CN104060775A - Composite root-penetration-resistant waterproof roll for planted roof and preparation method thereof - Google Patents
Composite root-penetration-resistant waterproof roll for planted roof and preparation method thereof Download PDFInfo
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- CN104060775A CN104060775A CN201410322553.9A CN201410322553A CN104060775A CN 104060775 A CN104060775 A CN 104060775A CN 201410322553 A CN201410322553 A CN 201410322553A CN 104060775 A CN104060775 A CN 104060775A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title abstract 6
- 239000010426 asphalt Substances 0.000 claims abstract description 65
- 239000000843 powder Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000010721 machine oil Substances 0.000 claims abstract description 19
- 239000000126 substance Substances 0.000 claims abstract description 14
- 238000003618 dip coating Methods 0.000 claims abstract description 3
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 40
- 239000011295 pitch Substances 0.000 claims description 38
- 235000013312 flour Nutrition 0.000 claims description 19
- 239000004575 stone Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- 239000000835 fiber Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 239000011889 copper foil Substances 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 4
- 239000010456 wollastonite Substances 0.000 abstract description 2
- 229910052882 wollastonite Inorganic materials 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 41
- 230000000052 comparative effect Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000004078 waterproofing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a composite root-penetration-resistant waterproof roll for a planted roof and a preparation method of the composite root-penetration-resistant waterproof roll and belongs to the technical field of building waterproof rolls. The composite root-penetration-resistant waterproof roll comprises a base, an asphalt layer and a high-density strong intersection film, wherein the asphalt layer is arranged on the base in a dip-coating mode. The asphalt layer comprises, by weight, 700-1500 parts of 10# asphalt, 700-1500 parts of 90# asphalt, 600-1200 parts of rubber powder, 50-250 parts of SBS, 50-250 parts of APP, 0-150 parts of IPP, 100-400 parts of machine oil, 1000-1800 parts of wollastonite powder, and 20-80 parts of chemical root resisting agent. The composite root-penetration-resistant waterproof roll for the planted roof and the preparation method of the composite root-penetration-resistant waterproof roll have the advantages that waterproof requirements of a building can be well met, roots of plants can also be prevented from intruding into the roll, and damage to the roof is avoided.
Description
Technical field
The invention belongs to building waterproof coil technical field, be specifically related to a kind of compound root resistant waterproof roll and preparation method thereof for planted roof.
Background technology
Waterproof roll is mainly used for construction wall, roofing and tunnel, highway, refuse landfill etc. and locates, play a kind of flexible building material product that is curled into web-like of resisting extraneous rainwater, ground water seepage, be connected as leakproof between engineering foundation and building, be the first barrier of whole engineering waterproofing, whole engineering is played to vital effect.
For improving housing conditions and living environment, roof garden becomes developer's and architect preferred option all over the world.But roof garden has very high requirement to waterproof roll, not only want energy waterproof, also want to keep out for a long time plant root and invade in coiled material.But existing waterproof roll cannot meet the demands.
The Chinese patent that application number is 201220422929X provides a kind of planted roof root resistant waterproof roll, comprise the compound plies of Copper Foil, the two sides of the compound plies of described Copper Foil are respectively equipped with SBS modified asphalt layer, and the external surface of described SBS modified asphalt layer is provided with overcoat; Described SBS modified asphalt layer is made up of the SBS modified bitumen that is added with chemical root resistance agent.
The Chinese patent that application number is 2013100691679 provides a kind of combination modified bitumen root resistant waterproof roll and preparation method thereof, is composited by surface layer, upper waterproofing course, tire basic unit, lower waterproofing course and bottom; Material composition and the percentage by weight proportioning of upper waterproofing course and lower waterproofing course are as follows; Material composition and the percentage by weight proportioning of described upper waterproofing course and lower waterproofing course are as follows: pitch 20～60%; Machine oil 15～20%; Polyolefin 2～15%; SBS3～15%; Wollastonite powder 10～25%; Silicon carbide whisker powder 1～5%; Silicon nitride crystal whisker powder 1～5%; Calcium carbonate crystal whisker powder 1～10%; Nano zine oxide 0.1～6%; Chemistry root resistance agent 0.5～5.0%.
