CN102106789B - Comprise the cosmetic composition of at least two volatile linear alkane and at least one non-protein cationic polymer - Google Patents
Comprise the cosmetic composition of at least two volatile linear alkane and at least one non-protein cationic polymer Download PDFInfo
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- CN102106789B CN102106789B CN201010606147.7A CN201010606147A CN102106789B CN 102106789 B CN102106789 B CN 102106789B CN 201010606147 A CN201010606147 A CN 201010606147A CN 102106789 B CN102106789 B CN 102106789B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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Abstract
The present invention relates to a kind of cosmetic composition, it is in medium used for cosmetic, with the volatile linear alkane more than or equal to 1.2/one or more polymer weight ratio, comprises two or more volatile linear alkanes and one or more non-protein cationic polymers.The invention still further relates to described cosmetic composition at keratin substances, the preferred angle azelon such as purposes in the cosmetic treatment of hair, and relate to a kind of method using described compositions keratin material dressing to carry out cosmetic treatment.
Description
Technical field
The present invention relates to one and comprise at least two volatile linear alkane and at least one non-protein sun
The cosmetic composition of ionomer, relates to it at keratin substances, preferred angle azelon such as head
Purposes in the cosmetic treatment sent out, and relate to a kind of using described compositions keratin material dressing to carry out
The method of cosmetic treatment.
Background technology
In hair treatment field, the hair rinsing or be not required to rinse that uses of volatile solvent protects
Reason product is known.They are typically due to different reasons and use.They are so that permissible
Its sensation is changed by giving the light quality (light texture) of the hair product non-cement in hands
Performance.They can also impart to the feature that it is smooth, and this contributes to product on hair, particularly exists
The dry distribution sent out.
Water-based emulsion in the oil-in-water type that can provide with more or less gelation paste form
In, the addition of volatile solvent it is also possible that siloxane glue material can be dissolved, described siloxane glue material base
To be difficult to combine in the composition in their inherent viscosity.
Usually liquid fatty acid esters, Fancol ID or the hydrocarbon ils of 2-Methylpentadecane type and/or silicone oil
These volatile solvents can specifically result in following point: greasy sensation, lack gloss and hair be stiff
Firmly.
Therefore need nonetheless remain for replacing these volatile solvents to avoid disadvantages mentioned above.
Summary of the invention
The applicant it has now surprisingly been that and it has surprisingly been found that at least two volatile linear alkane
Combination with at least one non-protein cationic polymer can be avoided disadvantages mentioned above and improve cosmetic
Moral character matter, such as slickness, gloss, the fiber transformation when rinsing, solution twines (disentangling),
Brightness, compliance, flexibility, it is provided that volumizing effect (volumizing giving effect) and curling
The restriction of the hai roll on hair.
Term " fiber transformation when rinsing " is understood to refer to rinse care product flushing
When falling, fiber presents submissive immediately, soft and smooth.
" volumizing effect (volumizing effect) " be in hands to feel hair weight effects and
Obtain when the global density of hair is felt.
Especially, wet is used allow to obtain more smooth and more shinny wet.It addition,
Dry luminescence is sliding and neat, does not has heavy property.
Thus, a theme of the present invention is a kind of cosmetic composition, and it is used for cosmetic
In (cosmetically acceptable) medium, with the volatile linear alkane/one more than or equal to 1.2
Or multiple non-protein cationic polymer weight ratio, comprise two kinds or more than two kinds of volatile linear alkanes
With a kind of, two kinds or more than two kinds of non-protein cationic polymers.
Another theme of the present invention be described compositions at keratin substances, preferred angle azelon is such as
Purposes in the cosmetic treatment of hair.
Another theme of the present invention is the described compositions keratin material dressing of a kind of use, preferred angle egg
The method that white fiber such as hair carries out cosmetic treatment.
Cosmetic composition according to the present invention comprises in medium used for cosmetic:
-two or more volatile linear alkane, and
-one or more non-protein cationic polymers,
Wherein volatile linear alkane/one or more non-protein cationic polymer weight ratios are more than or equal to
1.2。
According to an embodiment, cosmetic composition comprises in medium used for cosmetic:
-two or more straight chain C7-15Alkane, preferably C8-14Alkane, and
-one or more non-protein cationic polymers,
Wherein volatile linear alkane/one or more non-protein cationic polymer weight ratios are more than or equal to
1.2。
Described ratio range preferably from 1.2 to 50, be more preferably 2 to 30, and be the most more preferably
3 to 20.
Detailed description of the invention
Term " two or more volatile linear alkanes " is interpreted as not referring to " two kinds with making any distinction between
Above volatile linear alkane oil ".
Be suitable to the volatile linear alkane of the present invention in ambient temperature (about 25 DEG C) and at atmospheric pressure (101
325Pa or 760mmHg) under be liquid.
The term " volatile linear alkane " being suitable to the present invention is understood to refer to such linear paraffin,
It is in ambient temperature (25 DEG C) and can be under atmospheric pressure (101325Pa), when with contact skin
Evaporating in less than 1 hour, it is liquid in ambient temperature, and especially, it is at ambient temperature (25 DEG C)
And have at 0.01 to 15mg/cm under atmospheric pressure (101325Pa)2Evaporation speed in the range of/min
Rate.
It is preferably adapted to the volatile linear alkane of the present invention in ambient temperature (25 DEG C) and at air
Show at 0.01 to 3.5mg/cm under pressure (101325Pa)2In the range of/min, more preferably 0.01
To 1.5mg/cm2Evaporation rate in the range of/min.
It is highly preferred that be suitable to the volatile linear alkane of the present invention in ambient temperature (25 DEG C) and greatly
Show at 0.01 to 0.8mg/cm under air pressure (101325Pa)2In the range of/min, preferably 0.01
To 0.3mg/cm2In the range of/min, and more preferably at 0.01 to 0.12mg/cm2/ min scope
Interior evaporation rate.
The evaporation rate of volatility alkane according to the present invention (and more generally, volatile solvent) can
With especially by the scheme evaluation described in WO 06/013413, and more specifically, pass through
Following proposal is evaluated.
15g non-volatile hydrocarbon solvent is introduced in the crystallizing dish (diameter: 7cm) being placed on balance, institute
State balance to be in there is regulation temperature (25 DEG C) and the about 0.3m of hygrometry (relative humidity 50%)3Hold
In long-pending room.
Non-volatile hydrocarbon solvent is freely evaporated in the case of not stirring it, with being arranged in receiving volatilization
Fan (Papst-Motoren, the Ref. No. of the crystallizing dish upper vertical position of property hydrocarbon solvent
(reference) 8550N, 2700 revs/min of rotations) provide and ventilate, and flabellum is with relative to knot
Bottom brilliant ware, the distance of 20cm is towards crystallizing dish.
Time interval measurement in rule remains in the weight of the non-volatile hydrocarbon solvent in crystallizing dish.
Then by drawing the amount of the product of the evaporation as time (in terms of min) function (with mg/cm2
Meter) curve, obtain the evaporation curve figure of solvent.
Then, the evaporation rate corresponding to the tangent line at the initial point of curve obtained is calculated.Evaporation rate
Express in the following manner: per unit surface area (cm in time per unit (minute)2) volatility evaporated
The mg number of solvent.
According to a preferred embodiment, the volatile linear alkane being suitable to the present invention has in ambient temperature
There is non-zero vapor pressure (also referred to as saturated vapour pressure), specifically, in the range of 0.3Pa to 6000Pa
Vapour pressure.
The volatile linear alkane being preferably adapted to the present invention has 0.3 in ambient temperature (25 DEG C)
Vapour pressure to 2000Pa, the most more preferably vapour pressure in the range of 0.3 to 1000Pa.
It is highly preferred that the volatile linear alkane being suitable to the present invention has 0.4 in ambient temperature (25 DEG C)
To 600Pa, preferably 1 to 200Pa, and even more preferably vapour pressure in the range of 3 to 60Pa.
According to an embodiment, the volatile linear alkane being suitable to the present invention can show 30
To 120 DEG C, and more particularly, the flash-point in the range of 40 to 100 DEG C.Flash-point is according to standard ISO
3679 concrete measurements.
