CN106102700A - Emulsification deodorant compositions and deodorant - Google Patents
Emulsification deodorant compositions and deodorant Download PDFInfo
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- CN106102700A CN106102700A CN201580013148.1A CN201580013148A CN106102700A CN 106102700 A CN106102700 A CN 106102700A CN 201580013148 A CN201580013148 A CN 201580013148A CN 106102700 A CN106102700 A CN 106102700A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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Abstract
The present invention provides a kind of deodorant emulsifying deodorant compositions and possessing above-mentioned emulsification deodorant compositions, and this emulsification deodorant compositions can improve the survivability at coating object for the bactericide after coating tremendously.The emulsification deodorant compositions of the present invention is characterised by, it comprises composition A: polyether modified silicone；Composition B: Dimethicone/Vinyl Dimethicone cross-linked polymer；Composition C: palmitic acid 2 Octyl Nitrite；Components D: antiperspirant；Composition E: bactericide；With composition F: water.In addition, the deodorant of the present invention is characterised by, it possesses container and above-mentioned emulsification deodorant compositions, and above-mentioned emulsification deodorant compositions is filled in said vesse.
Description
Technical field
The present invention relates to comprise the emulsification deodorant compositions of antiperspirant and bactericide.Remove additionally, relate to possessing above-mentioned emulsification
The deodorant of smelly composition.
Background technology
The underarm odor bringing undesirable sensation is to mix and often occupied by skin bacterium to decompose produced with sebum due to sweat.
In the past, in order to prevent this undesirable underarm odor, deodorant compositions is employed.Known above-mentioned deodorant compositions have gel (gel),
The all kinds such as emulsifiable paste (cream), toner (lotion), aerosol spray (spray), spray (mist) and club
(referring for example to patent document 1～3).Wherein, the deodorant compositions as emulsification preparations such as emulsifiable pastes has the adaptation with skin
Good, do not occur sagging (hang down れ) and disperse (dance dissipates り) etc., the advantage such as usability is good.
Prior art literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2003-183144 publication
Patent document 2: Japanese Unexamined Patent Publication 2004-018513 publication
Patent document 3: Japanese Unexamined Patent Publication 2006-028084 publication
Content of the invention
Invention problem to be solved
But, existing deodorant compositions deposits the problem not enough long lasting for property of body odor inhibition after a procedure.
With regard to its reason, it is believed that be: after coating, deodorant compositions flows down because of sweat etc., and the skin of the bactericide in composition is residual
Sustainability reduces.
Therefore, it is an object of the invention to provide a kind of emulsification deodorant compositions, it can carry after coating tremendously
High bactericide is in the survivability of coating object.
For solving the scheme of problem
Present inventor has performed further investigation, it was found that by by polyether modified silicone, dimethyl silicone polymer/second
Thiazolinyl Dimethicone Crosspolymer, palmitic acid 2-Octyl Nitrite, antiperspirant, bactericide and water carry out mixture, thus
The available excellent emulsification deodorant compositions that improve the survivability at coating object for the bactericide, thus completes tremendously
The present invention.
That is, the present invention provides a kind of emulsification deodorant compositions, and it comprises: composition (A): polyether modified silicone；Composition (B):
Dimethicone/Vinyl Dimethicone cross-linked polymer；Composition (C): palmitic acid 2-Octyl Nitrite；Composition
(D): antiperspirant；Composition (E): bactericide；With composition (F): water.
Mentioned component (A) preferably has the polyether modified silicone of branched silicone chain.
Mentioned component (A) is preferably KF-6028.
Mentioned component (D) is preferably selected from the antiperspirant in the group being made up of chlorination hydroxyl aluminium, p-phenolsulfonic acid's zinc and alum.
Mentioned component (E) is preferably selected from by isopropyl methyl phenol, benzalkonium chloride, hinokitol, triclosan and salicylic acid
Bactericide in the group of composition.
Above-mentioned emulsification deodorant compositions is preferably emulsifiable paste shape.
In addition, the present invention provides a kind of deodorant, it possesses container and above-mentioned emulsification deodorant compositions, above-mentioned emulsification deodorizing
Composition is filled in said vesse.
Above-mentioned deodorant is preferably non-aerosol preparation.
The effect of invention
The emulsification deodorant compositions of the present invention is owing to having above-mentioned composition, thus the bactericide comprising in composition is in coating
Object through when survivability improve.Therefore, the body odor inhibition of the emulsification deodorant of the present invention is excellent long lasting for property
Different.
