CN109280234A - A kind of high-performance anti-corrosion water-proof environmental protection new material - Google Patents
A kind of high-performance anti-corrosion water-proof environmental protection new material Download PDFInfo
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- CN109280234A CN109280234A CN201710637899.1A CN201710637899A CN109280234A CN 109280234 A CN109280234 A CN 109280234A CN 201710637899 A CN201710637899 A CN 201710637899A CN 109280234 A CN109280234 A CN 109280234A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of high-performance anti-corrosion water-proof environmental protection new materials, including following raw material: 20-45 parts of neoprene, 20-30 parts of Corvic, 10-15 parts of acrylonitrile-butadiene-styrene resin, 6-10 parts of zinc oxide, 3-8 parts of benzoic acid, 10-15 parts of white carbon black, 4-9 parts of dibutyl hydroxy toluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, 2-8 parts of light stabilizer, 8-15 parts of watery water-proofing agent.A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, selecting using extensive rubber and resin is primary raw material, ingredient is simple, raw material is easy to get, the new material prepared has good anticorrosion, waterproof performance, have simultaneously good heat-resisting, it is fast light, anti-aging property, it can be widely applied in various adverse circumstances, the invention also provides a kind of preparation methods of high-performance anti-corrosion water-proof environmental protection new material, it is prepared by the way that auxiliary agent is added with resin high-temperature blending after the vulcanization of rubber, technological operation is simple, safety, environmental protection, it is pollution-free, it is at low cost, it can must be widely applied.
Description
Technical field
The present invention relates to anti-corrosion waterproof material technical field more particularly to a kind of high-performance anti-corrosion water-proof environmental protection new materials.
Background technique
Waterproof material is the general designation of impermeable leakage and the material corroded, and the building enclosure of building will prevent rainwater, snow
The infiltration of water and underground water；Prevent the erosion of the moisture, steam and other pernicious gases and liquid in air；Separation structure is wanted
Prevent the infiltration of plumbing from turning over.Waterproof material is various in style on the market, and one type is asphalt water-proof coiled material, is mainly used for building
Wall, roofing and tunnel, highway, refuse landfill etc. play and resist extraneous rainwater, one kind of underground water leakage can roll up
Song is connected at the flexible building material product of web-like as ne-leakage between engineering foundation and building, is the of entire engineering waterproofing
One of barrier plays a crucial role entire engineering, and it is light poisonous substance, high temperature item that anthracene, phenanthrene, pyridine etc. are contained in pitch
It is used under part, photochemical reaction can be caused under action of ultraviolet radiation, it is understood that there may be security risk, a kind of high property proposed by the present invention
Energy anti-corrosion water-proof environmental protection new material can effectively solve the above problem.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of high-performance anti-corrosion waterproof proposed
Environmental friendly material.
A kind of high-performance anti-corrosion water-proof environmental protection new material, including following raw material: 20-45 parts of neoprene, polychlorostyrene
20-30 parts of vinyl, 10-15 parts of acrylonitrile-butadiene-styrene resin, 6-10 parts of zinc oxide, 3-8 parts of benzoic acid, hard charcoal
10-15 parts black, 4-9 parts of dibutyl hydroxy toluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, 2-8 parts of light stabilizer, Waterproof
8-15 parts of agent.
Preferably, a kind of high-performance anti-corrosion water-proof environmental protection new material, including following raw material: neoprene
24-42 parts, 24-28 parts of Corvic, 12-14 parts of acrylonitrile-butadiene-styrene resin, 7-9 parts of zinc oxide, benzene first
4-6 parts sour, 11-13 parts of white carbon black, 5-8 parts of dibutyl hydroxy toluene, 5-7 parts of zinc soap, 4-6 parts of dihydropyridine, light stabilizer 3-6
Part, 9-13 parts of watery water-proofing agent.
Preferably, a kind of high-performance anti-corrosion water-proof environmental protection new material, including following raw material: neoprene 32
Part, 28 parts of Corvic, 14 parts of acrylonitrile-butadiene-styrene resin, 8 parts of zinc oxide, 5 parts of benzoic acid, white carbon black 12
Part, 6 parts of dibutyl hydroxy toluene, 7 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, 12 parts of watery water-proofing agent.
Preferably, the neoprene, Corvic, acrylonitrile-butadiene-styrene resin weight ratio be 2-
3∶2∶1。
Preferably, the light stabilizer is carbon black.
Preferably, the watery water-proofing agent is PM-4700.