According to an embodiment, the volatile linear alkane being suitable to the present invention can comprise 7 to 15
Individual carbon atom, preferably 8 to 14 carbon atoms, and also more preferably 9 to 14 carbon atoms.
It is highly preferred that the volatile linear alkane being suitable to the present invention comprises 10 to 14 carbon atoms, and
And even more preferably 11 to 14 carbon atoms.
The volatile linear alkane being suitable to the present invention can be advantageously the volatile straight chain alkane of plant origin
Hydrocarbon.
Preferably, the mixture bag of volatile linear alkane present in the compositions according to the present invention
Containing at least one carbon isotope14C (carbon 14).Specifically,14C isotope can be with following isotope number
Ratio (or14C/12C ratio) exist: more than or equal to 1 × 10-16, preferably greater than or equal to 1 × 10-15,
More preferably equal to or greater than 7.5 × 10-14, and also be even more preferably greater than or equal to 1.5 × 10-13.Preferably,14C/12C ratio is 6 × 10-13To 1.2 × 10-12In the range of.
In the mixture of volatile linear alkane14The isotopic amount of C can pass through art technology
Known to personnel, method determines, such as Libby counting method, liquid scintillation spectrometry or accelerator mass spectrometry
Method.
This alkane can directly obtain from plant material such as oil, butter, wax etc. or point several stages obtain
Arrive.
Example as the alkane being suitable to the present invention, it can be mentioned be at patent application WO
Alkane described in 2007/068371 and WO2008/155059.These alkane can obtain from fatty alcohol
Arriving, themselves obtains from Oleum Cocois or Petiolus Trachycarpi oil.
Example as the linear paraffin being suitable to the present invention, it can be mentioned be normal heptane (C7), the most pungent
Alkane (C8), n-nonane (C9), n-decane (C10), n-undecane (C11), n-dodecane (C12), positive 13
Alkane (C13), n-tetradecane (C14) and Pentadecane (C15).According to a specific embodiment, volatilization
Property linear paraffin selected from n-nonane, n-undecane, n-dodecane, n-tridecane and n-tetradecane.
According to a preferred embodiment, it can be mentioned be n-undecane (C11) and n-tridecane
(C13) mixture, its application WO2008/155059 embodiment 1 and 2 in obtain.
Can also be mentioned by Sasol respectively with Ref. No. (reference) Parafol 12-97 and
N-dodecane (the C that Parafol 14-97 sells12) and n-tetradecane (C14), and their mixture.
One embodiment includes different the waving of at least two using carbon number n each other to differ at least 1
The mixture of the property sent out linear paraffin, specifically, carbon number differs at least two difference of 1 or 2 each other
The mixture of volatile linear alkane.
According to an embodiment, use and comprise 10 to 14 carbon atoms, and carbon number difference each other
The mixture of the volatile linear alkane that at least two of at least 1 is different.As an example, can have
Body is mentioned that the C of volatile linear alkane10/C11, C11/C12Or C12/C13Mixture.
According to another embodiment, use and comprise 10 to 14 carbon atoms, and carbon number phase each other
The mixture of the volatile linear alkane that the difference at least two of at least 2 is different.As an example, permissible
It is mentioned that, for even number carbon number n, the C of volatile linear alkane10/C12Or C12/C14Mixture,
And for odd number carbon number n, C11/C13Mixture.
According to a preferred embodiment, use and comprise 10 to 14 carbon atoms, each other carbon number difference
The mixture of the volatile linear alkane that at least two of at least 2 is different, particularly volatile straight chain
The C of alkane11/C13Mixture or the C of volatile linear alkane12/C14Mixture.
Can use in the present invention and combine the volatile linear alkane according to the present invention more than 2 kinds
Other mixture, such as, such as comprise 7 to 15 carbon atoms, each other carbon number difference at least 1
The mixture of at least 3 kinds of individual different volatile linear alkanes.
In the case of the mixture of two kinds of volatile linear alkanes, the two volatile linear alkane
Preferably comprise mixture more than 95 weight %, and also more preferably heavier than 99 weight %.
A concrete form according to the present invention, in the mixture of volatile linear alkane, has
The volatile linear alkane of little carbon number is preponderated in the mixture.
According to another form of the invention, use the volatile linear alkane wherein with maximum carbon number
The mixture of the most dominant volatile linear alkane.
As the example of the mixture being suitable to the present invention, can be it is especially mentioned that following mixture:
Relative to the gross weight of alkane in described mixture,
50 to 90 weight %, preferably 55 to 80 weight %, more preferably 60 to 75 weight %
Volatile straight chain CnAlkane, and n is in the range of 7 to 15,
10 to 50 weight %, preferably 20 to 45 weight %, the volatilization of preferably 24 to 40 weight %
Property straight chain Cn+xAlkane, and x is more than or equal to 1, preferably x=1 or x=2, and n+x between
Between 8 to 14.
Specifically, the mixture of described volatile linear alkane can also contain:
Less than 2 weight %, the branched-chain hydrocarbons of preferably less than 1 weight %,
And/or less than 2 weight %, the aromatic hydrocarbon of preferably less than 1 weight %,
And/or less than 2 weight %, preferably less than 1 weight % and preferentially less than 0.1 weight % not
Saturated hydrocarbons,
Described percentage ratio is expressed relative to the gross weight of mixture.
More specifically, the volatile linear alkane being suitable to the present invention can mix with n-undecane/n-tridecane
The form of compound uses.
Specifically, the mixture of the volatile linear alkane of use is comprised:
Relative to the gross weight of alkane in described mixture,
55 to 80 weight %, the volatile straight chain C11 alkane (positive ten of preferably 60 to 75 weight %
One alkane) and
20 to 45 weight %, the volatile straight chain C13 alkane (positive ten of preferably 24 to 40 weight %
Three alkane).
According to a specific embodiments, the mixture of alkane is n-undecane/n-tridecane mixture.
Specifically, this mixture can be according to the embodiment 1 of application WO 2008/155059 or embodiment
2 obtain.
According to another specific embodiments, use to be gone out with Ref. No. Parafol 12-97 by Sasol
The n-dodecane sold.
According to another specific embodiments, use to be gone out with Ref. No. Parafol 14-97 by Sasol
The n-tetradecane sold.
According to another embodiment again, use n-dodecane and the mixture of n-tetradecane.
The compositions of the present invention can comprise 0.5 to 90 weight % relative to the gross weight of compositions, special
Not, 1 to 50 weight %, more particularly, 3 to 40 weight %, and also more preferably 3 to 30
The volatile linear alkane of weight %.
Term " cationic polymer " is understood to refer to comprise cation group and/or can be with ionizing
To provide any polymer of the group of cation group.
Cationic polymer that can be used according to the invention can be selected from itself due to improvement detergent
The all that cationic polymer that the cosmetic character of the hair of compositions-treated is known, i.e. concrete
Ground, in patent application EP-A-0 337 354 and at french patent application FR-A-2 270 846,2 383
660,2 598 611, those cationic polymers described in 2 470 596 and 2 519 863.
Preferably cationic polymer is selected from those cationic polymers comprising such unit, described
Unit comprises primary, secondary, uncle and/or quaternary amines, described primary, secondary, uncle and/or quaternary amines or
A part for main polymer chain can be formed, or can be by the side chain being directly connected with main polymer chain
Substituent group is carried.
The weight average molecular weight of the cationic polymer used is more than 105, preferably greater than 106, and also
More preferably between 106To 108Between.Cationic polymer is preferably non-siloxane polymer.
The cationic polymer used in the present invention is non-protein polymer, say, that they are not
Comprise any albumen block based on aminoacid or peptide or unit.As non-protein cationic polymer,
Can more specifically be mentioned that polyamine, polyaminoamide and the polymer of polyquaternary amine type.These are
Known product.