Additionally, emulsification deodorant compositions in use tacky few of the present invention, use feeling is also excellent.
Detailed description of the invention
The emulsification deodorant compositions of the present invention contains polyether modified silicone, dimethyl silicone polymer/vinylpolydimethyl
Dimethicone Crosspolymer, palmitic acid 2-Octyl Nitrite, antiperspirant, bactericide and water are as neccessary composition.Additionally, the present invention
Emulsification deodorant compositions also can contain other compositions.
It should be noted that in this specification, sometimes above-mentioned polyether modified silicone is referred to as " composition (A) "；Sometimes by upper
State Dimethicone/Vinyl Dimethicone cross-linked polymer and be referred to as " composition (B) "；Sometimes by above-mentioned palmitic acid
2-Octyl Nitrite is referred to as " composition (C) "；Sometimes above-mentioned antiperspirant is referred to as " composition (D) "；Sometimes above-mentioned bactericide is referred to as " becoming
Divide (E) "；Sometimes above-mentioned water is referred to as " composition (F) ".
The each composition, i.e. composition (A)～composition (F) and other compositions that comprise in the emulsification deodorant compositions of the present invention are respectively
Can only use a kind, it is possible to use two or more.
[composition (A): polyether modified silicone]
Mentioned component (A) is for comprising siloxane backbone (silicone chains) and the silicone compounds of polyether-based (polyether chain).Composition
(A) can the silicone compounds of block copolymer type or terminal-modified type for comprising polyether chain and silicone chains in main chain；Also may be used
Think the silicone compounds of the modified side chain type being bonded with polyether-based as the side chain of siloxane backbone.Wherein, from composition
The aspect of emulsion stability set out, be preferably the silicone compound at the side chain of siloxane backbone and/or end with polyether-based
Thing, more preferably has the silicone compounds of polyether-based at side chain.Composition (A) can only use a kind, it is possible to use 2 kinds with
On.
It as above-mentioned siloxane backbone (silicone chains), is not particularly limited, for example, can enumerate dimethyl polysiloxane (poly-
Dimethyl siloxane), methyl phenyl silicone, methylhydrogenpolysi,oxane etc..Wherein, preferably dimethyl polysiloxane.
It as above-mentioned polyether-based (polyether chain), is not particularly limited, for example, can enumerate polyoxyethylene groups, polyoxypropylene
Base, polybutylene base etc..It is wherein preferably polyoxyethylene groups.Oxyalkylene (for example, ethylene oxide) in composition (A) average
Addition molal quantity is not particularly limited, and preferably 5～30, more preferably 8～20.
The HLB of composition (A) is not particularly limited, from the aspect of the emulsion stability of composition, preferably 3.5～
9.0th, more preferably 4.0～8.0.
Wherein, from improve composition emulsion stability in terms of and suppression through when fouling from the aspect of, composition (A)
Preferably having the polyether modified silicone of branched silicone chain, the more preferably side chain at branched silicone chain has the polyethers of polyether chain
Modified silicone.There is as the above-mentioned side chain at branched silicone chain the polyether modified silicone of polyether chain, for example, can enumerate PEG-9
Polydimethylsiloxanes ethyl dimethyl silicone polymer.Above-mentioned KF-6028 for
INCI name (international cosmetic raw material dictionary and handbook (International Cosmetic Ingredient Dictionary
And Handbook), the 15th edition, volume 2, personal care product association of the U.S. (Personal Care Products
Council), 2014, p.2473): the compound that PEG-9POLYDIMETHYLSILOXYETHYL DIMETHICONE records.
