CN105603771B - A kind of high extension copper tire base root resistant waterproof roll and preparation method thereof - Google Patents
A kind of high extension copper tire base root resistant waterproof roll and preparation method thereof Download PDFInfo
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- CN105603771B CN105603771B CN201510960156.9A CN201510960156A CN105603771B CN 105603771 B CN105603771 B CN 105603771B CN 201510960156 A CN201510960156 A CN 201510960156A CN 105603771 B CN105603771 B CN 105603771B
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- copper tire
- waterproof roll
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- modified pitch
- oil
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N5/00—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch
- D06N5/003—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch coated with bitumen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N5/00—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch
- D06N5/003—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch coated with bitumen
- D06N5/006—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch coated with bitumen characterised by the means to apply it to a support or to another roofing membrane, e.g. self-adhesive layer or strip
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1628—Dimensional stability
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of high extension copper tire base root resistant waterproof roll, the waterproof roll is multi-layer compound structure, including intermediate layer and modified pitch coating.Intermediate layer is complex copper tire based nonwoven, and the upper and lower surface of complex copper tire based nonwoven scribbles modified pitch coating.The each component of the modified pitch coating, in terms of mass parts, content is：100 parts of matrix pitch, 5~20 parts of softening agent, 8~26 parts of modifying agent, 5~15 parts of accelerator of extension, 0.1~0.5 part of antioxidant, 0.1~1 part of propanoate ester derivatives.The present invention has excellent high and low temperature resistance, higher elongation percentage and root resistance performance.
Description
Technical field
The present invention relates to a kind of construction water proof material, more particularly to a kind of high extension copper tire base root-resistant puncturing waterproof volume
Material and preparation method thereof, belong to architectural waterproof material field.
Background technology
With Chinese Urbanization, industrialized high speed development, construction area is sharply increased, and greenery patches is constantly reduced, while respectively
The gas and vehicle exhaust of kind energy resource consumption release are continuously increased, and " urban heat island " effect getting worse, ecological environment is increasingly disliked
Change.One of effective way to solve the above problems is development planted roof.
It is well known that the plant roots and stems in planted roof system have extremely strong penetrability, waterproof material can be usually penetrated,
Cause leakage of buildings.And when seepage occurs, it is difficult to determine the destroyed accurate location of waterproof material, cause to overhaul workload
Greatly, take time and effort, cause huge economic loss.In addition, if the root system of plant penetrates roof protrusion（Elevator, ventilation
Hole etc.）Structure sheaf or parapet and cause structure to destroy, then entail dangers to building to a certain extent is safe to use.
Common complex copper tire base its internal void after high temperature prepregs, oiling expands, and causes elongation percentage to decline, directly affects
Adaptability to waterproof roll to basal plane deformation, so as to influence the waterproof root resistance function of planted roof.
Also there is research of the part to complex copper tire base root resistant waterproof roll the country at present, but to the compound of height extension
The research of copper tire base root resistant waterproof roll is less.A kind of complex copper tire base root-resistant puncturing of high extension of research and development is prevented
Water coiled material, China's construction quality can be greatly improved, create the social benefit that can not be estimated.Therefore the complex copper tire base of high extension
The research and development of root resistant waterproof roll are a job highly significant.
Prior art has following defect：（1）Copper tire base waterproof roll elongation percentage is relatively low;(2) it can not realize that copper tire base is prevented
The elongation percentage and paracentesis resistance of water coiled material can be simultaneously higher；（3）High and low temperature resistance is poor；（4）Water resistance and anti-deformation nature
It is not high.
The content of the invention
For above-mentioned technical problem, the present invention provides a kind of the complex copper tire base root resistant waterproof roll and system of high extension
Preparation Method, to realize following goal of the invention：
1st, copper tire base waterproof roll elongation percentage is improved；
2nd, while making copper tire base waterproof roll with compared with high-elongation, its root-resistant puncturing performance is improved；
3rd, copper tire base waterproof roll heat resistance is improved；
4th, copper tire base waterproof roll resistance to low temperature is improved；
5th, copper tire base waterproof roll water resistance and anti-deformation nature are improved.
For achieving the above object, the present invention provides following technical scheme：
A kind of high extension copper tire base root resistant waterproof roll, the waterproof roll are multi-layer compound structure, including centre
Layer and modified pitch coating.
It is the further improvement to above-mentioned technical proposal below：
Described intermediate layer is complex copper tire based nonwoven, and the upper and lower surface of complex copper tire based nonwoven scribbles modified drip
Blue or green coating.
The modified pitch coating includes following components：Matrix pitch, softening agent, modifying agent, extension accelerator, antioxygen
Agent, propanoate ester derivatives.
