CN109275660A - The preparation method of honey white-out agent - Google Patents
The preparation method of honey white-out agent Download PDFInfo
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- CN109275660A CN109275660A CN201811016991.7A CN201811016991A CN109275660A CN 109275660 A CN109275660 A CN 109275660A CN 201811016991 A CN201811016991 A CN 201811016991A CN 109275660 A CN109275660 A CN 109275660A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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Abstract
The invention discloses the preparation methods of honey white-out agent, it is prepared including vegetable oil pre-polymerization preparation, honey propolis liquid, plant extracts preparation, white-out agent preparation, wherein, vegetable oil pre-polymerization preparation step are as follows: take linseed oil, Vegetable Oils, turpentine oil, rosin, alchlor, tetrahydrofuran to be uniformly mixed, heating, sufficiently natural cooling after reaction, vegetable oil prepolymer is obtained, it is spare.Have the beneficial effect that the present invention prepares white-out agent using vegetable oil prepolymer and titanium dioxide slurry for the first time, made white-out agent adhesive force is strong, infiltration film forming, it is not easy to lose powder, crack, stem respiration is not influenced, pH neutral, traditional white-out agent is easily outer to be stuck up for solving, it falls off, exacerbation root soil salinization and alkalization and problem that cannot be mixed with Basic pesticides are avoided.The present invention provides a kind of new method and thinking for white-out agent preparation.
Description
Technical field
The present invention relates to field of tree protection, more particularly, to the preparation method of honey white-out agent.
Background technique
The benefit of tree whitening: 1) frost damage prevention and day burn, and avoid early spring frostbite.After entering the winter, day and night temperature is big, daytime tree
Dry sunny slope is irradiated by sunlight, and temperature is higher, and cortex absorbs high fever, and the cortical cell full of moisture is made to thaw, and has been arrived at night,
Temperature reduces, and cortical cell freezes again, this cold heat, can be by cortical cell frostbite, trunk cortex bursting by freezing.Apply dry-cure
Afterwards, due to white-out agent white can reflected sunlight, so that trunk is kept stable lower temperature, allow trunk cortical cell not
Reason is to occur violent temperature change and frostbite.2) insect killing and preventing kills and sets intracutaneous overwintering worm's ovum and the dry insect of moth.Due to
Pest generally all likes black, dirty place, does not like white, clean place.After trunk whitewashing, the pest in soil is just
It dare not climb on tree and endanger along trunk, also bark can be prevented by animal bites such as muroids.3) it sterilizes, prevents germ from infecting,
And accelerating wound healing.
Traditional white-out agent ingredient is added small part copper sulphate or lime sulfur etc. and is contained active element sulphur object based on lime
Matter is aided with salt, washing powder etc. and is made into.The shortcomings that traditional white-out agent: 1) winter tree deciduous leaf after rely primarily on trunk barks into
Row ventilating, after traditional white-out agent is whitewashed, so that the part trunk is not easy ventilating, to influence the life of trees second year
It is long；2) since white lime accounting is 80% or more, causing traditional white-out agent is in strong basicity, and pH value is 10 or so.By wind
After exposing to the sun and rain, traditional white-out agent is easy to fall off, and into soil, is changed soil ph, is caused soil hardening serious；And by
, cannot be mixed with Basic pesticides are avoided in the strong basicity property of traditional white-out agent itself, otherwise drug effect can be made to reduce, or even can lose
Effect；3) traditional white-out agent is there are unstable quality, poor adhesive force, attachment time short problem, thus it is annual need to apply twice, it is time-consuming
Arduously.Moreover, color at coating is not white if coating is too thin, reflection action is not played, if too thick, coating is outer after air-drying
Stick up, crack, be easy to fall off, do not have burn anti-day, the effect of worm is controlled in frost damage prevention, sterilization；4) traditional white-out agent is ready-to-use, cannot
It saves, disposably cannots be used up, raw material is caused largely to waste, and endanger soil ph.
Therefore, the today for increasingly paying attention to environmental protection in people, develop it is a kind of can be reserved for, adhesive force is strong, waterproof, resistance to
Wait, be ventilative, sterilization, insect prevention, neutrality, environmental protection white-out agent seem particularly significant.