A kind of preparation method of high-performance anti-corrosion water-proof environmental protection new material, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 4-8h by 150-170 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, high temperature 230-260
DEG C, 1-2h is heated, is melted completely to it；
S3, by near 170-190 DEG C of temperature in step S2, the Corvic of the specific gravity, heating stirring is added
1-2h obtains hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 25-45min at 110-130 DEG C,
Obtain mixture B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material of 3-6mm
C；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention is selected and is used based on extensive rubber and resin
Raw material is wanted, ingredient is simple, raw material is easy to get, and the new material prepared has good anticorrosion, waterproof performance, while having good
Heat-resisting, fast light, anti-aging property, the anti-corrosion water-proof environmental protection new material prepared can be widely applied in various adverse circumstances,
The invention also provides a kind of preparation method of high-performance anti-corrosion water-proof environmental protection new material, by after the vulcanization of rubber with resin high temperature
Addition auxiliary agent is blended to be prepared, technological operation is simple, safe and environment-friendly, pollution-free, and it is at low cost, it can must be widely applied.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, including following raw material: neoprene
28 parts, 20 parts of Corvic, 10 parts of acrylonitrile-butadiene-styrene resin, 7 parts of zinc oxide, 5 parts of benzoic acid, white carbon black
10 parts, 5 parts of dibutyl hydroxy toluene, 4 parts of zinc soap, 4 parts of dihydropyridine, 3 parts of light stabilizer, 8 parts of watery water-proofing agent.
Preparation method, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 5h by 165 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 245 DEG C of high temperature,
1.5h is heated, is melted completely to it；
S3, by near 180 DEG C of temperature in step S2, be added the Corvic of the specific gravity, heating stirring 1.5h,
Obtain hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 35min, obtain mixture at 120 DEG C
B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material C of 5mm；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
Embodiment two
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, including following raw material: neoprene
30 parts, 24 parts of Corvic, 12 parts of acrylonitrile-butadiene-styrene resin, 6 parts of zinc oxide, 4 parts of benzoic acid, white carbon black
11 parts, 6 parts of dibutyl hydroxy toluene, 5 parts of zinc soap, 3 parts of dihydropyridine, 2 parts of light stabilizer, 10 parts of watery water-proofing agent.
Preparation method, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 7h by 155 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 250 DEG C of high temperature,
1.2h is heated, is melted completely to it；
S3, by near 190 DEG C of temperature in step S2, the Corvic of the specific gravity is added, heating stirring 1h is obtained
Hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 40min, obtain mixture at 115 DEG C
B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material C of 4mm；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
Embodiment three
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, including following raw material: neoprene
42 parts, 30 parts of Corvic, 15 parts of acrylonitrile-butadiene-styrene resin, 10 parts of zinc oxide, 8 parts of benzoic acid, hard charcoal
Black 15 parts, 9 parts of dibutyl hydroxy toluene, 8 parts of zinc soap, 8 parts of dihydropyridine, 7 parts of light stabilizer, 15 parts of watery water-proofing agent.
Preparation method, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 4h by 170 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 230 DEG C of high temperature,
2h is heated, is melted completely to it；
S3, by near 185 DEG C of temperature in step S2, be added the Corvic of the specific gravity, heating stirring 1.2h,
Obtain hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 30min, obtain mixture at 125 DEG C
B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material C of 3mm；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
Example IV
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, including following raw material: neoprene
35 parts, 26 parts of Corvic, 13 parts of acrylonitrile-butadiene-styrene resin, 8 parts of zinc oxide, 6 parts of benzoic acid, white carbon black
12 parts, 7 parts of dibutyl hydroxy toluene, 6 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, 11 parts of watery water-proofing agent.
Preparation method, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 8h by 150 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 260 DEG C of high temperature,
1h is heated, is melted completely to it；
S3, by near 170 DEG C of temperature in step S2, the Corvic of the specific gravity is added, heating stirring 2h is obtained
Hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 25min, obtain mixture at 130 DEG C
B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material C of 6mm:
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
Embodiment five
A kind of high-performance anti-corrosion water-proof environmental protection new material proposed by the present invention, including following raw material: neoprene
40 parts, 28 parts of Corvic, 14 parts of acrylonitrile-butadiene-styrene resin, 9 parts of zinc oxide, 7 parts of benzoic acid, white carbon black
13 parts, 8 parts of dibutyl hydroxy toluene, 7 parts of zinc soap, 7 parts of dihydropyridine, 6 parts of light stabilizer, 13 parts of watery water-proofing agent.
