WO2019214126A1 - Novel high-performance anti-corrosion and waterproof environment-friendly material - Google Patents

Novel high-performance anti-corrosion and waterproof environment-friendly material Download PDF

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WO2019214126A1
WO2019214126A1 PCT/CN2018/105878 CN2018105878W WO2019214126A1 WO 2019214126 A1 WO2019214126 A1 WO 2019214126A1 CN 2018105878 W CN2018105878 W CN 2018105878W WO 2019214126 A1 WO2019214126 A1 WO 2019214126A1
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parts
new material
corrosion
waterproof
performance anti
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PCT/CN2018/105878
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French (fr)
Chinese (zh)
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王淑英
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淄博鸣桐环保技术研发有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00—Compositions of homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers

Definitions

  • the invention relates to the technical field of anti-corrosion and waterproof materials, in particular to a high-performance anti-corrosion waterproof and environmental protection new material.
  • Waterproof material is a general term for materials that are resistant to seepage, leakage and erosion.
  • the building envelope shall be protected from the infiltration of rain, snow and groundwater; and the erosion of moisture, steam and other harmful gases and liquids in the air shall be prevented;
  • the partition structure should prevent the seepage of the water supply and drainage.
  • waterproof materials there are many kinds of waterproof materials on the market, one of which is asphalt waterproofing membrane, which is mainly used for building walls, roofs, tunnels, highways, landfills, etc., to resist external rainwater and groundwater leakage.
  • Flexible building materials that can be rolled into a roll shape, as a foundation between the engineering foundation and the building, are the first barrier to waterproofing the entire project, and play a vital role in the whole project.
  • the asphalt contains bismuth and phenanthrene.
  • pyridine and the like are all light poisons, used under high temperature conditions, can cause photochemical reactions under the action of ultraviolet rays, and may have safety hazards.
  • the high-performance anti-corrosion waterproof and environmental protection new material proposed by the invention can effectively solve the above problems.
  • the object of the present invention is to solve the shortcomings existing in the prior art, and to provide a high-performance anti-corrosion waterproof and environmental protection new material.
  • a high-performance anti-corrosion waterproof and environmental protection new material including the following parts by weight: 20-45 parts of chloroprene rubber, 20-30 parts of polyvinyl chloride resin, 10-15 parts of acrylonitrile-butadiene-styrene resin, zinc oxide 6-10 parts, 3-8 parts of benzoic acid, 10-15 parts of white carbon, 4-9 parts of dibutylhydroxytoluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, light stabilizer 2- 8 parts, 8-15 parts of water-based waterproofing agent.
  • the high-performance anti-corrosion waterproof and environmental protection new material comprises the following raw materials by weight: 24-42 parts of chloroprene rubber, 24-28 parts of polyvinyl chloride resin, acrylonitrile-butadiene-styrene resin 12- 14 parts, 7-9 parts of zinc oxide, 4-6 parts of benzoic acid, 11-13 parts of white carbon, 5-8 parts of dibutylhydroxytoluene, 5-7 parts of zinc soap, 4-6 parts of dihydropyridine, 3-6 parts of light stabilizer and 9-13 parts of water-based water repellent.
  • the high-performance anti-corrosion waterproof and environmental protection new material comprises the following raw materials by weight: 32 parts of chloroprene rubber, 28 parts of polyvinyl chloride resin, 14 parts of acrylonitrile-butadiene-styrene resin, zinc oxide 8 Parts, 5 parts of benzoic acid, 12 parts of white carbon, 6 parts of dibutylhydroxytoluene, 7 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, and 12 parts of aqueous water repellent.
  • the weight ratio of the neoprene rubber, the polyvinyl chloride resin, and the acrylonitrile-butadiene-styrene resin is 2-3:2:1.
  • the light stabilizer is carbon black.
  • the aqueous waterproofing agent is PM-4700.
  • a preparation method of a high-performance anti-corrosion waterproof and environmental protection new material comprising the following steps:
  • step S3 the temperature in step S2 will be 170-190 ° C, adding the specific gravity of the polyvinyl chloride resin, heating and stirring for 1-2h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 110 Mixing at -130 ° C for 25-45 min to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 3-6 mm;
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, which adopts widely used rubber and resin as main raw materials, has simple composition and easy availability of raw materials, and the prepared new material has good anti-corrosion and waterproof performance, and has good performance at the same time.
