CN108271810A - A kind of multi-functional trunk whitewashing agent - Google Patents
A kind of multi-functional trunk whitewashing agent Download PDFInfo
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- CN108271810A CN108271810A CN201810301515.3A CN201810301515A CN108271810A CN 108271810 A CN108271810 A CN 108271810A CN 201810301515 A CN201810301515 A CN 201810301515A CN 108271810 A CN108271810 A CN 108271810A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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Abstract
The invention discloses a kind of multi-functional trunk whitewashing agent, belong to seedling growth technical field.It counts, weighs successively in parts by weight：80~100 parts of quick limes,2~5 parts of sulphur,15~25 parts of No. 1 additives,10~20 parts of numbers additives,5~12 parts of polyacrylic acid zinc,5~8 parts of pretreatment Bacillus pasteuriis,3~8 parts of sodium chloride and 150~180 parts of water,It adds water in blender,After being heated to 70~80 DEG C,Quick lime is added into blender,Sulphur,Sodium chloride and water,In temperature be 85~90 DEG C,Under conditions of rotating speed is 200~300r/min,After being stirred 15~45min,Obtain blank,Blank and No. 1 additive are mixed in batch mixer,And No. 2 additives are added into batch mixer,Polyacrylic acid zinc and pretreatment Bacillus pasteurii,In temperature be 30~38 DEG C,Under conditions of rotating speed is 200~400r/min,After being stirred 20~60min,Obtain the dry-coated white agent of Multifunctional tree.The multi-functional trunk whitewashing agent of gained of the invention has burn excellent resistance to day effect and resistance to jelly effect.
Description
Technical field
The invention discloses a kind of multi-functional trunk whitewashing agent, belong to seedling growth technical field.
Background technology
Trunk whitewashing refers to being whitewashed butt with the mixed liquor of quick lime, water, salt, sticker and lime sulfur
Process.The purpose is to prevent germ from infecting, sterilization, desinsection, insect prevention and other effects are played.Trunk whitewashing is cities and towns Urban Landscape Construction
In very important important link.Common trunk whitewashing method is lime sulfur quick lime white-out agent and novel trunk whitewashing
Agent.
In winter and early spring, greatly due to day and night temperature variation, tree body is easy to happen " day burning " and frostbite, many all into
Row whitewashes processing, i.e., the brush last layer white-out agent on trunk and major branch is whitewashed and had the benefit that：Tree whitening can effectively be prevented
The only freeze injury of winter fruit tree, because white has reflection action, heat absorption is few, and fruit tree will not be because temperature drastic change round the clock be by apparent shadow
Ring, can prevent and mitigate day burn, freeze injury；Fruit tree can also prevent germ from invading after whitewashing, because lime have certain sterilization, kill
Worm acts on, and can kill some overwintering fungies, bacterium and the pest colonized on trunk；Fruit tree whitewashes to eliminate and reside in
Overwintering pest on ornamental trees and shrubs reduces overwintering worm sources, carries because pest dare not climb to overwintering in soil along the trunk whitewashed
The disease resistance of high fruit tree, and the hibernacle of disease pest can also be destroyed, play a dual role of not only antifreeze but also desinsection, especially
The effects that overwintering mite class in bark, a red-spotted lizard class it is further preferred that；Tree whitening seems neat pure white, can also play beautification function.
The tree whitening agent being commonly used, if coating is too thin, the color at coating is not white, does not play reflective work
With, if too thick, coating cracks after air-drying, and sticks up outside, and coating is easy to fall off, adheres to that the time is short, do not have burn long-term anti-day,
Frost damage prevention, sterilization control the effect of worm.For traditional tree whitening agent at present there is also burn effect and resistance to jelly effect resistance to day not
Good problem, there is an urgent need for develop the good white-out agent of a kind of easy to use and effect.
