CN107083166A - A kind of preparation method of waterproof material - Google Patents

A kind of preparation method of waterproof material Download PDF

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Publication number
CN107083166A
CN107083166A CN201710429313.2A CN201710429313A CN107083166A CN 107083166 A CN107083166 A CN 107083166A CN 201710429313 A CN201710429313 A CN 201710429313A CN 107083166 A CN107083166 A CN 107083166A
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Prior art keywords
parts
preparation
waterproof material
mixture
ppg
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CN201710429313.2A
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Chinese (zh)
Inventor
吴旭
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Hefei Peak Energy Saving Technology Co Ltd
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Hefei Peak Energy Saving Technology Co Ltd
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Priority to CN201710429313.2A priority Critical patent/CN107083166A/en
Publication of CN107083166A publication Critical patent/CN107083166A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of preparation method of waterproof material, comprises the following steps:First, PPG is dehydrated under conditions of 150 200 DEG C, the PPG after dehydration is added in agitator, stirred, obtain mixture one;2nd, composite modifier is added into mixture one, is warming up to 60 80 DEG C, heated and stir 40 60min, obtain mixture two;3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, 2 3h are reacted at a temperature of 120 180 DEG C, mixture three is obtained;4th, it is cooled to after normal temperature.The present invention has excellent water resistance, and low, heat-resist, waterproof, anti-aging, the corrosion-resistant and anti-ultraviolet advantage of good endurance, cost, also there is excellent mechanical property, storage stability and higher thermal insulation, and its preparation method is simple, lower cost for material, is adapted to industrialization mass production.

