CN1530094A - Deodorization spraying composition - Google Patents
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- CN1530094A CN1530094A CNA2004100084963A CN200410008496A CN1530094A CN 1530094 A CN1530094 A CN 1530094A CN A2004100084963 A CNA2004100084963 A CN A2004100084963A CN 200410008496 A CN200410008496 A CN 200410008496A CN 1530094 A CN1530094 A CN 1530094A
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Abstract
This antiperspiration deodorant spray composition contains (a) a hydrophobic globular powder, (b) a polyether-modified silicone, (c) an antiperspirant salt and/or a microbicide, (d) an oil which is liquid at 25[deg.]C [provided that the component (b) is excluded], and (e) a propellant.
Description
Technical field
The present invention relates to the comfortable deodorization spraying composition of dermal sensation.
Background technology
Preventing to be clamminess, in the smelly deodorization goods, being the viscous sense of eliminating perspiration, be extensive use of the Powder Ject that is added with powder body because of perspiration.Usually, the Powder Ject that contains powder body is to be mixed with other composition by powder body and to make its dispersion and the compositions that obtains and propellant are filled into the product in the spray containers.When this spray containers left standstill, powder body was deposited in container bottom, thus need shake spray containers before use, so that powder body disperses once more.
When using Powder Ject under the state of powder dispersity difference, problem is that each composition can not evenly spray, and can not fully reach jeting effect.And owing to can not evenly spray powder body, can cause white residue (residual white) on skin, occurring because of the powder body cohesion thereupon, promptly, in order to realize desired properties, important part is, need make powder body redispersion fully, and the Powder Ject compositions can be sprayed before need precipitating once more at the powder body of redispersion.Particularly when powder body was organic powder, it is shorter that the powder body of redispersion can keep the time of fine dispersion state to trend towards.
So in order to improve the dispersibility of the powder body in the Powder Ject compositions, people have worked out various methods.
For example, the powder aerosol compositions that is disclosed in the Japanese kokai publication hei 3-157327 communique is characterised in that, comprising: Talcum, silicic acid anhydride, Kaolin, polymeric aluminum chloride hydrophilic inorganic powder body such as (aluminiumhydroxy chloride); Contain the propellant of one of them at least in liquefied petroleum gas and the dimethyl ether; In non-ionic surface active agent and the silicone oil at least one of them; And ethanol.But in this powder aerosol compositions, the dispersibility of powder body is still abundant inadequately.Although and it is the state that bleaches that is used for suppressing after this powder aerosol compositions is sprayed, because of its oiliness sense strong, so just can not get the skin feel that powder body brought of good dry feeling.
And the aerosol combination that contains powder that is disclosed in Japanese kokai publication hei 6-48919 communique is characterised in that, contains liquefied petroleum gas and inorganic powder, and is added with the sorbitan fatty acid ester and/or the polyoxyalkylene alkyl of specified quantitative.But contain in the aerosol combination of powder at this, the dispersibility of powder body is still abundant inadequately, and it and reckon without the dispersibility of organic powder.
In Japanese kokai publication hei 5-229925 communique, disclosed the liquid antiperspirant composition that antiperspirant materials such as alcohols and polyether modified silicone and polymeric aluminum chloride are matched and form.This antiperspirant composition utilizes polyether modified silicone and ethanol to prevent that the powder body in the compositions from forming crystallization, suppresses the residual white of hidroschesis salt.But,, just can not get suppressing fully residual white effect when except that antiperspirant, also being added with in this antiperspirant composition when being used to improve the powder body of skin feel such as dry feeling.
In Japanese kokai publication hei 8-12545 communique, disclosed mushroom inhibitor or antibacterial such as astringents such as containing polymeric aluminum chloride, trichloro hydroxyl diphenyl ether, also contain the specific spherical silicone rubber powder and the hidroschesis-deodorizer of fluid oil sexual element simultaneously.And, also disclosed and will comprise the solid-state or liquid silicone oil of polyoxyalkylene modified polyorganosiloxane as the content that can add the oiliness composition.But in this communique, only notice the sense of touch that improves the silicone rubber powder body, and the dispersibility that improves this spherical silicone rubber powder body is mentioned not it is abundant inadequately to suppress residual white effect.
What disclosed in the Japanese kokai publication hei 11-335254 communique is the aerosol combination of liquid oil preparationes such as a kind of composite granule that contains inorganic particles such as polymeric aluminum chloride, is made of different types of organopolysiloxane and isopropyl myristate.Although but this aerosol combination has dry feeling, it is abundant inadequately to suppress residual white effect.