Gathering of the polyamine that can use in the present compositions, polyaminoamide or polyquaternary amine type
Compound is those described in French Patent (FRP) 2 505 348 and 2 542 997.In these polymer
It is mentioned that:
(1) homopolymer or copolymer, its derived from propylene acid esters, methacrylate, acrylamide
Or Methacrylamide and at least one in comprising the unit of following formula:
Wherein:
R1And R2, it is identical or different, represents hydrogen atom or has the alkane of 1 to 6 carbon atom
Base, preferably methyl or ethyl；
R3, it is identical or different, represents hydrogen atom or CH3Group；
Symbol A, it is identical or different, represents and comprises 1 to 6 carbon atom, preferably 2 or 3
The straight or branched alkyl of individual carbon atom, or comprise the hydroxy alkyl of 1 to 4 carbon atom；
R4, R5And R6, it is identical or different, represents the alkyl with 1 to 18 carbon atom
Or benzyl, and preferably there is the alkyl of 1 to 6 carbon atom；
X-Represent derived from the inorganic or anion of organic acid, such as methyl sulfate anions or
Halogen ion, such as chloride ion or bromide ion.
The copolymer of race (1) can also comprise one or more unit derived from comonomer, its
Can be selected from following race: acrylic amide, methacryl amine, N-[2-(2-methyl-4-oxopentyl)
Class, by rudimentary (C on nitrogen-atoms1-C4) AAM class and Methacrylamide
Class, derived from propylene acids or methacrylic or the group of their ester, acyl in vinyl
Amine such as vinyl pyrrolidone or caprolactam, or vinyl ester.
Thus, in these copolymers of race (1), it can be mentioned:
-acrylamide and by dimethyl sulfate or by the quaternized dimethylaminoethyl acrylate methyl of methyl halide
The copolymer of base amino ethyl ester,
-such as acrylamide described in patent application EP-A-080 976 and methyl chloride third
The copolymer of alkene trimethylammonium trimethyl ammonium,
-acrylamide and the copolymerization of methacryloxyethyl trimethylammoniumethyl sulfate
Thing,
-vinyl pyrrolidone/propenoic acid dialkyl aminoalkyl ester or methacrylic acid dioxane
Base aminoalkyl ester copolymer, it can be quaternized or can not be quaternized.These polymerizations
Thing is described in detail in French Patent (FRP) 2 077 143 and 2 393 573.Such polymer is such as
By ISP with trade name Gafquat
755 sell,
-dimethylaminoethyl methacrylate/caprolactam/vinyl pyrrolidone
Terpolymer,
-vinyl pyrrolidone/methacryiamidopropyl dimethyl amine copolymer,
The dimethylaminopropyl methacryl amine copolymer of-vinyl pyrrolidone/quaternized
Thing, and
-methacryloxy (C1-C4) alkyl three (C1-C4) cross linked polymer of alkylammonium salt,
The polymer such as obtained by following method: by the methacrylic acid two quaternized by methyl chloride
Methylamino ethyl ester homopolymerization, or by acrylamide and the methacrylic acid two quaternized by methyl chloride
Methylamino ethyl ester copolymerization, with having ethylenic unsaturation after described homopolymerization or copolymerization
Compound, particularly methylene-bisacrylamide crosslinking.
Cross-linked polymeric as methacryloxy (C1-C4) alkyl three (C1-C4) alkylammonium salt
Thing, it can be mentioned be with title Salcare by Ciba
SC 92, Salcare
SC 95 He
Salcare
Those of SC 96 sale.
(2) cellulose ether comprising quaternary ammonium group described in French Patent (FRP) 1 492 597 derives
Thing, and especially, by Amerchol with title " Ucare Polymer JR " (JR 400LT,
JR 125, JR 30M) or " Ucare Polymer LR " (LR 400, LR 30M) sell poly-
Compound.As with the epoxide reactive hydroxy ethyl fiber replaced by trimethyl ammonium group
The quaternary ammonium of element, these polymer are also defined in CTFA dictionary.
(3) cationic cellulose derivative, such as, be grafted with the cellulose of water soluble quaternary ammonium monomer
Or the copolymer of cellulose derivative, and it is specifically described in patent US 4 131 576,
It is grafted with methylacryloyl ethyl trimethyl ammonium, methacryiamidopropyl three the most especially
Ammonium methyl or the hydroxy alkyl cellulose of dimethyldiallylammonium salt, such as methylol-, ethoxy
-or hydroxypropyl cellulose.
Corresponding to this commercially available product defined more specifically by National Starch with title
″CelquatL 200 " and " CelquatH 100 " the product sold.
(4) cationic polysaccharide described in patent US 3 589 578 and US 4 031 307,
Such as comprise the guar gum of trialkylammonium cation group.Use such as by 2,3-epoxy radicals third
The such as chlorination 2 of base leptodactyline, the guar gum that 3-epoxypropyl trimethyl ammonium is modified.
Such product especially by Rhodia with trade name JaguarC13S,
JaguarC15, JaguarC17 or JaguarC162 sells.
(5) it is made up of piperazinyl units and straight or branched divalent alkyl or hydroxy alkylidene
Polymer, it optionally interrupts by oxygen, sulfur or nitrogen-atoms, or is interrupted by aromatic ring or heterocycle, with
And the oxidation of these polymer and/or quaternized products.This polymer is particularly described in France special
In profit 2 162 025 and 2,280 361.
(6) water-soluble polyaminoamide, it is especially by the polycondensation system of acid compound Yu polyamine
Standby；These polyaminoamides can be cross-linked by the following: epihalohydrin, diepoxides,
Dianhydride, unsaturated dianhydride, double unsaturated derivants, double halohydrins, double azetidines(bisazetidinium), double halogenacyl diamidogen or alkyl dihalide, or alternatively, quilt
Oligomer cross-links, and described oligomer results from can be with double halohydrins, double azetidines
Double halos
Acyl group diamidogen, alkyl dihalide, epihalohydrin, diepoxides or double unsaturation are derivative
The reaction of the difunctional compound of thing reaction；Relative to the amino of the polyaminoamide of each,
Cross-linking agent uses with the ratio in the range of 0.025 to 0.35mol；These polyaminoamides can
To be partially alkylated or alkylated, or in the case of they comprise one or more tertiary amine functional group, can be by
Quaternized.Such polymer is specifically described in French Patent (FRP) 2 252 840 and 2 368 508.
(7) amide derivatives obtained from following methods: by polyalkylene polyamine with poly-
Carboxylic acid is condensed, and carries out the alkylation by two functionalizing agents subsequently.Such as it is mentioned that oneself
Diacid/dialkyl amido hydroxy alkyl two alkylene triamine polymer, wherein, alkyl comprise 1 to
4 carbon atoms, and preferably represent methyl, ethyl or propyl group, and alkylidene comprises 1 to 4
Individual carbon atom and preferably represent ethylidene.Such polymer is specifically described in French Patent (FRP)
In 1 583 363.
In these derivants, can more specifically mention adipic acid/dimethylamino hydroxypropyl
Diethylenetriamines polymer.
(8) by comprising the polyalkylene polyamine and two of two primary amine groups and at least one secondary amine
The polymer that the reaction of carboxylic acid obtains, described dicarboxylic acids is selected from diglycolic acid and has 3 to 8
The radical of saturated aliphatic dicarboxylic acids of carbon atom；The mol ratio of polyalkylene polyamine and dicarboxylic acids is between 0.8:
Between 1 to 1.4: 1；With the chloropropylene oxide between 0.5: 1 to 1.8: 1 and polyaminoamide
The mol ratio of secondary amine polyaminoamide therefrom is reacted with chloropropylene oxide.Such poly-
Compound is specifically described in United States Patent (USP) 3 227 615 and 2 961 347.
(9) cyclopolymers of alkyldiallylamine or the cyclic polymer of dialkyl diallyl ammonium, such as, wrap
Containing the unit corresponding to formula (Ia) or (Ib) as the homopolymer of the key component of chain or copolymerization
Thing:
Wherein, k and t is equal to 0 or 1, and summation k+t is equal to 1；R12Represent hydrogen atom or first
Base；R10And R11Represent the alkyl with 1 to 6 carbon atom, wherein alkyl independently of one another
Preferably there is the hydroxyalkyl of 1 to 5 carbon atom, or rudimentary (C1-C4) amido alkyl, or separately
Other places, R10And R11Nitrogen-atoms that can be in connection represents heterocyclic radical, such as piperazine in combination
Piperidinyl or morpholinyl；Y-For anion, such as bromide ion, chloride ion, acetate, borate,
Citrate, tartrate anion, bisulfate ion, bisulfite, sulfate radical or phosphate radical.This
A little polymer are specifically described in French Patent (FRP) 2 080 759 and additional testimonial (Certificate of thereof
Addition) in 2 190 406.