Description

A kind of preparation method of waterproof material
Technical field
The invention belongs to waterproof material technical field, and in particular to a kind of preparation method of waterproof material.
Background technology
China is a building big country, and the high speed development of building trade has also driven the development of anti-aquatic products industry, and existing Waterproof material has certain use limitation, such as waterproof roll in waterproof construction when the shape according to waterproof matrix is cut out Cut, need polylith to splice for complicated basic unit, the bonding of the mutual lap-joint of waterproof roll is loosely or service life short fatal lacks Fall into and be just completely exposed, by the effect of colding and heat succeed each other, easily caused leakage hidden trouble.The protection and leak of waterproof roll after construction Maintenance afterwards is also problem, and exposed waterproof layer seems very sensitive to external mechanical injuries, i.e., waterproof roll with Either Man Pu, Dian Pu, bar are spread the bonding of basic unit, sky is spread, and all will be to walk water layer between coiled material and basic unit, no matter any position Penetrability is damaged, degumming, leak adhesive, and the whole coupled water-proof function for passing through aspect is all by the mistake that all declines, if can not find breakage And rejected region, then need all to reform waterproof layer, cause great fund and waste of time.
Waterproof material waterproof layer is after being brushed in basic unit, by being generated after the physical and chemical reaction consolidation of material in itself Waterproof layer, traditional soluble polyurethane waterproof material is made up of polyurethane with coal tar as raw material, is volatilized in use Tar gas, toxicity is big and not easy-clear, and hardening time is long, and 2000 disabled in China.The polyurethane water-proof of existing in the market Material generally existing solid content is low, poor from thickening property, the characteristic such as water resistance and glued membrane intensity difference, and construction needs multipass brushing, often There is certain interval time all over brushing, the engineering time is longer.The problem of waterproof material waterproof layer is maximum is an exposure under sunlight, Easily the degradation and decomposition because of ultraviolet, loses the function of waterproof layer.In the urgent need to address these of current field of waterproof materials are asked Topic.
In summary, it is therefore desirable to a kind of preparation method of more preferable waterproof material, to improve the deficiencies in the prior art, from And promote the development of building trade.
The content of the invention
It is an object of the invention to provide a kind of preparation method of waterproof material, the present invention has excellent water proofing property Can, and low, heat-resist, waterproof, anti-aging, the corrosion-resistant and anti-ultraviolet advantage of good endurance, cost, also with excellent Different mechanical property, storage stability and higher thermal insulation, and its preparation method is simple, lower cost for material, is adapted to Industrialize mass production.
The invention provides following technical scheme:
A kind of preparation method of waterproof material, comprises the following steps:
First, PPG is dehydrated under conditions of 150-200 DEG C, the PPG after dehydration is added to stirring In device, stir, obtain mixture one;
2nd, composite modifier is added into mixture one, is warming up to 60-80 DEG C, heated and stir 40-60min, obtain mixture Two;
3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, it is anti-at a temperature of 120-180 DEG C 2-3h is answered, mixture three is obtained;
4th, it is cooled to after normal temperature.
It is preferred that, the waterproof material includes the raw material of following parts by weight:10-15 parts of PPG, composite modifier 8-12 parts of 10-14 parts, 8-16 parts of inorganic filler, 10-15 parts of stabilizer, 7-12 parts of plasticizer and softening agent.
It is preferred that, the waterproof material includes the raw material of following parts by weight:15 parts of PPG, composite modifier 10 8 parts of part, 16 parts of inorganic filler, 10 parts of stabilizer, 12 parts of plasticizer and softening agent.
It is preferred that, the composite modifier of the step 2 is styrene-butadiene block copolymer, polystyrene-fourth two Alkene copolymer, polyethylene and any of polypropylene and its derivative or a variety of combinations, the washability of the composition are numerous, So that material source scope is wide, it is with low cost, it is easy to prepare.
It is preferred that, the inorganic filler of the step 3 is calcium carbonate, barium sulfate or talcum powder.
It is preferred that, the species of the plasticizer of the step 3 is aliphatic dibasic acid ester, Phthalates, benzene polyacid Any of esters, benzoates, epoxies, citric acid ester type and polyesters or a variety of combinations.
It is preferred that, the softening agent softening agent of the step 3 is times in naphthenic oil, hydrocarbon oil and industrial vaseline One or more combinations, the composition is conducive to the hydrophobicity of raising mode material so that water resistance is improved.
It is preferred that, the step 4 is cooled to after normal temperature and stands 2-3 days again.
The beneficial effects of the invention are as follows:
The present invention has excellent water resistance, and good endurance, cost are low, heat-resist, waterproof, anti-aging, corrosion resistant Erosion and anti-ultraviolet advantage, also with excellent mechanical property, storage stability and higher thermal insulation, and it is prepared Method is simple, lower cost for material, is adapted to industrialization mass production.
The composite modifier of the step two of the present invention is styrene-butadiene block copolymer, styrene-butadiene is common Polymers, polyethylene and any of polypropylene and its derivative or a variety of combinations, the washability of the composition are numerous so that Material source scope is wide, with low cost, it is easy to prepare.
The softening agent softening agent of the step three of the present invention is any of naphthenic oil, hydrocarbon oil and industrial vaseline Or a variety of combinations, the composition is conducive to the hydrophobicity of raising mode material so that water resistance is improved.
Embodiment
Embodiment 1
A kind of preparation method of waterproof material, comprises the following steps:
First, PPG is dehydrated under conditions of 150 DEG C, the PPG after dehydration is added to agitator In, stir, obtain mixture one;
2nd, composite modifier is added into mixture one, is warming up to 80 DEG C, heated and stir 60min, obtain mixture two;
3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, is reacted at a temperature of 180 DEG C 3h, obtains mixture three;
4th, it is cooled to after normal temperature.
Waterproof material includes the raw material of following parts by weight:15 parts of PPG, 10 parts of composite modifier, inorganic filler 16 Part, 10 parts of stabilizer, 12 parts of plasticizer and 8 parts of softening agent.
The composite modifier of step 2 is styrene-butadiene block copolymer, PSB, gathered The combination of ethene and polypropylene and its derivative, the washability of the composition is numerous so that material source scope is wide, with low cost, It is easily prepared.
The inorganic filler of step 3 is calcium carbonate.
The species of the plasticizer of step 3 is aliphatic dibasic acid ester, Phthalates, benzoates, epoxy The combination of class, citric acid ester type and polyesters.
The softening agent softening agent of step 3 is the combination of naphthenic oil and industrial vaseline, and the composition is conducive to raising mode The hydrophobicity of material so that water resistance is improved.
Step 4 is cooled to after normal temperature stands 2 days again.
Embodiment 2
A kind of preparation method of waterproof material, comprises the following steps:
First, PPG is dehydrated under conditions of 200 DEG C, the PPG after dehydration is added to agitator In, stir, obtain mixture one;
2nd, composite modifier is added into mixture one, is warming up to 60 DEG C, heated and stir 40min, obtain mixture two;
3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, is reacted at a temperature of 180 DEG C 2h, obtains mixture three;
4th, it is cooled to after normal temperature.
Waterproof material includes the raw material of following parts by weight:15 parts of PPG, 14 parts of composite modifier, inorganic filler 8 Part, 15 parts of stabilizer, 7 parts of plasticizer and 8 parts of softening agent.
The composite modifier of step 2 is styrene-butadiene block copolymer, polyethylene and polypropylene and its derivative Combination, the washability of the composition is numerous so that material source scope is wide, with low cost, it is easy to prepare.
The inorganic filler of step 3 is talcum powder.
The species of the plasticizer of step 3 is Phthalates, many esters of gallic acid of benzene, benzoates, epoxies, lemon The combination of esters of gallic acid and polyesters.
The softening agent softening agent of step 3 is the combination of hydrocarbon oil and industrial vaseline, and the composition is conducive to raising side The hydrophobicity of formula material so that water resistance is improved.
Step 4 is cooled to after normal temperature stands 3 days again.
Embodiment 3
A kind of preparation method of waterproof material, comprises the following steps:
First, PPG is dehydrated under conditions of 200 DEG C, the PPG after dehydration is added to agitator In, stir, obtain mixture one;
2nd, composite modifier is added into mixture one, is warming up to 60 DEG C, heated and stir 60min, obtain mixture two;
3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, is reacted at a temperature of 180 DEG C 2h, obtains mixture three;
4th, it is cooled to after normal temperature.
Waterproof material includes the raw material of following parts by weight:10 parts of PPG, 14 parts of composite modifier, inorganic filler 8 Part, 10 parts of stabilizer, 12 parts of plasticizer and 12 parts of softening agent.
The composite modifier of step 2 is styrene-butadiene block copolymer, PSB, gathered The combination of ethene and polypropylene and its derivative, the washability of the composition is numerous so that material source scope is wide, with low cost, It is easily prepared.
The inorganic filler of step 3 is talcum powder.
The species of the plasticizer of step 3 be aliphatic dibasic acid ester, many esters of gallic acid of benzene, benzoates, epoxies, The combination of citric acid ester type and polyesters.
The softening agent softening agent of step 3 is the combination of naphthenic oil, hydrocarbon oil and industrial vaseline, and the composition is favourable In the hydrophobicity for improving mode material so that water resistance is improved.
Step 4 is cooled to after normal temperature stands 3 days again.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (8)