Summary of the invention
The invention provides a kind of dispersibility, make the comfortable deodorization spraying composition of dermal sensation by raising powder body composition.
Discoveries such as the inventor: contain the spherical powder body of (a) hydrophobicity and (b) deodorization spraying composition of polyether modified silicone can improve the dispersibility and the redispersibility of the spherical powder body of hydrophobicity (a), thereby reach desirable effect.
That is, the present invention contains the oil preparation (but not comprising composition (b)) that is in a liquid state under 25 ℃ of the spherical powder body of (a) hydrophobicity, (b) polyether modified silicone, (c) hidroschesis salt and/or antibacterial, (d) and (e) deodorization spraying composition of propellant.
The spherical powder body of hydrophobicity (a) is the surperficial at least near-spherical powder body with hydrophobic surface characteristic, when it is applicable to skin, has the effect that is clamminess and feels and improve skin feel such as dry feeling that inhibition causes because of perspiration.The spherical powder body of hydrophobicity of the present invention (a) uses and is considered to have the hydrophilic powder body that improves the skin feel effect as Talcum etc. all the time and compares the big spherical powder body of hydrophobicity.The shape of the spherical powder body of hydrophobicity (a) does not require it is the spherical of strictness, for example, can be the near-spherical as the cross section ovalize, and be preferably spherical.The mean diameter of the spherical powder body of hydrophobicity (a) is preferably 0.1～30 μ m, more preferably 1～10 μ m.When mean diameter when 0.1 μ m is above, can obtain desirable smooth sense of touch; And when mean diameter when 30 μ m are following, can obtain not having the good skin feel of harsh feeling.
As the hydrophobic criterion of the spherical powder body of hydrophobicity (a), preferred critical surface tension is below the 50mN/m.When critical surface tension is 50mN/m when following, hydrophilic is little, and powder body is absorbing sweat not, therefore can suppress the sense of being clamminess.
Consider the hydrophobicity degree and the shape of powder body, with regard to the spherical powder body of hydrophobicity of the present invention (a), more preferably use the latter in inorganic particle and the organic polymer powder.
As the spherical powder body of hydrophobicity (a), specifically can enumerate the powder body of organic polymers such as nylon resin, polystyrene resins, polyvinyl resin, polymethyl methacrylate resinoid, polyurethane kind resin, phenolic resinoid, silicones.
Particularly the water-repellancy height owing to the silicones powder body is preferred, for example, the polysiloxane compound that can enumerate methylsiloxane network polymers, compound silicone powder body, is had a free polymerizable group by a certain end carries out the dispersin polymerization of vinyl monomer as dispersant and polymer particles (with reference to TOHKEMY 2002-308909 communique) of obtaining etc. in solvent.In compound silicone powder body, the compound silicone powder body (cross-linking type silicone-netted silicone block copolymer) that covers the silicone rubber powder surface because of silicones has good dry feeling and has and can keep suppressing residual white effect for a long time, therefore also preferred this powder body.Because this composite granule can hold hereinafter described oil preparation suction in powder body inside, and continues to discharge on skin, so can think that it can make dry and comfortable sense of touch and suppress residual white effect lasting.
The used spherical powder body of hydrophobicity (a) of the present invention can for example can be enumerated SP-500 nylon resins such as (Toray) by buying in the commercially available product; FINE PEARL (Sumitomo Chemical), TECHPOLYMER SB (hydrops changes into product industry), FINE POWDER SGP polystyrene resins such as (combine and grind chemistry); FLOW BEADS polyvinyl resins such as (refining in the Sumitomo); MATSUMOTO MICROSPHERE M (pharmacy of this oils and fats of pine), TECH POLYMERMB (hydrops changes into product industry), FINE POWDER MP polymethyl methacrylate resinoids such as (combine and grind chemistry); KMP-590 (SHIN-ETSU HANTOTAI's chemical industry), TOSPEARL 130, TOSPEARL 145, TOSPEARL 2000B silicone powder body such as (above are the Silicones of GE-Toshiba product).Particularly with regard to above-mentioned compound silicone powder body (cross-linking type silicone-netted silicone block copolymer), can enumerate KSP-100, KSP-101, KSP-102, KSP-105 (above is SHIN-ETSU HANTOTAI's chemical industry product) etc.
The content of the spherical powder body of hydrophobicity (a) is preferably 0.1～30 quality % in comprising the total amount of propellant.Consider that particularly for suppressing residual white on the skin and obtain dry and comfortable sense of touch, the content of powder body (a) is preferably 0.3～10 quality %.
