CN109288696A - Mixture is used in flank of tooth cleaning - Google Patents
Mixture is used in flank of tooth cleaning Download PDFInfo
- Publication number
- CN109288696A CN109288696A CN201810812006.7A CN201810812006A CN109288696A CN 109288696 A CN109288696 A CN 109288696A CN 201810812006 A CN201810812006 A CN 201810812006A CN 109288696 A CN109288696 A CN 109288696A
- Authority
- CN
- China
- Prior art keywords
- flank
- tooth
- mass
- tooth cleaning
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000004140 cleaning Methods 0.000 title abstract description 52
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- 239000003292 glue Substances 0.000 description 1
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- 208000014674 injury Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- RHFUXPCCELGMFC-UHFFFAOYSA-N n-(6-cyano-3-hydroxy-2,2-dimethyl-3,4-dihydrochromen-4-yl)-n-phenylmethoxyacetamide Chemical compound OC1C(C)(C)OC2=CC=C(C#N)C=C2C1N(C(=O)C)OCC1=CC=CC=C1 RHFUXPCCELGMFC-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940080236 sodium cetyl sulfate Drugs 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- 229940048106 sodium lauroyl isethionate Drugs 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940079832 sodium starch glycolate Drugs 0.000 description 1
- 239000008109 sodium starch glycolate Substances 0.000 description 1
- 229920003109 sodium starch glycolate Polymers 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- BRMSVEGRHOZCAM-UHFFFAOYSA-M sodium;2-dodecanoyloxyethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)OCCS([O-])(=O)=O BRMSVEGRHOZCAM-UHFFFAOYSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940013618 stevioside Drugs 0.000 description 1
- OHHNJQXIOPOJSC-UHFFFAOYSA-N stevioside Natural products CC1(CCCC2(C)C3(C)CCC4(CC3(CCC12C)CC4=C)OC5OC(CO)C(O)C(O)C5OC6OC(CO)C(O)C(O)C6O)C(=O)OC7OC(CO)C(O)C(O)C7O OHHNJQXIOPOJSC-UHFFFAOYSA-N 0.000 description 1
- 235000019202 steviosides Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940105956 tea-dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000005086 tooth mineralization Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
- A61K8/21—Fluorides; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Abstract
A kind of flank of tooth cleaning mixture, which is characterized in that comprising 45 mass % or more and 61 mass % median particle diameters below are 5 μm or more and 24 μm calcium carbonate and/or calcirm-fluoride and liquid-like constituents below, and wherein pH value is 9 or more and 10 or less.
Description
Technical field
The flank of tooth that the present invention relates to a kind of for cleaning the flank of tooth (dental surface) is cleaned with mixture (composition (group
At object)).
Background technique
When carrying out daily brush teeth using toothbrush or gear division hospital using dedicated flank of tooth cleaning device to patient's flank of tooth into
When row cleaning, generally all using flank of tooth cleaning mixture.As existing flank of tooth cleaning mixture, such as there are a kind of high
Deploy (mixing) calcium compound concentration it is expected to promote the mixture of flank of tooth calcification again (for example, referring to patent document 1)
Deng.
However, deenergizing in existing flank of tooth cleaning mixture with regard to the tooth dirt and/or removing for color spot (stain) of tooth
For power, there is also rooms for improvement, therefore a kind of flank of tooth is needed to clean the higher flank of tooth cleaning mixture of ability.
In addition, there is also the flank of tooth to clean the more high then easier injury tooth of ability in existing flank of tooth cleaning mixture
The problem of face, therefore the lower flank of tooth cleaning mixture of invasion for needing a kind of pair of flank of tooth to be invaded.
Existing technical literature
Patent document
Patent document 1:(Japan) special open 2013-163656 bulletin.
Summary of the invention
Subject to be solved by the invention
Therefore, problem of the present invention is that, the invasion that a kind of flank of tooth cleaning ability is higher and is invaded to the flank of tooth are provided
Property the cleaning of the lower flank of tooth use mixture.
