CN106102700B - Emulsify deodorant compositions and deodorant - Google Patents
Emulsify deodorant compositions and deodorant Download PDFInfo
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- CN106102700B CN106102700B CN201580013148.1A CN201580013148A CN106102700B CN 106102700 B CN106102700 B CN 106102700B CN 201580013148 A CN201580013148 A CN 201580013148A CN 106102700 B CN106102700 B CN 106102700B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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Abstract
The present invention provides a kind of deodorant for emulsifying deodorant compositions and having above-mentioned emulsification deodorant compositions, which can be dramatically improved fungicide in the survivability of coating object after coating.Emulsification deodorant compositions of the invention are characterized in that it includes ingredient A：Polyether modified silicone；Ingredient B：Dimethicone/Vinyl Dimethicone cross-linked polymer；Ingredient C：Palmitinic acid 2- ethylhexyl；Ingredient D：Antiperspirant；Ingredient E：Fungicide；With ingredient F：Water.In addition, deodorant of the invention is characterized in that, have container and above-mentioned emulsification deodorant compositions, above-mentioned emulsification deodorant compositions are filled in said vesse.
Description
Technical field
The present invention relates to the emulsification deodorant compositions comprising antiperspirant and fungicide.It is removed in addition, being related to having above-mentioned emulsification
The deodorant of smelly composition.
Background technique
The underarm odor for bringing undesirable feeling is since sweat is mixed with sebum and is often occupied caused by bacterium decomposition by skin.
In the past, the undesirable underarm odor in order to prevent, has used deodorant compositions.Known above-mentioned deodorant compositions have gel (gel),
The various types such as emulsifiable paste (cream), toner (lotion), aerosol spray (spray), spray (mist) and club
(referring for example to Patent Documents 1 to 3).Wherein, there is the adaptation with skin as the deodorant compositions of the emulsification preparations such as emulsifiable paste
It is good, sagging (vertical れ) does not occur and disperses and (waves and dissipate り) etc., the advantages that usability is good.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2003-183144 bulletin
Patent document 2：Japanese Unexamined Patent Publication 2004-018513 bulletin
Patent document 3：Japanese Unexamined Patent Publication 2006-028084 bulletin
Summary of the invention
Subject to be solved by the invention
But existing deodorant compositions deposit the problem long lasting for property deficiency of body odor inhibitory effect after use.
About its reason, it is believed that be：After coating, deodorant compositions flow down because of sweat etc., and the skin of the fungicide in composition is residual
Sustainability reduces.
Therefore, it the purpose of the present invention is to provide a kind of emulsification deodorant compositions, can mention tremendously after coating
Survivability of the high fungicide in coating object.
Solution for solving the problem
Present inventor has performed further investigations, as a result, it has been found that, by by polyether modified silicone, dimethyl silicone polymer/second
Alkenyl Dimethicone Crosspolymer, palmitinic acid 2- ethylhexyl, antiperspirant, fungicide and water carry out mixture, thus
The excellent emulsification deodorant compositions that the survivability for improving fungicide tremendously in coating object can be obtained, are thus completed
The present invention.
That is, the present invention provides a kind of emulsification deodorant compositions, it includes：Ingredient (A)：Polyether modified silicone；Ingredient (B)：
Dimethicone/Vinyl Dimethicone cross-linked polymer；Ingredient (C)：Palmitinic acid 2- ethylhexyl；Ingredient
(D)：Antiperspirant；Ingredient (E)：Fungicide；With ingredient (F)：Water.
Mentioned component (A) is preferably the polyether modified silicone with branched silicone chain.
Mentioned component (A) is preferably PEG-9 Polydimethylsiloxyethyl Dimethicone.
Mentioned component (D) is preferably selected from the antiperspirant in the group being made of chlorination hydroxyl aluminium, P-phenol zinc sulfonate and alum.
Mentioned component (E) is preferably selected from by isopropyl methyl phenol, benzalkonium chloride, hinokitol, triclosan and salicylic acid
Fungicide in the group of composition.
Above-mentioned emulsification deodorant compositions are preferably emulsifiable paste shape.
In addition, the present invention provides a kind of deodorant, have container and above-mentioned emulsification deodorant compositions, above-mentioned emulsification deodorization
Composition is filled in said vesse.
Above-mentioned deodorant is preferably non-aerosol preparation.