  • Heat-resistant, light-resistant, anti-aging properties, prepared anti-corrosion, waterproof and environmentally friendly new materials can be widely used in various harsh environments.
  • the present invention also proposes a high-performance anti-corrosion waterproof and environmentally-friendly new material preparation method, which is cured by rubber and The resin is prepared by high-temperature blending with additives, and the process is simple, safe, environmentally friendly, non-polluting, low in cost, and widely applicable.
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 28 parts of chloroprene rubber, 20 parts of polyvinyl chloride resin, 10 parts of acrylonitrile-butadiene-styrene resin, and 7 parts of zinc oxide. 5 parts of benzoic acid, 10 parts of white carbon black, 5 parts of dibutylhydroxytoluene, 4 parts of zinc soap, 4 parts of dihydropyridine, 3 parts of light stabilizer, and 8 parts of aqueous water repellent.
  • the preparation method comprises the following steps:
  • step S3 the temperature in step S2 will be 180 ° C, adding the specific gravity of the polyvinyl chloride resin, heating and stirring for 1.5h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer, at 120 Mixing for 35 min at ° C to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 5 mm;
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials: 30 parts of chloroprene rubber, 24 parts of polyvinyl chloride resin, 12 parts of acrylonitrile-butadiene-styrene resin, and 6 parts of zinc oxide. 4 parts of benzoic acid, 11 parts of white carbon black, 6 parts of dibutylhydroxytoluene, 5 parts of zinc soap, 3 parts of dihydropyridine, 2 parts of light stabilizer, and 10 parts of aqueous water repellent.
  • the preparation method comprises the following steps:
  • step S3 the temperature in step S2 will be 190 ° C, the specific gravity of the polyvinyl chloride resin, heating and stirring for 1h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 115 Mixing for 40 min at ° C to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 4 mm;
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 42 parts of chloroprene rubber, 30 parts of polyvinyl chloride resin, 15 parts of acrylonitrile-butadiene-styrene resin, and 10 parts of zinc oxide. 8 parts of benzoic acid, 15 parts of white carbon black, 9 parts of dibutylhydroxytoluene, 8 parts of zinc soap, 8 parts of dihydropyridine, 7 parts of light stabilizer, and 15 parts of aqueous water repellent.
  • the preparation method comprises the following steps:
  • step S3 the temperature in step S2 will be 185 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 1.2h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 125 Mixing for 30 min at ° C to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 3 mm;
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 35 parts of chloroprene rubber, 26 parts of polyvinyl chloride resin, 13 parts of acrylonitrile-butadiene-styrene resin, and 8 parts of zinc oxide. 6 parts of benzoic acid, 12 parts of white carbon black, 7 parts of dibutylhydroxytoluene, 6 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, and 11 parts of aqueous water repellent.
  • the preparation method comprises the following steps:
  • step S3 the temperature in step S2 will be 170 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 2h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 130 Mixing for 25 min at ° C to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 6 mm;
  • the invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 40 parts of chloroprene rubber, 28 parts of polyvinyl chloride resin, 14 parts of acrylonitrile-butadiene-styrene resin, and 9 parts of zinc oxide. 7 parts of benzoic acid, 13 parts of white carbon black, 8 parts of dibutylhydroxytoluene, 7 parts of zinc soap, 7 parts of dihydropyridine, 6 parts of light stabilizer, and 13 parts of aqueous water repellent.
  • the preparation method comprises the following steps:
  • step S3 the temperature in step S2 will be 175 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 1.8h, to obtain a mixed resin A;
  • step S4 adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 110 Mixing for 45 min at ° C to obtain a mixture B;
  • the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 4.5 mm;
  • the water is sprinkled on the prepared waterproof material, and after 3 hours, the measurement is performed with a waterproof tester.
  • the new material prepared by the invention has good waterproof performance
  • the new material prepared in the second embodiment has the best waterproof effect.