Means for solving the problems
According to the present invention, a kind of flank of tooth cleaning mixture is provided, which is characterized in that include 45 mass % or more and 61 matter
Measure % median particle diameter below (median diameter) be 5 μm or more and 24 μm calcium carbonate and/or calcirm-fluoride below and
Liquid-like constituents, wherein pH value is 9 or more and 10 or less.
Invention effect
A kind of flank of tooth cleaning of the invention invasion that mixture is that flank of tooth cleaning ability is higher and is invaded to the flank of tooth
Property lower, excellent flank of tooth cleaning use mixture.
Specific embodiment
In flank of tooth cleaning mixture of the invention, as flank of tooth cleaning particle, can mix (allotment) calcium carbonate and/
Or calcirm-fluoride.The reason is that the flank of tooth of calcium carbonate and calcirm-fluoride cleaning ability is higher, and to the invasion that the flank of tooth is invaded
Property is relatively low.
For the combined amount (blending amount) of calcium carbonate and/or calcirm-fluoride in flank of tooth cleaning mixture, need to be 45
Quality % or more and 61 mass % or less.Its reason is that if it is less than 45 mass %, then the flank of tooth cleans ability and is lower, if super
61 mass % are crossed, then the character of cream (paste) is hardened, and operability is deteriorated.More preferably 49 mass % or more and 55 mass % or less.
In addition, the median particle diameter of particle needs to be 5 μm or more and 24 μm or less for calcium carbonate or calcirm-fluoride.Its
The reason is that, the flank of tooth cleans ability and is lower if median particle diameter is less than 5 μm, if it exceeds 24 μm, then the flank of tooth is invaded
Invasion get higher.More preferably, median particle diameter is 8 μm or more and 20 μm or less.
In flank of tooth cleaning mixture of the invention, (addition) can be mixed for improving the carbohydrate of taste.As carbohydrate,
Such as can enumerate: stevioside, xylitol, D-sorbite, oligosaccharides, acesulfame potassium, trehalose, Aspartame, mannitol,
Maltitol, lactitol (stevia, xylitol, sorbitol, oligosaccharides, acesulfame
Potassium, trehalose, aspartame, mannitol, maltitol, lactitol) etc..Can be used alone these sugar
Any one in class can also be used in mixed way any two or more carbohydrate therein.
For the combined amount (blending amount) of the carbohydrate in flank of tooth cleaning mixture, preferably 1 mass % or more and 5 matter
Measure % or less.Its reason is, by for 1 mass % or more, can improve the taste of cream and be easy to use, by for 5 mass % with
Under, frank sense can be kept.
In flank of tooth cleaning mixture of the invention, (addition) can be mixed for adjusting the binder of viscosity.As viscous
Tie agent, such as can enumerate: mosanom, propylene glycol alginate, carboxymethyl cellulose, sodium carboxymethylcellulose, carboxymethyl are fine
Tie up plain calcium, sodium starch glycollate, starch phosphate sodium, Sodium Polyacrylate, carboxypolymethylene, methylcellulose, avicel cellulose,
Hydroxyethyl cellulose, hydroxypropyl cellulose, starch, polyvinylpyrrolidone, guar gum, OK a karaoke club tie up bean gum, tara gum, Luo Wang
Sub- glue, Arabic gum, bassora gum, Karaya Gum, alginic acid, carrageenan, xanthan gum, gellan gum, curdlan, lactose, shell
Polysaccharide, chitosan (sodium alginate, alginic acid propylene glycol ester, carboxymethyl
cellulose、sodium carboxymethyl cellulose、calcium carboxymethyl cellulose、
sodium starch glycolate、sodium starch phosphate ester、sodium polyacrylate、
carboxypolymethylene、methyl cellulose、crystalline cellulose、hydroxyethyl
cellulose、hydroxypropyl cellulose、starch、polyvinyl pyrrolidone、guar gum、
karavi bean gum、tara gum、tamarind seed gum、gum arabic、tragacanth gum、karaya
gum、alginic acid、carrageenan、xanthan gum、gellan gum、curdlan、lactose、chitin、
Chitosan, chitosamine) etc. water soluble polymer.Any one that can be used alone in these binders, can also be right
Any two or more binder therein is used in mixed way.