The effect of invention
Emulsification deodorant compositions of the invention are due to above-mentioned composition, thus the fungicide for including in composition is being coated with
Object through when survivability improve.Therefore, the body odor inhibitory effect of emulsification deodorant of the invention is excellent long lasting for property
It is different.
In addition, emulsification deodorant compositions of the invention when in use tacky few, use feeling is also excellent.
Specific embodiment
Emulsification deodorant compositions of the invention contain polyether modified silicone, dimethyl silicone polymer/vinylpolydimethyl
Dimethicone Crosspolymer, palmitinic acid 2- ethylhexyl, antiperspirant, fungicide and water are as neccessary composition.In addition, of the invention
Emulsification deodorant compositions can also contain other ingredients.
It should be noted that above-mentioned polyether modified silicone is known as " ingredient (A) " sometimes in this specification；It sometimes will be upper
It states Dimethicone/Vinyl Dimethicone cross-linked polymer and is known as " ingredient (B) "；Sometimes by above-mentioned palmitinic acid
2- ethylhexyl is known as " ingredient (C) "；Sometimes above-mentioned antiperspirant is known as " ingredient (D) "；Sometimes by above-mentioned fungicide be known as " at
Divide (E) "；Sometimes above-mentioned water is known as " ingredient (F) ".
Each ingredient, i.e. ingredient (the A)~ingredient (F) for including in emulsification deodorant compositions of the invention and other ingredients difference
It may be used alone or in combination of two or more.
[ingredient (A)：Polyether modified silicone]
Mentioned component (A) is the silicone compounds comprising siloxane backbone (silicone chains) and polyether-based (polyether chain).Ingredient
It (A) can be the silicone compounds of block copolymer type or terminal-modified type comprising polyether chain and silicone chains in main chain；It can also
Think the side chain as siloxane backbone and is bonded with the silicone compounds of the modified side chain type of polyether-based.Wherein, from composition
Emulsion stability in terms of set out, preferably there is in the side chain of siloxane backbone and/or end the silicone compound of polyether-based
Object more preferably has the silicone compounds of polyether-based in side chain.Ingredient (A) can be used only a kind, also can be used 2 kinds with
On.
It as above-mentioned siloxane backbone (silicone chains), is not particularly limited, for example, dimethyl polysiloxane is (poly-
Dimethyl siloxane), methyl phenyl silicone, methylhydrogenpolysi,oxane etc..Wherein, preferably dimethyl polysiloxane.
It as above-mentioned polyether-based (polyether chain), is not particularly limited, for example, polyoxyethylene groups, polyoxypropylene
Base, polybutylene base etc..It is wherein preferably polyoxyethylene groups.Oxyalkylene (for example, ethylene oxide) in ingredient (A) is averaged
Addition molal quantity is not particularly limited, and preferably 5~30, more preferably 8~20.
The HLB of ingredient (A) is not particularly limited, from the emulsion stability aspect of composition, preferably 3.5~
9.0,4.0~8.0 are more preferably.
Wherein, from improve composition emulsion stability in terms of and inhibit through when fouling from the aspect of, ingredient (A)
Preferably with the polyether modified silicone of branched silicone chain, more preferably there is the polyethers of polyether chain in the side chain of branched silicone chain
Modified silicone.There is the polyether modified silicone of polyether chain as the above-mentioned side chain in branched silicone chain, for example, PEG-9
Polydimethylsiloxanes ethyl dimethyl silicone polymer.Above-mentioned PEG-9 Polydimethylsiloxyethyl Dimethicone be with
INCI (international cosmetic raw material dictionary and handbook (International Cosmetic Ingredient Dictionary
And Handbook), the 15th edition, volume 2, personal care product association of the U.S. (Personal Care Products
), Council 2014, p.2473)：The compound that PEG-9POLYDIMETHYLSILOXYETHYL DIMETHICONE is recorded.