  • the invention has the advantages of simple composition and easy availability of raw materials, and the prepared new material not only has good anti-corrosion and waterproof performance, but also has good heat resistance, light resistance and anti-aging property, and can be widely applied to various harsh environments, and the present invention proposes
  • the preparation method has the advantages of simple operation, safety, environmental protection, no pollution, low cost and wide application.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Disclosed by the present invention is a novel high-performance anti-corrosion and waterproof environment-friendly material, comprising the following raw materials in parts by weight: 20-45 parts of chloroprene rubber, 20-30 parts of polyvinyl chloride resin, 10-15 parts of acrylonitrile-butadiene-styrene resin, 6-10 parts of zinc oxide, 3-8 parts of benzoic acid, 10-15 parts of white carbon black, 4-9 parts of butylated hydroxytoluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, 2-8 parts of a photo-stabilizer, and 8-15 parts of a waterborne water-proofing agent. Further provided by the present invention is a preparation method for the novel high-performance anti-corrosion and waterproof environment-friendly material. According to the method, the novel material is obtained by blending vulcanized rubber with resin at a high temperature and then adding additives.

Description

一种高性能防腐防水环保新材料A high-performance anti-corrosion waterproof and environmental protection new material 技术领域Technical field
本发明涉及防腐防水材料技术领域，尤其涉及一种高性能防腐防水环保新材料。The invention relates to the technical field of anti-corrosion and waterproof materials, in particular to a high-performance anti-corrosion waterproof and environmental protection new material.
背景技术Background technique
防水材料是防渗透、渗漏和侵蚀的材料的统称，建筑物的围护结构要防止雨水、雪水和地下水的渗透；要防止空气中的湿气、蒸汽和其他有害气体与液体的侵蚀；分隔结构要防止给排水的渗翻。市面上防水材料品种繁多，其中一类为沥青防水卷材，主要是用于建筑墙体、屋面、以及隧道、公路、垃圾填埋场等处，起到抵御外界雨水、地下水渗漏的一种可卷曲成卷状的柔性建材产品，作为工程基础与建筑物之间无渗漏连接，是整个工程防水的第一道屏障，对整个工程起着至关重要的作用，沥青内含有蒽、菲、吡啶等均系光毒物，高温条件下使用，在紫外线作用下可引起光化学反应，可能存在安全隐患，本发明提出的一种高性能防腐防水环保新材料能有效的解决上述问题。Waterproof material is a general term for materials that are resistant to seepage, leakage and erosion. The building envelope shall be protected from the infiltration of rain, snow and groundwater; and the erosion of moisture, steam and other harmful gases and liquids in the air shall be prevented; The partition structure should prevent the seepage of the water supply and drainage. There are many kinds of waterproof materials on the market, one of which is asphalt waterproofing membrane, which is mainly used for building walls, roofs, tunnels, highways, landfills, etc., to resist external rainwater and groundwater leakage. Flexible building materials that can be rolled into a roll shape, as a foundation between the engineering foundation and the building, are the first barrier to waterproofing the entire project, and play a vital role in the whole project. The asphalt contains bismuth and phenanthrene. , pyridine and the like are all light poisons, used under high temperature conditions, can cause photochemical reactions under the action of ultraviolet rays, and may have safety hazards. The high-performance anti-corrosion waterproof and environmental protection new material proposed by the invention can effectively solve the above problems.
发明内容Summary of the invention
本发明的目的是为了解决现有技术中存在的缺点，而提出的一种高性能防腐防水环保新材料。The object of the present invention is to solve the shortcomings existing in the prior art, and to provide a high-performance anti-corrosion waterproof and environmental protection new material.
一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶20-45份、聚氯乙烯树脂20-30份、丙烯腈-丁二烯-苯乙烯树脂10-15份、氧化锌6-10份、苯甲酸3-8份、白炭黑10-15份、二丁基羟基甲苯4-9份、锌皂4-9份、二氢吡啶3-8份、光稳定剂2-8份、水性防水剂8-15份。A high-performance anti-corrosion waterproof and environmental protection new material, including the following parts by weight: 20-45 parts of chloroprene rubber, 20-30 parts of polyvinyl chloride resin, 10-15 parts of acrylonitrile-butadiene-styrene resin, zinc oxide 6-10 parts, 3-8 parts of benzoic acid, 10-15 parts of white carbon, 4-9 parts of dibutylhydroxytoluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, light stabilizer 2- 8 parts, 8-15 parts of water-based waterproofing agent.