As the commercially available product of composition (A), for example can enumerate trade name " KF-6028 " that chemical industry society of SHIN-ETSU HANTOTAI manufactures,
Trade name " KF-6028P " (HLB=4.0, KF-6028)；SH3773M (HLB=
8, PEG-12 dimethyl silicone polymers；Dow Corning Toray society manufactures), SH3775M (HLB=5, PEG-12 poly dimethyl
Siloxanes；Dow Corning Toray society manufactures), SH3749 (HLB=8, PEG/PPG-20/20 dimethyl silicone polymer；Dow
Corning Toray society manufactures), SS2910 (HLB=4, KF6017；Dow Corning Toray society system
Make), BY25-339 (HLB=8.5, PEG/PPG-30/10 dimethyl silicone polymer；Dow Corning Toray society manufactures),
KF-6012 (HLB=7, PEG/PPG-20/22 butyl ether dimethyl silicone polymer；SHIN-ETSU HANTOTAI chemistry society manufacture), KF-6015 (HLB
=4.5, PEG-12 dimethyl silicone polymer；SHIN-ETSU HANTOTAI chemistry society manufacture), KF-6016 (HLB=4.5, PEG-9 methyl ether poly dimethyl
Siloxanes；SHIN-ETSU HANTOTAI chemistry society manufacture), KF-6017 (HLB=4.5, KF6017；Chemistry society of SHIN-ETSU HANTOTAI manufactures),
SILSOFT305 (HLB=5～8, PEG/PPG-5/3 dimethyl silicone polymer；Momentive Performance
Materials Japan society manufactures), SILSOFT805 (HLB=5～8PEG-8 dimethyl silicone polymer；Momentive
Performance Materials Japan society manufactures), SILSOFT810 (HLB=5～8PEG-8 dimethyl silicone polymer；
Momentive Performance Materials Japan society manufactures) etc..
The content of the composition (A) in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the breast of the present invention
Change deodorant compositions 100 mass %, preferably 0.1 mass %～20.0 mass %, more preferably 1.0 mass %～10.0 matter
Amount %.By making above-mentioned content be more than 0.1 mass %, emulsion stability improves further.On the other hand, by making above-mentioned containing
Amount is below 20.0 mass %, and use feeling improves further.The content of mentioned component (A) is the emulsification deodorant compositions of the present invention
In the total amount of content of whole compositions (A).
[composition (B): Dimethicone/Vinyl Dimethicone cross-linked polymer]
Mentioned component (B) is as the dimethyl polysiloxane utilizing Vinyl Dimethicone to carry out crosslinking
Copolymer.As composition (B), for example can enumerate with INCI name (international cosmetic raw material dictionary and handbook, the 15th edition, the 1st
Volume, personal care product association of the U.S., 2014, p.1074-1075): DIMETHICONE/VINYL DIMETHICONE
Chemical combination that CROSSPOLYMER records, that be referred to as Dimethicone/Vinyl Dimethicone cross-linked polymer
Thing.Composition (B) can only use a kind, it is possible to use two or more.
As the commercially available product of composition (B), for example, can enumerate the trade name " KSG-15 " that chemical industry society of SHIN-ETSU HANTOTAI manufactures；Letter
The trade name " KSG-16 " that more chemical industry society manufactures；The trade name " KSG-1510 " that chemical industry society of SHIN-ETSU HANTOTAI manufactures；SHIN-ETSU HANTOTAI
Learn the trade name " KSG-1610 " etc. that industry society manufactures.
The content of the composition (B) in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the breast of the present invention
Change deodorant compositions 100 mass %, preferably 0.1 mass %～10.0 mass %, more preferably 0.5 mass %～6.0 matter
Amount %, more preferably 1.0 mass %～6.0 mass %.By making above-mentioned content be more than 0.1 mass %, can suppress from
Slurry, preparation stability improves further.On the other hand, if above-mentioned content is more than 10.0 mass %, then when the coating of composition
Produce sediment sometimes.The content of mentioned component (B) is containing of whole compositions (B) in the emulsification deodorant compositions of the present invention
The total amount of amount.
[composition (C): palmitic acid 2-Octyl Nitrite]
Mentioned component (C) is palmitic acid 2-Octyl Nitrite.In the system of the emulsification deodorant compositions of the present invention, by choosing
Use to selecting property composition (C), after composition is applied to skin, can prevent antiperspirant and bactericide from flowing down because of sweat, can
Improve the antiperspirant after coating and the bactericide survivability at skin tremendously, the deodorizing effect after coating can be effectively improved
Continuation.
The content of the composition (C) in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the breast of the present invention
Change deodorant compositions 100 mass %, preferably 0.1 mass %～15.0 mass %, more preferably 0.5 mass %～10.0 matter
Amount %.By making above-mentioned content be more than 0.1 mass %, composition (E) improves further in the survivability of skin, the breast of the present invention
The continuation of the deodorizing effect changing deodorant compositions improves further.On the other hand, by making above-mentioned content be 15.0 mass %
Hereinafter, tacky being inhibited, the use feeling (dry feeling) after coating improves further.