The Chinese patent that application number is 2013107386535 provides a kind of planted roof root resistant waterproof roll, comprise 28～30 parts of pitches, SBS2～6 part, SBR3～6 part, APP1.6～7 part, 15～23 parts of compound lards, 3～6 parts of fire retardants, 10～13 parts, the plasticizing agent of resistance to migration, 23～24 parts of Corvics, 8～10 parts, portland cement powder, 1.0～1.2 parts of nano zine oxides, 1～5 part of dibasic lead phosphite, 2～8 parts of ternary vinyl chloride-vinyl acetate resins, 1～5 part of ABS resin, 909 15～22 parts of anti-freezing type adhesive glue, 0.8～1.2 part of 10～12 parts of polypropylene fiber silks and chemical root resistance agent.
Therefore, develop a kind of waterproof roll that prevents that root system of plant from passing and become the technical problem of needing solution badly.
Summary of the invention
The object of this invention is to provide a kind of good water-proof effect, and can resist for a long time the compound root resistant waterproof roll of planted roof that plant root is invaded.
Another object of the present invention is to provide the preparation method of the compound root resistant waterproof roll of planted roof.
The technical solution used in the present invention is the compound root resistant waterproof roll of a kind of planted roof, comprises tire base, dip-coating bitumen layer and the powerful film that intersects of high density on tire base, and described bitumen layer is made up of the component of following parts by weight: 10
#700～1500 parts of pitches, 90
#700～1500 parts of pitches, 600～1200 parts of rubber powders, SBS50～250 part, APP50～250 part, IPP0～150 part, 100～400 parts, machine oil, 1000～1800 parts of stone flours, 20～80 parts of chemical root resistance agent.
As preferably, described bitumen layer is made up of the component of following parts by weight: 10
#900～1300 parts of pitches, 90
#900～1300 parts of pitches, 800～1000 parts of rubber powders, SBS100～200 part, APP100～200 part, IPP0～100 part, 200～300 parts, machine oil, 1200～1600 parts of stone flours, 40～60 parts of chemical root resistance agent.
As preferably, described bitumen layer is made up of the component of following parts by weight: 10
#1300 parts of pitches, 90
#900 parts of pitches, 900 parts of rubber powders, SBS100 part, APP200 part, IPP100 part, 200 parts, machine oil, 1400 parts of stone flours, 50 parts of chemical root resistance agent.
As preferably, described bitumen layer is made up of the component of following parts by weight: 10
#900 parts of pitches, 90
#1300 parts of pitches, 900 parts of rubber powders, SBS200 part, APP100 part, 300 parts, machine oil, 1400 parts of stone flours, 50 parts of chemical root resistance agent.
As preferably, granularity >=40 order of described rubber powder; Granularity >=200 order of described stone flour.
As preferably, described rubber powder comprises nylon rubber powder, steel wire tire rubber powder.
As preferably, described tire base comprises long fibre polyester fiber felt, complex copper tire base, Copper Foil tire base.
The present invention also provides the preparation method of the compound root resistant waterproof roll of a kind of described planted roof, comprises the following steps:
A, preparation bitumen layer: get 10
#pitch and 90
#asphalt heating to 195 DEG C～205 DEG C, then adds rubber powder while stirring, is warming up to 250 DEG C～260 DEG C, constant temperature stirs 1.5～2.5 hours, be cooled to 185 DEG C～195 DEG C, add machine oil, stir 5～10 minutes, add subsequently SBS, APP and IPP, under 175 DEG C～185 DEG C conditions, stir 0.5～1.5 hour, then grind 1～1.5 hour, then add stone flour and chemical root resistance agent, under 175 DEG C～185 DEG C conditions, stir 0.5～1.5 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on tire base, then in bitumen layer, cover the powerful film that intersects of high density.