优选的，所述一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶24-42份、聚氯乙烯树脂24-28份、丙烯腈-丁二烯-苯乙烯树脂12-14份、氧化锌7-9份、苯甲酸4-6份、白炭黑11-13份、二丁基羟基甲苯5-8份、锌皂5-7份、二氢吡啶4-6份、光稳定剂3-6份、水性防水剂9-13份。Preferably, the high-performance anti-corrosion waterproof and environmental protection new material comprises the following raw materials by weight: 24-42 parts of chloroprene rubber, 24-28 parts of polyvinyl chloride resin, acrylonitrile-butadiene-styrene resin 12- 14 parts, 7-9 parts of zinc oxide, 4-6 parts of benzoic acid, 11-13 parts of white carbon, 5-8 parts of dibutylhydroxytoluene, 5-7 parts of zinc soap, 4-6 parts of dihydropyridine, 3-6 parts of light stabilizer and 9-13 parts of water-based water repellent.
优选的，所述一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶32份、聚氯乙烯树脂28份、丙烯腈-丁二烯-苯乙烯树脂14份、氧化锌8份、苯甲酸5份、白炭黑12份、二丁基羟基甲苯6份、锌皂7份、二氢吡啶5份、光稳定剂4份、水性防水剂12份。Preferably, the high-performance anti-corrosion waterproof and environmental protection new material comprises the following raw materials by weight: 32 parts of chloroprene rubber, 28 parts of polyvinyl chloride resin, 14 parts of acrylonitrile-butadiene-styrene resin, zinc oxide 8 Parts, 5 parts of benzoic acid, 12 parts of white carbon, 6 parts of dibutylhydroxytoluene, 7 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, and 12 parts of aqueous water repellent.
优选的，所述氯丁橡胶、聚氯乙烯树脂、丙烯腈-丁二烯-苯乙烯树脂的重量比为2-3:2:1。Preferably, the weight ratio of the neoprene rubber, the polyvinyl chloride resin, and the acrylonitrile-butadiene-styrene resin is 2-3:2:1.
优选的，所述光稳定剂为碳黑。Preferably, the light stabilizer is carbon black.
优选的，所述水性防水剂为PM-4700。Preferably, the aqueous waterproofing agent is PM-4700.
一种高性能防腐防水环保新材料的制备方法，包括以下步骤：A preparation method of a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温150-170℃，硫化4-8h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 150-170 ° C, vulcanization 4-8h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温230-260℃，加热1-2h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a temperature of 230-260 ° C, heating for 1-2 h, until it is completely melted;
S3、将步骤S2中的温度将至170-190℃，加入所述比重的聚氯乙烯树脂，加热搅拌1-2h，得混合树脂A；S3, the temperature in step S2 will be 170-190 ° C, adding the specific gravity of the polyvinyl chloride resin, heating and stirring for 1-2h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在110-130℃下，混合25-45min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 110 Mixing at -130 ° C for 25-45 min to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为3-6mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 3-6 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
本发明提出的一种高性能防腐防水环保新材料，选用使用广泛的橡胶和树脂为主要原料，成分简单、原料易得，制备出的新材料具有良好的防腐蚀、防水性能，同时具有良好的耐热、耐光、抗老化性能，制备出的防腐防水环保新材料可广泛应用于各种恶劣环境中，本发明还提出了一种高性能防腐防水环保新材料的制备方法，通过橡胶硫化后与树脂高温共混加入助剂制备而得，工艺操作简单、安全、环保、无污染，成本低，可得广泛应用。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, which adopts widely used rubber and resin as main raw materials, has simple composition and easy availability of raw materials, and the prepared new material has good anti-corrosion and waterproof performance, and has good performance at the same time. Heat-resistant, light-resistant, anti-aging properties, prepared anti-corrosion, waterproof and environmentally friendly new materials can be widely used in various harsh environments. The present invention also proposes a high-performance anti-corrosion waterproof and environmentally-friendly new material preparation method, which is cured by rubber and The resin is prepared by high-temperature blending with additives, and the process is simple, safe, environmentally friendly, non-polluting, low in cost, and widely applicable.