Invention content
The present invention solves the technical problem of：It is ineffective for bright effect of traditional trees white-out agent resistance to day and resistance to jelly
The problem of, provide a kind of multi-functional trunk whitewashing agent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of multi-functional trunk whitewashing agent, is made of the raw material of following parts by weight：
80~100 parts of quick lime
2~5 parts of sulphur
No. 1 15~25 parts of additive
No. 2 10~20 parts of additives
5~12 parts of polyacrylic acid zinc
Pre-process 5~8 parts of Bacillus pasteurii
3~8 parts of sodium chloride
150~180 parts of water
The preparation method of No. 1 additive is：
By chitosan and acetum in mass ratio 1：50~1：60 mixing, and the fiber of 0.8~1.2 times of chitosan mass is added
Plain powder, is stirred, and obtains chitosan compound, and chitosan compound needle tubing is instilled hydroxide with the rate of 2~3mL/min
It in sodium mixed solution, cools and solidifies, filtering obtains chitosan microball；It will（N- amidino groups）Dodecylacrylamide and polyethylene glycol
Derivative in mass ratio 2：1~1：1 mixing, and the paracide of 0.1~0.2 times of polyethyleneglycol derivative quality and poly- second is added
The ferrocene that 0.08~0.12 times of diol, derivatives quality, is stirred, and obtains inorganic agent；Chitosan microball and inorganic agent are pressed into matter
Measure ratio 1：3~1：4 mixing, concentrated by rotary evaporation obtain No. 1 additive；
The preparation method of No. 2 additives is：
By linseed oil and gelatin solution in mass ratio 1：60~1：80 mixing, and the oxidation of 0.2~0.3 times of flax oil quality is added
Graphene mixture after being stirred, obtains mixed liquor, and the metabisulfite solution of 3~5 times of mixed liquor quality is added into mixed liquor,
After being stirred, cooling must pre-process blank liquid, by pretreatment blank liquid and formalin in mass ratio 80：1~120：1 is mixed
It closes, and adjusts the pH of pretreatment blank liquid and formalin mixture, obtain blank liquid, blank liquid is cured, filter washing, freezing
After drying, No. 2 additives are obtained；
The preparation method of the pretreatment Bacillus pasteurii is by Bacillus pasteurii and paraffin in mass ratio 1：3~1：4 is mixed
It closes, Freezing smashing obtains pretreatment Bacillus pasteurii.
The chitosan be deacetylation 80~90% chitosan compound, and the viscosity-average molecular weight of chitosan be 400~
480kDa。
The grain size of the cellulose powder is 5~20 μm.
The preparation method of the sodium hydroxide mixed solution be 20~30% by mass fraction sodium hydroxide and acetic acid second
Ester in mass ratio 80：1~100：1 mixing, obtains sodium hydroxide mixed solution.
The polyethyleneglycol derivative is any one in polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol salicylate
Kind.
The preparation method of the graphene oxide mixture is to mix graphene oxide with water, and adjust pH, and ultrasound is shaken
It swings, obtains graphene oxide mixture.
The beneficial effects of the invention are as follows：
（1）No. 1 additive is added in the present invention in multi-functional trunk whitewashing agent, and it is micro- to add chitosan first, in No. 1 additive
Ball, chitosan microball have porous structure, and the active ingredient that imitated vesicle structure is possessed after being mixed with inorganic agent, in inorganic agent can be with
Porous structure occurs to be fitted into, to which after being added in product, one layer of air layer can be formed on trunk surface layer after product use, from
And prevent heat diffusion and due to the presence of chitosan microball can block sunlight irradiation, and then make product that can effectively improve
The resistance to day of trees burns and freexing tolerance energy, secondly, cellulose is contained in chitosan microball, and in use, cellulose can be slow
Degradation, to generate water and carbon dioxide, the water of generation can further improve the performance of burning resistance to day of plant, and the titanium dioxide generated
Carbon can promote imitated vesicle structure to expand, to conducive to product falling off in the future；
（2）No. 2 additives are added in the present invention in multi-functional trunk whitewashing agent, on the one hand, use gelatin conduct in No. 2 additives
Wall material, gelatin is after wall material is made in crosslinking, after being added in hot water, and can hydrolyze, to make the linseed oil in external capsule be exposed to
In product, to improve the caking property of product, and after water evaporation, gelatin can provide viscosity, further increase the viscous of product
Knot property, on the other hand, in No. 2 additives adds graphene oxide mixture, it is dispersible in the product, improve the heat accumulation of product
Property, to make product further increase the freexing tolerance of plant, also, gelatin and cellulose can promote the numerous of Bacillus pasteurii
It grows, improves the yield of calcium carbonate, to make product can further improve the freexing tolerance of plant.