The prior art such as Authorization Notice No. is the Chinese invention patent of CN 105053006B, discloses a kind of ancient and famous trees
With neutral white-out agent and preparation method thereof, destruction soil ph of the existing technology is solved the problems, such as.By by polyethylene
1788 powder of alcohol, white pigment powder, aluminium-magnesium silicate suspension aids, 80% water be added a mixing bowl in, be stirred until homogeneous with blender
State adds Hollow Glass Sphere powder, is stirred until homogeneous state, finally cleans stirring casing wall and shaft with remaining water, then use
Blender is stirred until homogeneous state and both obtained.But the white-out agent sterilization and insect prevention effect is not strong, and not ventilative enough.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental protection using vegetable oil prepolymer and nano-titanium dioxide preparation is neutral
Honey white-out agent preparation method, provide a kind of new thinking for the preparation of white-out agent, white-out agent obtained can save for a long time,
Rate of drying is fast, and adhesive force is strong, water-proof climate resisting, is not easy to lose powder, crack, and infiltration film forming does not influence stem respiration.
The present invention in view of the above technology in the problem of mentioning, the technical solution taken are as follows:
The preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts system
Standby, white-out agent preparation, specific steps are as follows:
Vegetable oil pre-polymerization preparation: taking linseed oil, Vegetable Oils, turpentine oil, rosin, alchlor, tetrahydrofuran, mixes
Uniformly, it is heated to 120-130 DEG C, removes wherein moisture, then nitrogen protection, sufficiently reaction, natural cooling is heated and obtains vegetable oil
Prepolymer, it is spare；The vegetable oil such as linseed oil are unsaturated fatty acid, under hot conditions, it may occur that tautomerization, to send out
Raw conjugate addition reaction, alchlor and tetrahydrofuran collective effect make aluminium ion in alchlor provide hydridization unoccupied orbital, from
And the electronics of unsaturated fatty acid conjugated double bond offer is provided, accelerate the polyaddition reaction of unsaturated fatty acid, promotes polymerization
The generation of object oil film is unlikely to deteriorate the oil film of polymerization, to increase the holding time of white-out agent, allows to save for a long time；
The preparation of honey propolis liquid: by weight, taking 100 parts of original hair glue, is impregnated twice, is closed with 60~80% ethyl alcohol
And soak, ice bath cooling are added 0.02-0.2 parts of acetic acid, stand, and are filtered to remove lead precipitating, and 5-15 parts of honey, mixing is added
Uniformly, it is concentrated into the 1/10-1/5 of original volume, it is spare；
Plant extracts preparation: plant is cleaned, baking oven drying, bruisher coarse crushing, Ultra-Micro Grinding Equipment crushing granulating
The alcohol of urea, formic acid amidoxime, 50-70% is added in the Ultramicro-powder of diameter≤12 μm, impregnates, ultrasonic extraction, filtering, and supernatant is dense
Contracting, obtains plant extracts, spare；The presence of urea and formic acid amidoxime, can with permeation cell wall, by hydrogen bond, Van der Waals force,
The chemical affinities such as electrostatic attraction destroy cell wall and membrane structure, cooperate swelling, decomposition of the ethanol solution to cell,
To change cell wall and permeability of cell membranes, promote the release of intracellular protein, antibacterial material, while cooperateing with Ultramicro-powder
Cavitation, the shear action of broken Mechanical Crushing effect and ultrasonic wave, mutual cooperative gain greatly destroy the cell of plant cell
Wall, and accelerate the movement of intracellular molecules, promote antibacterial insect killing substance in cell to discharge and dissolve in the solution, improves antibacterial and kill
The recovery rate of worm substance；
White-out agent preparation: taking 3-5 parts of beeswax, 1-3 parts of Brazil wax, in 50-70 DEG C of stirring and dissolving, is uniformly mixed；Add
Enter 30-50 parts of vegetable oil prepolymer, 5-15 parts of honey propolis liquid, then titanium dioxide slurry 10- is added in 40-60 DEG C of stirring 15-30min
30 parts, 5-15 parts of plant extracts, 15-30min is stirred, stops heating, nickel formate 0.1-0.5 parts, oleic acid cerium 0.1-0.5 is added
Part, it cools down, is dispensed after cooling down completely while stirring, honey white-out agent is made；In white-out agent, the rate of drying of oil film is very heavy
It wants, dry is too slow, is unfavorable for smearing, also easily reduces whiteness in surface adhesion impurity, to damage the function of white-out agent, system
Middle addition oleic acid cerium and nickel formate, trivalent cerium ion, bivalent nickel ion outer electronic structure be easy to lose 1 electronics and become four
Valence cerium ion, trivalent nickel ion can participate in the curing reaction of vegetable oil prepolymer, promote the oxidation of vegetable oil prepolymer and gather
It closes, to accelerate the rate of drying of white-out agent film.