R10And R11The most preferably represent the alkyl with 1 to 4 carbon atom.
In the polymer being as defined above, can more specifically be mentioned that by Nalco Company
With title " Merquat100 " homopolymer of the dimethyldiallylammonium chloride sold is (and low
The homologue of weight average molecular weight), and with title " Merquat
550 " or " Merquat
7SPR " chloride sold and the copolymer of acrylamide.
(10) two quaternary ammonium polymers of repetitive corresponding to formula (II) are comprised:
Wherein:
R13, R14, R15And R16, it is identical or different, represents and comprises 1 to 20 carbon atom
Aliphatic series, alicyclic or aryl aliphatic, or lower aliphatic hydroxyalkyl, or additionally, R13,
R14, R15And R16Constitute together with the nitrogen-atoms jointly or respectively combined with them and optionally comprise
The second heteroatomic heterocycle beyond denitrogenating, or additionally, R13, R14, R15And R16Represent
By nitrile, ester, acyl group, amide or-CO-O-R17-E or-CO-NH-R17-E group is substituted directly
Chain or side chain C1-C6Alkyl, wherein R17It is quaternary ammonium group for alkylidene and E；
A1And B1Represent and comprise the polymethylene of 2 to 20 carbon atoms, its can be straight chain or
Side chain, and be saturated or undersaturated, and it can comprise and be bound to main chain or insertion
One or more aromatic rings in main chain or one or more oxygen or sulphur atom or sulfoxide, sulfone, two
Sulfide, amino, alkyl amino, hydroxyl, quaternary ammonium, urea groups, amide or ester group, and
X-Represent derived from the inorganic or anion of organic acid；
A1, R13And R15Two nitrogen-atoms that can be in connection form piperazine ring together；Separately
Outward, if A1Represent the saturated of straight or branched or undersaturated alkylidene or hydroxy alkylidene,
Then B1Also may indicate that following groups:
-(CH2)n-CO-E′-OC-(CH2)n-
Wherein, E ' represents:
A) residue of dihydric alcohol of formula-O-Z-O-, wherein Z represent straight or branched alkyl or corresponding to
The group of one of following formula:
-(CH2-CH2-O)x-CH2-CH2-
-[CH2-CH(CH3)-O]y-CH2-CH(CH3)-
Wherein x and y represents the integer of 1 to 4, represents limit and unique degree of polymerization, or
Any numeral of 1 to 4, represents average degree of polymerization；
B) double secondary diamine residues, such as bridged piperazine derivatives；
C) double primary diamines residues of formula-NH-Y-NH-, wherein Y represents straight or branched alkyl,
Or additionally, divalent group-CH2-CH2-S-S-CH2-CH2-；
D) ureylene of formula-NH-CO-NH-.
Preferably, X-For anion, such as chloride ion or bromide ion.
The polymer of this type is specifically described in French Patent (FRP) 2 320 330, and 2 270 846,
2 316 271,2 336 434 and 2 413 907 and United States Patent (USP) 2 273 780,
2 375 853,2 388 614,2 454 547,3 206 462,2 261 002,2 271 378,
3 874 870,4 001 432,3 929 990,3 966 904,4 005 193,4 025 617,
4 025 627,4 025 653, in 4 026 945 and 4 027 020.
Can more particularly use the polymer being made up of the repetitive corresponding to formula (III):
Wherein, R13, R14, R15And R16, it is identical or different, represents have about 1 to 4
The alkyl of individual carbon atom or hydroxyalkyl, n and p is about from the integer of 2 to 20 changes, and
X-For the anion derived from inorganic or organic acid.
(11) poly quaternary amine polymer being made up of the unit of formula (IV):
Wherein:
R18, R19, R20And R21, it is identical or different, represents hydrogen atom or methyl, second
Base, propyl group, beta-hydroxy ethyl, beta-hydroxy propyl group or-CH2CH2(OCH2CH2)pOH group,
Wherein equal to 0 or equal to the integer between 1 to 6, condition is R to p18, R19, R20With
R21Asynchronously represent hydrogen atom,
R and s, it is identical or different, is the integer between 1 to 6,
Q is equal to 0 or is equal to the integer between 1 to 34,
X-Represent anion, such as halogen ion,
A represents the group from dihalide, or preferably, table
Show-CH2-CH2-O-CH2-CH2-。
Such compound is specifically described in patent application EP-A-122 324.
(12) vinyl pyrrolidone and the quaternary ammonium polymer of vinyl imidazole, the most such as, by
BASF is with title Luviquat
The product that FC 905, FC 550 and FC 370 sells,
Mixture with them.
Other cationic polymer that can use in the context of the present invention is that polyalkylene is sub-
Amine, particularly polyethylene imine, comprise vinylpyridine or vinylpyridine
Gathering of unit
The condensation substance of compound, polyamine and chloropropylene oxide, quaternary ammonium poly-ureylene (quaternary
And chitin derivative polyureylenes).
In all cationic polymers that can use in the context of the present invention, preferably make
With race (1), (2) (9) and those cationic polymers of (12), and more specifically: quaternized
Vinyl pyrrolidone/propenoic acid dialkyl aminoalkyl ester or methacrylic acid dialkyl amido
Alkyl ester copolymer, such as by ISP with title Gafquat
755 products sold；Comprise season
The cellulose ether derivative of ammonium, such as by Amerchol with title " Ucare Polymer JR
400 LT " the product sold；Cation cyclic polymer, specifically, chlorodimethyl two allyl
Base ammonium homopolymer or copolymer, by Nalco Company with title Merquat
100,
Merquat
550, Merquat
S and Merquat
7SPR sells；Vinyl pyrrolidone
With the quaternary ammonium polymer of vinyl imidazole, such as by BASF with title Luviquat
FC 905,
The product that FC 550 and FC 370 sells；Methacryloxy (C1-C4) alkyl three (C1-C4)
The cross linked polymer of alkylammonium salt, such as by Ciba with title Salcare
SC 92, Salcare
SC 95 and Salcare
Those of SC 96 sale；Mixture with them.
Relative to the gross weight of compositions, non-protein cationic polymer is with preferably 0.05 to 10
The model of weight %, more preferably 0.1 to 5 weight %, and even more preferably 0.2 to 2 weight %
Enclose interior amount to exist.
Medium used for cosmetic is preferably made up of water or mixed by water and at least one solvent used for cosmetic
Compound forms, at least one solvent selected from lower C used for cosmetic described1-C4Alcohol, such as ethanol,
Isopropanol, the tert-butyl alcohol or n-butyl alcohol；Polyhydric alcohol, such as glycerol, propylene glycol and Polyethylene Glycol；
Mixture with them.
According to an embodiment, can also be comprised at least one according to the compositions of the present invention and satisfy
With or undersaturated straight or branched fatty alcohol, it comprises 8 to 32 carbon atoms, more preferably wraps
Containing 10 to 22 carbon atoms.As the example of the fatty alcohol that can use in the present invention, can
To be specifically mentioned that lauryl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, 16/octadecanol,
Oleyl alcohol, docosanol, hexyldecanol, 2-octyldodecanol, and their mixture.
In the presence of alcohol or one or more fatty alcohol, relative to the gross weight of compositions, according to
The compositions of the present invention can comprise 0.1 to 20 weight %, particularly 0.2 to 15 weight %,
And the described alcohol of more particularly 0.5 to 10 weight % or one or more fatty alcohol.
Preferably, according to the compositions of the present invention can also comprise at least one fatty acid ester and/
Or at least one siloxanes, described siloxanes is the most nonvolatile.
In one embodiment, at least one fat can also be comprised according to the compositions of the present invention
Fat acid esters, it is C2-30Unitary or polybasic carboxylic acid and C1-30, preferably C3-20Unitary or polyhydric alcohol
Fatty acid ester, the sum of the carbon atom in described ester 10 to 50 change.Especially, fat
The carboxylic acid of fat acid esters and alcohol are straight chains.