Polyether modified silicone (b) is side chain or terminal organopolysiloxane compound with polyoxyalkylenes, is paste or is high viscosity liquid.It residually has an inhibition effect in vain to what caused by the spherical powder body of hydrophobicity (a) and hidroschesis salt and/or antibacterial (c).And polyether modified silicone (b) can be enumerated for example polyoxyethylene-methyl polysiloxane copolymer, poly-(epoxy ethane-epoxy propane) methyl polysiloxane copolymer.Above-mentioned polyether modified silicone can be any in modified side chain, an end modification, the two ends modification.
Polyether modified silicone (b) can be by buying in the commercially available product, for example, can enumerate poly-(epoxy ethane-epoxy propane) methyl polysiloxane copolymer such as silicone KF-6011, KF-6013, KF-6015, KF-6017, KF-6019, KF-6028 (SHIN-ETSU HANTOTAI's chemical industry system) and SH-3771, SH-3775 polyoxyethylene-methyl polysiloxane copolymer KF-6012 (SHIN-ETSU HANTOTAI's chemical industry system) such as (Toray Dow Corning Silicon systems).
In the above-mentioned polyether modified silicone (b) HLB below 6 and the viscosity 25 ℃ the time be 500mm
2The above polyether modified silicone of/s has suitable surface activity energy, and the spherical powder body of hydrophobicity (a) redispersion in deodorization spraying composition the time, can be formed uniform dispersity, and can keep this good dispersity for a long time.
By use below the HLB6, the polyether modified silicone below the HLB5 more preferably, can not condense in the time of can making the spherical powder body of hydrophobicity (a) redispersion, and can be dispersed in the compositions.HLB herein represents hydrophile-lipophile balance (Hydrophile-Lipophile Balance), is the value of being tried to achieve by following Griffin formula:
Formula 1:
And the viscosity when using 25 ℃ is 500mm
2/ s is above, 600～2000mm more preferably
2The polyether modified silicone of/s can prolong the dispersive persistent period of the spherical powder body of hydrophobicity (a).Herein, the viscosity 25 ℃ the time can be recorded by the method 1 in the cosmetic material standard second edition (Ubbelohde capillary viscosimeter).
HLB6 viscosity following and 25 ℃ the time is 500mm
2The above polyether modified silicone of/s can be enumerated in above-mentioned commercially available product: (HLB 4.5, viscosity 600mm for silicone KF-6017
2/ s, SHIN-ETSU HANTOTAI's chemical industry), KF-6019 (HLB4.5, viscosity 850mm
2/ s, SHIN-ETSU HANTOTAI's chemical industry), KF-6028 (HLB4, viscosity 900mm
2/ s, SHIN-ETSU HANTOTAI's chemical industry), SH-3775 (HLB5, viscosity 1600mm
2/ s, the Silicones of GE-Toshiba).
For effectively improving the dispersibility of the spherical powder body of hydrophobicity (a) and bring into play the residual white effect of good inhibition, the used in amounts of polyether modified silicone (b) is more than to a certain degree, but skin feels comfortably cool when being coated with deodorization spraying composition in order to make, and its consumption is preferably an amount of.Comprehensive above-mentioned viewpoint is considered, polyether modified silicone in the deodorization spraying composition (b)---comprise and using below the HLB6 and the viscosity 25 ℃ the time is 500mm
2During the above polyether modified silicone of/s---content in comprising the total amount of propellant, be 0.001～5 quality %, be preferably 0.001～3 quality %, more preferably 0.01～3 quality % is preferably 0.01～1 quality % especially.
And by the dispersibility of powder body composition during with the coating deodorization spraying composition angle of dermal sensation consider, the mass ratio ((a): (b)) of spherical powder body of hydrophobicity (a) and polyether modified silicone (b) is preferably 1000: 1～5: 1 in the deodorization spraying composition, more preferably 300: 1～10: 1, be preferably 200: 1～10: 1 especially.
Can also contain hidroschesis salt and/or antibacterial (c) in the deodorization spraying composition of the present invention.With regard to hidroschesis salt and/or antibacterial (c), can enumerate the material that all the time is used for deodorizer.For example, with regard to hidroschesis salt, can enumerate polymeric aluminum chloride, aluminum zirconium double salt, aluminum chloride etc.And with regard to antibacterial, can enumerate for example trichloro hydroxyl diphenyl ether, isopropyl methyl phenol, benzoic acid, zephiran, trichlorine diphenylurea etc.The use capable of being combined of hidroschesis salt and antibacterial.In deodorization spraying composition of the present invention, in comprising the total amount of propellant, hidroschesis salt preferred content is 0.01～5 quality %, and the antibacterial preferred content is 0.005～0.1 quality %.