For the combined amount (blending amount) of the binder in flank of tooth cleaning mixture, preferably 0.1 mass % or more
And 1 below mass %.Its reason is, by for 0.1 mass % or more, cream can have the viscosity for being easy to invest on toothbrush, by
For 1 mass % hereinafter, cream can have the hardness appropriate for being easy to come out from pipe (tube).
In flank of tooth cleaning mixture of the invention, the fluorine compounds of (addition) other than calcirm-fluoride can be mixed.It is logical
Addition fluorine compounds are crossed, fluorine ion can be supplied into oral cavity, and there is better prevention of dental caries effect.Except calcirm-fluoride
Fluorine compounds, such as can enumerate: sodium fluoride, potassium fluoride, ammonium fluoride, stannous fluoride, sodium monofluorophosphate, single fluorophosphoric acid potassium
(sodium fluoride、potassium fluoride、ammonium fluoride、stannous fluoride、
Sodium monofluorophosphate, potassium monofluorophosphate) etc..Can be used alone these fluorine
Any one in compound can also be used in mixed way any two or more fluorine compounds therein.
For the combined amount (blending amount) of the fluorine compounds except the calcirm-fluoride in flank of tooth cleaning mixture, preferably
0.025 mass % or more and 0.9 mass % or less.Its reason is, by for 0.025 mass % or more, can have better dental caries
Tooth preventive effect, by for 0.9 mass % hereinafter, when routine use, will not have an impact raw body (for example, human body).
In flank of tooth cleaning mixture of the invention, (addition) preservative can be mixed.As preservative, such as can enumerate
Out: ethyl-para-hydroxybenzoate, methyl p-hydroxybenzoate (ethylparaben, methylparaben) etc..It can be used alone
Any one in these preservatives can also be used in mixed way any two or more preservative therein.
For the combined amount (blending amount) of the preservative in flank of tooth cleaning mixture, preferably 0.1 mass % or more
And 0.3 below mass %.The reason is that can have better anti-corrosion effect by for 0.1 mass % or more, by being 0.3
Quality % hereinafter, when routine use raw body (for example, human body) will not be had an impact.
In flank of tooth cleaning mixture of the invention, (addition) liquid-like constituents can be mixed.It, can by adding liquid-like constituents
It has an effect as solvent, to carry out livering.In addition, being alternatively arranged as wetting agent and playing a role.As liquid-like constituents, such as
It can enumerate: polyethylene glycol, ethylene glycol, propylene glycol, glycerol, chondroitin sulfate (polyethylene glycol, ethylene
Glycol, propylene glycol, glycerin, chondroitin sulfate) or its salt etc., water etc..It can be used alone
Any one in these liquid-like constituents can also be used in mixed way any two or more liquid-like constituents therein.
For the combined amount (blending amount) of the liquid-like constituents in flank of tooth cleaning mixture, preferably 20 mass % or more
And 54 below mass %.Its reason is, by for 20 mass % or more, can be changed to soft paste, by for 54 mass % with
Under, drippage is difficult to happen when investing toothbrush etc. above.More preferably 30 mass % or more and 45 mass % or less.