Preparation method, comprising the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzene first of the specific gravity is added
Acid, vulcanizes 6h by 160 DEG C of high temperature, spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 240 DEG C of high temperature,
1.8h is heated, is melted completely to it；
S3, by near 175 DEG C of temperature in step S2, be added the Corvic of the specific gravity, heating stirring 1.8h,
Obtain hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the ratio is added
White carbon black, the dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer of weight mix 45min, obtain mixture at 110 DEG C
B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material of 4.5mm
C；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
It is after the anti-corrosion water-proof environmental protection new material prepared in above-mentioned five groups of embodiments is carried out waterproof performance test below
As a result, water is sprinkled upon on obtained waterproof material, measured after 3h with waterproof tester, be measurement result below:
| Embodiment | Embodiment one | Embodiment two | Embodiment three | Example IV | Embodiment five |
| Seepage rate | 0.8‰ | 0.55‰ | 0.73‰ | 1.1‰ | 0.68‰ |
From the above results, the new material waterproof performance that the present invention prepares is good, and for preparing in embodiment two is new
Material waterproofing effect is best.Present component is simple, raw material is easy to get, the new material prepared not only have good anticorrosion,
Waterproof performance, while there is good heat-resisting, fast light, anti-aging property, it can be widely applied in various adverse circumstances, the present invention
The preparation method of proposition, technological operation is simple, safe and environment-friendly, pollution-free, at low cost, can must be widely applied.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of high-performance anti-corrosion water-proof environmental protection new material, which is characterized in that including following raw material: neoprene 20-
45 parts, 20-30 parts of Corvic, 10-15 parts of acrylonitrile-butadiene-styrene resin, 6-10 parts of zinc oxide, benzoic acid
3-8 parts, 10-15 parts of white carbon black, 4-9 parts of dibutyl hydroxy toluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, light stabilizer 2-8
Part, 8-15 parts of watery water-proofing agent.
2. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, which is characterized in that including following weight
Part raw material: 24-42 parts of neoprene, 24-28 parts of Corvic, 12-14 parts of acrylonitrile-butadiene-styrene resin, oxygen
Change zinc 7-9 parts, 4-6 parts of benzoic acid, 11-13 parts of white carbon black, 5-8 parts of dibutyl hydroxy toluene, 5-7 parts of zinc soap, dihydropyridine 4-6
Part, 3-6 parts of light stabilizer, 9-13 parts of watery water-proofing agent.
3. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, which is characterized in that including following weight
Part raw material: 32 parts of neoprene, 28 parts of Corvic, 14 parts of acrylonitrile-butadiene-styrene resin, 8 parts of zinc oxide,
It is 5 parts of benzoic acid, 12 parts of white carbon black, 6 parts of dibutyl hydroxy toluene, 7 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, aqueous anti-
12 parts of aqua.
4. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, which is characterized in that the neoprene rubber
Glue, Corvic, acrylonitrile-butadiene-styrene resin weight ratio be 2-3: 2: 1.
5. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, which is characterized in that the light stabilizer
For carbon black.
6. a kind of high-performance anti-corrosion water-proof environmental protection new material according to claim 1, which is characterized in that the Waterproof
Agent is PM-4700.
7. a kind of preparation method of high-performance anti-corrosion water-proof environmental protection new material, which comprises the following steps:
S1, the neoprene of the specific gravity is added in rubber vulcanizing tank, zinc oxide, the benzoic acid of the specific gravity is added, it is high
Warm 150-170 DEG C, vulcanize 4-8h, it is spare；
S2, the acrylonitrile-butadiene-styrene resin of the specific gravity is added in crucible melting furnace, 230-260 DEG C of high temperature,
1-2h is heated, is melted completely to it；
S3, by near 170-190 DEG C of temperature in step S2, be added the Corvic of the specific gravity, heating stirring 1-2h,
Obtain hybrid resin A；
S4, the rubber after vulcanizing in step S1, hybrid resin A are added in super mixer, while the specific gravity is added
White carbon black, dibutyl hydroxy toluene, zinc soap, dihydropyridine, light stabilizer mix 25-45min, obtain mixed at 110-130 DEG C
Close object B；
S5, mixture B is added in calender, compacting extension is uniform at surface, with a thickness of the sheet new material C of 3-6mm；
S6, watery water-proofing agent is uniformly sprayed on the two sides of new material C, naturally dry to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710637899.1A CN109280234A (en) | 2017-07-20 | 2017-07-20 | A kind of high-performance anti-corrosion water-proof environmental protection new material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710637899.1A CN109280234A (en) | 2017-07-20 | 2017-07-20 | A kind of high-performance anti-corrosion water-proof environmental protection new material |
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| Publication Number | Publication Date |
|---|---|
| CN109280234A true CN109280234A (en) | 2019-01-29 |
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ID=65185638
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710637899.1A Pending CN109280234A (en) | 2017-07-20 | 2017-07-20 | A kind of high-performance anti-corrosion water-proof environmental protection new material |
Country Status (1)
| Country | Link |
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| CN (1) | CN109280234A (en) |
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2017
- 2017-07-20 CN CN201710637899.1A patent/CN109280234A/en active Pending
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Application publication date: 20190129 |