In addition, deodorization spraying composition of the present invention also can contain the oil preparation (d) except that composition (b).Be preferably the oil preparation that is in a liquid state under 25 ℃ especially, can be further obtained the powder body composition is formed the inhibition effect of white residue thus on skin.
As 25 ℃ of liquid down oil preparationes (d), for example can enumerate, the viscosity in the time of 25 ℃ is 1000mm
2Hydro carbons such as silicone oil (but not comprising the material that is equivalent to polyether modified silicone (b)), three decanes, liquid paraffin such as the dimethyl silscone below/the s, decamethylcyclopentasiloxane, Methylphenylsilanone.; Glycerol, 1,3 butylene glycol, 1, polyalcohols such as 4-butanediol; The branched chain fatty acid class; Side chain alcohols such as isopropyl alcohol, 2-ethyl-butyl alcohol; Fatty acid esters such as myristyl myristate, isopropyl myristate, isopropyl palmitate, NPDC; Two glyceride such as myristic acid glyceryl isostearate; Triglyceride such as isostearic acid triglyceride, coco-nut oil fatty acid triglyceride etc.
Wherein, good because of suppressing residual white effect, so be preferably the compositions of side chain ester oils such as above-mentioned silicone oil and isopropyl myristate, isopropyl palmitate, NPDC, especially preferably use the compositions of silicone oil and side chain ester oil.When using the compositions of silicone oil and side chain ester oil, (the silicone oil: side chain ester oil) by quality ratio, be 5: 1～1: 10, be preferably 1: 1～1: 5 especially, just can be suppressed residual white effect significantly thus of the ratio between them.
The content of above-mentioned oil preparation is preferably 0.1～20 quality % in comprising the total amount of propellant, more preferably 0.5～15 quality %.When its content is 0.1 quality % when above, can give full play to and suppress residual white effect; And when 20 quality % are following, can make dermal sensation comfortable.
Deodorization spraying composition of the present invention is not particularly limited propellant, for example, can enumerate Freon gases such as Freon 13 4a, Freon 113; Hydrocarbon system gases such as propane, iso-butane, isopentane; Liquefied gas such as dimethyl ether; Carbon dioxide and nitrogen etc.In comprising the total amount of propellant, the content of propellant is about 60～99 quality %.
In addition, deodorization spraying composition of the present invention can suitably add pigment, pigment, spice, freshener, antiinflammatory, wetting agent, antioxidant, stabilizing agent etc. as required in the scope of effect of the present invention.
Deodorization spraying composition of the present invention can adopt the common method manufacturing, for example other uniform ingredients except that propellant is mixed, and the spray containers of again the gained mixture being packed into is filled propellant then, makes deodorization spraying composition thus.
As mentioned above, deodorization spraying composition of the present invention is used in combination by spherical powder body of hydrophobicity (a) and polyether modified silicone (b), can make good dispersion and jitter time when shaking spray containers etc. and make that the spherical powder body of hydrophobicity (a) redispersion is in compositions in the container long.Therefore, just can make the spherical powder body of hydrophobicity (a) by evenly ejection in the container, and make it to be uniformly coated on the skin.Thereby, the effect that is clamminess after the spherical powder body of hydrophobicity of the present invention (a) has the effect that very high inhibition perspiration is clamminess and suppresses just to have finished injection well, and continue to keep the effect of the dry and comfortable sense of touch of skin and suppress residual white effect on the skin.
In addition, when the redispersibility of the spherical powder body of hydrophobicity in the spray containers (a) is improved, the redispersibility of other composition in the compositions except that the spherical powder body of hydrophobicity (a) also is improved thereupon, so, deodorization composition in the deodorant compositions and the spherical powder body of hydrophobicity (a) are together, can both be equably by spraying in the spray containers, and be coated on the skin equably.Therefore, not only improved and suppressed the effect that perspiration is clamminess, also improved deodorizing effect.
And because the redispersibility of powder body is good and jitter time is long, so the operation of powder body redispersion is easy to implement, only before the injection that begins most, shake just redispersion equably of container gently, and the action that needn't in the middle of continuous injection deodorization spraying composition process, shake redispersion such as container repeatedly once more.
The specific embodiment
Further describe the present invention according to following embodiment, illustrate the specific embodiment of the present invention.
Embodiment A series
(embodiment A 1～A7 and Comparative examples A 1～A5)
(method for making)
The uniform ingredients except that LPG shown in the table 1 is mixed, and the gained mixture is filled into injection with in the withstand voltage glass container, fill LPG then, be modulated into the deodorization spraying composition of forming shown in the table 1.In addition, composition is represented with quality %.
