CN1193729C - Cosmetic compositions containing specific polysaccharide resins - Google Patents

Cosmetic compositions containing specific polysaccharide resins Download PDF

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Publication number
CN1193729C
CN1193729C CNB008124027A CN00812402A CN1193729C CN 1193729 C CN1193729 C CN 1193729C CN B008124027 A CNB008124027 A CN B008124027A CN 00812402 A CN00812402 A CN 00812402A CN 1193729 C CN1193729 C CN 1193729C
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China
Prior art keywords
compositions
amount
polysaccharide resins
phospholipid
pvp
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Expired - Fee Related
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CNB008124027A
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Chinese (zh)
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CN1372454A (en
Inventor
N·柯林斯
M·卡基
W·兰普雷希特
C·奥拉
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LOreal SA
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LOreal SA
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/044—Suspensions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/553—Phospholipids, e.g. lecithin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Biophysics (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

An embodiment of the present invention is a composition with enhanced film forming properties. The compositions of the present invention contain (a) at least one polysaccharide resin and (b) a film former other than said at least one polysaccharide resin. A cosmetic or pharmaceutical composition comprising the compositions of the present invention may be transfer-resistant, long wearing, and water resistant. Cosmetic and pharmaceutical compositions of the invention also may result in a flexible film that does not flake or crumble.

Description

The cosmetic composition that contains specific polysaccharide resins
The present invention relates to compositions, especially cosmetic composition that film property and dispersibility improve.Cosmetic composition of the present invention contain at least a polysaccharide resins and have one or more characteristics such as anti-transfer, wear-resisting, flexible and be easy to the coating.The present invention relates to contain the cosmetics and the drug products of this compositions.
Many painted cosmetic composition such as foundation cream, concealer, mascara, eye-liner and sunscreen of containing can stay the brittle film that the soft oil film that very easily shifts or formation can be peeled off or pulverize.Both of these case all causes the best persistency of said composition to reduce, and user needs to use repeatedly.For example, these compositionss when with some holder (as glass, teacup, medicated clothing or skin) can be when contacting attached to its surface (adhering to small part).In case adhere to, compositions is just left a trace on holder.
The cosmetic composition of anti-transfers more known in the art; But these compositions major parts all require further improvement.Known in the art being called " prevents shifting (transfer-free) ", and cosmetics comprise fatty material, volatile oil (especially volatile silicone oils and/or volatile hydrocarbon oil) usually in their composition.Therefore, most of these anti-metastatic compositions do not possess good film forming characteristics.For example, many these anti-compositions major parts that shift all are clamminess, and therefore the application and the spreadability of this compositions still need be improved.
Forming reason of failure film is that the anti-cosmetics that shift need use compound compositions, wherein the oily volatilized property solvent of part substitutes, these volatile solvents will volatilize with contact skin the time, stay the thin layer that is made of wax and/or resin, pigment, filler and activating agent substantially.Except the difficulty relevant with using the volatile compound preparation, this solution also has other shortcomings: powdering after the cosmetic and lacklustre effect.
Other compositions stays the brittle diaphragm that can come off and pulverize after use.The holder of cosmetic composition is natural bending and coiling as skin and hair.But the hard or brittle diaphragm that used film former use back, this area forms can not crooked or stretching.Therefore, especially when these preparations were used for setting or moulding such as hair or eyelashes, because their easily crisp characteristic, these compositionss were peeled off or are fallen down.
Still existing needs a kind of stable cosmetic composition that contains anti-transfer and pliability film former to be used for setting and moulding, and said composition does not have good cosmetic properties and is easy to makeup, level and smooth and even film forming, comfortable, easy makeup removing when using, and oily, sticking and do not take off woman's persona.The purpose of this invention is to provide cosmetic composition with these characteristics as much as possible.
Except the defective of many film former, in the formulation preparation process of cosmetics and pharmaceutical industries, also there is another problem, promptly constitute the dispersion of the composition of compositions.In order to obtain the good distribution or the dispersion of composition, need the cost plenty of time and the energy.The homodisperse of forming cosmetics or pharmaceutical composition composition will improve (comprising the dispersion of pigment) characteristic of compositions, as brighter, glossiness is better, between-lot the is stable improvement of the improvement of effect, color, still less lump and the required energy is still less when mixing.
The competent dispersion of pigment will improve the character of color make-up.This area has many products to can be used as the pigment dispersant, comprises KAMA KM13 (can from KAMA International Corp., the polysaccharide resins that Duluth, GA buy).Moistening (wetting) effect that KM13 can reduce the viscosity that contains colorant composition and improve pigment, thus color, glossiness and blended simple and easy degree improved.Know that also KM13 is formed on the thin film of air drying.But polysaccharide resins is water miscible, and this is unfavorable for the film former as anti-transfer or wear-resistant composition to a certain extent.
Therefore, except the compositions of the film former that contains improvement, also need a kind of compositions easier and more effective dispersive composition that contains.As mentioned above, the use of more effective disperse additive will improve the characteristic of cosmetics and drug products, and make it more even.
For these and other advantage of all or part of realization, the present invention has finished a kind of compositions in one embodiment, it contains at least a polysaccharide resins and at least a film former except that described polysaccharide resins, and their blended amounts can give described compositions at least a following characteristic effectively.These characteristics comprise the anti-transfer of (but being not restricted to) cosmetic composition (as mascara, eye-liner and sunscreen); The flexible film's of cosmetic composition (as mascara, eye-liner and sunscreen) formation; Mascara is rolled up the control of sticking up or increasing effect on eyelashes; Increase with sunscreen UV light absorption.Below will specifically describe these characteristics.
In another embodiment, the present invention relates to use on the keratin substances at least a polysaccharide resins and at least a except that described at least a polysaccharide resins film former and form the method for anti-divert film.Keratin substances defined herein refers to skin, hair, eyelashes, eyebrow and fingernail.Also be included in the practical application of the present invention on the keratin substances use at least a polysaccharide resins and at least a except that described at least a polysaccharide resins film former and form the method for the non-brittle thin film of pliability.Another aspect of the present invention is the flexible film who forms anti-transfer.