As the commercially available product of ingredient (A), for example, the trade name " KF-6028 " of chemical industry society manufacture,
Trade name " KF-6028P " (HLB=4.0, PEG-9 Polydimethylsiloxyethyl Dimethicone)；SH3773M (HLB=
8, PEG-12 dimethyl silicone polymers；Dow Corning Toray society manufacture), SH3775M (HLB=5, PEG-12 poly dimethyl
Siloxanes；Dow Corning Toray society manufacture), SH3749 (HLB=8, PEG/PPG-20/20 dimethyl silicone polymer；Dow
Corning Toray society manufacture), SS2910 (HLB=4, PEG-10 Polydimethylsiloxane；Dow Corning Toray society system
Make), BY25-339 (HLB=8.5, PEG/PPG-30/10 dimethyl silicone polymer；The manufacture of Dow Corning Toray society),
KF-6012 (HLB=7, PEG/PPG-20/22 butyl ether dimethyl silicone polymer；Chemistry society of SHIN-ETSU HANTOTAI manufacture), KF-6015 (HLB
=4.5, PEG-12 dimethyl silicone polymer；Chemistry society of SHIN-ETSU HANTOTAI manufacture), KF-6016 (HLB=4.5, PEG-9 methyl ether poly dimethyl
Siloxanes；Chemistry society of SHIN-ETSU HANTOTAI manufacture), KF-6017 (HLB=4.5, PEG-10 Polydimethylsiloxane；The manufacture of chemistry society of SHIN-ETSU HANTOTAI),
SILSOFT305 (HLB=5~8, PEG/PPG-5/3 dimethyl silicone polymer；Momentive Performance
Materials Japan society manufacture), SILSOFT805 (HLB=5~8PEG-8 dimethyl silicone polymer；Momentive
Performance Materials Japan society manufacture), SILSOFT810 (HLB=5~8PEG-8 dimethyl silicone polymer；
The manufacture of Momentive Performance Materials Japan society) etc..
The content of ingredient (A) in emulsification deodorant compositions of the invention is not particularly limited, relative to cream of the invention
Change 100 mass % of deodorant compositions, preferably 0.1 mass of mass %~20.0 %, more preferably 1.0 matter of mass %~10.0
Measure %.By making above-mentioned 0.1 mass % of content or more, emulsion stability is further increased.On the other hand, by making above-mentioned contain
Amount is 20.0 mass % hereinafter, use feeling further increases.The content of mentioned component (A) is emulsification deodorant compositions of the invention
In whole components (A) content total amount.
[ingredient (B)：Dimethicone/Vinyl Dimethicone cross-linked polymer]
Mentioned component (B) is as the dimethyl polysiloxane being crosslinked using Vinyl Dimethicone
Copolymer.As ingredient (B), for example, with INCI (international cosmetic raw material dictionary and handbook, the 15th edition, the 1st
Volume, personal care product association of the U.S., 2014, p.1074-1075)：DIMETHICONE/VINYL DIMETHICONE
Chemical combination that CROSSPOLYMER is recorded, being referred to as Dimethicone/Vinyl Dimethicone cross-linked polymer
Object.Ingredient (B) may be used alone or in combination of two or more.
As the commercially available product of ingredient (B), for example, the trade name " KSG-15 " of chemical industry society manufacture；Letter
The more trade name " KSG-16 " of chemical industry corporation manufacture；The trade name " KSG-1510 " of chemical industry society manufacture；SHIN-ETSU HANTOTAI
Learn the trade name " KSG-1610 " etc. of industrial society's manufacture.
The content of ingredient (B) in emulsification deodorant compositions of the invention is not particularly limited, relative to cream of the invention
Change 100 mass % of deodorant compositions, preferably 0.1 mass of mass %~10.0 %, more preferably 0.5 matter of mass %~6.0
Measure %, further preferably 1.0 mass of mass %~6.0 %.By making above-mentioned 0.1 mass % of content or more, can inhibit from
Slurry, preparation stability further increase.On the other hand, if above-mentioned content is more than 10.0 mass %, in the coating of composition
Sediment is generated sometimes.The content of mentioned component (B) is containing for whole components (B) in emulsification deodorant compositions of the invention
The total amount of amount.
[ingredient (C)：Palmitinic acid 2- ethylhexyl]
Mentioned component (C) is palmitinic acid 2- ethylhexyl.In the system of emulsification deodorant compositions of the invention, pass through choosing
It can prevent antiperspirant and fungicide from flowing down because of sweat after composition is applied to skin using ingredient (C) to selecting property, it can
Antiperspirant and fungicide after improving coating tremendously can effectively improve the deodorizing effect after being coated in the survivability of skin
Duration.