Specific implementation mode
By Bacillus pasteurii and paraffin in mass ratio 1：3~1：4 mixing, in temperature be 25~35 DEG C, rotating speed be 200~
After being stirred 30~40min under conditions of 300r/min, Freezing smashing obtains pretreatment Bacillus pasteurii；By chitosan with
The acetum in mass ratio 1 that mass fraction is 10~15%：50~1：60 are mixed in beaker, and shell is added into beaker and gathers
The cellulose powder that 0.8~1.2 times of saccharic amount is 45~50 DEG C in temperature, and rotating speed stirs mixed under conditions of being 200~300r/min
After closing 5~6h, chitosan compound is obtained, chitosan compound is instilled sodium hydroxide with needle tubing with the rate of 2~3mL/min to be mixed
It closes in solution, under conditions of being 2~12 DEG C in temperature after 10~12h of cooling and solidifying, filtering obtains chitosan microball；It will（N- amidines
Base）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 2：1~1：1 is mixed in flask, and adds into flask
Enter 0.1~0.2 times of polyethyleneglycol derivative quality paracide and 0.08~0.12 times of polyethyleneglycol derivative quality two
Luxuriant iron is 58~70 DEG C in temperature, after rotating speed is stirred 2~3h under conditions of being 230~300r/min, obtains inorganic agent；It will
Chitosan microball and inorganic agent in mass ratio 1：3~1：4 mixing obtain chitosan processing agent composition, chitosan inorganic agent are mixed
It is 55~65 DEG C that object, which is closed, in temperature, and rotating speed is 140~180r/min, under conditions of pressure is 500~600kPa, concentrated by rotary evaporation 2
After~3h, No. 1 additive is obtained；The gelatin solution in mass ratio 1 for being 3~5% by linseed oil and mass fraction：60~1：80 mixing,
And the graphene oxide mixture of 0.2~0.3 times of flax oil quality, Yu Wen are added into the mixture of linseed oil and gelatin solution
Degree is 45~65 DEG C, after rotating speed is stirred 1~2h under conditions of being 250~300r/min, obtains mixed liquor, adds into mixed liquor
Enter 3~5 times of mixed liquor quality mass fraction be 25~32% metabisulfite solution, in temperature be 25~30 DEG C, rotating speed 200
After being stirred 45~80min under conditions of~300r/min, the mixture of mixed liquor and metabisulfite solution is cooled to 10~
18 DEG C, blank liquid must be pre-processed, the formalin in mass ratio 80 that blank liquid and mass fraction are 35~38% will be pre-processed：1~
120：1 mixing, and the pH to 8.8~9.2 of pretreatment blank liquid and formalin mixture is adjusted, blank liquid is obtained, by blank liquid
Under conditions of being 10~15 DEG C in temperature after 40~50min of solidification, solidifying substance is obtained, solidifying substance is filtered and is washed, filter cake is obtained, will filter
After cake freeze-drying, No. 2 additives are obtained；It counts, weighs successively in parts by weight：80~100 parts of quick limes, 2~5 parts of sulphur, 15
~25 parts of No. 1 additives, 10~20 parts of numbers additives, 5~12 parts of polyacrylic acid zinc, 5~8 parts of pretreatment Bacillus pasteuriis, 3
~8 parts of sodium chloride and 150~180 parts of water, add water in blender, and after being heated to 70~80 DEG C, life is added into blender
Lime, sulphur, sodium chloride and water are 85~90 DEG C in temperature, under conditions of rotating speed is 200~300r/min, are stirred 15
After~45min, blank is obtained, blank and No. 1 additive are mixed in batch mixer, and No. 2 additives are added into batch mixer, is gathered
Zinc acrylate resin and pretreatment Bacillus pasteurii are 30~38 DEG C in temperature, under conditions of rotating speed is 200~400r/min, stir
After mixing 20~60min of mixing, the dry-coated white agent of Multifunctional tree is obtained.The chitosan is that the chitosan of deacetylation 80~90% mixes
Object, and the viscosity-average molecular weight of chitosan is 400~480kDa.The grain size of the cellulose powder is 5~20 μm.The sodium hydroxide
The preparation method of mixed solution be 20~30% by mass fraction sodium hydroxide and ethyl acetate in mass ratio 80：1~100：
1 mixing, obtains sodium hydroxide mixed solution.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol
Any one in salicylate.The preparation method of the graphene oxide mixture is to mix graphene oxide with water, and adjust
PH is saved, sonic oscillation obtains graphene oxide mixture.