As the example of the fatty acid ester that can use in the present invention, can it is especially mentioned that,
Capric acid 2-Octyl Nitrite/octanoic acid 2-Octyl Nitrite (or octyl/octyl octanoate), lauric acid second
Ester, butyl laurate, lauric acid hexyl ester, isohexyl laurate ester, isopropyl laurate, lima bean
Cool acid methyl ester, ethyl myristate, butyl myristate, myristic acid isobutyl ester, Semen Myristicae
Isopropyl propionate, myristic acid 2-octyldodecyl ester, myristyl myristate, myristic acid
Cetyl, myristic acid stearyl ester, single coconut oil 2-Octyl Nitrite (2-ethylhexyl
Monococoate) (or single octylcocoate), methyl hexadecanoate, ethyl palmitate, Palmic acid is different
Propyl ester, isobutyl palmitate, Palmic acid 2-Octyl Nitrite (or octyl palmitate), Palmic acid meat
Fructus Amomi Rotundus ester, cetin, Palmic acid stearyl ester, butyl stearate, isopropyl stearate,
Isobutyl stearate, Standamul 7061, stearic acid myristin, cetyl stearate,
Stearyl stearate, the different stearyl ester of isostearic acid, isopropyl isostearate, stearic acid 2-ethyl
Own ester (or octyl stearate), n-nonanoic acid 2-Octyl Nitrite (or octyl pelargonate), hydroxy stearic acid 2-
Octyl Nitrite (or octyl hydroxystearate), decyl oleate, diisopropyl adipate, adipic acid
Two-2-Octyl Nitrites (or dioctyl adipate), the different cetyl of adipic acid two, succinic acid 2-ethyl
Own ester (or octenyl succinate), Dermol DIPS, malic acid 2-Octyl Nitrite (or malic acid
Monooctyl ester), tetramethylolmethane decanoin/caprylate, pentaerythritol tetraoctyl stearate, caproic acid 2-second
The own ester of base (or caproic acid monooctyl ester), octanoic acid octyldodecyl ester, Dermol 105, neopentanoic acid is different
Stearyl ester, different n-nonanoic acid 16/octadecane ester, different isodecyl pelargonate, isononyl isononanoate, different nonyl
The different tridecane ester of acid, Lauryl lactate, Tetradecyl lactate, cetyl lactate, propanoic acid lima bean
Cool ester, KAK88SX (or 2 ethyl hexanoic acid monooctyl ester), octanoic acid 2-Octyl Nitrite (or
Octyl octanoate), benzoic acid C12-15Aliphatic alcohol ester (from the Finsolv TN of Finetex), Laurel
Acyl group sarcosine isopropyl ester (from the Eldew SL 205 of Unipex), carbonic acid two caprylyl ester (comes
From the Cetiol CC of Cognis), and their mixture.
Preferably, fatty acid ester can be selected from myristyl myristate, cetyl myristate,
Myristic acid stearyl ester, cetyl palmitat, cetin, Palmic acid stearyl ester,
Stearic acid myristin, cetyl stearate, stearyl stearate and their mixture.
When there are one or more fatty acid esters, relative to the gross weight of compositions, according to this
The compositions of invention can comprise 0.1 to 20 weight %, particularly 0.5 to 15 weight %, and
And more particularly 1 to 10 one or more fatty acid ester of weight %.
In addition to fatty alcohol defined above or ester, can also comprise according to the compositions of the present invention
At least one other hard fat material, such as wax.
In the implication of the present invention, term " wax " is understood to refer to such lipotropy
Compound, it is solid in ambient temperature (25 DEG C), show under certain conditions reversible solid/
Liquid changes, and has more than or equal to 30 DEG C of fusing points, its can at up to 200 DEG C,
And in the range of being specifically up to 120 DEG C.
When making wax reach liquid condition (melting), itself and oil can be made miscible and formed grand
See uniform mixture, but when the temperature making mixture reaches ambient temperature, obtain wax
Recrystallization in the oil of mixture.
The wax being applicable to the present invention can show more than or equal to 45 DEG C, particularly greater than or etc.
In the fusing point of 55 DEG C.
In the implication of the present invention, fusing point corresponds to the pass as at standard ISO 11357-3；
Heat described in 1999 analyzes the temperature of the maximum heat absorption honeybee that (DSC) observes.The fusing point of wax is permissible
Differential scanning calorimetry (DSC) (DSC) is used to measure, such as by TA Instruments with title " MDSC
2920 " calorimeter sold.
Specifically, it is adaptable to the wax of the present invention can be selected from animal, plant, mineral or synthesis to be come
The wax in source and their mixture.
As the example of the wax being applicable to the present invention, can with specifically mentioned chloroflo, such as Cera Flava,
The particularly chloroflo of biogenetic derivation, lanocerin, Chinese insect wax, rice bran wax, Brazil wax,
Candelilla wax, ouricury wax, esparto wax, berry wax, shellac wax, Japan wax (Japan
Wax), sumac wax, lignite wax, orange and Fructus Citri Limoniae wax, microwax, paraffin, ceresine, polyethylene
Wax, the wax obtained by Fischer-Tropsch synthesis and wax-like copolymer, also have their ester.
C can also be mentioned20-C60Microwax such as Microwax HW.
Can also be mentioned the PM 500 to sell with reference to title Permalen 50-L polyethylene
Tissuemat E.
Can also mention by having straight or branched C8-C32The animal or plant oil of aliphatic chain
The wax that catalytic hydrogenation obtains.
In these, can specifically mention the Jojoba oil (jojoba oil) of isomerization, such as by
Desert Whale is with business reference title Iso-Jojoba-50
The trans isomerism produced or sell
Part hydrogenated jojoba oil, hydrogenated sunflower oil, castor oil hydrogenated, hydrogenated coco, hydrogenate Pilus Caprae seu Ovis
Fatty oil, and by Heterene with title Hest 2T-4S
Two (1,1, the 1-trimethylolpropanes) sold
Tetrastearate.
Fluorination wax can also be mentioned.
Can also use by the Oleum Ricini being esterified by spermol is hydrogenated and the wax that obtains, its by
Sophim is with title Phytowax Castor 16L64
And 22L73
Sell.Such wax is retouched
It is set forth in application FR-A-2 792 190.
As wax, C can be used either individually or as mixture20-C40Alkyl (hydroxy stearate oxygen
Base) stearate (alkyl comprises 40 carbon atoms of 20 ester).
This wax especially by Koster Keunen with title " Kester Wax K 82 P
", " hydroxyl
Base polyester K 82 P
" and " Kester Wax K 80 P
" sell.
As the micro-wax (microwax) that can use in the present compositions, can be special
It is mentioned that: the micro-wax of babassu, such as by Micro Powders with title MicroCare
350
The micro-wax of babassu sold；The micro-wax of synthetic wax, such as by Micro Powders with name
Claim MicroEase 114S
The micro-wax of synthetic wax sold；By Brazil wax and Tissuemat E
Micro-wax of mixture composition, such as by Micro Powders with title MicroCare 300
With
310
Those sold；The micro-wax being made up of the mixture of Brazil wax and synthetic wax, such as
By Micro Powders with title MicroCare 325
The micro-wax sold；The micro-wax of polyethylene,
Such as by Micro Powders with title Micropoly 200
220
220L
With
250S
Those sold；Wax micro-with politef, such as by Micro Powders with title
Microslip 519
And 519L
Those sold.
According to an embodiment, the wax being suitable to the present invention can be chosen in particular from candelilla wax, bar
Western palm wax, rice bran wax, Cera Flava, the most identified biological Cera Flava, isomerization flash
Bar oil and their mixture.
When present, relative to the gross weight of compositions, the compositions according to the present invention is permissible
Comprise one or more waxes of 0.1 to 20 weight %, particularly 0.2 to 10 weight %, more special
Not 0.5 to 5 weight %, and also one or more waxes of more preferably 0.5 to 3 weight %.
In one embodiment, at least one silicon can also be comprised according to the compositions of the present invention
Oxygen alkane.
Siloxanes that can be used according to the invention can be volatile or nonvolatile, and
And it is the most nonvolatile.
Siloxanes that can be used according to the invention can be soluble or insoluble in compositions.They
Polysiloxane that can be the most insoluble, and with oil, wax,
The form of resin or sizing material provides.