The content of ingredient (C) in emulsification deodorant compositions of the invention is not particularly limited, relative to cream of the invention
Change 100 mass % of deodorant compositions, preferably 0.1 mass of mass %~15.0 %, more preferably 0.5 matter of mass %~10.0
Measure %.By making above-mentioned 0.1 mass % of content or more, ingredient (E) is further increased in the survivability of skin, cream of the invention
The duration for changing the deodorizing effect of deodorant compositions further increases.On the other hand, by making above-mentioned 15.0 mass % of content
Hereinafter, tacky be inhibited, the use feeling (dry feeling) after coating is further increased.
[ingredient (D)：Antiperspirant]
Mentioned component (D) is antiperspirant.Ingredient (D) for example inhibits the generation of sweat by restraining skin.As ingredient (D)
It is not particularly limited, conventionally known antiperspirant can be enumerated.As ingredient (D), for example, aluminium salt and Pyrogentisinic Acid's sulphur
Sour zinc etc..As above-mentioned aluminium salt, can enumerate aluminium chloride, aluminum sulfate, aluminum aluminum sulfate (potassium alum), alum (ammonia-alum),
Aluminium acetate, chlorination hydroxyl aluminium and allantoin chlorohydroxyaluminum hydroxyl aluminium etc..Wherein, from the aspect of further increasing sweat effect processed, preferably
Chlorination hydroxyl aluminium, P-phenol zinc sulfonate, alum, more preferably chlorination hydroxyl aluminium, P-phenol zinc sulfonate.Ingredient (D) can be used only 1
Kind, two or more also can be used.
The content of ingredient (D) in emulsification deodorant compositions of the invention is not particularly limited, relative to cream of the invention
Change 100 mass % of deodorant compositions, preferably 0.01 mass of mass %~30.0 %, more preferably 0.1 matter of mass %~20.0
Measure %.By making above-mentioned 0.01 mass % of content or more, the sweat effect processed of emulsification deodorant compositions of the invention and its continue
Property further increases.On the other hand, by making above-mentioned 30.0 mass % of content hereinafter, emulsion stability and use feeling are further
It improves.The content of mentioned component (D) is the total amount of the content of the whole components (D) in emulsification deodorant compositions of the invention.
[ingredient (E)：Fungicide]
Mentioned component (E) is fungicide.Ingredient (E) is for example with bactericidal effect.It is not particularly limited as ingredient (E),
Conventionally known fungicide can be enumerated.As ingredient (E), examined in terms of further increasing bactericidal effect and its duration
Worry, preferably isopropyl methyl phenol, benzalkonium chloride, hinokitol, triclosan, salicylic acid, more preferably isopropyl methyl phenol,
Benzalkonium chloride.Ingredient (E) may be used alone or in combination of two or more.
The content of ingredient (E) in emulsification deodorant compositions of the invention is not particularly limited, relative to cream of the invention
Change 100 mass % of deodorant compositions, preferably 0.03 mass of mass %~2.0 %, more preferably 0.05 matter of mass %~1.0
Measure %.By making above-mentioned 0.03 mass % of content or more, the bactericidal effect of emulsification deodorant compositions of the invention and its continue
Property further increases.On the other hand, by making above-mentioned 2.0 mass % of content hereinafter, emulsion stability further increases.It is above-mentioned
The content of ingredient (E) is the total amount of the content of the whole components (E) in emulsification deodorant compositions of the invention.
[ingredient (F)：Water]
Mentioned component (F) is not particularly limited, preferably pure water.Ingredient in emulsification deodorant compositions of the invention
(F) content is not particularly limited, relative to 100 mass % of emulsification deodorant compositions of the invention, preferably 10.0 mass %
~90.0 mass %, more preferably 30.0 mass of mass %~80.0 %.
Emulsification deodorant compositions of the invention can also containing other than mentioned component (A)~ingredient (F) ingredient (it is other at
Point).It is not particularly limited as above-mentioned other ingredients, for example, the surfactant (cationic other than ingredient (A)
Surfactant, anionic surfactant, amphoteric surfactant etc.), the ester oil other than ingredient (C), grease, hydrocarbon ils,
Wax, higher fatty acids, silicone oil, lower alcohol, higher alcohol, polyalcohol, ultraviolet absorbing agent, powder, antioxidant, preservative, perfume (or spice)
Thickener, vitamins, neutralizer, amino acid, pH adjusting agent other than material, colorant, chelating agent, freshener, ingredient (B),
Additives such as whitening agent, anti-inflammatory agent, deodorant, animal and plant extracts, chelating agent, essential oil etc..Other ingredients can be used only 1
Kind, two or more also can be used.