Example 1
By Bacillus pasteurii and paraffin in mass ratio 1：4 mixing are 35 DEG C in temperature, and rotating speed stirs under conditions of being 300r/min
After mixing mixing 40min, Freezing smashing obtains pretreatment Bacillus pasteurii；The acetum for being 15% by chitosan and mass fraction
In mass ratio 1：60 are mixed in beaker, and into beaker be added 1.2 times of chitosan mass cellulose powder, in temperature be 50
DEG C, rotating speed be 300r/min under conditions of be stirred 6h after, obtain chitosan compound, by chitosan compound needle tubing with
The rate of 3mL/min instills in sodium hydroxide mixed solution, and under conditions of being 12 DEG C in temperature after cooling and solidifying 12h, filtering obtains
Chitosan microball；It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 1：1 is mixed in flask,
And be added into flask 0.2 times of polyethyleneglycol derivative quality paracide and 0.12 times of polyethyleneglycol derivative quality two
Luxuriant iron is 70 DEG C in temperature, after rotating speed is stirred 3h under conditions of being 300r/min, obtains inorganic agent；By chitosan microball with
Inorganic agent in mass ratio 1：4 mixing, obtain chitosan processing agent composition, by chitosan processing agent composition in temperature be 65 DEG C,
Rotating speed is that 180r/min after concentrated by rotary evaporation 3h, obtains No. 1 additive under conditions of pressure is 600kPa；By linseed oil and quality point
The gelatin solution in mass ratio 1 that number is 5%：80 mixing, and flax oil quality is added into the mixture of linseed oil and gelatin solution
0.3 times of graphene oxide mixture is 65 DEG C in temperature, after rotating speed is stirred 2h under conditions of being 300r/min, obtains mixed
Close liquid, the metabisulfite solution that the mass fraction of 5 times of mixed liquor quality is 32% be added into mixed liquor, in temperature be 30 DEG C, rotating speed
After being stirred 80min under conditions of 300r/min, the mixture of mixed liquor and metabisulfite solution is cooled to 18 DEG C, is obtained pre-
Blank liquid is handled, the formalin in mass ratio 120 that blank liquid and mass fraction are 38% will be pre-processed：1 mixing, and adjust pre-
The pH to 9.2 for handling blank liquid and formalin mixture, obtains blank liquid, cures under conditions of being 15 DEG C in temperature by blank liquid
After 50min, solidifying substance is obtained, solidifying substance is filtered and is washed, filter cake is obtained, after filter cake is freeze-dried, obtains No. 2 additives；By weight
Number meter, weighs successively：100 parts of quick limes, 5 parts of sulphur, 25 parts of No. 1 additives, 20 parts of numbers additives, 12 parts of polyacrylic acid
Zinc, 8 parts of pretreatment Bacillus pasteuriis, 8 parts of sodium chloride and 180 parts of water, add water in blender, after being heated to 80 DEG C, to
Quick lime, sulphur, sodium chloride and water are added in blender, is 90 DEG C in temperature, under conditions of rotating speed is 300r/min, stirring is mixed
After closing 45min, blank is obtained, blank and No. 1 additive are mixed in batch mixer, and No. 2 additives are added into batch mixer, gathered
Zinc acrylate resin and pretreatment Bacillus pasteurii are 38 DEG C in temperature, under conditions of rotating speed is 400r/min, are stirred
After 60min, the dry-coated white agent of Multifunctional tree is obtained.The chitosan is the chitosan compound of deacetylation 90%, and chitosan is glutinous
Average molecular weight is 480kDa.The grain size of the cellulose powder is 20 μm.The preparation method of the sodium hydroxide mixed solution is will
The sodium hydroxide that mass fraction is 30% and ethyl acetate in mass ratio 100：1 mixing, obtains sodium hydroxide mixed solution.It is described poly-
Ethylene glycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.The preparation method of the graphene oxide mixture is that will aoxidize stone
Black alkene is mixed with water, and adjusts pH, sonic oscillation, obtains graphene oxide mixture.