Preferably, in the preparation of vegetable oil prepolymer, each raw material composition are as follows: by weight, 40-55 part of linseed oil, normal
See 10-20 parts of vegetable oil, 15-25 parts of turpentine oil, 15-25 parts of rosin, 0.5-5 parts of alchlor, 5-15 parts of tetrahydrofuran；Flax
Oil is a kind of drying oil, that is, dry very fast after brushing, light specific gravity, glossiness are good, can penetrate into trees surface layer, adhesive force is strong, it is heat-resisting,
Acidproof, waterproof, anti-corrosion form one layer of bright oil film in ebon wood surface after doing, to play the role of closed protection；It plants
Object oil reduces cost, while enhancing the weatherability and durability of oil plant；The dissolubility that turpentine oil has had, can be by several oil plants
Together, rosin is a kind of natural resin for dissolution, is soluble in turpentine oil, and rosin is added, and not only improves the brightness of oil film, even more
The good adhesive of each component in oil plant, to further improve heat resistance, waterproofness and the adhesive force of oil film.
Further preferably, the reaction system of vegetable oil prepolymer preparation needs nitrogen protection, reaction temperature 180-250
DEG C, reaction time 4-6h.
Still more preferably, Vegetable Oils are maize germ oil, peanut oil, soybean oil, sunflower oil, cottonseed oil, dish
One or more of seed oil.
Preferably, in plant extracts preparation step, each raw material composition are as follows: 100 parts of plant, 5-15 parts of urea, formic acid
400-600 parts of alcohol of 5-15 parts of amidoxime, 50-70%, soaking time 12-24h, ultrasonic time 0.5-1.5h, ultrasound temperature
Degree is 40-60 DEG C.
Further preferably, it is China tree, tree-of-heaven, castor-oil plant, radix euphorbiae lantu, datura, black false hellebore, Huang that plant extracts, which prepares plant used,
One or more of flower wormwood artemisia, aloe, lemon seed, shaddock seed, purple perilla, gleditsia sinensis；In China tree containing there are many alkaloid, salt algae sugar,
Camellia phenol etc. contains castor oil and castor-oil plant containing saponin, Zhuo Ning, essential oil, quercitrin flavone etc. in tree-of-heaven in castor seeds
Alkali, branches and leaves contain hydrogen cyanide, and radix euphorbiae lantu whole body contains various plants alkali, contains hyoscine, hyoscyamine, atropine etc. in datura
A variety of alkaloids, black false hellebore contain jervine, and artemisia annua contains by saturating alcohol, absinth ketone, different absinth ketone etc., and lemon seed, shaddock seed contain
Limonin contains saponin in gleditsia sinensis, and tinctura aloes are contained in aloe, contains perilla leaf anthocyanin in purple perilla, perillaldehyde etc., these
Substance or the very strong substance of antibiotic property have and kill fungi, mould, bacterium, virus, inhibit and the development of eliminating pathogen is numerous
The effects of growing, or desinsection, deinsectization can be played the role of, to protect infringement of the plant not by microorganism and pest.
Preferably, titanium dioxide slurry is that nano-titanium dioxide sand milling is made, and partial size is between 30-50nm in white-out agent preparation.
Compared with the prior art, the advantages of the present invention are as follows: the present invention under crude vegetal high temperature through alchlor to urge
Metaplasia can penetrate into trees surface layer at plant oil polymer, polymer oil film, and adhesion strength is strong, accelerate through methyl nickel, oleic acid cerium
After air-drying, fixed force is stronger, and white-out agent can be made firmly to be adhered to bark surface, and no matter thickness is not easily to fall off when smearing.