In another embodiment, the present invention relates to using the compositions that contains at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins on the keratin fiber, volume sticks up or the method for modeling effect thereby produce on these keratin fibers.
The invention still further relates to effective control mascara product and on eyelashes, increase the method for effect and/or volume.Specifically, brushing contains the mascara of at least a polysaccharide resins, at least a film former, at least a volatile solvent and at least a microsphere particle except that described at least a polysaccharide resins layer by layer, up to the eyelashes that obtain Len req or volume.
In another embodiment, the present invention relates to increase the method for light screening composition ultraviolet light (UV) absorption characteristic, by in light screening composition, comprising at least a polysaccharide resins.
Another embodiment of the present invention is for using the compositions that contains polysaccharide resins and optional at least a film former except that described at least a polysaccharide resins, the composition that disperses cosmetics or pharmaceutical composition comprises (but being not restricted to) pigment and/or disperses the chemical compound of UV light as these compositions.
Now describe example of the present invention in detail.
The invention particularly relates to a kind of compositions, it comprises at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins, and their combined amount is enough to give said composition at least a specific characteristic.In first embodiment, compositions of the present invention is with the form of anti-transfusion cosmetics compositions, and wherein at least a polysaccharide resins and at least a film former exist with the combined amount that is enough to give the anti-transfer characteristic of compositions.This anti-transfusion cosmetics compositions can be mascara, eye-liner or light screening composition.Below will go through each compositions.This anti-transfusion cosmetics compositions can be selected from (but being not restricted to) foundation emulsion, concealer, rouge, eye shadow, lip pomade and nial polish.
Except that anti-transfusion cosmetics compositions, the invention still further relates to by at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins are applied on the keratin substances, form the method for anti-divert film.
The invention still further relates to the cosmetic composition that forms the flexible film, wherein said composition contains at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins, exists effectively to give the flexible combined amount of thin film.In the present invention, flexible being defined as under moving condition, as countenance, the persistency of thin film, i.e. the opposing of thin film in this embodiment of the invention comes off or becomes fragile.The cosmetic composition that forms the flexible film can be as mascara, eye-liner or light screening composition.The thin film that is formed by compositions in the embodiment of the invention has a kind of following characteristic at least:
, pliability good with the absorption of substrate, wear-resisting, drying time short, sticking, good, the anti-transfer of retention and/or come off few etc. in a period of time.
The cosmetic composition that forms the flexible film can be selected from (but being not restricted to) foundation emulsion, concealer, rouge, eye shadow, lip pomade and nial polish.
Another embodiment of the present invention is by at least a polysaccharide resins and at least a film former except that this at least a polysaccharide resins are applied to the method that forms the flexible film on the keratin substances.
Another embodiment of the present invention is around the compositions that forms a kind of not only anti-transfer but also flexible thin film, this compositions comprises at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins, exists effectively to give anti-transfer of thin film and flexible combined amount.The cosmetic composition that forms anti-transfer and pliable membrane can be as mascara, eye-liner, sunscreen, foundation emulsion, concealer, rouge, eye shadow, lip pomade or nial polish.
Remove the cosmetic combinations beyond the region of objective existence that forms the pliable membrane of anti-the transfer, also relate to by at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins are applied on the keratin substances in another embodiment of the present invention, and form the method for the pliable membrane of anti-the transfer.
When solvent when helping allowing the speed volatilization of the continuous and abundant complete formation of thin film, form thin film.Polysaccharide resins of the present invention is a film former known in the art.But at least a polysaccharide resins improves the film forming characteristics synergism of (comprising anti-transfer and waterproof) with will producing mixing of at least a other film former (as polymer or wax).The single of at least a polysaccharide resins do not play anti-transfer or film forming characteristics with (promptly not mixing with another kind of other different film former) yet, constitutes an example of the present composition yet.
There is (promptly this amount is enough to obtain required effect, as anti-transfer, form the flexible film, the mascara volume is stuck up or increases the control of effect and the increase of sunscreen UV light absorption) at least a polysaccharide resins and at least a film former with the combined amount of giving at least a desirable characteristics of the present composition.
By practical application and required characteristic, those skilled in the art can be identified for the polysaccharide resins in the present composition and the effective dose of other film former routinely.By practical application, those skilled in the art can also determine polysaccharide resins film former, other film former routinely and obtain stable cosmetics or the amount of other composition that drug products is required.As described herein, stable cosmetics or drug products is meant that (thereby being enough to stable) can make cosmetics or the effectively commercial fully stable product of drug products.
Generally speaking, compositions of the present invention can provide the characteristic below a kind of at least in using widely: anti-transfer, adhesion, pliability and antiwear characteristic, shaping or moulding characteristic and composition dispersing characteristic.These compositionss of the present invention can be following form (but being not restricted to): color make-up comprises foundation emulsion, concealer, rouge, mascara, eye-liner, lip pomade, eye shadow and nial polish or nail varuish; Hair jelly, gel and mousse, ultra light sun block lotion, moisture retention liquid, skin care liquid, the oil that contains active component or spice or facial cream.
Product of the present invention can be used in particular for relating to preparation energy firm attachment in any cosmetics or the medicinal application of the mantle preparation of keratin substances.In addition, compositions of the present invention can be can be used for local coating, activity or functional components are fixed or be incorporated on the substrate.Activity or functional components can comprise pigment, UV filtering agent, wetting agent, spice, medicine, and cosmetics or known other activity of drug world or functional components.