Insoluble silicone disperses in the composition the most in the form of a particle, and described particle is usual
Have between 2 nanometers to 100 micron, be preferably between 20 nanometers between 20 microns
The equal size of number (is measured with particle size measurement instrument (particle sizer)).
Work " siloxanes chemistry and technology (Chemistry and Technology of at Walter Noll
Silicones) " (1968) Academic Press defines organopolysiloxane in more detail.They are permissible
It is volatility or nonvolatile, and the most nonvolatile.
When they are volatile, siloxanes is particularly selected from boiling point between 60 DEG C to 260 DEG C
Those siloxanes, be still more specifically selected from:
I () contains 3 to 7, and the annular siloxane of preferably 4 or 5 silicon atoms.They are examples
Prestox as sold with title " Volatile Silicone 7207 " especially by Union Carbide is ring-type
Four polysiloxanes, or " Silbione 70045 V 2 " sold by Rhodia, by Union Carbide
Ring-type five polysiloxanes of decamethyl sold with title " Volatile Silicone 7158 ", or by Rhodia
" Silbione 70045 V 5 " sold, and their mixture.
The cyclocopolymer of dimethyl siloxane/methyl alkyl siloxane class can also be mentioned, as by
" the Silicone Volatile FZ 3109 " that Union Carbide sells, it has the following chemical structure:
The mixture of the derivative organic compound of annular siloxane and silicon can also be mentioned, such as prestox ring
Shape four polysiloxanes and the mixture (50/50) of four (trimethylsilyl) tetramethylolmethane, and prestox
Ring-type four polysiloxanes and 1,1 '-oxygen (six-2,2,2 ', 2 ', 3,3 '-trimethyl silyl epoxide) double neopentanes
Mixture；
(ii) containing 2 to 9 silicon atoms and have less than or equal to 5 × 10 at 25 DEG C-6m2/ s's is viscous
The linear volatile silicones of degree.They for example, by Toray Silicone especially with title " SH 200 "
Decamethyl four polysiloxanes sold.The siloxanes being included in this apoplexy due to endogenous wind is also described in cosmetics and cosmetic
Apparatus (Cosmetics and Toiletries), volume 91, Jan.76, the literary composition published in the 27-32 page
Chapter Todd & Byers " volatile siloxane fluid (the Volatile Silicone Fluids for cosmetics
For Cosmetics) " in.
In non-volatile siloxane, it is mentioned that polyalkylsiloxane especially；Poly-polty (arylsiloxane)
Alkane；Polyalkylaryl siloxane；Siloxane glue material and resin；Poly-having by organo-functional group modification
Organic siloxane；(A-B)nThe polysiloxanes (A) of type and n ＞ 3-polyoxyalkylene (B) linear multiblock is common
Polymers；Having the grafted silicone polymer of non-silicone organic backbone, it comprises by not silicone-containing
Organic monomer formed organic backbone, at least one polysiloxane macromers in described chain also
And be optionally grafted on described organic backbone in its at least one end；Have and be grafted with non-silicone
The grafted silicone polymer of the polysiloxane backbone of organic monomer, it comprises polysiloxane backbone, extremely
The organic macromolecule monomer of a few not silicone-containing in described chain and optionally at it at least one
End is grafted in described polysiloxane backbone；Mixture with them.
As the example of polyalkylsiloxane, can be specifically mentioned containing trimethylsilyl end groups
Polydimethylsiloxane, it is 5 × 10 the viscosity of 25 DEG C-6To 2.5m2/ s and preferably 1 × 10-5
To 1m2/s.The viscosity of siloxanes is such as surveyed according to standard ASTM 445Appendix C at 25 DEG C
Amount.
In these polyalkylsiloxanes, can mention that following commercialization is produced in a non limiting manner
Product:
-by
The Silbione oil of 47 and 70047 series sold or Mirasil
Oil, such as oil 70047V 500000；
-by
The oil of the Mirasil series sold；
-from the oil of 200 series of Dow Corning, such as, more specifically, viscosity is 60000cSt
DC200；
-Viscasil the oil from General Electric and the SF series from General Electric
Some oil of (SF 96, SF 18).
Can also mention that the polydimethylsiloxane containing dimethyl-silicon alkanol end group is (according to CTFA name
Be referred to as dimethiconol), as from
The oil of 48 series.
In such polyalkylsiloxane, it is also possible to mention by Goldschmidt with title " Abil Wax
9800 " and " " product sold, they are poly-(C to Abil Wax 98011-C20) alkylsiloxane.
Polyalkylaryl siloxane can be in particular selected from the poly dimethyl (aminomethyl phenyl) of straight chain and/or side chain
Siloxanes or polydimethyldiphenylsiloxane, it is 1 × 10 the viscosity of 25 DEG C-5To 5 × 10-2
m2/s。
In these Polyalkylaryl siloxane, it is mentioned that via example and sell with following denotations
Product:
-from
70641 series Silbione oil；
-from
The oil of Rhodorsil 70633 and 763 series；
-from the oily Dow Corning 556 Cosmetic Grade Fluid of Dow Corning；
-from siloxanes serial for the PK of Bayer, such as product P K20；
-from siloxanes serial for PN and PH of Bayer, such as product P N1000 and PH1000；
-oily, such as SF 1023, SF 1154, SF from serial for SF some of General Electric
1250 and SF 1265.
Siloxane glue material that can be used according to the invention is particularly alone or as in a solvent
Mixture use polydiorganosiloxanewith, it has between 200000 to 1000000
High number-average molecular weight.This solvent can be selected from volatile siloxane, polydimethylsiloxane
(PDMS) oil, polyphenyl methyl siloxane (PPMS) oil, isoparaffin, polyisobutylene, dichloromethane
Alkane, pentane, dodecane, tridecane, or its mixture.
Can more specifically mention following products:
-polydimethylsiloxane gum,
-polydimethylsiloxane/methylvinylsiloxane gums material,
-polydimethylsiloxane/diphenyl siloxane sizing material,
-polydimethylsiloxane/phenyl methyl siloxane sizing material,
-polydimethylsiloxane/diphenyl siloxane/methylvinylsiloxane gums material.
Can be mixture according to the siloxanes used in the compositions of the present invention, such as:
By in the chain end hydroxylated polydimethylsiloxane (name according to CTFA dictionary
Method is referred to as dimethiconol) and the annular dimethyl polysiloxane (life according to CTFA dictionary
Name method is referred to as annular dimethyl polysiloxane) mixture that formed, as sold by Dow Corning
Product Q2 1401；
The mixture formed by polydimethylsiloxane gum and annular siloxane, as from
The product SF 1214 Silicone Fluid of General Electric；This product is corresponding poly dimethyl
The sizing material SF 30 of siloxanes (dimethicone), it has the number-average molecular weight of 500000, molten
Solution is in the oily SF 1202 Silicone Fluid of five polysiloxanes ring-type corresponding to decamethyl；
There is the mixture of two kinds of PDMS of different viscosities, more particularly PDMS sizing material
The mixture oily with PDMS, such as the product SF 1236 from General Electric.Product
SF 1236 be viscosity defined above be 20m2The sizing material SE 30 of/s and viscosity are 5 × 10-6
m2The mixture of the oily SF 96 of/s.This product preferably contains the sizing material SE 20 and 85% of 15%
Oily SF 96.
Can organopolysiloxane resins used according to the invention be the crosslinking including the following units
Siloxane systems: R2SiO2/2, R3SiO1/2, RSiO3/2And SiO4/2, wherein R represents containing 1
Alkyl or phenyl to 16 carbon atoms.
In these products, particularly preferred product is that wherein R represents rudimentary C1-C4Alkyl,
More particularly those of methyl or phenyl.
In these resins, it can be mentioned with title " Dow Corning 593 " sell product or
By General Electric with title " Silicone Fluid SS 4230 " and " Silicone Fluid
SS 4267 " those products of selling, it is the silicon with dimethyl/trimethicone structure
Oxygen alkane.
Can also mention by Shin-Etsu especially with title X22-4914, X21-5034 and
The trimethylsiloxysilicate resinoid that X21-5037 sells.
Organically-modified siloxanes that can be used according to the invention is siloxanes as defined above, this silicon
Oxygen alkane comprises one or more organo-functional group connected by alkyl in its structure.