The each component of the modified pitch coating, in terms of mass parts, content is：
100 parts of matrix pitch, 5~20 parts of softening agent, 8~26 parts of modifying agent, 5~15 parts of accelerator of extension, antioxidant 0.1
~0.5 part, 0.1~1 part of propanoate ester derivatives.
The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm.
Described softening agent is one or more of combinations in naphthenic oil, aromatic naphtha, paraffin oil, machine oil, rubber oil.
Described modifying agent is SBS, styrene-isoprene-phenylethene is embedding
One or more of combinations in section copolymer, butadiene-styrene rubber, APP, APAO；
Described extension accelerator is oil-extended styrene buadiene rubber, oil-extended butadiene rubber, one kind in oil-filled isoprene rubber or several
The combination of kind.
A kind of preparation method of high extension copper tire base root resistant waterproof roll, it is characterised in that：Including feeding, be made change
Property pitch, forming step.
It is 120~180 DEG C to control whipping temp, and speed of agitator is 60~120rpm.
The preimpregnation temperature of complex copper tire based nonwoven is 180~200 DEG C；
The application temperature of modified pitch is 180~200 DEG C, and levels modified pitch coating is respectively 0.8~1.2mm；
Chill roll rotating speed is 5~10rpm, and the pressure of extruding is 0.3~0.6MPa.
Compared with prior art, the invention has the advantages that：
1st, waterproof roll elongation percentage of the present invention is high, and Longitudinal extending rate is 50~65%, extends laterally rate as 56~69%；
2nd, waterproof roll root-resistant puncturing performance of the present invention is good, and root system of plant can not penetrate waterproof roll of the present invention；
3rd, waterproof roll of the present invention is heat-resist, and 105~125 DEG C drip without trickling；
4th, waterproof roll low temperature flexibility of the present invention is good, -25~-35 DEG C of flawlesses；
5th, waterproof roll good water-proof effect of the present invention, anti-deformation energy are high；Impermeability is 0.3MPa, and 30~90min is impermeable
Water；Longitudinal pulling force is 1088~1396N/50mm, and lateral pull is 1195~1438N/50mm.
Waterproof roll of the present invention has that tensile strength is high, elongation percentage is big, good stability of the dimension, and base-layer contraction is deformed and opened
Split the characteristics of adaptable；There is excellent high and low temperature resistance, ageing-resistant performance, higher elongation percentage and anti-deformation simultaneously
Performance and root resistance performance.High extension complex copper tire base root resistant waterproof roll simple production process provided by the invention, cost
It is cheap, it is easy for construction, it is a kind of waterproof roll of wide market.
Embodiment
For purposes of illustration only, the high extension complex copper tire base root resistant waterproof roll of one kind and preparation method of invention are done in detail
Describe in detail bright.
A kind of high extension copper tire base root resistant waterproof roll of embodiment 1
The waterproof roll, is three-layer composite structure, and intermediate layer is complex copper tire based nonwoven, complex copper tire based nonwoven
Upper and lower surface be modified pitch coating；
Intermediate layer thickness is 2mm, and levels modified pitch coating layer thickness is respectively 1mm；
The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm；
The modified pitch coating, it is polymer modified asphalt coating, in parts by mass containing following component：
100 parts of matrix pitch, 10 parts of softening agent, 12 parts of modifying agent, 5 parts of accelerator of extension, 0.1 part of antioxidant, propionic ester
0.3 part of derivative；
The softening agent is naphthenic oil：Condensation point≤- 20 DEG C, fugitive constituent≤1%, flash-point >=200 DEG C；The modifying agent is benzene
Ethene-isoprene-styrene block copolymer；Model SIS1105, block ratio 15/85；
The extension accelerator is oil-filled isoprene rubber, oil-filled quantity 20%；
The antioxidant model 1010；
The propanoate ester derivatives are Preventol B2.
The preparation method of the waterproof roll：
1st, weigh
By formula rate precise matrix pitch, softening agent, softening agent, extension accelerator, antioxidant 1010 and propionic acid
Ester derivant；
2nd, feed
Matrix pitch, softening agent, softening agent, extension accelerator, antioxidant and propionic ester are sequentially added into mixing apparatus
Derivative；
3rd, modified pitch is made
Stirring is opened, it is 120-180 DEG C to control temperature, rotating speed 60-120rpm, is stirred until homogeneous；Obtained polymer changes
Property pitch, discharging to apply oil sump in, it is standby；
4th, complex copper tire based nonwoven is prepared
The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm；
5th, it is molded
Complex copper tire based nonwoven is presoaked, preimpregnation temperature is 180 DEG C；
Into oil sump coating modified pitch is applied, 180 DEG C of application temperature, levels modified pitch coating is respectively 1mm；
Cooled down through the chill roll that rotating speed is 5rpm, extruding, pressure 0.3MPa；
Upper and lower surface covers PE films, then carries out cooling water cooling, sizing.
6th, length, trimming are counted, winds, be packaged to be finished product.