In another embodiment of the present invention, the compositions of the present invention that comprises at least a polysaccharide resins and at least a other film former is waterproof effectively.It is minimum that thereby these compositionss can fall to reducing to washing of activity or functional components.The thin film that covers by formation also reduces through the epidermis moisture loss, and these compositionss also can postpone skin dehydration.In another embodiment, these compositionss can form the barrier layer between skin and environment, keep activity and/or functional components here.Thereby can promote the activity of functional components to increase sun protection factor (SPF) and the protection of UV light, and/or the effect of blockading dampness and environment by the barrier layer that described compositions forms.
In another embodiment, at least a polysaccharide resins of the present invention contains many hydroxyls and hydrophobic group.This polysaccharide resins can be the colloidal suspension form of thin and tall degree modified particles (as starch granules).This fine grain particle diameter is variable, comprises that diameter is 10 microns or littler granule.In another embodiment, the compositions of anti-transfer of formation of the present invention and pliable membrane comprises:
(1) at least a polysaccharide resins that contains many hydroxyls and hydrophobic group, its be thin and tall degree modification the starch granules form and
(2) at least a film former except that described at least a polysaccharide resins, wherein (1) and (2) exists with the combined amount of effectively giving anti-transfer of compositions and/or formation pliable membrane characteristic.
In another embodiment, polysaccharide resins of the present invention is selected from the InternationalCorp. from KAMA, the polysaccharide resins that Duluth, GA buy.For example, polysaccharide resins KM13 is a kind of high modification, the diameter colloidal suspension of starch granules in water less than 10 microns segmentation.KM13 be can with other resin formation hydrogen bond altogether-reacting resin.KM13 contains many hydroxyls (pigment in the wet water system) and hydrophobic group (be in the solvent system acceptable and non-pigment flocculation or suspend).
Polysaccharide resins is water miscible, therefore polysaccharide resins can be dissolved in preparation polysaccharide film former in the aqueous systems.In another embodiment, be scattered in the solvent system, thereby polysaccharide resins added the system on other solvent basis by the polysaccharide resins that will be dissolved in the water.Also can in Water-In-Oil or oil-in-water solvent, use at least a polysaccharide resins and at least a film former compositions except that this polysaccharide resins of containing of the present invention.Can or contain the polysaccharide resins film former in the two and the film former except that polysaccharide resins at water or oil phase.In one embodiment, at least a polysaccharide resins film former is at aqueous phase, and at least a other (promptly non--polysaccharide resins) film former is in oil phase.In other embodiments of the invention, at least a other film former can be at oil phase, aqueous phase, or at least a other film former is arranged in each water and oil phase.
Those skilled in the art will know that the compatibility how to consider material prepares and prepare the compositions with desirable characteristics.By the selected at least a polysaccharide resins of application and at least a other film former for imagination, those skilled in the art can determine the system of solubility parameter and selective solvent or water base plinth.Polysaccharide film former and non-polysaccharide film former should be compatible with other raw material in the preparation.
By practical application, the concentration change of the polysaccharide resins in the present composition can be very big.Those skilled in the art can determine the preferred concentration of polysaccharide resins by practical application or required characteristic.In an exemplary embodiments, polysaccharide resins that compositions of the present invention contains such as the amount of KM13 account for 1% to 50% of total composition weight.In another embodiment, the amount of polysaccharide resins is 5% to 40% concentration (weight).For example, for the cosmetics foundation emulsion, the concentration of used polysaccharide resins is 1% to 50% (weight), also can be 1% to 20% (weight).For the eye-liner preparation, at least a polysaccharide resins film former can be 1% to 30% (weight), also can be 2% to 20% (weight).For mascara preparations, at least a polysaccharide resins film former can be 0.5% to 50% (weight), also can be 1% to 20% (weight).
At least a other film former except that at least a polysaccharide resins that is used for the present invention's application can be selected from (but being not restricted to): cellulose and modified cellulose such as hydroxyethyl-cellulose; Diblock, three blocks or radiation block copolymer film former such as KRATON  film former; Vinyl pyrrolidone/vinyl acetate (PVP/VA) copolymer is as the Luviskol VA grade (all scopes) of BASF  Corporation and the PVP/VA series of ISP; Fluorinated acrylamide acids Emulsion film former comprises Foraperle  film former, as the Foraperle  303D of EIf Atochem, (though Foraperle  may not be preferred for some cosmetic formulations); GANEX  copolymer is as butylated PVP, PVP/ hexadecene copolymer, PVP/ eicosylene copolymer or melene base; Poly-(vinyl pyrrolidone/diethylaminoethyl methacrylate) or PVP/ copolymer of dimethylaminoethyl methacrylate such as copolymer 845; Resin A CO-5014 (the IB/MA copolymer of imidization); Other PVP based polyalcohol and copolymers; Siloxane glue; Cyclohexyl methyl siloxanes and polydimethylsiloxane cross linked polymer; Siloxy silicic acid trimethyl is as SR 1000, SS4230 or the SS4267 that can buy from GE Silicones; The cycloalkyl alkyl acrylate copolymer; Mexomere  film former and other stearic acid allyl ester/vinyl acetate copolymers (stearic acid allyl ester/VA copolymer); Polyol prepolymer such as PPG-12/SMDI copolymer and poly-(oxygen-ethylene (ethanediyl), alpha-hydro-omega-hydroxy-poly compound and 1,1 '-methylene-two-(4-isocyanato-cyclohexane extraction) (can buy) from Bamet; Avalure AC polymer (acrylate copolymer) and Avalure UR polymer (polyurethane dispersion liquid) can be buied from BF Goodrich; With disclosed other film former, especially disclosed film former in the 1636-1638 page or leaf in international cosmetics dictionary and handbook (the 2nd volume, the 7th edition, 1997).This paper all includes the disclosure of international cosmetics dictionary and handbook the 2nd volume 1636-1638 page or leaf as a reference in.