具体实施方式detailed description
下面结合具体实施例对本发明作进一步解说。The invention is further illustrated below in conjunction with specific embodiments.
实施例一Embodiment 1
本发明提出的一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶28份、聚氯乙烯树脂20份、丙烯腈-丁二烯-苯乙烯树脂10份、氧化锌7份、苯甲酸5份、白炭黑10份、二丁基羟基甲苯5份、锌皂4份、二氢吡啶4份、光 稳定剂3份、水性防水剂8份。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 28 parts of chloroprene rubber, 20 parts of polyvinyl chloride resin, 10 parts of acrylonitrile-butadiene-styrene resin, and 7 parts of zinc oxide. 5 parts of benzoic acid, 10 parts of white carbon black, 5 parts of dibutylhydroxytoluene, 4 parts of zinc soap, 4 parts of dihydropyridine, 3 parts of light stabilizer, and 8 parts of aqueous water repellent.
其制备方法，包括以下步骤：The preparation method comprises the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温165℃，硫化5h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 165 ° C, vulcanization for 5 h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温245℃，加热1.5h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a temperature of 245 ° C, heating for 1.5 h, until it is completely melted;
S3、将步骤S2中的温度将至180℃，加入所述比重的聚氯乙烯树脂，加热搅拌1.5h，得混合树脂A；S3, the temperature in step S2 will be 180 ° C, adding the specific gravity of the polyvinyl chloride resin, heating and stirring for 1.5h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在120℃下，混合35min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer, at 120 Mixing for 35 min at ° C to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为5mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 5 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
实施例二Embodiment 2
本发明提出的一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶30份、聚氯乙烯树脂24份、丙烯腈-丁二烯-苯乙烯树脂12份、氧化锌6份、苯甲酸4份、白炭黑11份、二丁基羟基甲苯6份、锌皂5份、二氢吡啶3份、光稳定剂2份、水性防水剂10份。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials: 30 parts of chloroprene rubber, 24 parts of polyvinyl chloride resin, 12 parts of acrylonitrile-butadiene-styrene resin, and 6 parts of zinc oxide. 4 parts of benzoic acid, 11 parts of white carbon black, 6 parts of dibutylhydroxytoluene, 5 parts of zinc soap, 3 parts of dihydropyridine, 2 parts of light stabilizer, and 10 parts of aqueous water repellent.
其制备方法，包括以下步骤：The preparation method comprises the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温155℃，硫化7h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 155 ° C, vulcanization for 7 h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温250℃，加热1.2h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a high temperature of 250 ° C for 1.2 h, until it is completely melted;
S3、将步骤S2中的温度将至190℃，加入所述比重的聚氯乙烯树脂，加热搅拌1h，得混合树脂A；S3, the temperature in step S2 will be 190 ° C, the specific gravity of the polyvinyl chloride resin, heating and stirring for 1h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在115℃下，混合40min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 115 Mixing for 40 min at ° C to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为4mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 4 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
实施例三Embodiment 3
本发明提出的一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶42份、聚氯乙烯树脂30份、丙烯腈-丁二烯-苯乙烯树脂15份、氧化锌10份、苯甲酸8份、白炭黑15份、二丁基羟基甲苯9份、锌皂8份、二氢吡啶8份、光稳定剂7份、水性防水剂15份。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 42 parts of chloroprene rubber, 30 parts of polyvinyl chloride resin, 15 parts of acrylonitrile-butadiene-styrene resin, and 10 parts of zinc oxide. 8 parts of benzoic acid, 15 parts of white carbon black, 9 parts of dibutylhydroxytoluene, 8 parts of zinc soap, 8 parts of dihydropyridine, 7 parts of light stabilizer, and 15 parts of aqueous water repellent.