In flank of tooth cleaning mixture of the invention, (addition) surface (interface) activating agent can be mixed.Pass through mixture table
Face activating agent, flank of tooth cleaning mixture can be improved cleans (cleaning) effect and/or foaming effect.As surfactant,
Such as it can enumerate: lauroyl sodium sulfate, sodium lauroyl sarcosine, sodium lauroylmethyl taurate, lauryl betaine, 16
Sodium alkyl sulfate, sodium lauryl tri(oxyethyl) sulfate, lauryl sulfosuccinic acid ammonium, Texapon Special, Zetesol AP, the moon
Osmanthus acyl sodium isethionate, neopelex, dodecyl benzene sulfonic acid triethanolamine, cocoyl isethionate
(sodium lauryl sulfate、sodium lauroyl sarcosinate、sodium lauroyl methyl
taurate、lauryl betaine、sodium cetyl sulfate、sodium lauryl ether sulfate、
ammonium lauryl sulfosuccinate、ammonium lauryl sulfate、ammonium lauryl ether
sulfate、sodium lauroyl isethionate、sodium dodecyl benzene sulfonate、
Triethanolamine dodecylbenzenesulfonate, sodium cocoyl isethionate) etc..
For flank of tooth cleaning mixture of the invention, viscosity is suitable when being 80~400Pas at 25 DEG C (temperature)
It in being used in oral cavity, therefore is preferred.More preferably, the viscosity at 25 DEG C is 150~250Pas.
In flank of tooth cleaning mixture of the invention, (addition) can be mixed for adjusting the tackifier of viscosity.As increasing
Stick, such as can enumerate: the silica chemical combination of silicic acid anhydride (silicic anhydride), silica gel (silica gel) etc.
Object (silica compound).
For flank of tooth cleaning mixture of the invention, pH value needs to be 9 or more and 10 or less.The reason is that
If pH, less than 9, the flank of tooth cleans ability and is lower, the stimulation meeting if pH value is more than 10, when using in oral cavity to oral cavity
Become larger.
In flank of tooth cleaning mixture of the invention, can also properly mix (addition) colorant, preservative agent, mould inhibitor,
The additive of fragrance etc..
[embodiment]
The present invention is described in detail with reference to embodiments, but the present invention is not limited to embodiments below.
1 > of < embodiment
As shown in table 1, to the calcium carbonate of 53 mass % (median particle diameter: 10 μm), the D-sorbite of 3 mass %, 0.6 matter
Measure sodium monofluorophosphate, the 0.2 mass % of the sodium carboxymethylcellulose of %, the hydroxyethyl cellulose of 0.8 mass %, 0.5 mass %
Methyl p-hydroxybenzoate, the silicic acid anhydride of 0.4 mass %, the purified water of 24.5 mass %, 16 mass % glycerol and 1 matter
The fragrance of amount % is deployed (mixing), and is kneaded using mixing machine, has thus been made the flank of tooth paste and has been cleaned with mixing
Object.
< embodiment 2~5 and the Comparative Examples 1 to 5 >
Using constituent shown in table 1, and by method similarly to Example 1, the flank of tooth paste is made and has cleaned
Use mixture.
[table 1]
[pH value measurement]
For various flank of tooth cleaning mixtures, using pH value analyzer (" hole field makes institute " corporation, D-52) measurement
PH value.As a result shown in table 1.
[median particle diameter of calcium carbonate or calcium fluoride particles]
Using laser diffraction/scattering formula particle size distribution analyzer, the intermediate value grain of calcium carbonate or calcium fluoride particles is determined
Diameter (volume reference).
[invasion that the flank of tooth is invaded]
In order to which the invasion invaded to the flank of tooth to various flank of tooth cleaning mixtures is evaluated, implement as follows
Test.
Using waterproof paper (#4000) and 3 μ of diamond cream, 1 μ and soft object (buff) to ox tooth enamel (enamel) matter surface
Mirror ultrafinish is carried out, using as test film.
Then, for the lapped face of test film, using the various flank of tooth cleaning mixtures of 0.1g, and it is clear using the flank of tooth
It sweeps and is carried out under conditions of 1940rpm and 1 minute with rubber cup (rubber cup) (" GC society " corporation, PTC Cup II)
Flank of tooth cleaning.
For the position for having carried out flank of tooth cleaning, using laser microscope (laser microscope) (" Keyence society "
Corporation, VK-X200) arithmetic surface roughness (Ra) is determined.
The aggressive evaluation index invaded to the flank of tooth is as described below.As a result shown in table 1.