The present invention uses plant extracts and honey propolis liquid as antibacterial insecticidal constituent, the spy to form a film by vegetable oil polymer penetration
Point can make timber have ventilative, dry, waterproof, the excellent performances such as insect prevention；The present invention uses nano-titanium dioxide, obtained
White-out agent color is pure white, and the duration is long, need to only brush within 1 year it is primary, it is saving of labor, time saving.Honey white-out agent produced by the present invention can
Sealed cans save for a long time, and it is ready-to-use to solve traditional white-out agent, wasting disadvantage.The present invention uses vegetable oil pre-polymerization for the first time
Raw material of the object as white-out agent, white-out agent obtained is neutral, solves the disadvantage that cause alkalization of soils after traditional white-out agent falls off,
A kind of new method and thinking are provided for the preparation of white-out agent.
Specific embodiment
The present invention program is described further below by embodiment:
Embodiment 1:
The preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts system
Standby, white-out agent preparation, specific steps are as follows:
1) vegetable oil pre-polymerization: by weight, 47 parts of linseed oil, 15 parts of Vegetable Oils, 18 parts of turpentine oil, rosin 20 are taken
Part, 2 parts of alchlor 10 parts of tetrahydrofuran, are mixed and heated to 125 DEG C, remove wherein moisture, are then heated to 210 DEG C, reaction
5h, natural cooling obtain vegetable oil prepolymer, spare；The vegetable oil such as linseed oil are unsaturated fatty acid, under hot conditions, can be sent out
Raw tautomerization, so that conjugate addition reaction occur, alchlor and tetrahydrofuran collective effect make aluminium in alchlor
Ion provides hydridization unoccupied orbital, to receive the electronics of unsaturated fatty acid conjugated double bond offer, accelerates unsaturated fatty acid
Polyaddition reaction promotes the generation of polymer oil film, is unlikely to deteriorate the oil film of polymerization, thus when increasing the preservation of white-out agent
Between, allow to save for a long time；
2) prepared by honey propolis liquid: by weight, taking 100 parts of original hair glue, is impregnated twice, merged with 70% ethyl alcohol
Soak, ice bath cooling, is added 0.05 part of acetic acid, stands, and is filtered to remove lead precipitating, 10 parts of honey are added, be uniformly mixed, concentration
It is spare to the 1/10 of original volume；
3) prepared by plant extracts: taking 100 parts of plant to clean, baking oven drying, bruisher coarse crushing, Ultra-Micro Grinding Equipment powder
It is broken into the Ultramicro-powder of partial size≤12 μm, 15 parts of urea, 5 parts of formic acid amidoxime, 600 parts of alcohol of 70% is added, impregnate 12h, 50 DEG C
Under, ultrasonic extraction 1h, filtering, supernatant concentration obtains plant extracts, spare；The presence of urea and formic acid amidoxime can permeate
Cell wall destroys cell wall and membrane structure by chemical affinities such as hydrogen bond, Van der Waals force, electrostatic attractions, cooperates second
Swelling, decomposition of the alcoholic solution to cell, thus change cell wall and permeability of cell membranes, promotion intracellular protein,
The release of antibacterial material, while the Mechanical Crushing of ultramicro grinding being cooperateed with to act on cavitation, shear action with ultrasonic wave, mutually cooperate with
Gain, greatly destroys the cell wall of plant cell, and accelerates the movement of intracellular molecules, promotes antibacterial insect killing substance in cell
It discharges and dissolves in the solution, improve the recovery rate of antibacterial insect killing substance；
4) prepared by white-out agent: taking 3 parts of beeswax, 3 parts of Brazil wax, in 70 DEG C of stirring and dissolvings, is uniformly mixed；Plant is added
Then 30 parts of oily prepolymer, 15 parts of honey propolis liquid, 50 DEG C of stirring 15min are added 30 parts of titanium dioxide slurry, 5 parts of plant extracts, stir
30min is mixed, heating is stopped, nickel formate 0.1,0.1 part of oleic acid cerium is added, cools down while stirring, is dispensed after cooling down completely, is made
Honey white-out agent；In white-out agent, the rate of drying of oil film is extremely important, and dry is too slow, is unfavorable for smearing, also easily in surface adhesion
Impurity and reduce whiteness, oleic acid cerium and nickel formate, trivalent cerium ion, divalent are added to damage the function of white-out agent, in system
The outer electronic structure of nickel ion, which is easy to lose 1 electronics, becomes tetravalence cerium ion, trivalent nickel ion, can participate in vegetable oil pre-polymerization
The curing reaction of object promotes the oxidation and polymerization of vegetable oil prepolymer, to accelerate the rate of drying of white-out agent film；Beeswax and
The alkali resistance and tolerable temperature of white-out agent can be improved in Brazil wax；Antimicrobial component there are many containing in honey propolis liquid, also has
There is certain insect prevention effect, plant extracts has sterilization and disinsection effect, and honey propolis liquid and plant extracts act synergistically, mention
The sterilization and insect prevention of high white-out agent acts on；Nano titanium dioxide is in neutrality, itself has bactericidal effect, is sanded through sand mill to thin
≤ 50 μm of degree, the fine dispersion in vegetable oil prepolymer greatly increases the whiteness and brightness of white-out agent, prevents trees disease pest
Evil.