(evaluation methodology)
Spray composite evenly and in right amount is coated on 10 ginseng survey persons' upper arm parts, the inhibition of the sense of being clamminess, residual white inhibition, dry feeling is continued to carry out the sense evaluation according to following standard.Collect each one evaluation and count, by count meansigma methods classification of evaluation.Evaluation result is as shown in table 1 with composition.
＜evaluation criterion 〉
(1) inhibition (having or not the sense of being clamminess after estimating coating) of being clamminess and feeling
5: the sense of not being clamminess fully;
4: the sense of not being clamminess;
3: be unable to explain clearly;
2: the sense of being clamminess is arranged slightly;
1: the sense of being clamminess is arranged.
(2) lasting (the estimating the dry feeling of coating after 1 hour) of dry feeling
5: dry and comfortable;
4: dry feeling is arranged slightly;
3: be unable to explain clearly;
2: not too dry and comfortable;
1: have no dry feeling.
＜estimate the meansigma methods of counting 〉
◎：4.5～5.0；
○：3.5～4.4；
○△：2.5～3.4；
△：1.5～2.4；
×：1.0～1.4。
(3) residual white (estimating the degree of turning white of coating back range estimation)
4: do not bleach;
3: almost do not bleach;
2: have slightly to bleach;
1: bleach.
＜estimate the meansigma methods of counting 〉
◎：3.5～4.0；
○：2.5～3.4；
△：1.5～2.4；
×：1.0～1.4。
The result of table 1 expression embodiment A 1～A7 and Comparative examples A 1～A5.
According to its result as can be known, the deodorization spraying composition of the present invention of being furnished with the liquid oil preparation (d) (except that polyether modified silicone) under the spherical powder body of hydrophobicity (a), polyether modified silicone (b), hidroschesis salt and/or antibacterial (c) and 25 ℃ is that residual white inhibition effect, skin feel or its persistence are all fine.Side chain ester oil (isopropyl palmitate) and Methylphenylsilanone. be used in combination as the embodiment A 4 of oil preparation compare with the embodiment A 3 of only using isopropyl palmitate, residual white inhibition effect is higher, equally, embodiment A 7 is compared with embodiment A 6, and this index improves too.And use cross-linking type silicone-reticular pattern silicone block copolymer to compare with embodiment A 2 as the embodiment A 5 of the spherical powder body of hydrophobicity, improved the persistence of dry feeling.And embodiment A 7 is compared with embodiment A 4, also can observe the same effect of improving.
On the other hand, degree is high especially and the Comparative examples A 5 that do not contain the spherical powder body of hydrophobicity is clamminess to contain hydrophilic powder body Talcum.And the Comparative examples A 1 that does not contain polyether modified silicone is compared with A5 with embodiment A 2 with A2, significant residual white phenomenon is not only arranged, and skin feel such as dry feeling is also very poor, even adopt cross-linking type silicone-web-like silicon ketone copolymers also not reach high evaluation value as the spherical powder body of hydrophobicity.And contain the spherical powder body of hydrophobicity but the Comparative examples A 3 that do not contain the oil preparation that is in a liquid state under 25 ℃ and A4 and embodiment A 3 have also been found same difference when comparing with A4.
Embodiment B series
(Embodiment B 1～B4 and comparative example B1～B2)
(method for making)
The uniform ingredients except that LPG shown in the table 2 is mixed, and the gained mixture is filled into injection with in the withstand voltage glass container, fill LPG then, be modulated into the deodorization spraying composition of forming shown in the table 2.In addition, composition is represented with quality %.
(evaluation)
According to following method to the dispersibility of gained deodorization spraying composition, deodorizing effect and to perspiration the be clamminess inhibition of sense estimate.Evaluation result is as shown in table 2 with composition.
(1) dispersibility
Deodorization spraying composition is filled into injection with in the withstand voltage glass container, leaves standstill, examine content, confirm the powder body post precipitation, shake container gently and make the powder body redispersion, and then leave standstill, measure the jitter time of powder body by the glass container standing motionless as if facing a wall.After this jitter time is meant and shakes container gently, by leaving standstill to forming layering institute more than the 2mm through the time.
＜evaluation criterion 〉
Zero: jitter time is more than 15 seconds;
△: jitter time less than 15 seconds;
*: can not redispersion, keep state of aggregation.
(2) deodorizing effect, perspiration be clamminess the sense inhibition
The gained deodorization spraying composition is shaken gently, is sprayed on 10 oxters then with ginseng survey person of strong bromhidrosis, after 8 hours, according to following standard to deodorizing effect and to perspiration be clamminess the sense the inhibition effect estimate.Collect each one evaluation and count, by count meansigma methods classification of evaluation.