From improving moisture retention and improving preparation stability aspect, emulsification deodorant compositions of the invention are preferably comprised
Polyalcohol.As above-mentioned polyalcohol, for example, glycols, glycerols, sugar alcohol etc..As above-mentioned glycols, without spy
It does not limit, for example, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoprene, 1,3- fourth two
Alcohol, 1,2- butanediol, 1,2- pentanediol, 1,2- hexylene glycol, 1,2- ethohexadiol, Decane-1,2-diol, polyethylene glycol etc..As above-mentioned
Glycerols are not particularly limited, for example, glycerol, diglycerol, polyglycereol etc..It is not particularly limited as above-mentioned sugar alcohol,
For example, D-sorbite, maltitol, trehalose etc..Polyalcohol may be used alone or in combination of two or more.
The content of polyalcohol in emulsification deodorant compositions of the invention is not particularly limited, and combines relative to emulsification deodorization of the invention
100 mass % of object, preferably 1.0 mass of mass %~60.0 %, more preferably 5.0 mass of mass %~40.0 %.It is above-mentioned more
The content of first alcohol is the total amount of the content of whole polyalcohols in emulsification deodorant compositions of the invention.
From improving use feeling aspect, emulsification deodorant compositions of the invention preferably comprise silicone oil.As above-mentioned silicon
Oil is not particularly limited, for example, methyl polysiloxane, high polymer methylpolysiloxane, methyl phenyl silicone,
The straight chains silicone oil such as methylhydrogenpolysi,oxane；Octamethyltrisiloxane, decamethyl tetrasiloxane, octamethylcy-clotetrasiloxane, ten first
The cyclic silicone oils such as base cyclopentasiloxane, ten diformazan basic rings, six siloxanes, octamethylpolysiloxane；It is alcohol modified silicone, alkyl-modified
Modified silicon oils such as silicone, amino modified silicone, epoxy-modified silicone (wherein, not including the substance for meeting ingredient (A)) etc..This hair
The content of above-mentioned silicone oil in bright emulsification deodorant compositions is not particularly limited, relative to emulsification deodorant compositions of the invention
100 mass %, preferably 0.5 mass of mass %~70.0 %, more preferably 1.0 mass of mass %~50.0 %.Above-mentioned silicone oil
Content be whole silicone oil in emulsification deodorant compositions of the invention content total amount.
From assigning fragrance aspect, emulsification deodorant compositions of the invention may include essential oil.As above-mentioned essential oil,
For example, rosemary leaf oil, lavender oil, eucalyptus oil (Eucalyptus Globulus oil), spearmint oil, sage oil, caryophyllus oil, cortex cinnamomi
Oil, peppermint oil, fennel oil, oil of chamomile, orange oil etc..The content of above-mentioned essential oil in emulsification deodorant compositions of the invention does not have
It is particularly limited to, relative to 100 mass % of emulsification deodorant compositions of the invention, preferably 0.001 mass of mass %~1.0 %.
The content of above-mentioned essential oil is the total amount of the content of whole essential oils in emulsification deodorant compositions of the invention.
From improve composition in fungicide skin survivability in terms of and inhibit it is tacky, improve use feeling in terms of etc.
It sets out, emulsification deodorant compositions of the invention are emulsification composition, the particularly preferably emulsification of water-in-oil type [W/O (W/Si) type]
Composition.
As the dosage form of emulsification deodorant compositions of the invention, be not particularly limited, for example, gel, emulsifiable paste,
Lotion etc..Wherein, preferably emulsifiable paste.That is, emulsification deodorant compositions of the invention are preferably cream emulsification deodorant compositions paste.
Emulsification deodorant compositions of the invention can use conventional method and be manufactured.For example, following methods
Deng：Above-mentioned each constituent is mixed, is stirred using well known method, specifically using homomixer etc..
[deodorant]
The above-mentioned emulsification deodorant compositions that deodorant of the invention has container and is filled in the container.
As said vesse, rollon container, tubular container etc. can be enumerated.Said vesse is preferably that tubular container or emulsifiable paste hold
Device.From the formulation properties aspect such as viscosity, deodorant of the invention is preferably non-aerosol preparation.
Emulsification deodorant compositions of the invention and deodorant of the invention are not particularly limited, for prevent or remove body odor or
The constituent or preparation of bad smell of perspiration.It should be noted that emulsification deodorant compositions of the invention and deodorant of the invention for example may be used
Think any one of cosmetics, quasi drug, pharmaceuticals, groceries.