Example 2
The acetum in mass ratio 1 for being 15% by chitosan and mass fraction：60 are mixed in beaker, and are added into beaker
The cellulose powder that 1.2 times of chitosan mass is 50 DEG C in temperature, after rotating speed is stirred 6h under conditions of being 300r/min, obtains
Chitosan compound is instilled chitosan compound needle tubing in sodium hydroxide mixed solution with the rate of 3mL/min, in temperature
After cooling and solidifying 12h under conditions of being 12 DEG C, filtering obtains chitosan microball；It will（N- amidino groups）Dodecylacrylamide with it is poly-
Ethylene glycol derivative in mass ratio 1：1 is mixed in flask, and pair of 0.2 times of polyethyleneglycol derivative quality is added into flask
The ferrocene of 0.12 times of dichloro-benzenes and polyethyleneglycol derivative quality is 70 DEG C in temperature, and rotating speed is under conditions of 300r/min
After being stirred 3h, inorganic agent is obtained；By chitosan microball and inorganic agent in mass ratio 1：4 mixing obtain the mixing of chitosan inorganic agent
Object, it is 65 DEG C, rotating speed 180r/min that chitosan, which is handled agent composition in temperature, under conditions of pressure is 600kPa, revolving
After concentrating 3h, No. 1 additive is obtained；The gelatin solution in mass ratio 1 for being 5% by linseed oil and mass fraction：80 mixing, and to Asia
The graphene oxide mixture of 0.3 times of flax oil quality is added in the mixture of sesame oil and gelatin solution, is 65 DEG C in temperature, turns
After speed is stirred 2h under conditions of being 300r/min, mixed liquor is obtained, the quality point of 5 times of mixed liquor quality is added into mixed liquor
Number is 32% metabisulfite solution, is 30 DEG C in temperature, after rotating speed is stirred 80min under conditions of being 300r/min, will mix
The mixture of liquid and metabisulfite solution is cooled to 18 DEG C, must pre-process blank liquid, is 38% by pretreatment blank liquid and mass fraction
Formalin in mass ratio 120：1 mixing, and the pH to 9.2 of pretreatment blank liquid and formalin mixture is adjusted, obtain base
Feed liquid obtains solidifying substance, solidifying substance is filtered and is washed, must be filtered under conditions of being 15 DEG C in temperature by blank liquid after solidification 50min
Cake after being freeze-dried filter cake, obtains No. 2 additives；It counts, weighs successively in parts by weight：100 parts of quick limes, 5 parts of sulphur, 25
No. 1 additive of part, 20 parts of numbers additives, 12 parts of polyacrylic acid zinc, 8 parts of sodium chloride and 180 parts of water, add water in blender,
After being heated to 80 DEG C, quick lime, sulphur, sodium chloride and water are added into blender, in temperature be 90 DEG C, rotating speed 300r/min
Under conditions of, after being stirred 45min, blank is obtained, blank and No. 1 additive are mixed in batch mixer, and into batch mixer
Be added No. 2 additives, polyacrylic acid zinc, in temperature be 38 DEG C, rotating speed be 400r/min under conditions of, after being stirred 60min,
Obtain the dry-coated white agent of Multifunctional tree.The chitosan is the chitosan compound of deacetylation 90%, and the viscosity-average molecular weight of chitosan
For 480kDa.The grain size of the cellulose powder is 20 μm.The preparation method of the sodium hydroxide mixed solution is by mass fraction
Sodium hydroxide for 30% and ethyl acetate in mass ratio 100：1 mixing, obtains sodium hydroxide mixed solution.The polyethylene glycol spreads out
Biology is polyethylene glycol-p-methyl benzenesulfonic acid ester.The preparation method of the graphene oxide mixture is by graphene oxide and water
Mixing, and pH is adjusted, sonic oscillation obtains graphene oxide mixture.
Example 3
By Bacillus pasteurii and paraffin in mass ratio 1：4 mixing are 35 DEG C in temperature, and rotating speed stirs under conditions of being 300r/min
After mixing mixing 40min, Freezing smashing obtains pretreatment Bacillus pasteurii；It will（N- amidino groups）Dodecylacrylamide and poly- second
Diol, derivatives in mass ratio 1：1 is mixed in flask, and be added into flask 0.2 times of polyethyleneglycol derivative quality to two
The ferrocene of 0.12 times of chlorobenzene and polyethyleneglycol derivative quality is 70 DEG C in temperature, and rotating speed stirs under conditions of being 300r/min
After mixing mixing 3h, inorganic agent is obtained；By chitosan and inorganic agent in mass ratio 1：4 mixing obtain chitosan processing agent composition, by shell
It is 65 DEG C, rotating speed 180r/min that glycan, which handles agent composition in temperature, under conditions of pressure is 600kPa, concentrated by rotary evaporation 3h
Afterwards, No. 1 additive is obtained；The gelatin solution in mass ratio 1 for being 5% by linseed oil and mass fraction：80 mixing, and to linseed oil with
The graphene oxide mixture of 0.3 times of flax oil quality is added in the mixture of gelatin solution, is 65 DEG C in temperature, rotating speed is
After being stirred 2h under conditions of 300r/min, mixed liquor is obtained, the mass fraction that 5 times of mixed liquor quality is added into mixed liquor is
32% metabisulfite solution, in temperature be 30 DEG C, rotating speed be 300r/min under conditions of be stirred 80min after, by mixed liquor with