[composition (D): antiperspirant]
Mentioned component (D) is antiperspirant.The generation that composition (D) for example suppresses sweat by convergence skin.As composition (D)
It is not particularly limited, existing known antiperspirant can be enumerated.As composition (D), for example, can enumerate aluminium salt and Pyrogentisinic Acid's sulphur
Acid zinc etc..As above-mentioned aluminium salt, can enumerate aluminium chloride, aluminum sulfate, alum (potassium alum), alum (ammonia-alum),
Aluminium acetate, chlorination hydroxyl aluminium and allantoin chlorohydroxyaluminum hydroxyl aluminium etc..Wherein, it from the aspect of improving sweat effect processed further, is preferably
Chlorination hydroxyl aluminium, p-phenolsulfonic acid's zinc, alum, more preferably chlorination hydroxyl aluminium, p-phenolsulfonic acid's zinc.Composition (D) can only use 1
Kind, it is possible to use two or more.
The content of the composition (D) in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the breast of the present invention
Change deodorant compositions 100 mass %, preferably 0.01 mass %～30.0 mass %, more preferably 0.1 mass %～20.0 matter
Amount %.By making above-mentioned content be more than 0.01 mass %, the present invention emulsification deodorant compositions sweat effect processed and continue
Property improves further.On the other hand, by making above-mentioned content be below 30.0 mass %, emulsion stability and use feeling are further
Improve.The content of mentioned component (D) is the total amount of the content of the whole compositions (D) in the emulsification deodorant compositions of the present invention.
[composition (E): bactericide]
Mentioned component (E) is bactericide.Composition (E) for example has bactericidal action.It is not particularly limited as composition (E),
Existing known bactericide can be enumerated.As composition (E), from improve further bactericidal effect and continuation thereof in terms of examine
Consider, preferably isopropyl methyl phenol, benzalkonium chloride, hinokitol, triclosan, salicylic acid, more preferably isopropyl methyl phenol,
Benzalkonium chloride.Composition (E) can only use a kind, it is possible to use two or more.
The content of the composition (E) in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the breast of the present invention
Change deodorant compositions 100 mass %, preferably 0.03 mass %～2.0 mass %, more preferably 0.05 mass %～1.0 matter
Amount %.By making above-mentioned content be more than 0.03 mass %, the present invention emulsification deodorant compositions bactericidal effect and continue
Property improves further.On the other hand, by making above-mentioned content be below 2.0 mass %, emulsion stability improves further.Above-mentioned
The content of composition (E) is the total amount of the content of the whole compositions (E) in the emulsification deodorant compositions of the present invention.
[composition (F): water]
Mentioned component (F) is not particularly limited, preferably pure water.Composition in the emulsification deodorant compositions of the present invention
(F) content is not particularly limited, relative to emulsification deodorant compositions 100 mass % of the present invention, preferably 10.0 mass %
～90.0 mass %, more preferably 30.0 mass %～80.0 mass %.
The emulsification deodorant compositions of the present invention also can be containing composition (other one-tenth beyond mentioned component (A)～composition (F)
Point).It is not particularly limited as other compositions above-mentioned, for example, can enumerate the surfactant (cationic beyond composition (A)
Surfactant, anionic surfactant, amphoteric surfactant etc.), the ester oil beyond composition (C), grease, hydrocarbon ils,
Wax, higher fatty acids, silicone oil, lower alcohol, higher alcohol, polyalcohol, ultra-violet absorber, powder, antioxidant, preservative, perfume (or spice)
Thickener beyond material, colouring agent, chelating agent, freshener, composition (B), vitamins, nertralizer, amino acid, pH adjusting agent,
The additives etc. such as whitening agent, anti-inflammatory agent, deodorant, animals and plants extract, chelating agent, essential oil.Other compositions can only use 1
Kind, it is possible to use two or more.
From the aspect improving moisture retention and improve preparation stability, the emulsification deodorant compositions of the present invention preferably comprises
Polyalcohol.As above-mentioned polyalcohol, for example, can enumerate glycols, glycerols, sugar alcohol etc..As above-mentioned glycols, there is no spy
Do not limit, for example can enumerate ethylene glycol, diethylene glycol, triethylene glycol, propane diols, DPG, isoprene, 1,3-fourth two
Alcohol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexylene glycol, 1,2-ethohexadiol, Decane-1,2-diol, polyethylene glycol etc..As above-mentioned
Glycerols is not particularly limited, for example, can enumerate glycerine, diglycerol, polyglycereol etc..It is not particularly limited as above-mentioned sugar alcohol,
For example can enumerate D-sorbite, maltitol, trehalose etc..Polyalcohol can only use a kind, it is possible to use two or more.