Emulsification deodorant compositions of the invention and deodorant of the invention are preferably applied to skin and use.As applicable portion
Position is not particularly limited, for example, body, head (scalp) etc..Wherein it is preferably body (body), for example,
Chest, behind, arm, leg, neck, oxter etc..Emulsification deodorant compositions of the invention and deodorant of the invention are particularly preferably used
It is used as the deodorant compositions and deodorant of oxter.
Emulsification deodorant compositions of the invention are that polyether modified silicone [ingredient (A)] is used to carry out cream as surfactant
Emulsification composition made of change (the especially emulsification composition of w/o type), the adaptation of composition and skin improves as a result, group
The skin survivability for closing object is excellent.Furthermore, it is suppressed that due to palmitinic acid 2- ethylhexyl [ingredient (C)] or antiperspirant [ingredient
(D)] tacky, use feeling is also excellent.
In addition, emulsification deodorant compositions of the invention are using as the poly dimethyl silicon of specific cross-linking type silicone compounds
Oxygen alkane/vinyl dimethicone cross polymer [ingredient (B)] is viscosified.Composition and skin is close as a result,
Conjunction property, the skin survivability of composition further increase.In addition, preparation stability, tacky inhibitory effect further increase, use
Feel excellent.
In addition, in the present invention, by ingredient (C) of the mixture as specific ester oil in the above system, it is thus been found that group
It closes the case where object flows down because of sweat to be further suppressed, fungicide is further increased in the survivability of skin after coating.
Therefore, pass through the effect of above-mentioned each ingredient, for emulsification deodorant compositions of the invention, deodorization ingredient after coating
(especially fungicide) is tremendously excellent in the survivability of skin, is thus the extremely excellent deodorization of the duration of deodorizing effect
Composition.In addition, it is tacky few caused by compounding ingredients, play excellent use feeling.
In addition to this, ingredient (A) is polyether modified silicone (the especially PEG-9 poly dimethyl silicon with branched silicone chain
Oxygen ethyl dimethyl silicone polymer) in the case where, emulsify deodorant compositions through when foul and extraordinarily inhibited, thus be preferred
's.
Embodiment
In the following, the present invention is described in more detail based on embodiment, but the present invention is not limited to these embodiments.It needs
Illustrating, blend amount is the blend amount (that is, blend amount of the effective component in each raw material) of each ingredient, unless otherwise specified,
Otherwise it is indicated with " quality % ".
Embodiment 1
According to following compositions, cream w/o type emulsification deodorant compositions paste are prepared by a conventional method.
<Composition>
Comparative example 1
According to following compositions, cream w/o type emulsification deodorant compositions paste are prepared by a conventional method.
<Composition>
For each deodorant compositions obtained in above-described embodiment 1 and comparative example 1, the following survivability for evaluating fungicide.
(evaluation of the survival rate of fungicide (benzalkonium chloride and isopropyl methyl phenol))
According to JIS L0848：2004 are prepared for synthetic perspiration.Specifically, by L-Histidine hydrochloride monohydrate
0.5g, sodium chloride 5g, sodium dihydrogen phosphate dihydrate 2.2g are dissolved in the water, be subsequently added into 0.1mol/L sodium hydroxide 15mL and
So that total amount is reached the water of 1L, prepares acid synthetic perspiration.The pH of obtained acidity synthetic perspiration is 5.5.
Obtained 20 μ L of deodorant compositions is applied on keratin cloth.Above-mentioned acidity synthetic perspiration 20mL is packed into
After in 100mL beaker, the keratin cloth after coating is put into beaker, the angle with 100rpm oscillation 10 minutes, after being vibrated
Albumen cloth.
After methanol 10mL is added in 15mL centrifuge tube, the keratin cloth after oscillation is put into centrifuge tube, with 150rpm
Oscillation 10 minutes.Later, the liquid in centrifuge tube is filtered with 0.45 μm of membrane filter.
Later, the amount (Y) of the fungicide in filtered liquid is had rated using HPLC.In addition, separately having prepared institute
Obtained 20 μ L of deodorant compositions is applied to the evaluation sample on keratin cloth, do not vibrate in acid synthetic perspiration and into
It has gone same processing, the amount (X) of the fungicide in filtered liquid at this time has been evaluated.With the amount of fungicide
(X) on the basis of, the survival rate ((Y)/(X) × 100%) of fungicide is found out.It should be noted that for benzalkonium chloride and isopropyl
Ylmethyl phenol separately carries out the calculating of survival rate.