The mixture of metabisulfite solution is cooled to 18 DEG C, must pre-process blank liquid, will pre-process the first that blank liquid and mass fraction are 38%
Aldehyde solution in mass ratio 120：1 mixing, and the pH to 9.2 of pretreatment blank liquid and formalin mixture is adjusted, blank liquid is obtained,
Under conditions of being 15 DEG C in temperature by blank liquid after solidification 50min, solidifying substance is obtained, solidifying substance is filtered and is washed, filter cake is obtained, will filter
After cake freeze-drying, No. 2 additives are obtained；It counts, weighs successively in parts by weight：100 parts of quick limes, 5 parts of sulphur, 25 parts No. 1 adds
Add agent, 20 parts of numbers additives, 12 parts of polyacrylic acid zinc, 8 parts of pretreatment Bacillus pasteuriis, 8 parts of sodium chloride and 180 parts of water, it will
Water be added blender in, after being heated to 80 DEG C, quick lime, sulphur, sodium chloride and water are added into blender, in temperature be 90
DEG C, under conditions of rotating speed is 300r/min, after being stirred 45min, blank is obtained, blank and No. 1 additive are mixed in batch mixing
In machine, and No. 2 additives are added into batch mixer, polyacrylic acid zinc and pretreatment Bacillus pasteurii are 38 DEG C in temperature, turn
Under conditions of speed is 400r/min, after being stirred 60min, the dry-coated white agent of Multifunctional tree is obtained.The chitosan is deacetylation
90% chitosan compound, and the viscosity-average molecular weight of chitosan is 480kDa.The grain size of the cellulose powder is 20 μm.It is described
The preparation method of sodium hydroxide mixed solution be 30% by mass fraction sodium hydroxide and ethyl acetate in mass ratio 100：1
Mixing, obtains sodium hydroxide mixed solution.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.The oxidation stone
The preparation method of black alkene mixture is to mix graphene oxide with water, and adjust pH, and sonic oscillation obtains graphene oxide mixing
Object.
Example 4
By Bacillus pasteurii and paraffin in mass ratio 1：4 mixing are 35 DEG C in temperature, and rotating speed stirs under conditions of being 300r/min
After mixing mixing 40min, Freezing smashing obtains pretreatment Bacillus pasteurii；The acetum for being 15% by chitosan and mass fraction
In mass ratio 1：60 are mixed in beaker, and into beaker be added 1.2 times of chitosan mass cellulose powder, in temperature be 50
DEG C, rotating speed be 300r/min under conditions of be stirred 6h after, obtain chitosan compound, by chitosan compound needle tubing with
The rate of 3mL/min instills in sodium hydroxide mixed solution, and under conditions of being 12 DEG C in temperature after cooling and solidifying 12h, filtering obtains
No. 1 additive；The gelatin solution in mass ratio 1 for being 5% by linseed oil and mass fraction：80 mixing, and it is molten with gelatin to linseed oil
The graphene oxide mixture of 0.3 times of flax oil quality is added in the mixture of liquid, in temperature be 65 DEG C, rotating speed 300r/min
Under conditions of be stirred 2h after, obtain mixed liquor, the sulphur that the mass fraction of 5 times of mixed liquor quality is 32% be added into mixed liquor
Acid sodium solution, in temperature be 30 DEG C, rotating speed be 300r/min under conditions of be stirred 80min after, by mixed liquor and sodium sulphate
The mixture of solution is cooled to 18 DEG C, must pre-process blank liquid, will pre-process the formalin that blank liquid and mass fraction are 38%
In mass ratio 120：1 mixing, and the pH to 9.2 of pretreatment blank liquid and formalin mixture is adjusted, blank liquid is obtained, by blank
Under conditions of liquid is 15 DEG C in temperature after solidification 50min, solidifying substance is obtained, solidifying substance is filtered and is washed, filter cake is obtained, filter cake is freezed
After drying, No. 2 additives are obtained；It counts, weighs successively in parts by weight：100 parts of quick limes, 5 parts of sulphur, 25 parts of No. 1 additives, 20
Part additive, 12 parts of polyacrylic acid zinc, 8 parts of pretreatment Bacillus pasteuriis, 8 parts of sodium chloride and 180 parts of water, add water to and stir
It mixes in device, after being heated to 80 DEG C, quick lime, sulphur, sodium chloride and water is added into blender, be 90 DEG C in temperature, rotating speed is
Under conditions of 300r/min, after being stirred 45min, blank is obtained, blank and No. 1 additive are mixed in batch mixer, and to
In batch mixer be added No. 2 additives, polyacrylic acid zinc and pretreatment Bacillus pasteurii, in temperature be 38 DEG C, rotating speed 400r/
Under conditions of min, after being stirred 60min, the dry-coated white agent of Multifunctional tree is obtained.The chitosan is that the shell of deacetylation 90% is poly-
Sugared mixture, and the viscosity-average molecular weight of chitosan is 480kDa.The grain size of the cellulose powder is 20 μm.The sodium hydroxide is mixed
The preparation method for closing solution be 30% by mass fraction sodium hydroxide and ethyl acetate in mass ratio 100：1 mixing, obtains hydrogen-oxygen
Change sodium mixed solution.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.The graphene oxide mixture
Preparation method is to mix graphene oxide with water, and adjust pH, and sonic oscillation obtains graphene oxide mixture.