On November 1st, 2017 uses 100 plants of trees of the honey white-out agent brushing in Zhejiang Linan area, and trunk brushes thickness
It is 30-100 μm, in mid-June, 2018 checks, without sticking up outside, falling phenomenon, trunk part is existing without insect pest for all trunk whitewashing agent
As.
Embodiment 2:
The preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts system
Standby, white-out agent preparation, specific steps are as follows:
1) vegetable oil pre-polymerization: by weight, 40 parts of linseed oil, 20 parts of Vegetable Oils, 20 parts of turpentine oil, rosin 20 are taken
Part, 0.5 part of alchlor 5 parts of tetrahydrofuran, are mixed and heated to 120 DEG C, remove wherein moisture, be then heated to 180 DEG C, instead
4h is answered, natural cooling obtains vegetable oil prepolymer, spare；
2) prepared by honey propolis liquid: by weight, taking 100 parts of original hair glue, is impregnated twice, merged with 75% ethyl alcohol
Soak, ice bath cooling, is added 0.08 part of acetic acid, stands, and is filtered to remove lead precipitating, 10 parts of honey are added, be uniformly mixed, concentration
It is spare to the 1/10 of original volume；
3) prepared by plant extracts: taking 100 parts of plant to clean, baking oven drying, bruisher coarse crushing, Ultra-Micro Grinding Equipment powder
It is broken into the Ultramicro-powder of partial size≤12 μm, 10 parts of urea, 10 parts of formic acid amidoxime, 500 parts of alcohol of 60% is added, impregnate 20h, 50 DEG C
Under, ultrasonic extraction 1h, filtering, supernatant concentration obtains plant extracts, spare；
4) prepared by white-out agent: taking 4 parts of beeswax, 2 parts of Brazil wax, in 60 DEG C of stirring and dissolvings, is uniformly mixed；Plant is added
40 parts of oily prepolymer, 10 parts of honey propolis liquid, 50 DEG C of stirring 30min, then 20 parts of titanium dioxide slurry of addition, 10 parts of plant extracts,
30min is stirred, heating is stopped, 0.3 part of nickel formate, 0.3 part of oleic acid cerium is added, cools down while stirring, is dispensed after cooling down completely,
Honey white-out agent is made.
On November 1st, 2017 uses 100 plants of trees of the honey white-out agent brushing in Zhejiang Linan area, and trunk brushes thickness
It is 100-200 μm, in mid-June, 2018 checks, all trunk whitewashing agent are without sticking up outside, falling phenomenon, and trunk part is without insect pest
Phenomenon.