＜evaluation criterion 〉
Deodorizing effect (estimating the deodorizing effect of spraying after 8 hours)
4: deodorizing effect is very high;
3: the deodorizing effect height;
2: deodorizing effect is low slightly;
1: deodorizing effect is low.
To the be clamminess inhibition (estimate spraying after 8 hours to the be clamminess inhibition of sense of perspiration) of sense of perspiration
4: very good;
3: good;
2: poor slightly;
1: poor.
＜estimate the meansigma methods of counting 〉
◎：3.5～4.0；
○：2.5～3.4；
△：1.5～2.4；
×：1.0～1.4。
The result of table 2 expression Embodiment B 1～B4 and comparative example B1～B2.
According to its result as can be known, in deodorization spraying composition of the present invention, be 500mm when containing 25 ℃ of following viscosity
2The above polyether modified silicone of/s is the dispersibility, deodorizing effect, or all fine to the be clamminess inhibition effect of sense of perspiration of the spherical powder body of hydrophobicity with as polyether modified silicone (b) time.Particularly will compare with the Embodiment B 1 of using nylon powder as the Embodiment B 2 of the spherical powder body of hydrophobicity (a), have better deodorizing effect and the be clamminess inhibition effect of sense of perspiration by the compound silicone powder body (cross-linking type silicone-reticular pattern silicone block copolymer) that silicones covers the silicone rubber powder surface.
And contain 25 ℃ of following viscosity numbers less than 500mm
2Polyether modified silicone 3 (HLB4.5, the 150mm of/s
2/ s) Embodiment B 3, although can suppress the perspiration sense of being clamminess, dispersibility and deodorizing effect are also not too abundant.
Contain polyether modified silicone equally with Embodiment B 3, and contain above-mentioned silicone powder body (cross-linking type silicone-reticular pattern silicone block copolymer) to compare with Embodiment B 3 as the Embodiment B 4 of the spherical powder body of hydrophobicity (a), deodorizing effect is better.
On the other hand, no matter the comparative example B1 and the comparative example B2 that do not contain polyether modified silicone adopt the spherical powder body of which kind of hydrophobicity (a), and its dispersibility is all insufficient, be deodorizing effect or to perspiration be clamminess the sense the inhibition effect all than embodiment difference.
(Embodiment B 5)
With following prescription (quality %) spray composite that makes powder.
Nylon powder (nylon powder SP-500, Toray) 4.00
Isopropyl methyl phenol 0.002
Isopropyl myristate 1.50
Polyoxyethylene-methyl polysiloxane copolymer 0.03
(SH-3775, Toray Dow Corning Silicon, HLB5, viscosity 1600mm
2/ s)
Spice 0.02
Ethanol 4.268
LPG?????????????????????????????????????90.00
(Embodiment B 6)
With following prescription (quality %) spray composite that makes powder.
Cross-linking type silicone-reticular pattern silicone block copolymer
(KSP-105, SHIN-ETSU HANTOTAI's chemical industry) 2.00
Polymeric aluminum chloride
(RocronP Hoechst AG company) 2.00
Polyoxyethylene-methyl polysiloxane copolymer 0.05
(KF-6017, chemical industrial company of SHIN-ETSU HANTOTAI, HLB4.5, viscosity 600mm
2/ s)
Isooctadecanol 0.50
Spice 0.10
Polyoxyethylene solidifies Oleum Ricini 0.15
Decamethylcyclopentasiloxane 3.20
(SH-245，Toray?Dow?Corning?Silicon)
LPG?????????????????????????????????????92.00
(Embodiment B 7)
With following prescription (quality %) spray composite that makes powder.