Example 5
By Bacillus pasteurii and paraffin in mass ratio 1：4 mixing are 35 DEG C in temperature, and rotating speed stirs under conditions of being 300r/min
After mixing mixing 40min, Freezing smashing obtains pretreatment Bacillus pasteurii；The acetum for being 15% by chitosan and mass fraction
In mass ratio 1：60 are mixed in beaker, and into beaker be added 1.2 times of chitosan mass cellulose powder, in temperature be 50
DEG C, rotating speed be 300r/min under conditions of be stirred 6h after, obtain chitosan compound, by chitosan compound needle tubing with
The rate of 3mL/min instills in sodium hydroxide mixed solution, and under conditions of being 12 DEG C in temperature after cooling and solidifying 12h, filtering obtains
Chitosan microball；It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 1：1 is mixed in flask,
And be added into flask 0.2 times of polyethyleneglycol derivative quality paracide and 0.12 times of polyethyleneglycol derivative quality two
Luxuriant iron is 70 DEG C in temperature, after rotating speed is stirred 3h under conditions of being 300r/min, obtains inorganic agent；By chitosan microball with
Inorganic agent in mass ratio 1：4 mixing, obtain chitosan processing agent composition, by chitosan processing agent composition in temperature be 65 DEG C,
Rotating speed is that 180r/min after concentrated by rotary evaporation 3h, obtains No. 1 additive under conditions of pressure is 600kPa；It counts in parts by weight, according to
It is secondary to weigh：100 parts of quick limes, 5 parts of sulphur, 25 parts of No. 1 additives, 20 parts of numbers additives, 12 parts of polyacrylic acid zinc, 8 parts of pre- places
Bacillus pasteurii, 8 parts of sodium chloride and 180 parts of water are managed, are added water in blender, after being heated to 80 DEG C, are added into blender
Enter quick lime, sulphur, sodium chloride and water, in temperature be 90 DEG C, rotating speed be 300r/min under conditions of, after being stirred 45min,
Blank is obtained, blank and No. 1 additive are mixed in batch mixer, and polyacrylic acid zinc and pretreatment Pasteur are added into batch mixer
Bacillus is 38 DEG C in temperature, under conditions of rotating speed is 400r/min, after being stirred 60min, it is dry-coated white to obtain Multifunctional tree
Agent.The chitosan is the chitosan compound of deacetylation 90%, and the viscosity-average molecular weight of chitosan is 480kDa.The fibre
The grain size of the plain powder of dimension is 20 μm.The preparation method of the sodium hydroxide mixed solution be 30% by mass fraction sodium hydroxide
With ethyl acetate in mass ratio 100：1 mixing, obtains sodium hydroxide mixed solution.The polyethyleneglycol derivative is polyethylene glycol-
P-methyl benzenesulfonic acid ester.The preparation method of the graphene oxide mixture is to mix graphene oxide with water, and adjust pH, is surpassed
Sound oscillation obtains graphene oxide mixture.
Comparative example：The trunk whitewashing agent of Lianyun Harbour Industrial Technology Co., Ltd production.
1 to 5 gained trunk whitewashing agent of example and comparative example product are subjected to performance detection, specific detection method is as follows：
White-out agent whitewashes method using a high position.In the dry outer coating in all centers of veteran tree body, at all tree bodies of treelet and center
Dry outer coating.Old treelet respectively set by processing 10.It whitewashes rear spring in next year tune detection and applies white effect.
Specific testing result is as shown in table 1：
Table 1：Performance detection table
By 1 testing result of table it is found that the multi-functional trunk whitewashing agent of present invention gained has effect of burning excellent resistance to day.