Other film former that can be used in the framework of the present invention comprise any chemical membrane agent known in the art such as PVP, acrylate and urethanes; Synthetic condensation polymer copolymer, synthetic free radical polyalcohol, synthetic ionomer; Natural polymer such as wheat protein film former; With above-mentioned mixture or in cosmetics and pharmaceutical field practice the technical staff can determine it is other compatible film former.
Other (being non-polysaccharide tree) fat film former can improve other characteristic of required cosmetics of level and smooth and even film forming, waterproof, anti-transfer, pliability or those skilled in the art or medicine.Other film former comprises hydroxyethyl-cellulose, Radix Acaciae senegalis, polyvinylpyrrolidone class and hydrolyzed wheat protein.The polyvinylpyrrolidone class can be selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
Can determine the concentration of non-polysaccharide resins film former by those skilled in the art, and can great changes have taken place by practical application.For example, for cosmetic emulsion, the amount of used at least a non-polysaccharide resins film former also can be 1% to 5% (weight) with respect to 1% to 10% of total composition weight.For the eye-liner preparation, the amount of used at least a non-polysaccharide resins film former is 0.1% to 10% (weight), also can be 1% to 5% (weight).For mascara preparations, the amount of used at least a non-polysaccharide resins is 0.1% to 10% (weight), also can be 1% to 5% (weight).
In compositions of the present invention, also can add known in the art other and can on keratin fiber, stay the compositions of thin film, comprise the normally used isostearyl glyceryl pentaerythrityl ether in this area and other compositions.These other compositions can comprise: gel, oil, wax, antiseptic, thickening agent, solvent, surfactant, isostearyl glyceryl pentaerythrityl ether and other mix the composition that can remain on skin surface behind the preparation and not adhere to substrate by force.As viewed in some esters and organic sunscreen agent, some characteristic in these materials comprises oiliness sensation and the spreadability that increases.In the embodiment that these materials is added in the preparation of the present invention with the spreadability that improves product and flexibility, preferably the concentration that exists of above-mentioned substance should be very low, keeps its anti-transfer characteristic and form the characteristic of pliable membrane to guarantee preparation.The selection of scalable polysaccharide resins, other film former and their concentration to change other cosmetic properties, as being shaped or moulding characteristic and composition dispersion effect, will be discussed following.
The isostearyl glyceryl pentaerythrityl ether that can be used for the present composition comprises glycerol, propylene glycol, cyclohexyl methyl siloxanes, polydimethylsiloxane and international cosmetics dictionary and handbook the 2nd volume (the 7th edition, 1997) disclosed isostearyl glyceryl pentaerythrityl ether and other similar compositions, the especially disclosed isostearyl glyceryl pentaerythrityl ether of 1656-1661 page or leaf.This paper introduces international cosmetics dictionary and handbook the 2nd is rolled up the 1656-1661 page or leaf as a reference.In a preferred embodiment, the concentration that exists of isostearyl glyceryl pentaerythrityl ether is about 0.1% to about 20% total composition weight.
Compositions of the present invention also comprises institute Focus Area used formulation adjuvant usually.The used formulation adjuvant of the present invention can be (but being not restricted to) fatty material.Available fatty material comprises that (but being not restricted to) is used for the organic of Water-In-Oil system and organosiloxane emulsifying agent.The example of organic emulsifier comprises the surfactant of any ethoxylation known in the art, roll up (the 7th edition as polysorbate-20, Laureth-7 and Laureth-4, Sepigel 305 (can buy) and international cosmetics dictionary and handbook the 2nd from SEPPIC, 1997) disclosed other analogous components, the especially disclosed emulsifying agent of 1679-1687 page or leaf.This paper all includes the content of international cosmetics dictionary and handbook the 2nd volume 1679-1687 page or leaf as a reference in.The example of organosiloxane emulsifying agent comprise the cetyl dimethicone copolyol-poly-4-glyceryl isostearate-lauric acid hexyl ester (ABIL WE 09) that can buy from Goldschmidt Chemical Corporation, cetyl dimethicone copolyol (ABIL  EM 90), (ABIL  EM 97), lauryl methyl copolymeric siloxane alcohol (5200), cyclohexyl methyl siloxanes (with) dimethicone copolyol (DC 5225C and DC 3225C) (can buy) from GE Silicone, Huan Wuguiyangwan ﹠amp; Dimethicone copolyol (GE SF 1528) or any other formulation adjuvant well known by persons skilled in the art.Other fatty material that can be used as formulation adjuvant comprises that (but being not restricted to) is with esterification or without siloxanes (as the behenic acid polydimethylsiloxane) and non-silicone fatty material (comprising oil, as vegetable oil or mineral oil), animal and/or synthetic wax such as Cera Flava, paraffin, rice bran wax, candelilla wax, Brazil wax and their derivant of the solid-state form of the liquid form of esterification or esterification; With alkane gel or bentonite type gel such as GelSS71, Gel EA2786, Quaternium-18 Bentonite, 38CE, Gel ISD or Gel ISD.In one embodiment, the amount of formulation adjuvant is about 0.1% to 25% concentration of total composition weight.
Those skilled in the art can select these different materials, have the compositions of desirable characteristics (as denseness or quality) with preparation.Specifically, compositions of the present invention comprises at least a above-mentioned wax, to guarantee good mechanical strength, especially when compositions is shaft-like form.
Also plasticizer can be added in the compositions of the present invention the pliability and the forming characteristic of the preparation that obtains with improvement.Plasticizer is the material that can soften synthetic polymer.Usually need them to avoid the fragility and the cracking of film former.By required characteristic and practical application, those skilled in the art can select the amount of required plasticizer routinely.The plasticizer that can be used for practical application of the present invention comprises lecithin, many sorbitol, dimethicone copolyol, ethylene glycol, citrate, glycerol, dimethyl siloxane and international cosmetics dictionary and handbook the 2nd volume (the 7th edition, 1997) disclosed other analogous components in (especially international cosmetics dictionary and handbook the 2nd volume the 1654th page in disclosed plasticizer), this paper all includes it as a reference in.