A kind of high extension copper tire base root resistant waterproof roll of embodiment 2
The waterproof roll, is three-layer composite structure, and intermediate layer is complex copper tire based nonwoven, complex copper tire based nonwoven
Upper and lower surface be modified pitch coating；
Intermediate layer thickness is 2mm, and levels modified pitch coating layer thickness is respectively 1mm；
The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm；
The modified pitch coating, it is polymer modified asphalt coating, in parts by mass containing following component：
100 parts of matrix pitch, 15 parts of softening agent, 15 parts of modifying agent, 8 parts of accelerator of extension, 0.3 part of antioxidant, propionic ester
0.5 part of derivative；
The softening agent is machine oil：Condensation point≤- 25 DEG C, fugitive constituent≤1%, flash-point >=180 DEG C；The modifying agent is benzene second
Alkene-butadiene-styrene block copolymer；Model SBS1401, block ratio 30/70；
The extension accelerator is oil-extended butadiene rubber, oil-filled quantity 27.5%；
The antioxidant model 1010；
The propanoate ester derivatives are Preventol B2.
The preparation method of the waterproof roll, it is identical with the preparation method of embodiment 1,
Only change step 5 to be shaped to：
Complex copper tire based nonwoven is presoaked, preimpregnation temperature is 190 DEG C；
Into oil sump coating modified pitch is applied, 190 DEG C of application temperature, levels modified pitch coating is respectively 1mm；
Cooled down through the chill roll that rotating speed is 6rpm, extruding, pressure 0.4MPa；
Upper and lower surface covers PE films, then carries out cooling water cooling, sizing.
A kind of high extension copper tire base root resistant waterproof roll of embodiment 3
The waterproof roll, is three-layer composite structure, and intermediate layer is complex copper tire based nonwoven, complex copper tire based nonwoven
Upper and lower surface be modified pitch coating；
Intermediate layer thickness is 2mm, and levels modified pitch coating layer thickness is respectively 1mm；
The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm；
The modified pitch coating, it is polymer modified asphalt coating, in parts by mass containing following component：
100 parts of matrix pitch, 20 parts of softening agent, 20 parts of modifying agent, 12 parts of accelerator of extension, 0.5 part of antioxidant, propionic ester
0.8 part of derivative；
The softening agent is aromatic naphtha：Condensation point≤- 30 DEG C, fugitive constituent≤1%, flash-point >=220 DEG C；The modifying agent is benzene
Ethylene-butadiene-styrene block copolymer；Model SBS501, block ratio 30/70；
The extension accelerator is oil-extended styrene buadiene rubber, oil-filled quantity 32.5%；
The antioxidant model 1010；
The propanoate ester derivatives are Preventol B2.
The preparation method of the waterproof roll, it is identical with the preparation method of embodiment 1,
Only change step 5 to be shaped to：
Complex copper tire based nonwoven is presoaked, preimpregnation temperature is 200 DEG C；
Into oil sump coating modified pitch is applied, 200 DEG C of application temperature, levels modified pitch coating is respectively 1mm；
Cooled down through the chill roll that rotating speed is 10rpm, extruding, pressure 0.6MPa；
Upper and lower surface covers PE films, then carries out cooling water cooling, sizing.
As a result detect：
Performance detection is carried out to embodiment 1-3 complex copper tire base root resistant waterproof roll,
Standard GB/T 18242-2008 is pressed in product waterproof property test《Elastomer modified asphalt waterproof roll》Test
Method is carried out；
The performance test of product root resistance uses JC/T 1075-2008《Planted roof root resistant waterproof roll》It is defined
Investigate the method progress whether root system of plant penetrates coiled material.
Its testing result is as shown in table 1：
Table 1：
From table 1, elongation percentage of the present invention is high, and Longitudinal extending rate is 50~65%, extends laterally rate as 56~69%；This hair
Bright heat-resist, 105~125 DEG C drip without trickling；Low temperature flexibility is good, -25~-35 DEG C of flawlesses；Longitudinal pulling force be 1088~
1396N/50mm, lateral pull are 1195~1438N/50mm；Impermeability is 0.3MPa, and 30~90min is waterproof；Resistance to is worn
Thorn performance is good, and test result is shown, root system of plant does not penetrate waterproof roll of the present invention.
Embodiment 2 is preferred embodiment, and its longitudinal pulling force is 1396N/50mm, and lateral pull is 1438 N/50mm, longitudinal direction
Elongation percentage is 65%, extends laterally rate as 69%.
It should be noted that above three embodiment describes to the preferred forms of the present invention, it is obvious that at this
Any change made under the inventive concept of invention should all be fallen within the scope of protection of the present invention.