Embodiment 3:
The preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts system
Standby, white-out agent preparation, specific steps are as follows:
1) vegetable oil pre-polymerization: by weight, 55 parts of linseed oil, 10 parts of Vegetable Oils, 15 parts of turpentine oil, rosin 20 are taken
Part, 5 parts of alchlor 15 parts of tetrahydrofuran, are mixed and heated to 130 DEG C, remove wherein moisture, are then heated to 250 DEG C, reaction
6h, natural cooling obtain vegetable oil prepolymer, spare；
2) prepared by honey propolis liquid: by weight, taking 100 parts of original hair glue, is impregnated twice, merged with 75% ethyl alcohol
Soak, ice bath cooling, is added 0.02 part of acetic acid, stands, and is filtered to remove lead precipitating, 5 parts of honey are added, be uniformly mixed, concentration
It is spare to the 1/10 of original volume；
3) prepared by plant extracts: taking 100 parts of plant to clean, baking oven drying, bruisher coarse crushing, Ultra-Micro Grinding Equipment powder
It is broken into the Ultramicro-powder of partial size≤12 μm, 5 parts of urea, 5 parts of formic acid amidoxime, 400 parts of alcohol of 50% is added, impregnate 12h, 40 DEG C
Under, ultrasonic extraction 0.5h, filtering, supernatant concentration obtains plant extracts, spare；
4) prepared by white-out agent: taking 3 parts of beeswax, 1 part of Brazil wax, in 50 DEG C of stirring and dissolvings, is uniformly mixed；Plant is added
Then 30 parts of oily prepolymer, 5 parts of honey propolis liquid, 40 DEG C of stirring 15min are added 10 parts of titanium dioxide slurry, 5 parts of plant extracts, stir
15min is mixed, heating is stopped, 0.1 part of nickel formate, 0.1 part of oleic acid cerium is added, cools down while stirring, is dispensed after cooling down completely, is made
Obtain honey white-out agent.
On November 1st, 2017 uses 100 plants of trees of the honey white-out agent brushing in Zhejiang Linan area, and trunk brushes thickness
It is 50-150 μm, in mid-June, 2018 checks, without sticking up outside, falling phenomenon, trunk part is existing without insect pest for all trunk whitewashing agent
As.
Embodiment 4:
The preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts system
Standby, white-out agent preparation, specific steps are as follows:
1) vegetable oil pre-polymerization: by weight, 47 parts of linseed oil, 15 parts of Vegetable Oils, 18 parts of turpentine oil, rosin 20 are taken
Part, 2 parts of alchlor 10 parts of tetrahydrofuran, are mixed and heated to 125 DEG C, remove wherein moisture, are then heated to 210 DEG C, reaction
5h, natural cooling obtain vegetable oil prepolymer, spare；
2) prepared by honey propolis liquid: by weight, taking 100 parts of original hair glue, is impregnated twice, merged with 80% ethyl alcohol
Soak, ice bath cooling, is added 0.2 part of acetic acid, stands, and is filtered to remove lead precipitating, 15 parts of honey are added, be uniformly mixed, concentration
It is spare to the 1/5 of original volume；
3) prepared by plant extracts: taking 100 parts of plant to clean, baking oven drying, bruisher coarse crushing, Ultra-Micro Grinding Equipment powder
It is broken into the Ultramicro-powder of partial size≤12 μm, 15 parts of urea, 15 parts of formic acid amidoxime, 600 parts of alcohol of 70% is added, impregnates for 24 hours, 60 DEG C
Under, ultrasonic extraction 1.5h, filtering, supernatant concentration obtains plant extracts, spare；
4) prepared by white-out agent: taking 5 parts of beeswax, 3 parts of Brazil wax, in 70 DEG C of stirring and dissolvings, is uniformly mixed；Plant is added
Then 30 parts of oily prepolymer, 15 parts of honey propolis liquid, 40 DEG C of stirring 15min are added 30 parts of titanium dioxide slurry, 5 parts of plant extracts, stir
30min is mixed, heating is stopped, 0.2 part of nickel formate, 0.2 part of oleic acid cerium is added, cools down while stirring, is dispensed after cooling down completely, is made
Obtain honey white-out agent.
In November, 2017, the walnut of Linan base autumn plant are overwintering, cold-proof to carry out trunk painting using traditional white-out agent
Brush, the tradition white-out agent are tested with pH test paper, pH value 10, and appearance is outer after the wheat harvesting period time sticks up, obscission, after 3 months,
Most of white-out agent falls off, and usage tree root soil hardening is serious, and traditional white-out agent needs are respectively brushed once in annual spring, autumn；
After the honey white-out agent brushing of this formula, the duration is long, can continue to that coming year bud in April is sprouted, only need to apply every year
Brush is primary, and does not influence trees soil environment, is conducive to the holding for setting edaphon greatly, and breathe freely, and does not influence to set greatly thin
Born of the same parents' breathing, it is healthy of great advantage to big tree is kept, while adhesion is good, no matter smearing thickness, equal color is pure white, does not fall after rain
Color, it is not outer to stick up, it does not fall off.