In containing the product of pigment, the amount of scalable polysaccharide resins and other film former, thus make them adhere to skin or hair best and have best resistance to water.What need the emphasis consideration is the ratio of pigment and film former.Be appreciated that pigment is meant inorganic or organic, white or colored particles.The typical pigment that can be used for practical application of the present invention comprises carbon black, titanium dioxide, D; C Red No.7 Calcium Lake, D ﹠amp; C RedNo.21 Aluminum Lake, Iron Oxides, FD ﹠amp; C Yellow No.5 Aluminum Lake, FD ﹠amp; Known other pigments of C Blue No.1 Aluminum Lake and cosmetic field or activation pigment.Because the inherent pigment dispersing characteristic of polysaccharide resins, it is particularly preferred making the use of the present composition in containing pigment product.
Also can in described preparation, add filler and Concha Margaritifera (mothers-of-pearl), with the quality and tarnish (the matteness)/luster effect of improved composition.Filler can be understood as lamelliform or non-lamelliform, inorganic or synthetic, colourless or white particle.That Concha Margaritifera can refer to be generated in their shell by some Mollusca or other synthetic pearlescent particles.The precious photo etching (pearling agent) that can be used for practical application of the present invention comprises known any other the precious photo etching of Muscovitum, ferrum oxide, titanium dioxide and cosmetic field.
Also can in compositions of the present invention, add any cosmetics (at the bottom of comprising face powder, eye-liner, lip pomade, mascara, eye shadow, concealer, facial milk cleanser, nial polish, or other practical applications of mentioning of the present invention) any conventional additives in the prescription field is as being selected from following additive (but being not restricted to): thickening agent is (as clay, or organic clay, Silicon stone, cellulose derivative), lithium montmorillonite (hectorite), stabilizing agent, synthetic polymer (as acrylic polymer or contain the association polymer of polyurethane), lipophilic polymer, natural gum and especially xanthan gum, spreading agent, dispersant, antiseptic (especially waterborne-type preservation), defoamer, wetting agent, chelate such as EDTA and salt thereof, the UV-screening agent, spice, filler, antioxidant, essential oil, cosmetics or pharmaceutically active agents, wetting agent, the vitamin or derivatives thereof, biomaterial and its derivant.
Certainly those skilled in the art should carefully select the additive compound chosen wantonly and/or their amount, make the advantageous properties of the present composition not be subjected to or not be subjected to substantially the infringement of these additives.
Another object of the present invention is a mascara.The mascara of anti-transfer and formation pliable membrane has been discussed.Use the mascara of the present composition to have the stability of increase and can adhere to keratin fiber preferably, better wear resistance, improved resistance to water and improved cosmetic properties.In addition, compositions of the present invention also can be used for setting and moulding keratin fiber, by forming the thin film can be shaped to required structure or when brushing it being carried out moulding and can keep the thin film of its shape after using.For example, compositions of the present invention can be used for setting, moulding and/or volume rake angle azelon, as eyelashes.After using these compositionss, eyelashes moulding or that volume sticks up are kept the shape of type, and this part is because the thin film that forms adheres on the eyelashes and keeps the required shape of eyelashes.This thin film is flexible but also can is waterproof.
It is that 4% polysaccharide resins is the purposes of KAMA KM13 in mascara that PCT/US98/10617 discloses with respect to compositions gross weight concentration.Inventor of the present invention also discloses when the amount of polysaccharide resins can observe curling effect during more than or equal to 5% (preferably for more than or equal to 10%) of compositions gross weight.This curling effect is surprising, can not obtain with the existing conventional film former in this area.For example, polysaccharide resins KAMA KM13 is mixed with the mascara that contains the hydroxyethyl-cellulose film former.When being low to moderate 10%KM 13, existence in the mascara observes curling effect.The same preparation that does not comprise KM13 does not then have this curling effect.Therefore, in one embodiment, the present invention can produce the compositions of curling effect, contains at least a polysaccharide resins with the amount with respect to compositions gross weight 5% to 50%.
Therefore, relate to the method that go up to produce curling effect at keratin fiber (as eyelashes) in the practical application of the present invention, this method comprises that the mode that moves with prying will contain at least a polysaccharide resins and at least a film former except that described at least a polysaccharide resins is applied on the keratin fiber.Setting or moulding except that volume sticks up if desired, move mode brushing that can be different.
But repetitive administration compositions of the present invention is to strengthen required shape or effect.But most of mascara can not cover the mode brushing of one deck with one deck.In other words, by brushing in layer, conventional mascara can not be controlled the growth effect of mascara on eyelashes.
Therefore, in another embodiment of the present invention, available compositions of the present invention is controlled at the extension on the keratin fiber (as eyelashes) or increases effect.At least a film former except that described at least a polysaccharide resins strengthens the anti-transfer effect of said composition.This compositions also contains volatile solvent and/or hard microsphere particle, with the auxiliary repetitive administration of mascara on keratin fiber, this two kinds of compositions will be discussed below.
Therefore, one embodiment of the present of invention are the mascaras that contain at least a polysaccharide resins, at least a described polysaccharide resins film former, at least a volatile solvent and at least a microsphere particle in addition.The combined amount that the moulding composition exists is controlled the growth effect of mascara on keratin fiber effectively.But one deck covers this growth form mascara of one deck ground brushing.The mascara that the amount by the mascara used or the number of times of brushing are controlled the eyelash growing effect also belongs within the scope of the invention.
Therefore, in another embodiment, the present invention relates to by being coated with brushing eyelash with the compositions that contains at least a polysaccharide resins, at least a film former, at least a volatile solvent and at least a microsphere particle except that described at least a polysaccharide resins, control the method for the growth effect of mascara product on eyelashes, wherein use said composition up to realizing required length or volume effect.