The content of the polyalcohol in the emulsification deodorant compositions of the present invention is not particularly limited, relative to the emulsification deodorizing combination of the present invention
Thing 100 mass %, preferably 1.0 mass %～60.0 mass %, more preferably 5.0 mass %～40.0 mass %.Above-mentioned many
The content of unit's alcohol is the total amount of the content of the whole polyalcohols in the emulsification deodorant compositions of the present invention.
From the aspect improving use feeling, the emulsification deodorant compositions of the present invention preferably comprises silicone oil.As above-mentioned silicon
Oil is not particularly limited, for example can enumerate methyl polysiloxane, high polymeric MAO polysiloxanes, methyl phenyl silicone,
The straight chain silicone oil such as methylhydrogenpolysi,oxane；Octamethyltrisiloxane, decamethyl tetrasiloxane, octamethylcy-clotetrasiloxane, ten first
The cyclic silicone oils such as base D5, ten diformazan basic ring six siloxanes, octamethylpolysiloxane；Alcohol modified silicone, alkyl-modified
The modified silicon oils such as silicone, amino modified silicone, epoxide modified silicone (wherein, not including the material meeting composition (A)) etc..This
The content of the bright above-mentioned silicone oil in emulsification deodorant compositions is not particularly limited, relative to the emulsification deodorant compositions of the present invention
100 mass %, preferably 0.5 mass %～70.0 mass %, more preferably 1.0 mass %～50.0 mass %.Above-mentioned silicone oil
Content be the present invention emulsification deodorant compositions in the total amount of content of whole silicone oil.
From the aspect giving fragrance, the emulsification deodorant compositions of the present invention can comprise essential oil.As above-mentioned essential oil,
For example can enumerate rosemary leaf oil, lavender oil, eucalyptus oil (Eucalyptus Globulus oil), spearmint oil, sage oil, caryophyllus oil, Chinese cassia tree
Oil, peppermint oil, fennel oil, oil of chamomile, orange oil etc..The content of the above-mentioned essential oil in the emulsification deodorant compositions of the present invention does not has
It is particularly limited to, relative to emulsification deodorant compositions 100 mass % of the present invention, preferably 0.001 mass %～1.0 mass %.
The content of above-mentioned essential oil is the total amount of the content of the whole essential oils in the emulsification deodorant compositions of the present invention.
In terms of the skin survivability of the bactericide improving composition and suppress tacky, improve use feeling in terms of etc.
Setting out, the emulsification deodorant compositions of the present invention is emulsification composition, particularly preferably the emulsification of water-in-oil type [W/O (W/Si) type]
Composition.
As the present invention emulsification deodorant compositions formulation, be not particularly limited, for example can enumerate gel, emulsifiable paste,
Emulsion etc..Wherein, preferably emulsifiable paste.That is, the emulsification deodorant compositions of the present invention is preferably the emulsification deodorant compositions of emulsifiable paste shape.
The emulsification deodorant compositions of the present invention can utilize conventional method to manufacture.For example can enumerate following method
Deng: above-mentioned each constituent is mixed, utilizes known method, specifically utilize homomixer etc. to be stirred.
[deodorant]
The deodorant of the present invention possesses container and the above-mentioned emulsification deodorant compositions being filled in this container.
As said vesse, rollon container, tubular container etc. can be enumerated.Said vesse is preferably tubular container or emulsifiable paste holds
Device.From the aspect of the formulation properties such as viscosity, the deodorant of the present invention is preferably non-aerosol preparation.
The emulsification deodorant compositions of the present invention and the deodorant of the present invention are not particularly limited, for prevent or remove body odor or
The constituent of bad smell of perspiration or preparation.It should be noted that the deodorant of the emulsification deodorant compositions of the present invention and the present invention for example may be used
Think any one in cosmetics, quasi drug, pharmaceuticals, groceries.
The deodorant of the emulsification deodorant compositions of the present invention and the present invention is preferably applied to skin and uses.As applicable portion
Position is not particularly limited, for example, can enumerate health, head (scalp) etc..It is wherein preferably health (body), for example, can enumerate
Chest, behind, arm, leg, neck, oxter etc..The deodorant of the emulsification deodorant compositions of the present invention and the present invention is particularly preferably used
It is used as deodorant compositions and the deodorant of oxter.