Cross-linking type silicone-reticular pattern silicone block copolymer
(KSP-100, SHIN-ETSU HANTOTAI's chemical industry) 2.00
Polymeric aluminum chloride
(REACH101，REHEIS)??????????????????????2.00
Polyoxyethylene-methyl polysiloxane copolymer 0.05
(SH-3775, Toray Dow Corning Silicon, HLB5, viscosity 1600mm
2/ s)
Isopropyl myristate 0.50
Dimethyl silscone (10mm
2/ s) 0.10
Spice 0.15
Decamethylcyclopentasiloxane 3.20
(SH-245，Toray?Dow?Corning?Silicon)
LPG?????????????????????????????????????92.00
Table 1
| Composition (quality %) | Embodiment A | Comparative examples A | ||||||||||||
| ??1 | ????2 | ????3 | ????4 | ????5 | ????6 | ????7 | ????1 | ????2 | ????3 | ????4 | ????5 | |||
| ?a’ | ?1 | Talcum | ??- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????3 |
| ?a | ?2 | Polystyrene resin *1 | ??3 | ????3 | ????- | ????- | ????- | ????- | ????- | ????3 | ????- | ????3 | ????- | ????- |
| ?3 | The methylsiloxane network polymers *2 | ??- | ????- | ????3 | ????3 | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | |
| ?4 | Cross-linking type silicone-reticular pattern silicone block copolymer *3 | ??- | ????- | ????- | ????- | ????3 | ????3 | ????3 | ????- | ????3 | ????- | ????3 | ????- | |
| ?b | ?5 | Polyoxyethylene methyl polysiloxane copolymer *4 | ??0.05 | ????0.05 | ????0.05 | ????0.05 | ????0.05 | ????0.05 | ????0.05 | ????- | ????- | ????0.05 | ????0.05 | ????0.05 |
| ?c | ?6 | Isopropyl methyl phenol | ??0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 | ????0.01 |
| ?7 | Polymeric aluminum chloride *5 | ??0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 | |
| ?d | ?8 | Dimethyl silscone *6 | ??1.5 | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????- | ????1.5 |
| ?9 | Isopropyl myristate | ??- | ????1.5 | ????1.5 | ????1 | ????1.5 | ????- | ????1 | ????1.5 | ????1.5 | ????- | ????- | ????- | |
| ?10 | Methylphenylsilanone. *7 | ??- | ????- | ????- | ????0.5 | ????- | ????1.5 | ????0.5 | ????- | ????- | ????- | ????- | ????- | |
| ?11 | LPG | ??94.94 | ????94.94 | ????94.94 | ????94.94 | ????94.94 | ????94.94 | ????94.94 | ????94.99 | ????94.99 | ????96.44 | ????96.44 | ????94.94 | |
| Add up to | ??100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ????100 | ||
| Estimate | The sense of being clamminess | ??○△ | ????○ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????○△ | ????○ | ????△ | ????○△ | ????× | |
| Residual white | ??○ | ????○ | ????○ | ????◎ | ????○ | ????○ | ????◎ | ????× | ????× | ????△ | ????△ | ????○ | ||
| Continuing of dry feeling | ??○△ | ????○△ | ????○ | ????○ | ????◎ | ????◎ | ????◎ | ????△ | ????○△ | ????× | ????△ | ????× | ||
*1:FINE PEARL 3000SP, Sumitomo Chemical
*2:KMP590, SHIN-ETSU HANTOTAI's chemical industry
*3:KSP-105, SHIN-ETSU HANTOTAI's chemical industry
*4:KF-6015, SHIN-ETSU HANTOTAI's chemical industry (HLB4.5,150mm
2/ s)
*5:REACH 501, REHEIS company
*6:KF-96 10cs, SHIN-ETSU HANTOTAI's chemical industry
*7：SH-556，Toray?Dow?Corning?Silicon
Table 2
| Embodiment B | Comparative example B | ||||||
| ????1 | ????2 | ????3 | ????4 | ???1 | ???2 | ||
| ?a | Nylon powder *1 | ????3 | ????- | ????3 | ????- | ???3 | ???- |
| Cross-linking type silicone reticular pattern silicone block copolymer *2 | ????- | ????3 | ????- | ????3 | ???- | ???3 | |
| ?b | Polyoxyethylene methyl polysiloxane copolymer 1 (polyether modified silicone 1) *3 | ????0.1 | ????0.1 | ????- | ????- | ???- | ???- |
| Polyoxyethylene methyl polysiloxane copolymer 2 (polyether modified silicone 2) *4 | ????- | ????- | ????- | ????- | ???- | ???- | |
| Polyoxyethylene methyl polysiloxane copolymer 3 (polyether modified silicone 3) *5 | ????- | ????- | ????0.1 | ????0.1 | ???- | ???- | |
| ?c | Polymeric aluminum chloride *6 | ????2 | ????2 | ????2 | ????2 | ???2 | ???2 |
| ?d | Isopropyl myristate | ????2 | ????2 | ????2 | ????2 | ???2 | ???2 |
| Decamethylcyclopentasiloxane *7 | ????10 | ????10 | ????10 | ????10 | ???10 | ???10 | |
| LPG | ????82.9 | ????82.9 | ????82.9 | ????82.9 | ???83 | ???83 | |
| Add up to | ????100.0 | ????100.0 | ????100.0 | ????100.0 | ???100.0 | ???100.0 | |
| Estimate | Dispersibility | ????○ | ????○ | ????△ | ????△ | ???△ | ???△ |
| Deodorizing effect | ????○ | ????◎ | ????△ | ????○ | ???△ | ???△ | |
| The inhibition of being clamminess and feeling to antiperspirant | ????○ | ????◎ | ????○ | ????○ | ???△ | ???△ | |
*1: nylon powder SP-500, Toray
*2:KSP-105, SHIN-ETSU HANTOTAI's chemical industry
*3:KF-6019, SHIN-ETSU HANTOTAI's chemical industry (HLB4.5,850mm
2/ s)
*4:KF-6013, SHIN-ETSU HANTOTAI's chemical industry (HLB4.5,400mm
2/ s)
*5:KF-6016, SHIN-ETSU HANTOTAI's chemical industry (HLB4.5,150mm
2/ s)
*6:REACH501, REHEIS company
*7：SH-245，Toray?Dow?Corning?Silicon
Claims (6)
1. a deodorization spraying composition is characterized in that, contains
(a) the spherical powder body of hydrophobicity;
(b) polyether modified silicone;
(c) hidroschesis salt and/or antibacterial;
(d) oil preparation (but not comprising composition (b)) that is in a liquid state 25 ℃ the time; With
(e) propellant.