Fine: Ra is less than 0.10 μm
Preferable: Ra is 0.10 μm more than and less than 0.15 μm
Bad: Ra is 0.15 μm or more
[flank of tooth cleaning ability]
It is evaluated in order to which the flank of tooth to various flank of tooth cleaning mixtures cleans ability, has carried out following test.
After being ground using waterproof paper (#4000) to ox tooth enamel surface, it is immersed in ferric tannate (iron
Tannate it is) 10 minutes in the coloring liquid of principal component, color spot (stain) deposition (deposition) has been carried out, using as test
Piece.Later, the color of the test film is determined using spectral photometric colour measuring meter (" Konicaminolta society " corporation, CM-700d).
Then, it for test film, is brushed using the various flank of tooth cleaning mixtures of 0.1g, and using flank of tooth cleaning with PTC
(brush), under conditions of 1940rpm and 30 second, flank of tooth cleaning has been carried out.
For the position for having carried out flank of tooth cleaning, color is determined using spectral photometric colour measuring meter, and calculate the flank of tooth
Clean the color difference Δ E*ab of the L*a*b* color space of front and back.
The evaluation index that the flank of tooth cleans ability is as described below.As a result shown in table 1.
Fine: Δ E*ab is 10 or more
Preferable: Δ E*ab is 5 more than and less than 10
Bad: Δ E*ab is less than 5
Confirmed by table 1, for the flank of tooth of the invention is cleaned with mixture, invasion that the flank of tooth is invaded compared with
It is low, and flank of tooth cleaning ability is also higher.
Based on above-mentioned, the present invention provides a kind of flank of tooth cleaning mixture, which is characterized in that comprising 45 mass % or more and
61 mass % median particle diameters below be 5 μm or more and 24 μm calcium carbonate and/or calcirm-fluoride and liquid-like constituents below, wherein
PH value is 9 or more and 10 or less.
Embodiments of the present invention are illustrated above, but above content is not to carry out to the contents of the present invention
The content of restriction.
Claims (1)
1. a kind of flank of tooth clean with mixture, characterized by comprising:
45 mass % or more and 61 mass % median particle diameters below are 5 μm or more and 24 μm of calcium carbonate below and/or fluorination
Calcium;And
Liquid-like constituents,
Wherein, pH value is 9 or more and 10 or less.
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JP2017143546A JP7126811B2 (en) | 2017-07-25 | 2017-07-25 | Tooth cleaning composition |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54157843A (en) * | 1978-05-25 | 1979-12-13 | Colgate Palmolive Co | Dental cream composition |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS582921B2 (en) * | 1973-03-20 | 1983-01-19 | ライオン株式会社 | toothpaste |
JPS60146814A (en) * | 1983-12-29 | 1985-08-02 | Lion Corp | Tooth paste composition |
WO2006003989A1 (en) * | 2004-07-06 | 2006-01-12 | Lion Corporation | Dentifrice composition |
KR101490782B1 (en) * | 2008-10-14 | 2015-02-09 | 주식회사 엘지생활건강 | Toothpaste composition |
JP2013163656A (en) | 2012-02-10 | 2013-08-22 | Gc Corp | Dentifrice |
JP2016503036A (en) * | 2012-12-24 | 2016-02-01 | コルゲート・パーモリブ・カンパニーColgate−Palmolive Company | Oral care composition |
WO2016004597A1 (en) * | 2014-07-10 | 2016-01-14 | The Procter & Gamble Company | Anti-calculus oral compositions |
JP6451562B2 (en) * | 2015-09-07 | 2019-01-16 | ライオン株式会社 | Oral composition |
-
2017
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54157843A (en) * | 1978-05-25 | 1979-12-13 | Colgate Palmolive Co | Dental cream composition |
Non-Patent Citations (1)
Title |
---|
裘炳毅,高志红: "《现代化妆品科学与技术》", 31 March 2016, 中国轻工业出版社 * |
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JP2019026555A (en) | 2019-02-21 |
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