其制备方法，包括以下步骤：The preparation method comprises the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温170℃，硫化4h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 170 ° C, vulcanization for 4 h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温230℃，加热2h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a high temperature of 230 ° C for 2 h, until it is completely melted;
S3、将步骤S2中的温度将至185℃，加入所述比重的聚氯乙烯树脂，加热搅拌1.2h，得混合树脂A；S3, the temperature in step S2 will be 185 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 1.2h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在125℃下，混合30min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 125 Mixing for 30 min at ° C to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为3mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 3 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
实施例四Embodiment 4
本发明提出的一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶35份、聚氯乙烯树脂26份、丙烯腈-丁二烯-苯乙烯树脂13份、氧化锌8份、苯甲酸6份、白炭黑12份、二丁基羟基甲苯7份、锌皂6份、二氢吡啶5份、光稳定剂4份、水性防水剂11份。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 35 parts of chloroprene rubber, 26 parts of polyvinyl chloride resin, 13 parts of acrylonitrile-butadiene-styrene resin, and 8 parts of zinc oxide. 6 parts of benzoic acid, 12 parts of white carbon black, 7 parts of dibutylhydroxytoluene, 6 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, and 11 parts of aqueous water repellent.
其制备方法，包括以下步骤：The preparation method comprises the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温150℃，硫化8h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 150 ° C, vulcanization for 8 h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温260℃，加热1h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to a crucible melting furnace, heating at a high temperature of 260 ° C for 1 h, until it is completely melted;
S3、将步骤S2中的温度将至170℃，加入所述比重的聚氯乙烯树脂，加热搅拌2h，得混合树脂A；S3, the temperature in step S2 will be 170 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 2h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在130℃下，混合25min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 130 Mixing for 25 min at ° C to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为6mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 6 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
实施例五Embodiment 5
本发明提出的一种高性能防腐防水环保新材料，包括以下重量份原料：氯丁橡胶40份、聚氯乙烯树脂28份、丙烯腈-丁二烯-苯乙烯树脂14份、氧化锌9份、苯甲酸7份、白炭黑13份、二丁基羟基甲苯8份、锌皂7份、二氢吡啶7份、光稳定剂6份、水性防水剂13份。The invention provides a high-performance anti-corrosion waterproof and environmental protection new material, comprising the following raw materials by weight: 40 parts of chloroprene rubber, 28 parts of polyvinyl chloride resin, 14 parts of acrylonitrile-butadiene-styrene resin, and 9 parts of zinc oxide. 7 parts of benzoic acid, 13 parts of white carbon black, 8 parts of dibutylhydroxytoluene, 7 parts of zinc soap, 7 parts of dihydropyridine, 6 parts of light stabilizer, and 13 parts of aqueous water repellent.
其制备方法，包括以下步骤：The preparation method comprises the following steps:
S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温160℃，硫化6h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 160 ° C, vulcanization for 6 h, standby;
S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温240℃，加热1.8h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a temperature of 240 ° C for 1.8 h, until it is completely melted;
S3、将步骤S2中的温度将至175℃，加入所述比重的聚氯乙烯树脂，加热搅拌1.8h，得混合树脂A；S3, the temperature in step S2 will be 175 ° C, the specific gravity of the polyvinyl chloride resin, heated and stirred for 1.8h, to obtain a mixed resin A;
S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在110℃下，混合45min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 110 Mixing for 45 min at ° C to obtain a mixture B;
S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为4.5mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 4.5 mm;
S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
以下是将上述五组实施例中制备出的防腐防水环保新材料进行防水性能 测试后的结果，将水洒在所制得的防水材料上，3h后用防水测试仪进行测量，以下是测量结果：The following are the results of the waterproof performance test of the anti-corrosion and waterproof new materials prepared in the above five groups of examples. The water is sprinkled on the prepared waterproof material, and after 3 hours, the measurement is performed with a waterproof tester. The following are the measurement results. :
实施例Example 实施例一Embodiment 1 实施例二Embodiment 2 实施例三Embodiment 3 实施例四Embodiment 4 实施例五Embodiment 5
渗水率Water permeability 0.8‰0.8‰ 0.55‰0.55‰ 0.73‰0.73‰ 1.1‰1.1‰ 0.68‰0.68‰
由上述结果可知，本发明制备出的新材料防水性能良好，实施例二中制备出的新材料防水效果最佳。本发明成分简单、原料易得，制备出的新材料不仅具有良好的防腐蚀、防水性能，同时具有良好的耐热、耐光、抗老化性能，可广泛应用于各种恶劣环境中，本发明提出的制备方法，工艺操作简单、安全、环保、无污染，成本低，可得广泛应用。It can be seen from the above results that the new material prepared by the invention has good waterproof performance, and the new material prepared in the second embodiment has the best waterproof effect. The invention has the advantages of simple composition and easy availability of raw materials, and the prepared new material not only has good anti-corrosion and waterproof performance, but also has good heat resistance, light resistance and anti-aging property, and can be widely applied to various harsh environments, and the present invention proposes The preparation method has the advantages of simple operation, safety, environmental protection, no pollution, low cost and wide application.