In the growth form mascara preparations, use volatile solvent also to allow the drying aid time to reuse fast.Volatile solvent in the practical application of the present invention comprises that (but being not restricted to) alcohol is as ethanol, silicone, petroleum distillate and isoparaffin.
In the growth form mascara preparations, use microsphere particle, to strengthen level and smooth sense and compositions repetitive administration (when said composition is used in the mode of one deck covering one deck) at distribution on the keratin fiber or auxiliary mascara.Microsphere chemical compound in the practical application of the present invention comprises polyurethanes such as BPD 500, nylon 12, silicon oxide, polymethyl methacrylate and other acrylate or methacrylate and their ester and other microsphere.
The use of polysaccharide resins pigment dispersing characteristic also is within the scope of the present invention.For example, available polysaccharide resins of the present invention improves the dispersion and the uniformity of other composition in cosmetics or the drug products, thereby the effect of higher active component is provided.Be not wishing to be bound by theory, the improvement of dispersibility can make the more uniform covering of active component, thus the better effects if of active component.
For example, compositions of the present invention can be improved the dispersion of opacifier and UV absorbent in the sunscreen, thereby increases the absorption characteristic of UV or increase the SPF of every part of UV absorbent in the preparation.In addition, because the dispersing characteristic of polysaccharide resins, the UV Absorption of compositions can be more unified.In one embodiment, the improvement of composition dispersibility will improve characteristic such as effect, make that color is brighter, glossiness is higher, product lot quantity is more unified, caking still less with mix energy consumption still less.
Therefore, the invention still further relates to the method for the UV light absorption that increases light screening composition, this method is included in adds at least a polysaccharide resins in the light screening composition.
Those skilled in the art can be selected and prepare to be used for the packing and the application device of any product of the present invention by their general knowledge, and can be adjusted by the characteristic of compositions to be packaged.In fact, the type of selected device is special relevant with the denseness (especially its viscosity) of compositions, also depends on the characteristic of the composition (as the volatile compound that exists) that exists in the compositions.
Further specify the present invention with following embodiment, this only has been an illustration, and scope of the present invention is not had any restriction.
Embodiment
Embodiment 1: light screening composition
Polysaccharide resins KAMA KM13 is added in the light screening composition that contains other film former such as PVP/ eicosylene copolymer and acrylate/acrylate cross linked copolymer of C10-30 pi-allyl, improves UV absorbent (TiO 2) dispersion.So the light screening composition of preparation is an oil in water emulsion.
Sunscreen g
A1 stearic acid 1
Tristerin/stearate PEG-100 1
Isopropyl palmitate 12
Dimethicone 1
Phenoxyethanol 0.7
Propyl parabene 0.05
PVP/ eicosylene copolymer 1
A2 triethanolamine 0.3
B1 glycerol 4
Propylene glycol 4
Methyl hydroxybenzoate 0.15
B2 TiO 2 10
KAMA-KM13 1
C xanthan gum 0.1
D acrylate/C10-30 alkyl acrylate crosspolymer 0.2
Isopropyl palmitate 2.5
E triethanolamine 0.2
Water 1
F D5 7
G water gsp100
Step:
Composition among the A1 is mixed.In A1, add A2, with the mixture heated that so obtains to about 80 ℃.Water mixing B1 in another container, and be heated to about 80 ℃.With this biphase strong agitation mixed for several minutes up to mix homogeneously.Mix B2 then, and it is added in the previous mixture.The mixture limit constant speed that obtains is stirred the limit be cooled to room temperature, add remaining composition.Add entry to volume.
Embodiment 2: volume sticks up the type mascara
KAMA KM13 is added in the mascara of oil in water emulsion form.Said composition also contains other film former, hydrolyzed wheat protein and hydroxyethyl-cellulose.With its brushing eyelash the time, can observe curling effect.By the process of brushing eyelash promptly the volume of brushing mascara stick up mobilely, can increase this curling effect.
The oil in water emulsion mascara
Oil in water emulsion mascara %
A1 natural paraffin wax 23
A2 black iron oxide 8
A3 triethanolamine stearate (C18/C16 50/50) 7.85
B1 water qsp100
B2 hydroxyethyl-cellulose 0.2
B3 Radix Acaciae senegalis 1.5
C antiseptic qs
D defoamer 0.12
E KAMA?KM13 10
F hydrolyzed wheat protein 0.2
Step:
With A1, A2 and A3 mixing A, and be heated to 85-90 ℃.Mix them until evenly.Separately B1 is heated to 85-90 ℃ while stirring, sprays B2 and B3 to mix homogeneously.With phase A and mutually B mix, this carries out vigorous stirring to mix homogeneously with stable maintenance in 85 ℃ the time.Add C at blended A+B in mutually then, be cooled to 30 ℃ while stirring.Add components D during mixing again to F.
Embodiment 3: setting (shaping) and dense type (contouring) mascara
KAMA KM13 is added in the limpid mascara compositions that contains the film former hydroxyethyl-cellulose.After being coated with brushing eyelash, observe qualitative or dense effect.Can control this setting and dense effect by the brushing process.
Limpid mascara %
A1 water qsp100
A2 hydroxyethyl-cellulose 0.1
A3 CARBOPOL 1.32
A4 triethanolamine 1.32
B KAMA?KM13 33
C antiseptic qsp
Step:
A1 is heated to 85 ℃ while stirring.In the eddy current that blender produces, slowly add A2, and then add A3.Add A4 and mix homogeneously.Mixture is cooled to room temperature, adds B and C.Stir this mixture 10 minutes to mix homogeneously.
Embodiment 4: volume sticks up the type mascara
KAMA KM13 is added in the mascara preparations of wax microdispersion.This compositions also contains other film former hydroxyethyl-cellulose.After being coated with brushing eyelash, can observe curling effect.Can strengthen this curling effect by the brushing process.