Above-mentioned evaluation as a result, the survival rate of the benzalkonium chloride of emulsification deodorant compositions (embodiment 1) of the invention is
97.9%, the survival rate of isopropyl methyl phenol is 54.1%.On the other hand, (the ratio of the emulsification deodorant compositions without ingredient (C)
Compared with example 1) the survival rate of benzalkonium chloride be 88.0%, the survival rate of isopropyl methyl phenol is 41.6%.That is, cream of the invention
Change the survival rate that deodorant compositions show excellent fungicide (benzalkonium chloride and isopropyl methyl phenol).
Embodiment 2
According to following compositions, cream w/o type emulsification deodorant compositions paste are prepared by a conventional method.
<Composition>
The emulsification deodorant compositions of above-described embodiment 2 are saved 2 months under 40 DEG C of environment, the stink after preservation is changed
Carry out sensory evaluation.As control, uses and saved 2 months preservation product under 5 DEG C of environment.
Sample (under 40 DEG C of environment save 2 months preservation product) and control (are saved under 5 DEG C of environment 2 months guarantors
Deposit product) stink be adjacent to and be compared, as a result, sample does not have difference, the emulsification deodorization combination of embodiment 2 with the stink compareed
Object through when anti-fouling it is excellent.
Next, the emulsification deodorant compositions of embodiment 1 and embodiment 2 are applied to oxter, sense of touch is confirmed.As a result,
The emulsification deodorant compositions of embodiment 1 and embodiment 2 show excellent use feeling there is no tacky when coating.It needs
Bright, the evaluation of above-mentioned use feeling is carried out by 8 professional judging panels.
In addition, the Formulation Example of emulsification deodorant compositions of the invention described below.
Formulation Example 1：Gel (translucent emulsifiable paste)
Formulation Example 2：Gel (translucent emulsifiable paste)
Formulation Example 3：Gel (translucent emulsifiable paste)
Formulation Example 4：Lotion
Formulation Example 5：Gel (translucent emulsifiable paste)
Formulation Example 6：Gel (translucent emulsifiable paste)
Formulation Example 7：Gel (translucent emulsifiable paste)
Formulation Example 8：Gel (translucent emulsifiable paste)
Formulation Example 9：Gel (translucent emulsifiable paste)
It should be noted that the details for each ingredient recorded in embodiment and Formulation Example is as follows.
PEG-10 Polydimethylsiloxane：Trade name " KF-6017 ", chemical industry society manufacture, HLB=4.5
Dimethicone/Vinyl Dimethicone cross-linked polymer(*1)：Trade name " KSG-15 ", SHIN-ETSU HANTOTAI
Chemical industry corporation manufacture
Dimethicone/Vinyl Dimethicone cross-linked polymer(*2)：Trade name " KSG-16 ", SHIN-ETSU HANTOTAI
Chemical industry corporation manufacture
Palmitinic acid 2- ethylhexyl：Trade name " コ ー ヨ ー POC ", the manufacture of KOYO fine chemical society
Dimethyl silicone polymer：Trade name " KF 96A-6CS ", chemical industry society manufacture
Chlorination hydroxyl aluminium：Trade name " PAC 1000 ", the manufacture of more wooden chemistry societies
Isopropyl methyl phenol：Trade name " isopropyl methyl phenol ", the manufacture of Osaka chemical conversion society
Benzalkonium chloride：Trade name " カ チ オ Application G-50 ", the manufacture of chemical conversion industry society of Sanyo
Dipropylene glycol：Trade name " DPG-FC ", the manufacture of Asahi Glass society
Concentrated glycerin：Trade name " cosmetic concentrated glycerin ", the manufacture of this chemical industry of slope society
Polyethylene glycol 400：Trade name " PEG-400 ", the manufacture of chemical conversion industry society of Sanyo
1,3 butylene glycol：Trade name " 1,3 butylene glycol ", the manufacture of Daicel society
Methyl p-hydroxybenzoate：Trade name " メ ッ キ Application ス-M ", the manufacture of u'eno pharmacy society
Ethyl alcohol：Trade name " 95 ° of general fermentation alcohol ", the manufacture of Bao Jiuzao society
Glucose：Trade name " Japanese Pharmacopoeia glucose NG-TDA ", the manufacture of San-ei Sucrochemical society
Glycine betaine：Trade name " Aminocoat ", the manufacture of chemistry society of Asahi Chemical Industry
Isononyl isononanoate：Trade name " SALACOS 99 ", the manufacture of day Qing Aoliyou society
Dimethyl silicone polymer：Trade name " SH2O0C 10CS-JASU ", the manufacture of Dow Corning Toray society
Decamethylcyclopentaandoxane：Trade name " KF-995 ", chemical industry society manufacture
Industrial applicibility
Emulsification deodorant compositions of the invention and deodorant of the invention are not particularly limited, and are used as purpose and are to prevent
Or remove the product of body odor or bad smell of perspiration.Emulsification deodorant compositions of the invention and deodorant of the invention be used for example as cosmetics,
Quasi drug, pharmaceuticals, groceries etc..