In organically-modified siloxanes, it can be mentioned comprise following polysiloxane:
-optionally comprise C6-C24The poly-ethyleneoxy group of alkyl and/or polytrimethylene epoxide, as claimed
For the product of dimethicone copolyol, by DOW CORNING with title DC
1248 sell, or the Silwet from Union CarbideL 722, L 7500, L 77 and L
711 oil, the and (C sold with title Q25200 by DOW CORNING12) the poly-first of alkyl
Radical siloxane (methicone) copolyol；
-substituted or unsubstituted amino, as by Genesee with title GP 4 Silicone Fluid
The product sold with GP 7100, or by Dow Corning with title Q2 8220 and Dow
The product that Corning 929 or 939 sells.Substituted amino particularly amino (C1-C4Alkyl)
Group；
-quaternary ammonium group, as by Goldschmidt with title Abilquat 3272 and Abilquat 3474
The product sold；
-thiol, such as the product sold with title " GP 72A " and " GP 71 " by Genesee；
The group of-alkoxylate, as by SWS Silicones with title " Silicone
Copolymer F-755 " product sold, and the Abil Wax sold by Goldschmidt
2428,2434 and 2440；
-hydroxylated group, as having hydroxyl described in french patent application FR-A-85 16334
The polysiloxane of alkyl functional group；
-acyloxyallcyl, such as, such as poly-organic described in patent US-A-4 957 732
Siloxanes；
The anionic group of-carboxylic acid type, such as, such as from Chisso Corporation
Patent EP 186 507 described in product in；Or the anionic group of alkyl carboxyl type,
Such as present in the product X-22-3701E from Shin-Etsu those；2-hydroxy alkyl
Sulfonate radical；2-hydroxy-alkylthio sulfate radical, such as by Goldschmidt with title " Abil
S201 " and " AbilS255 " the product sold；
-hydroxyl acyl amino, the such as polysiloxane described in application EP 342 834.
It can be mentioned that such as from the product Q2-8413 of Dow Corning.
The most particularly preferred siloxanes is to have trimethyl silyl or dimethyl-silicon
The polydimethylsiloxane of alkane alkanol functional end-group, has the polydimethylsiloxanes of amine functional group
Alkane, and their mixture.
In a preferred embodiment, siloxanes is to have trimethylsilyl terminal official
The polydimethylsiloxane that can roll into a ball, such as by Wacker with trade name Belsil DM 300000
The polydimethylsiloxane sold.
When at least one existed in described siloxanes, relative to the gross weight of compositions, institute
State siloxanes with in preferably 0.1 to 20 weight %, particularly 0.2 to 10 weight %, the most more preferably
Amount in the range of ground 0.5 to 5 weight %, and the most more preferably 0.5 to 4 weight % exists.
Compositions according to the present invention can also comprise the routine that one or more are well known in the art
Additive, such as ion or non-ionic association or non-association polymer, polyhydric alcohol, albumen,
Vitamin, reducing agent, plasticizer, softening agent, defoamer, wetting agent, pigment, clay,
Inorganic filler, UV screener, inorganic colloid, peptizer, solubilizing agent, spice, preservative,
Anion, cation, nonionic or amphoteric surfactant, pearling agent, propellant, inorganic
Or organic thickening agent, dandruff removing agent, oils and fats controlling agent, it is used for resisting alopecia or raw for hair
Long reagent.
Those skilled in the art will be carefully chosen optional additive and their amount so that they
Do not endanger the character of the present composition.
Relative to the gross weight of compositions, in the range of these additives are generally with 0 to 20 weight %
Amount be present in according in the compositions of the present invention.
Compositions according to the present invention can be need to rinse or be not required to the shape of the care composition of flushing
Formula provides, and these carry with the form of the washing liquid of more or less thickening, cream, gel or emulsion
Supply.
Another theme of the present invention be cosmetic composition as above at keratin substances,
Preferred angle azelon such as the purposes in the cosmetic treatment of hair.
The invention still further relates to a kind of for by keratin substances, preferred angle azelon such as hair
The method that adornment processes, described method includes being applied in the cosmetic composition as above of effective dose
On described material, and optionally, rinse out after optional indwelling time.
When the compositions according to the present invention is used with the form of washing liquid or cream, it is optionally on hair
Retain about 1/2min to 5 minute, then optionally it is rinsed out with water.
In order to demonstrate the invention, the following example is given.
In the examples below that, unless otherwise noted, all of amount is all with the gross weight relative to compositions
The products weight % form of amount represents.
Embodiment
Embodiment 1
The following care composition that need to rinse is prepared from the composition shown in following table.
AM: active material
Head is tested this care composition that need to rinse, and by itself and identical comparison combination
Thing compares, and described comparative composition comprises ring-type five polysiloxanes of volatile silicone solvent
Replace hendecane and the mixture of tridecane.These compositionss are coated to hair in ambient temperature
On, last 1 minute, with afterflush.
Compared with comparative composition, for observing in slickness according to the compositions of the present invention,
Improvement in terms of flexibility and compliance.
Compared with the comparative composition comprising ring-type five polysiloxanes, when in the composition by 11
The mixture n-dodecane of alkane and tridecane, n-tetradecane, or n-dodecane and n-tetradecane
Mixture replace time, also observe that this improves.
Embodiment 2
The following care composition being not required to and rinsing is prepared from the composition shown in following table.
This compositions is coated on hair.After drying, it was observed that excellent slickness,
Flexibility and compliance result.
Embodiment 3
The following care composition being not required to and rinsing is prepared from the composition shown in following table.
AM: active material
This compositions is coated on hair.After drying, it was observed that extraordinary visual light
Slip, excellent sensation and the biggest molding easiness.
Visual light slip and molding easiness are better than with wherein replacing 11 with ring-type five polysiloxanes
Those visual light slips that the same combination of alkane/tridecane mixture obtains and molding easiness.
Embodiment 4
The following care composition being not required to and rinsing is prepared from the composition shown in following table.
AM: active material
This compositions is coated on hair.After drying, it was observed that extraordinary visual light
Slip, excellent sensation and extraordinary molding easiness.
Visual light slip and molding easiness are better than with wherein replacing 11 with ring-type five polysiloxanes
Those visual light slips that the same combination of alkane/tridecane mixture obtains and molding easiness.
The compositions be given in an embodiment can be sprayable, such as, spray via pumping action
Device sprays.
The compositions of embodiment 4 is packaged in pumping action ejector.Then can easily exist
The compositions of injection it is distributed on hair.
Claims (29)
1. cosmetic composition, described cosmetic composition is in medium used for cosmetic, with model
Enclose volatile linear alkane/one or more non-protein cationic polymer weight of 1.2 to 20
Ratio, comprises:
The two or more volatile linear alkane of-1 to 50 weight %, and
One or more non-protein cationic polymers of-0.1 to 5 weight %,
Wherein said non-protein cationic polymer is selected from:
-acrylamide and by dimethyl sulfate or by the quaternized dimethylaminoethyl acrylate methyl of methyl halide
The copolymer of base amino ethyl ester,
-acrylamide and the copolymer of methyl chloride acryloyloxyethyl trimethyl ammonium,
-acrylamide and the copolymerization of methacryloxyethyl trimethylammoniumethyl sulfate
Thing,
-vinyl pyrrolidone/propenoic acid dialkyl aminoalkyl ester or methacrylic acid dioxane
Base aminoalkyl ester copolymer, it can be quaternized or can not be quaternized,
-dimethylaminoethyl methacrylate/caprolactam/vinyl pyrrolidone
Terpolymer,
-vinyl pyrrolidone/methacryiamidopropyl dimethyl amine copolymer,
The dimethylaminopropyl methacryl amine copolymer of-vinyl pyrrolidone/quaternized
Thing, and
-methacryloxy (C1-C4) alkyl three (C1-C4) cross linked polymer of alkylammonium salt.
Cosmetic composition the most according to claim 1, it is characterised in that described volatilization
Property linear paraffin is the linear paraffin comprising 7 to 15 carbon atoms.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that described
Volatile linear alkane be selected from normal heptane, normal octane, n-nonane, n-decane, n-undecane,
N-dodecane, n-tridecane, n-tetradecane and Pentadecane.