2. deodorization spraying composition as claimed in claim 1 is characterized in that, the HLB of described polyether modified silicone (b) is below 6, and the viscosity 25 ℃ the time is 500mm
2More than/the s.
3. deodorization spraying composition as claimed in claim 1 is characterized in that, the spherical powder body of described hydrophobicity (a) is the organic polymer powder.
4. deodorization spraying composition as claimed in claim 3 is characterized in that, the spherical powder body of described hydrophobicity (a) is the silicone powder body.
5. deodorization spraying composition as claimed in claim 4 is characterized in that, the spherical powder body of described hydrophobicity (a) is the compound silicone powder body that is covered the silicone rubber powder surface by silicones.
6. deodorization spraying composition as claimed in claim 1 is characterized in that, the oil preparation that is in a liquid state under 25 ℃ (d) contains silicone oil and side chain ester oil.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003067231 | 2003-03-12 | ||
| JP2003067231 | 2003-03-12 | ||
| JP2003427087A JP4262081B2 (en) | 2003-12-24 | 2003-12-24 | Deodorant spray composition |
| JP2003427087 | 2003-12-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1530094A true CN1530094A (en) | 2004-09-22 |
| CN100417374C CN100417374C (en) | 2008-09-10 |
Family
ID=34315584
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100084963A Expired - Fee Related CN100417374C (en) | 2003-03-12 | 2004-03-12 | Deodorization spraying composition |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN100417374C (en) |
| TW (1) | TWI354566B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101467937B (en) * | 2007-12-28 | 2011-02-16 | 上海家化联合股份有限公司 | Spray components for suppressing perspiration |
| CN105473128A (en) * | 2014-03-28 | 2016-04-06 | 株式会社漫丹 | Deodorant or refreshing cosmetic material, and non-aerosol type spray product |
| CN106102700A (en) * | 2014-09-30 | 2016-11-09 | 株式会社漫丹 | Emulsification deodorant compositions and deodorant |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05229925A (en) * | 1992-02-19 | 1993-09-07 | Shiseido Co Ltd | Liquid antiperspirant composition |
| JP3178970B2 (en) * | 1994-06-30 | 2001-06-25 | 東レ・ダウコーニング・シリコーン株式会社 | Antiperspirant and deodorant |
-
2004
- 2004-03-12 TW TW93106656A patent/TWI354566B/en not_active IP Right Cessation
- 2004-03-12 CN CNB2004100084963A patent/CN100417374C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101467937B (en) * | 2007-12-28 | 2011-02-16 | 上海家化联合股份有限公司 | Spray components for suppressing perspiration |
| CN105473128A (en) * | 2014-03-28 | 2016-04-06 | 株式会社漫丹 | Deodorant or refreshing cosmetic material, and non-aerosol type spray product |
| CN105473128B (en) * | 2014-03-28 | 2018-01-05 | 株式会社漫丹 | Deodorant or refrigerant cosmetics and non-aerosol sprays product |
| CN106102700A (en) * | 2014-09-30 | 2016-11-09 | 株式会社漫丹 | Emulsification deodorant compositions and deodorant |
| CN106102700B (en) * | 2014-09-30 | 2018-11-16 | 株式会社漫丹 | Emulsify deodorant compositions and deodorant |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI354566B (en) | 2011-12-21 |
| TW200423965A (en) | 2004-11-16 |
| CN100417374C (en) | 2008-09-10 |
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