In the present invention, the abbreviation that SBS is s-B-S; The agent of chemistry root resistance, long fibre polyester fiber felt, complex copper tire base, Copper Foil tire base are commercially available prod, purchased from the producer with legal qualification.
Beneficial effect of the present invention is: can ensure well the waterproof requirement of building, can also keep out for a long time plant root and invade coiled material, avoid roof to produce and destroy, thereby reach good waterproof effect.
Detailed description of the invention
For making those skilled in the art understand in detail production technology of the present invention and technique effect, further introduce application of the present invention and technique effect with concrete production instance below.
Embodiment 1:
A, preparation bitumen layer: get 1300kg10
#pitch and 900kg90
#asphalt heating to 195 DEG C, then adds 900kg40 object nylon rubber powder while stirring, is warming up to 250 DEG C, constant temperature stirs 2.5 hours, be cooled to 185 DEG C, add 200kg machine oil, stir 10 minutes, add subsequently 100kgSBS, 200kgAPP and 100kgIPP, under 180 DEG C of conditions, stir 1 hour, then grind 1 hour, then add 1400kg200 object stone flour and the agent of 50kg chemistry root resistance, under 180 DEG C of conditions, stir 1.5 hours the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on long fibre polyester fiber felt, then in bitumen layer, cover the powerful film that intersects of high density.
Embodiment 2:
A, preparation bitumen layer: get 900kg10
#pitch and 1300kg90
#asphalt heating to 200 DEG C, then adds the 40 object steel wire tire rubber powders of 900kg while stirring, is warming up to 260 DEG C, constant temperature stirs 2 hours, be cooled to 185 DEG C, add 300kg machine oil, stir 5 minutes, add subsequently 200kgSBS, 100kgAPP, under 180 DEG C of conditions, stir 1 hour, then grind 1 hour, then add 1400kg200 object stone flour and the agent of 50kg chemistry root resistance, under 175 DEG C of conditions, stir 1 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on complex copper tire base, then in bitumen layer, cover the powerful film that intersects of high density.
10
#900 parts of pitches, 90
#1300 parts of pitches, 900 parts of rubber powders, SBS200 part, APP100 part, 300 parts, machine oil, 1400 parts of stone flours, 50 parts of chemical root resistance agent.
Embodiment 3:
A, preparation bitumen layer: get 1500kg10
#pitch and 700kg90
#asphalt heating to 200 DEG C, then adds 600kg80 object nylon rubber powder while stirring, is warming up to 255 DEG C, constant temperature stirs 2 hours, be cooled to 190 DEG C, add 400kg machine oil, stir 5 minutes, add subsequently 50kgSBS, 250kgAPP and 150kgIPP, under 185 DEG C of conditions, stir 1.5 hours, then grind 1.5 hours, then add 1000kg200 object stone flour and the agent of 20kg chemistry root resistance, under 185 DEG C of conditions, stir 1 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on complex copper tire base, then in bitumen layer, cover the powerful film that intersects of high density.
Embodiment 4:
A, preparation bitumen layer: get 700kg10
#pitch and 1500kg90
#asphalt heating to 205 DEG C, then adds 1200kg60 object nylon rubber powder while stirring, is warming up to 260 DEG C, constant temperature stirs 2.5 hours, be cooled to 185 DEG C, add 100kg machine oil, stir 5 minutes, add subsequently 250kgSBS, 50kgAPP and 50kgIPP, under 185 DEG C of conditions, stir 0.5 hour, then grind 1 hour, then add 1800kg200 object stone flour and the agent of 80kg chemistry root resistance, under 185 DEG C of conditions, stir 1 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on Copper Foil tire base, then in bitumen layer, cover the powerful film that intersects of high density.