Routine operation in operating procedure of the invention is well known to those skilled in the art, herein without repeating.
Technical solution of the present invention is described in detail in embodiment described above, it should be understood that the above is only
For specific embodiments of the present invention, it is not intended to restrict the invention, all any modifications made in spirit of the invention,
Supplement or similar fashion substitution etc., should all be included in the protection scope of the present invention.
Claims (10)
1. the preparation method of honey white-out agent, including vegetable oil pre-polymerization preparation, the preparation of honey propolis liquid, plant extracts preparation,
White-out agent preparation, it is characterised in that: the vegetable oil pre-polymerization preparation step are as follows: take linseed oil, Vegetable Oils, turpentine oil, pine
Perfume, alchlor, tetrahydrofuran are uniformly mixed, heating, sufficiently natural cooling after reaction, obtain vegetable oil prepolymer, spare.
2. the preparation method of honey white-out agent according to claim 1, it is characterised in that: each original of vegetable oil prepolymer
Material composition are as follows: by weight, 40-55 parts of linseed oil, 10-20 parts of Vegetable Oils, 15-25 parts of turpentine oil, rosin 15-25
Part, 0.5-5 parts of alchlor, 5-15 parts of tetrahydrofuran.
3. the preparation method of honey white-out agent according to claim 1, it is characterised in that: the vegetable oil prepolymer step
In, reaction system needs nitrogen protection, and reaction temperature is 180-250 DEG C, reaction time 4-6h.
4. the preparation method of honey white-out agent according to claim 1, it is characterised in that: the Vegetable Oils are corn
Embryo oil, peanut oil, soybean oil, sunflower oil, cottonseed oil, one or more of rapeseed oil.
5. the preparation method of honey white-out agent according to claim 1, it is characterised in that: the honey propolis liquid preparation step
Suddenly are as follows: by weight, 100 parts of original hair glue are taken, impregnated twice with 60~80% ethyl alcohol, merges soak, ice bath cools down,
0.02-0.2 parts of acetic acid are added, stand, is filtered to remove lead precipitating, 5-15 parts of honey is added, be uniformly mixed, be concentrated into original volume
, spare.
6. the preparation method of honey white-out agent according to claim 1, it is characterised in that: the plant extracts preparation step
Suddenly are as follows: plant is cleaned, drying, coarse crushing, ultramicro grinding, the alcohol of urea, formic acid amidoxime, 50-70% is added, impregnate, surpass
Sound extracts, filtering, and supernatant concentration obtains plant extracts, spare.
7. the preparation method of honey white-out agent according to claim 6, it is characterised in that: the plant extracts preparation
In, each raw material group becomes 100 parts of plant, 5-15 part of urea, 5-15 parts of formic acid amidoxime, 400-600 parts of alcohol of 50-70%, soaks
The bubble time is 12-24h, and ultrasonic time 0.5-1.5h, ultrasonic temperature is 40-60 DEG C.
8. the preparation method of honey white-out agent according to claim 6, it is characterised in that: the plant extracts preparation step
In rapid, plant used is China tree, tree-of-heaven, castor-oil plant, radix euphorbiae lantu, datura, black false hellebore, artemisia annua, aloe, lemon seed, shaddock seed, purple
One or more of Soviet Union, gleditsia sinensis.
9. the preparation method of honey white-out agent according to claim 1, it is characterised in that: the white-out agent preparation step
Are as follows: 3-5 parts of beeswax, 1-3 parts of Brazil wax are taken, in 50-70 DEG C of stirring and dissolving, is uniformly mixed；Vegetable oil prepolymer 30- is added
Then 50 parts, 5-15 parts of honey propolis liquid, 40-60 DEG C of stirring 15-30min are added titanium dioxide slurry 10-30 parts, plant extracts 5-
15 parts, 15-30min is stirred, stops heating, nickel formate, 0.1-0.5 parts of oleic acid cerium is added, cools down while stirring, to completely cooling
After dispense, be made honey white-out agent.
10. the preparation method of honey white-out agent according to claim 9, it is characterised in that: the titanium dioxide slurry is nanometer two
Titanium oxide, which is sanded, to be made, and partial size is between 30-50nm.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109997881A (en) * | 2019-03-15 | 2019-07-12 | 泓森林业有限公司 | A kind of white-out agent of insect-pest |
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