The emulsification deodorant compositions of the present invention carries out breast for using polyether modified silicone [composition (A)] as surfactant
The emulsification composition (the particularly emulsification composition of w/o type) changed, thus, composition improves with the adaptation of skin, group
The skin survivability of compound is excellent.Additionally, inhibit due to palmitic acid 2-Octyl Nitrite [composition (C)] or antiperspirant [composition
(D)] tacky, use feeling is also excellent.
In addition, the emulsification deodorant compositions of the present invention utilizes the poly dimethyl silicon as specific cross-linking type silicone compounds
Oxygen alkane/vinyl dimethicone cross polymer [composition (B)] is viscosified.Thus, composition and skin is close
Conjunction property, the skin survivability of composition improve further.Additionally, preparation stability, tacky inhibition improve further, use
Feel excellent.
Additionally, in the present invention, by mixture in above-mentioned system as the composition (C) of specific ester oil, it is thus been found that group
The situation that compound flows down because of sweat is suppressed further, and after coating, bactericide improves further in the survivability of skin.
Therefore, the effect by above-mentioned each composition, for the emulsification deodorant compositions of the present invention, deodorizing composition after coating
(particularly bactericide) the survivability of skin tremendous excellent, be thus the deodorizing that the continuation of deodorizing effect is extremely excellent
Composition.Additionally, compounding ingredients cause tacky few, given play to excellent use feeling.
In addition, composition (A) is polyether modified silicone (the particularly PEG-9 poly dimethyl silicon with branched silicone chain
Oxygen ethyl dimethyl silicone polymer) in the case of, emulsification deodorant compositions through when foul and suppressed extraordinarily, thus be preferred
's.
Embodiment
Below, illustrate in greater detail the present invention based on embodiment, but the present invention is not limited to these embodiments.Need
Illustrating, blend amount is the blend amount (that is, the blend amount of the active ingredient in each raw material) of each composition, unless otherwise specified,
Otherwise represent with " quality % ".
Embodiment 1
It according to following composition, is prepared by a conventional method the w/o type emulsification deodorant compositions of emulsifiable paste shape.
<composition>
Comparative example 1
It according to following composition, is prepared by a conventional method the w/o type emulsification deodorant compositions of emulsifiable paste shape.
<composition>
For each deodorant compositions obtaining in above-described embodiment 1 and comparative example 1, the following survivability evaluating bactericide.
(evaluation of the survival rate of bactericide (benzalkonium chloride and isopropyl methyl phenol))
It is prepared for synthetic perspiration according to JIS L0848:2004.Specifically, by L-Histidine hydrochloride monohydrate
0.5g, sodium chloride 5g, sodium dihydrogen phosphate dihydrate 2.2g are dissolved in the water, be subsequently added into 0.1mol/L NaOH 15mL and
Make total amount reach the water of 1L, prepare acid synthetic perspiration.The pH of obtained acid synthetic perspiration is 5.5.
It is applied to obtained deodorant compositions 20 μ L on keratin cloth.Above-mentioned acid synthetic perspiration 20mL is loaded
After in 100mL beaker, put into the keratin cloth after coating in beaker, vibrate 10 minutes with 100rpm, the angle after being vibrated
Albumen cloth.
After adding methyl alcohol 10mL in 15mL centrifuge tube, the keratin cloth after vibration is put in centrifuge tube, with 150rpm
Vibrate 10 minutes.Afterwards, with the film filter of 0.45 μm, the liquid in centrifuge tube is filtered.
Afterwards, the amount (Y) of the bactericide in liquid after utilizing HPLC to have rated filtration.In addition, prepared institute separately
The evaluation sample that the deodorant compositions 20 μ L obtaining is applied on keratin cloth, does not vibrates in acid synthetic perspiration and enters
Go same process, the amount (X) of the bactericide in the liquid after filtration now has been evaluated.Amount with bactericide
(X), on the basis of, the survival rate ((Y)/(X) × 100%) of bactericide is obtained.It should be noted that for benzalkonium chloride and isopropyl
Ylmethyl phenol, separately carries out the calculating of survival rate.