Paraffin fine dispersions mascara %
A1 E west palm wax 22
A2 glyceryl oxyethylene group (30OE) monostearate 5.5
A3 water 45
B sodium hydroxide 0.05
C black iron oxide 5
D Radix Acaciae senegalis 3.3
E hydroxyethyl-cellulose 0.55
F KAMA?KM13 10
G antiseptic qs
H water qsp100
Step:
By U.S. Patent No. 5,858,338 described preparation Brazil waxs, glyceryl oxyethylene group (30OE) monostearate and water.Room temperature is mixed the wax microdispersion that obtains with B and C, and mix homogeneously.In this stirred mixture, slowly spray D and E until mix homogeneously.In this compositions, add F, G and H then.Mixing is up to evenly.
Embodiment 5: the waterproof mascara
Preparation contains the mascara preparations of polysaccharide resins KAMAKM13 and other film former stearic acid allyl ester/VA copolymer.Following preparation shows that this water soluble polysaccharide film former is effective in preparation waterproof and the mascara of anti-the transfer.
Waterproof mascara %
A1 petroleum distillate 50.59
2 pigments and/or carbon black 6.00
B1 bentonite 5.54
2 isoparaffins 10.50
C1 rice starch 1.00
D1 propylene carbonate 1.82
E1 wax 15.12
2 pi-allyls stearate/VA copolymer 2.43
3 polyoxyethylene lauryls acid ethylene 1.00
4 microsphere particles 1.00
F1 KAMA?KM13 2.50
2 water 2.49
3 antiseptic 0.01
Step:
Mix the A composition and with their homogenizes 1 hour.In the A mixture of ingredients, add the B composition, and homogenize 10 minutes, and then add C1.With whole mixture homogenize 10 minutes, add D1 then, again with this mixture 15 minutes.This E composition is heated to 90-95 ℃, and is added in the said mixture, homogenize was 30 minutes when this mixture was maintained at 60-65 ℃.At last, add the F composition,, be cooled to 30-32 ℃ while stirring the preparation homogenize that finally obtains 3 minutes.
Embodiment 6: the scalable mascara
The following preparation can effectively be regulated the mascara that is brushed to the mascara on the eyelashes.Brush described mascara layer by layer, up to the eyelashes that obtain Len req or volume.The mascara of volume or length controlled contains polysaccharide resins KAMA KM13 and other film former PVP/ hexadecene copolymer and PVP/ eicosylene copolymer.
Scalable mascara %
A1 wax 15.1
2 stearic acid 4.70
3 antiseptic 0.75
4 PVP/ eicosylene copolymer 1 .00
B1 water 35.70
2 aqueous thickener solutions 0.40
3 KAMA?KM13 1.25
4 lecithin 0.15
5 pigments and/or carbon black 9.00
6 PVP/ hexadecene copolymer 1 .00
7 ethylene glycol 3.50
8 triethanolamine 2.35
C1 defoamer 0.10
D1 volatility silicone 3.00
2 silicone rubber 2.50
3 filleies 4.50
E1 polyurethanes 10.00
F alcohol 5.00
Step:
Mix the A composition, and be heated to 85-90 ℃, mix homogeneously.In another destructor, B1 is heated to 40-45 ℃, slowly add eddy current with B2 this moment.With the mixture heated to 85 of B1 and B2 ℃, add composition B3 to B8, with the mixture heated to 85 that obtains ℃, and ground 30 minutes.
The B composition is added in the A composition, ground again 10 minutes.Then C is added in the mixture of A and B, this preparation is cooled to 40-45 ℃ while mixing.In another destructor, mix the D composition up to mix homogeneously, and it is added in A, B and the C mixture of ingredients.Mix this preparation to even.Add E1 at last, mix homogeneously also is cooled to 30 ℃, adds F then, and the preparation that this is final mixed 15 minutes.
Embodiment 7: foundation emulsion
Polysaccharide resins KAMA KM13 is added in the cosmetic foundation emulsion compositions that contains other film former Cyclomethicone and dimethyl silscone cross linked polymer.
Cosmetic foundation emulsion %
A1 water 25.00
2 intercalating agents 0.10
3 emulsifying agents 0.40
B1 water 15.00
2 antiseptic 0.30
3 KAMA?KM13 2.00
Sorbitol more than 4 20 0.25
5 pigments 12.50
C1 emulsifying agent 0.70
2 filleies 10.00
D1 wetting agent 7.00
2 thickening agents 0.15
E1 silicone oil phase 13.00
2 emulsifying agents 1.10
3 antiseptic 0.10
4 Cyclomethicones and dimethyl silscone cross linked polymer 5.00
5 wetting agents 5.00
F water qsp100
Step
In being furnished with the mixer of propeller type mixer, phase A is mixed and being heated to 70 ℃.Mixed phase B and be heated to 70 ℃ in another container, constant speed is mixed to mix homogeneously.Phase B is added among the phase A.When with propeller-type blender mixed phase A and B, add phase C, and then add phase D.70 ℃, the compositions that so obtains is added among the phase E, homogenize is to even.Add F, this compositions homogenize to evenly, is swung cooling then.

Claims (28)

1. a cosmetic composition is characterized in that, described compositions comprises:
Polysaccharide resins KAMA KM13, it is a kind of colloidal suspension of starch granules, the diameter of described starch granules be 10 microns or littler and
At least a film former except that described polysaccharide resins,
Wherein said polysaccharide resins is 5-50% with respect to the amount of compositions gross weight, and
Described polysaccharide resins and at least a film former exist with the amount that can effectively give the anti-transfer characteristic of described compositions and
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
2. cosmetic composition as claimed in claim 1 is characterized in that, described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
3. cosmetic composition as claimed in claim 2 is characterized in that, described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
4. cosmetic composition as claimed in claim 1 is characterized in that described compositions also comprises at least a plasticizer.
5. cosmetic composition as claimed in claim 4 is characterized in that, described plasticizer is selected from lecithin, polysorbate, dimethyl silscone polyol, ethylene glycol, citrate and glycerol.