Claims (7)
1. a kind of multi-functional trunk whitewashing agent, which is characterized in that be made of the raw material of following parts by weight：
80~100 parts of quick lime
2~5 parts of sulphur
No. 1 15~25 parts of additive
No. 2 10~20 parts of additives
5~12 parts of polyacrylic acid zinc
Pre-process 5~8 parts of Bacillus pasteurii
3~8 parts of sodium chloride
150~180 parts of water
The preparation method of No. 1 additive is：
By chitosan and acetum in mass ratio 1：50~1：60 mixing, and the fiber of 0.8~1.2 times of chitosan mass is added
Plain powder, is stirred, and obtains chitosan compound, and chitosan compound needle tubing is instilled hydroxide with the rate of 2~3mL/min
It in sodium mixed solution, cools and solidifies, filtering obtains chitosan microball；It will（N- amidino groups）Dodecylacrylamide and polyethylene glycol
Derivative in mass ratio 2：1~1：1 mixing, and the paracide of 0.1~0.2 times of polyethyleneglycol derivative quality and poly- second is added
The ferrocene that 0.08~0.12 times of diol, derivatives quality, is stirred, and obtains inorganic agent；Chitosan microball and inorganic agent are pressed into matter
Measure ratio 1：3~1：4 mixing, concentrated by rotary evaporation obtain No. 1 additive；
The preparation method of No. 2 additives is：
By linseed oil and gelatin solution in mass ratio 1：60~1：80 mixing, and the oxidation of 0.2~0.3 times of flax oil quality is added
Graphene mixture after being stirred, obtains mixed liquor, and the metabisulfite solution of 3~5 times of mixed liquor quality is added into mixed liquor,
After being stirred, cooling must pre-process blank liquid, by pretreatment blank liquid and formalin in mass ratio 80：1~120：1 is mixed
It closes, and adjusts the pH of pretreatment blank liquid and formalin mixture, obtain blank liquid, blank liquid is cured, filter washing, freezing
After drying, No. 2 additives are obtained.
2. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The pretreatment Pasteur gemma bar
The preparation method of bacterium is by Bacillus pasteurii and paraffin in mass ratio 1：3~1：4 mixing, Freezing smashing must pre-process Pasteur
Bacillus.
3. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The chitosan is deacetylation
80~90% chitosan compound, and the viscosity-average molecular weight of chitosan is 400~480kDa.
4. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The grain size of the cellulose powder is
5~20 μm.
5. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The sodium hydroxide mixed solution
Preparation method be 20~30% by mass fraction sodium hydroxide and ethyl acetate in mass ratio 80：1~100：1 mixing, obtains
Sodium hydroxide mixed solution.
6. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The polyethyleneglycol derivative is
Any one in polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol salicylate.
7. a kind of multi-functional trunk whitewashing agent according to claim 1, it is characterised in that：The graphene oxide mixture
Preparation method be to mix graphene oxide with water, and adjust pH, sonic oscillation obtains graphene oxide mixture.
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| CN109275660A (en) * | 2018-09-03 | 2019-01-29 | 新昌县云河虫害防治技术开发有限公司 | The preparation method of honey white-out agent |
| CN109997578A (en) * | 2019-04-23 | 2019-07-12 | 杭州德问贸易有限公司 | A kind of high viscous tree whitening agent of environmental protection |
| CN110024779A (en) * | 2019-05-24 | 2019-07-19 | 苏农（广德）生物科技有限公司 | A kind of fenoxapropPethyl aqueous emulsion and its preparation process |
| CN113367129A (en) * | 2021-05-08 | 2021-09-10 | 河南省莱恩坪安园林植保有限公司 | Special acid-base regulator for trunk whitening |
| CN114747589A (en) * | 2022-04-24 | 2022-07-15 | 山东省长清农药厂有限公司 | Dispersible oil suspending agent containing nicosulfuron and atrazine and preparation method thereof |
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| CN113367129A (en) * | 2021-05-08 | 2021-09-10 | 河南省莱恩坪安园林植保有限公司 | Special acid-base regulator for trunk whitening |
| CN114747589A (en) * | 2022-04-24 | 2022-07-15 | 山东省长清农药厂有限公司 | Dispersible oil suspending agent containing nicosulfuron and atrazine and preparation method thereof |
| CN114747589B (en) * | 2022-04-24 | 2023-11-10 | 山东省长清农药厂有限公司 | Dispersible oil suspending agent containing nicosulfuron and atrazine and preparation method thereof |
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Application publication date: 20180713 |