Embodiment 5:
A, preparation bitumen layer: get 1500kg10
#pitch and 700kg90
#asphalt heating to 200 DEG C, then adds 600kg80 object steel wire tire rubber powder while stirring, is warming up to 255 DEG C, constant temperature stirs 2 hours, be cooled to 190 DEG C, add 400kg machine oil, stir 5 minutes, add subsequently 50kgSBS and 250kgAPP, under 185 DEG C of conditions, stir 1.5 hours, then grind 1.5 hours, then add 1000kg200 object stone flour and the agent of 20kg chemistry root resistance, under 185 DEG C of conditions, stir 1 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on complex copper tire base, then in bitumen layer, cover the powerful film that intersects of high density.
Embodiment 6:
A, preparation bitumen layer: get 700kg10
#pitch and 1500kg90
#asphalt heating to 205 DEG C, then adds 1200kg60 object steel wire tire rubber powder while stirring, is warming up to 260 DEG C, constant temperature stirs 2.5 hours, be cooled to 185 DEG C, add 100kg machine oil, stir 5 minutes, add subsequently 250kgSBS and 50kgAPP, under 185 DEG C of conditions, stir 0.5 hour, then grind 1 hour, then add 1800kg200 object stone flour and the agent of 80kg chemistry root resistance, under 185 DEG C of conditions, stir 1 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on Copper Foil tire base, then in bitumen layer, cover the powerful film that intersects of high density.
Comparative example 1:
By 90 in bitumen layer
#pitch is replaced by 10
#pitch, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 1.
Comparative example 2:
By 10 in bitumen layer
#pitch is replaced by 90
#pitch, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 2.
Comparative example 3:
By 90 in bitumen layer
#pitch is replaced by 100
#pitch, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 3.
Comparative example 4:
By 90 in bitumen layer
#pitch is replaced by 10
#pitch, all the other are implemented by the method for embodiment 2 completely, obtain comparative example 4.
Comparative example 5:
By 10 in bitumen layer
#pitch is replaced by 90
#pitch, all the other are implemented by the method for embodiment 2 completely, obtain comparative example 5.
For verifying technique effect of the present invention, inspection below special work:
Finally it should be noted that, above embodiment is the unrestricted technical scheme of the present invention in order to explanation only, although the present invention is had been described in detail with reference to above-described embodiment, those skilled in the art are to be understood that, still can modify or be equal to replacement the present invention, and not departing from any modification or partial replacement of the spirit and scope of the present invention, it all should be encompassed in claim scope of the present invention.
Claims (8)
1. the compound root resistant waterproof roll of planted roof, comprises tire base, dip-coating bitumen layer and the powerful film that intersects of high density on tire base, it is characterized in that, described bitumen layer is made up of the component of following parts by weight: 10
#700～1500 parts of pitches, 90
#700～1500 parts of pitches, 600～1200 parts of rubber powders, SBS50～250 part, APP50～250 part, IPP0～150 part, 100～400 parts, machine oil, 1000～1800 parts of stone flours, 20～80 parts of chemical root resistance agent.
2. the compound root resistant waterproof roll of planted roof according to claim 1, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 10
#900～1300 parts of pitches, 90
#900～1300 parts of pitches, 800～1000 parts of rubber powders, SBS100～200 part, APP100～200 part, IPP0～100 part, 200～300 parts, machine oil, 1200～1600 parts of stone flours, 40～60 parts of chemical root resistance agent.
3. the compound root resistant waterproof roll of planted roof according to claim 2, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 10
#1300 parts of pitches, 90
#900 parts of pitches, 900 parts of rubber powders, SBS100 part, APP200 part, IPP100 part, 200 parts, machine oil, 1400 parts of stone flours, 50 parts of chemical root resistance agent.
4. the compound root resistant waterproof roll of planted roof according to claim 2, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 10
#900 parts of pitches, 90
#1300 parts of pitches, 900 parts of rubber powders, SBS200 part, APP100 part, 300 parts, machine oil, 1400 parts of stone flours, 50 parts of chemical root resistance agent.