The result of above-mentioned evaluation, the survival rate of the benzalkonium chloride of the emulsification deodorant compositions (embodiment 1) of the present invention is
97.9%, the survival rate of isopropyl methyl phenol is 54.1%.On the other hand, (the ratio of the emulsification deodorant compositions without composition (C)
Compared with example 1) the survival rate of benzalkonium chloride be 88.0%, the survival rate of isopropyl methyl phenol is 41.6%.That is, the breast of the present invention
Change deodorant compositions and demonstrate the survival rate of excellent bactericide (benzalkonium chloride and isopropyl methyl phenol).
Embodiment 2
It according to following composition, is prepared by a conventional method the w/o type emulsification deodorant compositions of emulsifiable paste shape.
<composition>
The emulsification deodorant compositions of above-described embodiment 2 is preserved 2 months under 40 DEG C of environment, the stink after preserving is changed
Carry out sensory evaluation.As comparison, employ the preservation product saving 2 months under 5 DEG C of environment.
Sample (preserving the preservation product of 2 months under 40 DEG C of environment) and comparison (are preserved the guarantor of 2 months under 5 DEG C of environment
Deposit product) stink be adjacent to compare as a result, sample does not has difference with the stink compareing, the emulsification deodorizing of embodiment 2 combination
Thing through when anti-fouling excellent.
It follows that the emulsification deodorant compositions of embodiment 1 and embodiment 2 is applied to oxter, confirm sense of touch.Its result,
Tacky when the emulsification deodorant compositions of embodiment 1 and embodiment 2 does not exist coating, demonstrates excellent use feeling.Need
Bright, the evaluation of above-mentioned use feeling is carried out by 8 specialty judging panels.
Additionally, the Formulation Example of the emulsification deodorant compositions of the present invention described below.
Formulation Example 1: gel (translucent emulsifiable paste)
Formulation Example 2: gel (translucent emulsifiable paste)
Formulation Example 3: gel (translucent emulsifiable paste)
Formulation Example 4: emulsion
Formulation Example 5: gel (translucent emulsifiable paste)
Formulation Example 6: gel (translucent emulsifiable paste)
Formulation Example 7: gel (translucent emulsifiable paste)
Formulation Example 8: gel (translucent emulsifiable paste)
Formulation Example 9: gel (translucent emulsifiable paste)
It should be noted that the details of embodiment and each composition described in Formulation Example is as follows.
KF6017: trade name " KF-6017 ", the manufacture of chemical industry society of SHIN-ETSU HANTOTAI, HLB=4.5
Dimethicone/Vinyl Dimethicone cross-linked polymer(*1): trade name " KSG-15 ", SHIN-ETSU HANTOTAI
Chemical industry society manufactures
Dimethicone/Vinyl Dimethicone cross-linked polymer(*2): trade name " KSG-16 ", SHIN-ETSU HANTOTAI
Chemical industry society manufactures
Palmitic acid 2-Octyl Nitrite: trade name " U ヨ POC ", KOYO fine chemical society manufacture
Dimethyl silicone polymer: trade name " KF 96A-6CS ", chemical industry society of SHIN-ETSU HANTOTAI manufacture
Chlorination hydroxyl aluminium: trade name " PAC 1000 ", many wooden chemistries society manufacture
Isopropyl methyl phenol: trade name " isopropyl methyl phenol ", Osaka chemical conversion society manufacture
Benzalkonium chloride: trade name " カ チ オ Application G-50 ", chemical conversion industry society of Sanyo manufacture
DPG: trade name " DPG-FC ", Asahi Glass society manufacture
Concentrated glycerin: trade name " cosmetic concentrated glycerin ", slope this chemical industry society manufacture
PEG400: trade name " PEG-400 ", chemical conversion industry society of Sanyo manufacture
1,3 butylene glycol: trade name " 1,3 butylene glycol ", Daicel society manufacture
Methyl p-hydroxybenzoate: trade name " メ ッ キ Application ス-M ", u'eno pharmacy society manufacture
Ethanol: trade name " 95 ° of general fermentation alcohol ", Bao Jiuzao society manufacture
Glucose: trade name " Japanese Pharmacopoeia glucose NG-TDA ", San-ei Sucrochemical society manufacture
Glycine betaine: trade name " Aminocoat ", chemistry society of Asahi Chemical Industry manufacture
Isononyl isononanoate: trade name " SALACOS 99 ", day Qing Aoliyou society manufacture
Dimethyl silicone polymer: trade name " SH2O0C 10CS-JASU ", Dow Corning Toray society manufacture
Decamethylcyclopentaandoxane: trade name " KF-995 ", chemical industry society of SHIN-ETSU HANTOTAI manufacture
Industrial applicibility
The deodorant of the emulsification deodorant compositions of the present invention and the present invention is not particularly limited, and is used as purpose and is to prevent
Or remove the goods of body odor or bad smell of perspiration.The emulsification deodorant compositions of the present invention and the deodorant of the present invention be used for example as cosmetics,
Quasi drug, pharmaceuticals, groceries etc..