Cosmetic composition the most according to claim 3, it is characterised in that described volatilization
Property linear paraffin selected from n-nonane, n-undecane, n-dodecane, n-tridecane and positive 14
Alkane.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that described
Volatile linear alkane is the volatile linear alkane of plant origin.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that relatively
In the gross weight of described compositions, described volatile linear alkane is with the content of 3 to 40 weight %
Exist.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that relatively
In the gross weight of described compositions, described volatile linear alkane is with the content of 3 to 30 weight %
Exist.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that relatively
In the gross weight of described compositions, one or more non-protein cationic polymers described are with 0.2
Content to 2 weight % exists.
Cosmetic composition the most according to claim 1 and 2, it is characterised in that described
Volatile linear alkane/one or more non-protein cationic polymer weight ratios are 3 to 20
In the range of.
Cosmetic composition the most according to claim 1, it is characterised in that describedization
Cosmetic compositions comprise at least one comprise the saturated or undersaturated of 8 to 32 carbon atoms and
It it is the fatty alcohol of straight or branched.
11. cosmetic compositions according to claim 10, it is characterised in that described fat
Fat alcohol be selected from lauryl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, 16/octadecanol, oleyl alcohol,
Docosanol, hexyldecanol, 2-octyldodecanol, and their mixture.
12. according to the cosmetic composition described in claim 10 or 11, it is characterised in that
Relative to the gross weight of described compositions, one or more fatty alcohol described are with at 0.1 to 20 weight
Content in the range of amount % exists.
13. according to the cosmetic composition described in claim 10 or 11, it is characterised in that
Relative to the gross weight of described compositions, one or more fatty alcohol described are with at 0.2 to 15 weight
Content in the range of amount % exists.
14. according to the cosmetic composition described in claim 10 or 11, it is characterised in that
Relative to the gross weight of described compositions, one or more fatty alcohol described are with at 0.5 to 10 weight
Content in the range of amount % exists.
15. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
Stating cosmetic composition and comprise at least one fatty acid ester, described fatty acid ester is C2-30Unitary or
Polybasic carboxylic acid and C1-30Unitary or the fatty acid ester of polyhydric alcohol, the sum of the carbon atom in described ester
From 10 to 50 changes.
16. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
Stating cosmetic composition and comprise at least one fatty acid ester, described fatty acid ester is C2-30Unitary or
Polybasic carboxylic acid and C3-20Unitary or the fatty acid ester of polyhydric alcohol, the sum of the carbon atom in described ester
From 10 to 50 changes.
17. cosmetic compositions according to claim 15, it is characterised in that described extremely
Few a kind of fatty acid ester is selected from myristyl myristate, cetyl myristate, myristic acid
Stearyl ester, cetyl palmitat, cetin, Palmic acid stearyl ester, stearic acid meat
Fructus Amomi Rotundus ester, cetyl stearate, stearyl stearate and their mixture.
18. cosmetic compositions according to claim 15, it is characterised in that relative to
The gross weight of described compositions, at least one fatty acid ester described is with at 0.1 to 20 weight % model
Enclose interior content to exist.
19. cosmetic compositions according to claim 15, it is characterised in that relative to
The gross weight of described compositions, at least one fatty acid ester described is with at 0.5 to 15 weight % model
Enclose interior content to exist.
20. cosmetic compositions according to claim 15, it is characterised in that relative to
The gross weight of described compositions, at least one fatty acid ester described is with in 1 to 10 weight % scope
Interior content exists.
21. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
State cosmetic composition and also comprise at least one siloxanes.
22. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
State cosmetic composition and also comprise at least one non-volatile siloxane.
23. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
Stating cosmetic composition and also comprise additive, described additive is selected from: ion or non-ionic form
Close or non-association polymer, polyhydric alcohol, albumen, vitamin, reducing agent, plasticizer, soften
Agent, defoamer, wetting agent, pigment, clay, inorganic filler, UV screener, inorganic glue
Body, peptizer, solubilizing agent, spice, preservative, anion, cation, nonionic or two
Property surfactant, propellant, and inorganic or organic thickening agent.
24. cosmetic compositions according to claim 1 and 2, it is characterised in that institute
State cosmetic composition and also comprise pearling agent.
25. according to cosmetic composition in any one of the preceding claims wherein at keratin thing
Purposes in the cosmetic treatment of matter, wherein, described purposes is for non-treatment purpose.
26. purposes according to claim 25, it is characterised in that described keratin thing
Matter is hair.
27. methods being used for cosmetic treatment keratin substances, described method includes using according to power
Profit requires that the cosmetic composition according to any one of 1 to 24, wherein said method are for non-
Therapeutic purposes.
28. methods according to claim 27, it is characterised in that described keratin thing
Matter is keratin fiber.
29. methods according to claim 27, it is characterised in that described keratin thing
Matter is hair.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0959482A FR2954139B1 (en) | 2009-12-23 | 2009-12-23 | COSMETIC COMPOSITION COMPRISING AT LEAST ONE VOLATILE LINEAR ALKANE AND AT LEAST ONE NON-PROTEIN CATIONIC POLYMER |
| FR0959482 | 2009-12-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102106789A CN102106789A (en) | 2011-06-29 |
| CN102106789B true CN102106789B (en) | 2016-08-10 |
Family
ID=42537941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010606147.7A Expired - Fee Related CN102106789B (en) | 2009-12-23 | 2010-12-23 | Comprise the cosmetic composition of at least two volatile linear alkane and at least one non-protein cationic polymer |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9095528B2 (en) |
| EP (1) | EP2356975A1 (en) |
| JP (1) | JP5946987B2 (en) |
| CN (1) | CN102106789B (en) |
| BR (1) | BRPI1005713A2 (en) |
| FR (1) | FR2954139B1 (en) |
| MX (1) | MX2010014536A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2954108B1 (en) | 2009-12-23 | 2012-03-09 | Oreal | USE OF A COSMETIC COMPOSITION COMPRISING A VOLATILE LINEAR ALKANE AND A NONIONIC ASSOCIATIVE POLYMER FOR CONDITIONING HAIR |
| ES2703136T5 (en) * | 2011-12-20 | 2022-03-24 | Oreal | Cosmetic treatment procedure with a composition comprising an anionic surfactant, a solid fatty alcohol and a solid fatty ester |
| CN106456487B (en) | 2014-06-17 | 2020-01-31 | 宝洁公司 | Composition for reducing hair frizz |
| DE102014214463A1 (en) * | 2014-07-24 | 2016-01-28 | Beiersdorf Ag | Deodorant preparations comprising polyquaternium polymers |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US20180078489A1 (en) * | 2015-07-14 | 2018-03-22 | L'oreal | Solid anhydrous composition comprising a combination of waxes |
| US10561591B2 (en) | 2015-12-04 | 2020-02-18 | The Procter And Gamble Company | Hair care regimen using compositions comprising moisture control materials |
| CN108289814B (en) | 2015-12-04 | 2022-04-01 | 宝洁公司 | Composition for hair frizz reduction |
| ITUA20161870A1 (en) * | 2016-03-21 | 2017-09-21 | Cristiano Ravetta | SPRAY DISPENSER AND COMPOSITION DEVICE FOR TOPIC APPLICATION |
| WO2017173050A1 (en) | 2016-04-01 | 2017-10-05 | The Procter & Gamble Company | Composition for fast dry of hair |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
| DE102017212403A1 (en) * | 2017-07-19 | 2019-01-24 | Henkel Ag & Co. Kgaa | "Hair products" |
| US11039990B2 (en) | 2018-05-04 | 2021-06-22 | Johnson & Johnson Consumer Inc. | Cleansing compositions |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2011132235A (en) | 2011-07-07 |
| FR2954139A1 (en) | 2011-06-24 |
| JP5946987B2 (en) | 2016-07-06 |
| US9095528B2 (en) | 2015-08-04 |
| CN102106789A (en) | 2011-06-29 |
| US20120009138A1 (en) | 2012-01-12 |
| EP2356975A1 (en) | 2011-08-17 |
| FR2954139B1 (en) | 2012-05-11 |
| MX2010014536A (en) | 2011-06-22 |
| BRPI1005713A2 (en) | 2013-06-11 |
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