1. a kind of preparation method of waterproof material, it is characterised in that comprise the following steps:
First, PPG is dehydrated under conditions of 150-200 DEG C, the PPG after dehydration is added to stirring In device, stir, obtain mixture one;
2nd, composite modifier is added into mixture one, is warming up to 60-80 DEG C, heated and stir 40-60min, obtain mixture Two;
3rd, inorganic filler, stabilizer, plasticizer and softening agent are added into mixture two successively, it is anti-at a temperature of 120-180 DEG C 2-3h is answered, mixture three is obtained;
4th, it is cooled to after normal temperature.
2. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the waterproof material bag Include the raw material of following parts by weight:10-15 parts of PPG, 10-14 parts of composite modifier, 8-16 parts of inorganic filler, stabilizer 8-12 parts of 10-15 parts, 7-12 parts of plasticizer and softening agent.
3. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the waterproof material bag Include the raw material of following parts by weight:15 parts of PPG, 10 parts of composite modifier, 16 parts of inorganic filler, 10 parts of stabilizer, plasticising 8 parts of 12 parts of agent and softening agent.
4. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the step 2 is answered Conjunction modifying agent is styrene-butadiene block copolymer, PSB, polyethylene and polypropylene and its spread out Any of biology or a variety of combinations.
5. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the nothing of the step 3 Machine filler is calcium carbonate, barium sulfate or talcum powder.
6. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the increasing of the step 3 The species for moulding agent is aliphatic dibasic acid ester, Phthalates, many esters of gallic acid of benzene, benzoates, epoxies, citric acid Any of esters and polyesters or a variety of combinations.
7. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the step 3 it is soft Agent softening agent is any of naphthenic oil, hydrocarbon oil and industrial vaseline or a variety of combinations.
8. a kind of preparation method of waterproof material according to claim 1, it is characterised in that the step 4 cooling 2-3 days are stood again after to normal temperature.
CN201710429313.2A 2017-06-08 2017-06-08 A kind of preparation method of waterproof material Withdrawn CN107083166A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108342939A (en) * 2018-01-08 2018-07-31 深圳市东进技术服务有限公司 A kind of anti-ponding type asphalt pavement construction method
CN109712750A (en) * 2019-02-26 2019-05-03 广州粤道智能科技发展有限公司 A kind of comprehensive wiring cable of resistance to limiting temperature
CN113085429A (en) * 2021-03-26 2021-07-09 广东虎彩影像有限公司 Digital stained paper ceramic thermal transfer printing process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031545A (en) * 2014-06-11 2014-09-10 江苏通铨防水材料科技有限公司 W-OH-WP permeable reactive waterproof material and preparation method and using method thereof
CN106221250A (en) * 2016-08-15 2016-12-14 安庆越球建筑防水材料有限公司 A kind of rubber modified asphalt waterproof material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031545A (en) * 2014-06-11 2014-09-10 江苏通铨防水材料科技有限公司 W-OH-WP permeable reactive waterproof material and preparation method and using method thereof
CN106221250A (en) * 2016-08-15 2016-12-14 安庆越球建筑防水材料有限公司 A kind of rubber modified asphalt waterproof material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108342939A (en) * 2018-01-08 2018-07-31 深圳市东进技术服务有限公司 A kind of anti-ponding type asphalt pavement construction method
CN109712750A (en) * 2019-02-26 2019-05-03 广州粤道智能科技发展有限公司 A kind of comprehensive wiring cable of resistance to limiting temperature
CN113085429A (en) * 2021-03-26 2021-07-09 广东虎彩影像有限公司 Digital stained paper ceramic thermal transfer printing process

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Application publication date: 20170822