5. the compound root resistant waterproof roll of planted roof according to claim 2, is characterized in that, granularity >=40 order of described rubber powder; Granularity >=200 order of described stone flour.
6. the compound root resistant waterproof roll of planted roof according to claim 2, is characterized in that, described rubber powder comprises nylon rubber powder, steel wire tire rubber powder.
7. the compound root resistant waterproof roll of planted roof according to claim 2, is characterized in that, described tire base comprises long fibre polyester fiber felt, complex copper tire base, Copper Foil tire base.
8. the preparation method with compound root resistant waterproof roll based on planted roof described in claim 1 or 2, is characterized in that, comprises the following steps:
A, preparation bitumen layer: get 10
#pitch and 90
#asphalt heating to 195 DEG C～205 DEG C, then adds rubber powder while stirring, is warming up to 250 DEG C～260 DEG C, constant temperature stirs 1.5～2.5 hours, be cooled to 185 DEG C～195 DEG C, add machine oil, stir 5～10 minutes, add subsequently SBS, APP and IPP, under 175 DEG C～185 DEG C conditions, stir 0.5～1.5 hour, then grind 1～1.5 hour, then add stone flour and chemical root resistance agent, under 175 DEG C～185 DEG C conditions, stir 0.5～1.5 hour the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer preparing uniform fold on tire base, then in bitumen layer, cover the powerful film that intersects of high density.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410322553.9A CN104060775B (en) | 2014-07-08 | 2014-07-08 | Planted roof compound root resistant waterproof roll and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410322553.9A CN104060775B (en) | 2014-07-08 | 2014-07-08 | Planted roof compound root resistant waterproof roll and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104060775A true CN104060775A (en) | 2014-09-24 |
| CN104060775B CN104060775B (en) | 2016-08-24 |
Family
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505217A (en) * | 2015-12-14 | 2016-04-20 | 刘冠麟 | Self-bonding waterproof roll applied to planted roof and preparation method of self-bonding waterproof roll |
| CN105603771A (en) * | 2015-12-21 | 2016-05-25 | 潍坊市宏源防水材料有限公司 | High-extension copper tire based root puncture-resistant waterproofing coiled material and preparation method thereof |
| CN105966002A (en) * | 2016-04-27 | 2016-09-28 | 寿光市宏图化工有限公司 | Root resistant waterproof coiled material and preparation method thereof |
| CN106433155A (en) * | 2015-08-05 | 2017-02-22 | 天津市奇才防水材料有限公司 | Preparation method of non hot-melt type self-adhere persisting-root through-puncture water resistance coil material |
| CN106479199A (en) * | 2015-08-31 | 2017-03-08 | 天津市奇才防水材料有限公司 | A kind of preparation method of flame retardant type root resistant waterproof roll |
| CN109355926A (en) * | 2018-09-25 | 2019-02-19 | 四川杨氏达防水材料有限公司 | Planted roof root resistance puncture resistant waterproof roll and preparation method |
| CN110356066A (en) * | 2019-08-15 | 2019-10-22 | 广西禹杰防水防腐材料有限公司 | A kind of SBS modified pitch root resistant waterproof roll and its production method |
| CN114808481A (en) * | 2022-04-08 | 2022-07-29 | 湖北工业大学 | Novel root-resistant puncture modified asphalt waterproof coiled material and preparation method thereof |
| CN117601521A (en) * | 2023-12-01 | 2024-02-27 | 新乐市世纪鑫瑞无纺制品有限公司 | Root penetration-resistant waterproof coiled material and preparation method thereof |
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Denomination of invention: Composite root puncture resistant waterproofing membrane for planting roofs and its preparation method Granted publication date: 20160824 Pledgee: Agricultural Bank of China Co.,Ltd. Kunming Jinning District Branch Pledgor: YUNNAN XINCHENG WATERPROOF SCIENCE & TECHNOLOGY CO.,LTD. Registration number: Y2024980024546 |
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