6. an anti-transfer mascara product is characterized in that, described anti-transfer mascara product comprises:
Polysaccharide resins KAMA KM13, it is a kind of colloidal suspension of starch granules, the diameter of described starch granules be 10 microns or littler and
At least a film former except that described polysaccharide resins,
Wherein said polysaccharide resins accounts for the 5-50% of compositions gross weight, and
Described polysaccharide resins and at least a film former exist with the amount that can effectively give the anti-transfer characteristic of described mascara product and
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
7. anti-transfer mascara product as claimed in claim 6 is characterized in that described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
8. anti-transfer mascara product as claimed in claim 7 is characterized in that, described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
9. anti-transfer mascara product as claimed in claim 6 is characterized in that, described anti-transfer mascara product also comprises carbon black.
10. anti-transfer mascara product as claimed in claim 6 is characterized in that, described anti-transfer mascara product also comprises at least a plasticizer.
11. anti-transfer mascara product as claimed in claim 10 is characterized in that described plasticizer is selected from lecithin, polysorbate, dimethyl silscone polyol, ethylene glycol, citrate and glycerol.
12. method that forms anti-divert film, it is characterized in that, described method comprises that the compositions that will contain polysaccharide resins KAMA KM13 and at least a film former except that described polysaccharide resins is applied on the keratin substances, wherein, described polysaccharide resins accounts for the 5-50% of compositions gross weight, it is a kind of colloidal suspension of starch granules, and the diameter of described starch granules is 10 microns or littler;
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
13. the method for the anti-divert film of formation as claimed in claim 12 is characterized in that, described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
14. the method for the anti-divert film of formation as claimed in claim 13 is characterized in that, described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
15. method that forms the flexible film, it is characterized in that, described method comprises that the compositions that will contain polysaccharide resins KAMA KM13 and at least a film former except that described polysaccharide resins is applied on the keratin substances, wherein, described polysaccharide resins accounts for the 5-50% of compositions gross weight, it is a kind of colloidal suspension of starch granules, and the diameter of described starch granules is 10 microns or littler
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
16. formation flexible film's as claimed in claim 15 method is characterized in that described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
17. formation flexible film's as claimed in claim 16 method is characterized in that described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
18. method that forms anti-transfer flexible film, it is characterized in that, described method comprises that the compositions that will contain polysaccharide resins KAMA KM13 and at least a film former except that described polysaccharide resins is applied on the keratin substances, wherein, described polysaccharide resins accounts for the 5-50% of compositions gross weight, it is a kind of colloidal suspension of starch granules, and the diameter of described starch granules is 10 microns or littler
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
19. the anti-transfer of formation as claimed in claim 18 flexible film's method, it is characterized in that described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
20. the anti-transfer of formation as claimed in claim 19 flexible film's method is characterized in that described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
21. a method that produces curling effect on keratin fiber is characterized in that described method is included in described keratin fiber prying and uses compositions movably, described compositions includes
Polysaccharide resins KAMA KM13, it is a kind of colloidal suspension of starch granules, the diameter of described starch granules be 10 microns or littler and
At least a film former except that described polysaccharide resins,
Wherein said polysaccharide resins accounts for the 5-50% of compositions gross weight;
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
22. the method that produces curling effect on keratin fiber as claimed in claim 21 is characterized in that the amount that described polysaccharide resins is equivalent to the gross weight of compositions is 10-50%.
23. the method that on keratin fiber, produces curling effect as claimed in claim 21, it is characterized in that described at least a film former except that described polysaccharide resins is selected from the wheat protein of Radix Acaciae senegalis, hydroxyethyl-cellulose, polyvinylpyrrolidone class and hydrolysis.
24. the method that produces curling effect on keratin fiber as claimed in claim 23 is characterized in that described polyvinylpyrrolidone class is selected from PVP, PVP/ eicosylene copolymer and PVP/ hexadecene copolymer.
25. a mascara is characterized in that, described mascara comprises following composition:
Polysaccharide resins KAMA KM13,
At least a film former except that described polysaccharide resins,
At least a volatile solvent and
At least a microsphere particle, this microsphere particle are the microsphere chemical compound that is selected from polyurethanes, nylon 12, silicon oxide, polymethyl methacrylate and other acrylate or methacrylate and their ester;
Wherein, described polysaccharide resins accounts for the 5-50% of compositions gross weight;
Wherein said composition increases effect with effective control mascara on keratin fiber combined amount exist and
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
26. mascara as claimed in claim 25 is characterized in that, described mascara also contains plasticizer.
27. mascara as claimed in claim 25 is characterized in that, described mascara also contains carbon black.
28. control mascara product increases effect on eyelashes method for one kind, it is characterized in that described method comprises that with in described eyelashes last layer one deck brushing compositions, described compositions comprises
Polysaccharide resins KAMA KM13,
At least a film former except that described polysaccharide resins,
At least a volatile solvent and
At least a microsphere particle, this microsphere particle are the microsphere chemical compound that is selected from polyurethanes, nylon 12, silicon oxide, polymethyl methacrylate and other acrylate or methacrylate and their ester;
Wherein said polysaccharide resins accounts for the 5-50% of compositions gross weight;
Wherein brush described compositions up to the growth of realizing ideal or volume effect and
Condition is, described compositions does not comprise following compositions, and said composition comprises: at least a organic phospholipid that can form bilayer in aqueous solution; At least a amphoteric surfactant, its amount is equal to or higher than the amount of described at least a phospholipid, by weight; At least a non-ionic surface active agent, its amount is equal to or higher than the amount of described at least a phospholipid, by weight.
CNB008124027A 1999-09-03 2000-09-01 Cosmetic compositions containing specific polysaccharide resins Expired - Fee Related CN1193729C (en)

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BR0014168A (en) 2002-05-07
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CA2384098A1 (en) 2001-03-15
CN1372454A (en) 2002-10-02

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