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any technical person skilled in the art within the technical scope disclosed by the present invention, the technical solution according to the present invention Equivalent substitutions or modifications of the inventive concept are intended to be included within the scope of the invention.

Claims (7)

  1. 一种高性能防腐防水环保新材料，其特征在于，包括以下重量份原料：氯丁橡胶20-45份、聚氯乙烯树脂20-30份、丙烯腈-丁二烯-苯乙烯树脂10-15份、氧化锌6-10份、苯甲酸3-8份、白炭黑10-15份、二丁基羟基甲苯4-9份、锌皂4-9份、二氢吡啶3-8份、光稳定剂2-8份、水性防水剂8-15份。The utility model relates to a high-performance anti-corrosion waterproof and environment-friendly new material, which comprises the following raw materials by weight: 20-45 parts of chloroprene rubber, 20-30 parts of polyvinyl chloride resin, acrylonitrile-butadiene-styrene resin 10-15 Parts, 6-10 parts of zinc oxide, 3-8 parts of benzoic acid, 10-15 parts of white carbon, 4-9 parts of dibutylhydroxytoluene, 4-9 parts of zinc soap, 3-8 parts of dihydropyridine, light 2-8 parts of stabilizer and 8-15 parts of water-based water repellent.
  2. 根据权利要求1所述的一种高性能防腐防水环保新材料，其特征在于，包括以下重量份原料：氯丁橡胶24-42份、聚氯乙烯树脂24-28份、丙烯腈-丁二烯-苯乙烯树脂12-14份、氧化锌7-9份、苯甲酸4-6份、白炭黑11-13份、二丁基羟基甲苯5-8份、锌皂5-7份、二氢吡啶4-6份、光稳定剂3-6份、水性防水剂9-13份。The invention relates to a high-performance anti-corrosion and waterproof environmental protection new material according to claim 1, which comprises the following raw materials by weight: 24-42 parts of chloroprene rubber, 24-28 parts of polyvinyl chloride resin, acrylonitrile-butadiene. - 12-14 parts of styrene resin, 7-9 parts of zinc oxide, 4-6 parts of benzoic acid, 11-13 parts of white carbon, 5-8 parts of dibutylhydroxytoluene, 5-7 parts of zinc soap, dihydrogen 4-6 parts of pyridine, 3-6 parts of light stabilizer, and 9-13 parts of aqueous water repellent.
  3. 根据权利要求1所述的一种高性能防腐防水环保新材料，其特征在于，包括以下重量份原料：氯丁橡胶32份、聚氯乙烯树脂28份、丙烯腈-丁二烯-苯乙烯树脂14份、氧化锌8份、苯甲酸5份、白炭黑12份、二丁基羟基甲苯6份、锌皂7份、二氢吡啶5份、光稳定剂4份、水性防水剂12份。A high-performance anti-corrosion and waterproof environmental protection new material according to claim 1, comprising the following raw materials by weight: 32 parts of chloroprene rubber, 28 parts of polyvinyl chloride resin, acrylonitrile-butadiene-styrene resin 14 parts, 8 parts of zinc oxide, 5 parts of benzoic acid, 12 parts of white carbon, 6 parts of dibutylhydroxytoluene, 7 parts of zinc soap, 5 parts of dihydropyridine, 4 parts of light stabilizer, and 12 parts of aqueous water repellent.
  4. 根据权利要求1所述的一种高性能防腐防水环保新材料，其特征在于，所述氯丁橡胶、聚氯乙烯树脂、丙烯腈-丁二烯-苯乙烯树脂的重量比为2-3:2:1。The high-performance anti-corrosion and waterproof environmental protection new material according to claim 1, wherein the weight ratio of the neoprene rubber, the polyvinyl chloride resin, and the acrylonitrile-butadiene-styrene resin is 2-3: 2:1.