Claims (8)
1. emulsifying a deodorant compositions, it comprises:
Composition (A): polyether modified silicone；
Composition (B): Dimethicone/Vinyl Dimethicone cross-linked polymer；
Composition (C): palmitic acid 2-Octyl Nitrite；
Composition (D): antiperspirant；
Composition (E): bactericide；With
Composition (F): water.
2. emulsification deodorant compositions as claimed in claim 1, wherein, described composition (A) is the polyethers with branched silicone chain
Modified silicone.
3. emulsification deodorant compositions as claimed in claim 1 or 2, wherein, described composition (A) is PEG-9 polydimethylsiloxanes
Ethyl dimethyl silicone polymer.
4. the emulsification deodorant compositions as according to any one of claims 1 to 3, wherein, described composition (D) is for selected from by chlorination
Antiperspirant in the group of hydroxyl aluminium, p-phenolsulfonic acid's zinc and alum composition.
5. the emulsification deodorant compositions as according to any one of Claims 1 to 4, wherein, described composition (E) is for selected from by isopropyl
Bactericide in the group of ylmethyl phenol, benzalkonium chloride, hinokitol, triclosan and salicylic acid composition.
6. the emulsification deodorant compositions as according to any one of Claims 1 to 5, which is emulsifiable paste shape.
7. a deodorant, it possesses the emulsification deodorant compositions according to any one of container and claim 1～6, above-mentioned breast
Change deodorant compositions to be filled in said vesse.
8. deodorant as claimed in claim 7, which is non-aerosol preparation.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-199775 | 2014-09-30 | ||
| JP2014199775 | 2014-09-30 | ||
| PCT/JP2015/076773 WO2016052277A1 (en) | 2014-09-30 | 2015-09-18 | Emulsified deodorant composition and deodorant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106102700A true CN106102700A (en) | 2016-11-09 |
| CN106102700B CN106102700B (en) | 2018-11-16 |
Family
ID=55630317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580013148.1A Expired - Fee Related CN106102700B (en) | 2014-09-30 | 2015-09-18 | Emulsify deodorant compositions and deodorant |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5951155B1 (en) |
| CN (1) | CN106102700B (en) |
| WO (1) | WO2016052277A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109922788A (en) * | 2016-11-14 | 2019-06-21 | 株式会社资生堂 | Dermatologic preparation composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6692703B2 (en) * | 2016-06-10 | 2020-05-13 | 株式会社 資生堂 | Antiperspirant or deodorant cosmetics |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183144A (en) * | 2001-12-21 | 2003-07-03 | Lion Corp | Body odor-inhibiting composition |
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
| JP2004292446A (en) * | 2003-03-12 | 2004-10-21 | Kao Corp | Antiperspiration deodorant spray composition |
| JP2014047186A (en) * | 2012-08-31 | 2014-03-17 | Mandom Corp | Deodorant |
-
2015
- 2015-09-18 JP JP2016506396A patent/JP5951155B1/en active Active
- 2015-09-18 WO PCT/JP2015/076773 patent/WO2016052277A1/en active Application Filing
- 2015-09-18 CN CN201580013148.1A patent/CN106102700B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183144A (en) * | 2001-12-21 | 2003-07-03 | Lion Corp | Body odor-inhibiting composition |
| CN1530094A (en) * | 2003-03-12 | 2004-09-22 | 花王株式会社 | Deodorization spraying composition |
| JP2004292446A (en) * | 2003-03-12 | 2004-10-21 | Kao Corp | Antiperspiration deodorant spray composition |
| JP2014047186A (en) * | 2012-08-31 | 2014-03-17 | Mandom Corp | Deodorant |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109922788A (en) * | 2016-11-14 | 2019-06-21 | 株式会社资生堂 | Dermatologic preparation composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5951155B1 (en) | 2016-07-13 |
| JPWO2016052277A1 (en) | 2017-04-27 |
| CN106102700B (en) | 2018-11-16 |
| WO2016052277A1 (en) | 2016-04-07 |
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