04 花王株式会社 External preparation composition
JP7240857B2 (en) * 2018-11-15 2023-03-16 ポーラ化成工業株式会社 Water-in-oil emulsion composition

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1030698A (en) * 1987-06-27 1989-02-01 贺曼萍 The compound method that axil reveals
US4985238A (en) * 1989-03-14 1991-01-15 The Procter & Gamble Company Low residue antiperspirant sticks
GB8914905D0 (en) * 1989-06-29 1989-08-23 Unilever Plc Cosmetic composition
JPH05229925A (en) * 1992-02-19 1993-09-07 Shiseido Co Ltd Liquid antiperspirant composition
KR100406345B1 (en) 1995-07-12 2004-02-18 가부시키가이샤 시세이도 Oil-in-alcohol emulsion composition
JP4949550B2 (en) * 2000-12-11 2012-06-13 信越化学工業株式会社 Cosmetics
JP4266926B2 (en) * 2002-10-21 2009-05-27 ロレアル Method for dissolving lipophilic compound in aqueous solution using amphiphilic block copolymer, and cosmetic composition
EP1708674B1 (en) * 2004-01-30 2014-01-22 The Procter and Gamble Company Antiperspirant aerosol composition
FR2916633B1 (en) * 2007-05-29 2009-08-28 Chanel Parfums Beaute Sas Unip COSMETIC USE OF AN ACTIVE ACTIVE TO STIMULATE THE EXPRESSION OF TENSIN 1
US9238786B2 (en) * 2011-05-04 2016-01-19 Shiseido Company, Ltd. Translucent fragrance composition
JP6369887B2 (en) * 2011-12-27 2018-08-08 東レ・ダウコーニング株式会社 Novel co-modified organopolysiloxane, treatment agent containing the same, and external preparation
JP6063197B2 (en) * 2012-10-02 2017-01-18 東レ・ダウコーニング株式会社 Novel co-modified organopolysiloxane, powder treating agent and powder composition containing the same
JP6452396B2 (en) * 2013-11-14 2019-01-16 ライオン株式会社 Antiperspirant composition
CN106102700B (en) * 2014-09-30 2018-11-16 株式会社漫丹 Emulsify deodorant compositions and deodorant

Also Published As

Publication number Publication date
JP6692703B2 (en) 2020-05-13
JP2017218440A (en) 2017-12-14
WO2017212973A1 (en) 2017-12-14
KR20190016951A (en) 2019-02-19
CN109310617B (en) 2021-10-12
CN109310617A (en) 2019-02-05
SG11201809819QA (en) 2018-12-28

Similar Documents

Publication Publication Date Title
US6221927B1 (en) Polar solvent-in-oil emulsions and multiple emulsions
JP2582275B2 (en) Silicone gel composition and cosmetic containing the same
JP5457034B2 (en) Swellable silicone composition and preparation method thereof
JP4954308B2 (en) Hair cosmetics
WO2011065101A1 (en) Lip cosmetic
JP2007532644A (en) Low molecular weight silicone oil emulsion in water
TWI705830B (en) Anhydrous powder type cosmetic composition
JP6486384B2 (en) Novel silicone surfactants, water-in-oil emulsion compositions, powder compositions, and their cosmetic / medical applications
KR101976102B1 (en) Cosmetic composition in the form of high internal phase water in silicone formulation with excellent stability
KR102260054B1 (en) Emulsified cosmetic composition comprising amphiphilic clay mineral
JP5697150B2 (en) Silicone emulsion
JP2017066068A (en) Fine emulsion-type cosmetic and method for producing the same
TW201801711A (en) Antiperspirant or deodorant cosmetic
JPH086035B2 (en) Silicone gel composition and cosmetics containing the same
CN106102700B (en) Emulsify deodorant compositions and deodorant
JP2001002925A (en) Water-in-oil type emulsion cosmetic having high inner water phase content
JP2018104358A (en) Oil-in-water type silicone emulsion composition
KR101219645B1 (en) Non-aqueous wax-type hair cosmetic composition
JP3605746B2 (en) Acne cosmetics
JPH08299783A (en) Emulsified composition
JP2019210227A (en) Water-in-oil emulsion composition
JP2004307371A (en) Water-in-oil emulsion cosmetic agent with large internal aqueous phase
EP3030223B1 (en) A soft solid antiperspirant deodorant composition
JP4000024B2 (en) Water-in-oil emulsified cosmetic
WO2020034134A1 (en) An oily composition