Claims (7)
1. a kind of emulsification deodorant compositions, it includes：
Ingredient (A)：Selected from by PEG-10 Polydimethylsiloxane and PEG-9 Polydimethylsiloxyethyl Dimethicone group
At at least one of group polyether modified silicone；
Ingredient (B)：Dimethicone/Vinyl Dimethicone cross-linked polymer；
Ingredient (C)：Palmitinic acid 2- ethylhexyl；
Ingredient (D)：Antiperspirant；
Ingredient (E)：Fungicide；With
Ingredient (F)：Water.
2. emulsification deodorant compositions as described in claim 1, wherein the ingredient (A) is PEG-9 polydimethylsiloxanes ethyl
Dimethyl silicone polymer.
3. emulsification deodorant compositions as claimed in claim 1 or 2, wherein the ingredient (D) is selected from by chlorination hydroxyl aluminium, right
Antiperspirant in the group of zinc phenolsulfonate and alum composition.
4. emulsification deodorant compositions as claimed in claim 1 or 2, wherein the ingredient (E) is selected from by isopropyl-methyl-benzene
The fungicide in group that phenol, benzalkonium chloride, hinokitol, triclosan and salicylic acid form.
5. emulsification deodorant compositions as claimed in claim 1 or 2 are emulsifiable paste shape.
6. a kind of deodorant has container and emulsification deodorant compositions according to any one of claims 1 to 5,
Above-mentioned emulsification deodorant compositions are filled in said vesse.
7. deodorant as claimed in claim 6 is non-aerosol preparation.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014199775 | 2014-09-30 | ||
| JP2014-199775 | 2014-09-30 | ||
| PCT/JP2015/076773 WO2016052277A1 (en) | 2014-09-30 | 2015-09-18 | Emulsified deodorant composition and deodorant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106102700A CN106102700A (en) | 2016-11-09 |
| CN106102700B true CN106102700B (en) | 2018-11-16 |
Family
ID=55630317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580013148.1A Expired - Fee Related CN106102700B (en) | 2014-09-30 | 2015-09-18 | Emulsify deodorant compositions and deodorant |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5951155B1 (en) |
| CN (1) | CN106102700B (en) |
| WO (1) | WO2016052277A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6692703B2 (en) * | 2016-06-10 | 2020-05-13 | 株式会社 資生堂 | Antiperspirant or deodorant cosmetics |
| KR102477212B1 (en) * | 2016-11-14 | 2022-12-12 | 가부시키가이샤 시세이도 | Composition for external application for skin |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183144A (en) * | 2001-12-21 | 2003-07-03 | Lion Corp | Body odor-inhibiting composition |
| JP4639053B2 (en) * | 2003-03-12 | 2011-02-23 | 花王株式会社 | Antiperspirant deodorant spray composition |
| JP5963616B2 (en) * | 2012-08-31 | 2016-08-03 | 株式会社マンダム | Deodorant |
-
2015
- 2015-09-18 JP JP2016506396A patent/JP5951155B1/en active Active
- 2015-09-18 CN CN201580013148.1A patent/CN106102700B/en not_active Expired - Fee Related
- 2015-09-18 WO PCT/JP2015/076773 patent/WO2016052277A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106102700A (en) | 2016-11-09 |
| JPWO2016052277A1 (en) | 2017-04-27 |
| JP5951155B1 (en) | 2016-07-13 |
| WO2016052277A1 (en) | 2016-04-07 |
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