  5. 根据权利要求1所述的一种高性能防腐防水环保新材料，其特征在于，所述光稳定剂为碳黑。A high-performance anti-corrosion and waterproof environmental protection new material according to claim 1, wherein the light stabilizer is carbon black.
  6. 根据权利要求1所述的一种高性能防腐防水环保新材料，其特征在于，所述水性防水剂为PM-4700。A high-performance anti-corrosion waterproof and environment-friendly new material according to claim 1, wherein the aqueous water repellent is PM-4700.
  7. 一种高性能防腐防水环保新材料的制备方法，其特征在于，包括以下步骤：The invention discloses a preparation method of a high-performance anti-corrosion waterproof and environmental protection new material, which comprises the following steps:
    S1、将所述比重的氯丁橡胶加入到橡胶硫化罐中，加入所述比重的氧化锌、苯甲酸，高温150-170℃，硫化4-8h，备用；S1, adding the specific gravity of the chloroprene rubber to the rubber vulcanization tank, adding the specific gravity of zinc oxide, benzoic acid, high temperature 150-170 ° C, vulcanization 4-8h, standby;
    S2、将所述比重的丙烯腈-丁二烯-苯乙烯树脂加入到坩埚熔化炉中，高温230-260℃，加热1-2h，待其完全融化；S2, adding the specific gravity of the acrylonitrile-butadiene-styrene resin to the crucible melting furnace, heating at a temperature of 230-260 ° C, heating for 1-2 h, until it is completely melted;
    S3、将步骤S2中的温度将至170-190℃，加入所述比重的聚氯乙烯树脂，加热搅拌1-2h，得混合树脂A；S3, the temperature in step S2 will be 170-190 ° C, adding the specific gravity of the polyvinyl chloride resin, heating and stirring for 1-2h, to obtain a mixed resin A;
    S4、将步骤S1中硫化后的橡胶、混合树脂A加入到高速混合器中，同时加入所述比重的白炭黑、二丁基羟基甲苯、锌皂、二氢吡啶、光稳定剂，在110-130℃下，混合25-45min，得混合物B；S4, adding the rubber and mixed resin A after vulcanization in step S1 to a high-speed mixer, and simultaneously adding the specific gravity of white carbon, dibutylhydroxytoluene, zinc soap, dihydropyridine, and light stabilizer at 110 Mixing at -130 ° C for 25-45 min to obtain a mixture B;
    S5、将混合物B加入到压延机中，压制展延成表面均匀，厚度为3-6mm的片状新材料C；S5, the mixture B is added to the calender, and is pressed into a sheet-like new material C having a uniform surface and a thickness of 3-6 mm;
    S6、将水性防水剂均匀的喷涂在新材料C的两面，自然晾干，即得。S6. Spray the water-based waterproofing agent evenly on both sides of the new material C, and dry it naturally.
PCT/CN2018/105878 2018-05-08 2018-09-15 Novel high-performance anti-corrosion and waterproof environment-friendly material WO2019214126A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112759889A (en) * 2021-01-22 2021-05-07 王聪 Modified waterproof coiled material and preparation method thereof

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CN1089974A (en) * 1993-01-12 1994-07-27 中国科学院沈阳分院建筑工程公司 Polyvinyl-chloride water-proof paint and preparation method
CN1232853A (en) * 1998-04-17 1999-10-27 抚顺市辽东合成防水材料厂 Five-element butyl rubber-asphalt waterproof cold adhering material
CN106317528A (en) * 2016-09-04 2017-01-11 淄博夸克医药技术有限公司 Novel high-performance anticorrosion waterproof environment-friendly material

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Publication number Priority date Publication date Assignee Title
CN1089974A (en) * 1993-01-12 1994-07-27 中国科学院沈阳分院建筑工程公司 Polyvinyl-chloride water-proof paint and preparation method
CN1232853A (en) * 1998-04-17 1999-10-27 抚顺市辽东合成防水材料厂 Five-element butyl rubber-asphalt waterproof cold adhering material
CN106317528A (en) * 2016-09-04 2017-01-11 淄博夸克医药技术有限公司 Novel high-performance anticorrosion waterproof environment-friendly material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112759889A (en) * 2021-01-22 2021-05-07 王聪 Modified waterproof coiled material and preparation method thereof

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