Claims (4)
- A kind of 1. high extension copper tire base root resistant waterproof roll, it is characterised in that：The waterproof roll is multi-layer compound structure, Including intermediate layer and modified pitch coating；Described intermediate layer is complex copper tire based nonwoven, and the upper and lower surface of complex copper tire based nonwoven scribbles modified pitch painting Layer；The each component of the modified pitch coating, in terms of mass parts, content is：100 parts of matrix pitch, 5~20 parts of softening agent, 8~26 parts of modifying agent, extension 5~15 parts of accelerator, antioxidant 0.1~ 0.5 part, 0.1~1 part of propanoate ester derivatives Preventol B2；Described softening agent is one or more of combinations in naphthenic oil, aromatic naphtha, paraffin oil, machine oil, rubber oil；Described modifying agent is SBS, styrene-isoprene-phenylethene block is total to One or more of combinations in polymers, butadiene-styrene rubber, APP, APAO；Described extension accelerator is one or more of in oil-extended styrene buadiene rubber, oil-extended butadiene rubber, oil-filled isoprene rubber Combination；The complex copper tire based nonwoven：Longitudinal extending rate >=40%, extend laterally rate >=40%, thickness 2mm.
- 2. a kind of preparation method of high extension copper tire base root resistant waterproof roll according to claim 1, its feature exist In：Including feeding, modified pitch, forming step is made.
- 3. a kind of preparation method of high extension copper tire base root resistant waterproof roll according to claim 2, its feature exist In：Described obtained modified pitch step：It is 120~180 DEG C to control whipping temp, and speed of agitator is 60~120rpm.
- 4. a kind of preparation method of high extension copper tire base root resistant waterproof roll according to claim 2, its feature exist In：Described forming step：The preimpregnation temperature of complex copper tire based nonwoven is 180~200 DEG C；The application temperature of modified pitch is 180~200 DEG C, and levels modified pitch coating is respectively 0.8~1.2mm；Chill roll rotating speed is 5~10rpm, and the pressure of extruding is 0.3~0.6MPa.
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| CN201510960156.9A CN105603771B (en) | 2015-12-21 | 2015-12-21 | A kind of high extension copper tire base root resistant waterproof roll and preparation method thereof |
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| CN106118478B (en) * | 2016-08-27 | 2018-10-23 | 潍坊市宏源防水材料有限公司 | Meltable uncured rubber asphalt waterproof coating of one kind and preparation method thereof |
| CN110467904B (en) * | 2019-08-14 | 2021-05-11 | 广东万泓九鼎石油科技有限公司 | Rubber oil for producing modified asphalt waterproof coiled material and preparation method thereof |
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| CN101781469A (en) * | 2009-12-08 | 2010-07-21 | 重庆市智翔铺道技术工程有限公司 | Polymer composite modified asphalt |
| CN103726617A (en) * | 2013-12-20 | 2014-04-16 | 葛加君 | Building roof afforestation three-layer root thorn precontrol method |
| CN104060775A (en) * | 2014-07-08 | 2014-09-24 | 云南欣城防水科技有限公司 | Composite root-penetration-resistant waterproof roll for planted roof and preparation method thereof |
| CN104553170A (en) * | 2014-12-24 | 2015-04-29 | 锦州东方雨虹建筑材料有限责任公司 | Root-resistant waterproof coiled material and preparation method thereof |
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2015
- 2015-12-21 CN CN201510960156.9A patent/CN105603771B/en active Active
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|---|---|---|---|---|
| CN101781469A (en) * | 2009-12-08 | 2010-07-21 | 重庆市智翔铺道技术工程有限公司 | Polymer composite modified asphalt |
| CN103726617A (en) * | 2013-12-20 | 2014-04-16 | 葛加君 | Building roof afforestation three-layer root thorn precontrol method |
| CN104060775A (en) * | 2014-07-08 | 2014-09-24 | 云南欣城防水科技有限公司 | Composite root-penetration-resistant waterproof roll for planted roof and preparation method thereof |
| CN104553170A (en) * | 2014-12-24 | 2015-04-29 | 锦州东方雨虹建筑材料有限责任公司 | Root-resistant waterproof coiled material and preparation method thereof |
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Address after: 262735 Taitou Town, Shouguang City, Weifang City, Shandong Province, 2000 meters west of the government Patentee after: HONGYUAN WATERPROOF TECHNOLOGY GROUP Co.,Ltd. Address before: 262735 Taitou Town, Shouguang City, Weifang City, Shandong Province, 2000 meters west of the government Patentee before: WEIFANG HONGYUAN WATERPROOF MATERIAL Co.,Ltd. |
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Denomination of invention: A high elongation copper based root puncture resistant waterproof roll material and its preparation method Effective date of registration: 20230829 Granted publication date: 20180403 Pledgee: Shandong Shouguang Rural Commercial Bank Co.,Ltd. Pledgor: HONGYUAN WATERPROOF TECHNOLOGY GROUP Co.,Ltd. Registration number: Y2023980054251 |