CN109267433A - 一种高强度纸杯的制备方法 - Google Patents

一种高强度纸杯的制备方法 Download PDF

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CN109267433A
CN109267433A CN201811004992.XA CN201811004992A CN109267433A CN 109267433 A CN109267433 A CN 109267433A CN 201811004992 A CN201811004992 A CN 201811004992A CN 109267433 A CN109267433 A CN 109267433A
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王生龙
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Anqing Shuanglong Paper Co Ltd
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Abstract

本发明公开了一种高强度纸杯的制备方法,包括如下步骤:将E44型环氧树脂、聚乙二醇4000混合均匀,加入聚醚胺D230、三‑(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度搅拌,冷却,干燥,粉碎得到物料a;将针叶木浆、桑树木浆、物料a、水混合,磨浆,然后加入醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉混合均匀,调节体系至中性得到物料b;向物料b中加入明矾、马来松香、活性氧化钙、沸石粉、白土、抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥,裁边得到高强度纸杯。

Description

一种高强度纸杯的制备方法
技术领域
本发明涉及纸杯技术领域,尤其涉及一种高强度纸杯的制备方法。
背景技术
目前,造纸工艺中为了提高生活用纸的湿强度通常是在浆料中添加湿强剂来实现。抄造生活用纸的浆料通常为长纤维和短纤维的混合体,也即浆料为针叶木浆与桑树木浆的混合浆。然而直接在混合浆中添加湿强剂,湿强剂的保留率不高,导致增加成纸湿强度的效果不够明显。
发明内容
基于背景技术存在的技术问题,本发明提出了一种高强度纸杯的制备方法,可有效增强纸杯的强度,在保证纸杯力学性能优异的基础上,也不会对纸杯的微孔结构造成堵塞,保证纸杯的透气性,显著提高使用寿命。
本发明提出的一种高强度纸杯的制备方法,包括如下步骤:
S1、将E44型环氧树脂、聚乙二醇4000混合均匀,加入聚醚胺D230、三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度搅拌,冷却,干燥,粉碎得到物料a;
S2、将针叶木浆、桑树木浆、物料a、水混合,磨浆,然后加入醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉混合均匀,调节体系至中性得到物料b;
S3、向物料b中加入明矾、马来松香、活性氧化钙、沸石粉、白土、抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥,裁边得到高强度纸杯。
优选地,S1中,调节温度至80-90℃,搅拌2-8h。
优选地,S1中,E44型环氧树脂、聚乙二醇4000、聚醚胺D230、三-(二甲胺基甲基)苯酚的重量比为20-30:100-120:1-2:0.1-0.4。
优选地,S2中,针叶木浆、桑树木浆、物料a、水、醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉的重量比为20-32:10-19:4-8:20-30:4-10:1-4:1-2:1-2:0.2-1。
优选地,S3中,在模具压合状态下进行加热干燥,加热干燥时间为2-3min,加热干燥温度为185-200℃。
优选地,S3中,物料b、明矾、马来松香、活性氧化钙、沸石粉、白土、抗光氧化的重量比为60-80:4-10:1-3:5-9:10-16:15-20:1-2。
本发明S1中,E44型环氧树脂与聚乙二醇4000复配,在固化剂聚醚胺D230、促进剂三-(二甲胺基甲基)苯酚的作用下发生交联反应,形成网络结构,聚乙二醇分散在网络结构中,限制了聚乙二醇结晶链段的自由运动,热稳定性好;S2中针叶木浆、桑树木浆的初生壁结构质密,经过磨浆处理后,纤维的结晶度降低,同心层产生弯曲、发生位移和变形,纤维产生裂纹及表面分丝起毛,纤维层和层间变的疏松,纤维丝层间空隙变大,物料a易于进入纤维丝层间空隙,增强了木浆纤维和醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉的结合能力,纤维之间的结合能高,可有效增强纸杯的强度,在保证纸杯力学性能优异的基础上,也不会对纸杯的微孔结构造成堵塞,保证纸杯的透气性,显著提高使用寿命。本发明原料来源广,成本较低,便于大规模生产。
具体实施方式
下面,通过具体实施例对本发明的技术方案进行详细说明。
实施例1
一种高强度纸杯的制备方法,包括如下步骤:
S1、将20kg E44型环氧树脂、120kg聚乙二醇4000混合均匀,加入1kg聚醚胺D230、0.4kg三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度至80℃,搅拌8h,冷却,干燥,粉碎得到物料a;
S2、将20kg针叶木浆、19kg桑树木浆、4kg物料a、30kg水混合,磨浆,然后加入4kg醋酸酯纤维、4kg丙烯酸树脂、1kg聚酯树脂、2kg天然橡胶、0.2kg醚化淀粉混合均匀,采用浓度为1.9mol/L氢氧化钠溶液调节体系至中性得到物料b;
S3、向60kg物料b中加入10kg明矾、1kg马来松香、9kg活性氧化钙、10kg沸石粉、20kg白土、1kg抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥3min,加热干燥温度为185℃,裁边得到高强度纸杯。
实施例2
一种高强度纸杯的制备方法,包括如下步骤:
S1、将30kg E44型环氧树脂、100kg聚乙二醇4000混合均匀,加入2kg聚醚胺D230、0.1kg三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度至90℃,搅拌2h,冷却,干燥,粉碎得到物料a;
S2、将32kg针叶木浆、10kg桑树木浆、8kg物料a、20kg水混合,磨浆,然后加入10kg醋酸酯纤维、1kg丙烯酸树脂、2kg聚酯树脂、1kg天然橡胶、1kg醚化淀粉混合均匀,采用浓度为1.2mol/L氢氧化钠溶液调节体系至中性得到物料b;
S3、向80kg物料b中加入4kg明矾、3kg马来松香、5kg活性氧化钙、16kg沸石粉、15kg白土、2kg抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥2min,加热干燥温度为200℃,裁边得到高强度纸杯。
实施例3
一种高强度纸杯的制备方法,包括如下步骤:
S1、将22kg E44型环氧树脂、115kg聚乙二醇4000混合均匀,加入1.2kg聚醚胺D230、0.3kg三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度至82℃,搅拌6h,冷却,干燥,粉碎得到物料a;
S2、将24kg针叶木浆、18kg桑树木浆、5kg物料a、28kg水混合,磨浆,然后加入6kg醋酸酯纤维、3kg丙烯酸树脂、1.3kg聚酯树脂、1.7kg天然橡胶、0.4kg醚化淀粉混合均匀,采用浓度为1.8mol/L氢氧化钠溶液调节体系至中性得到物料b;
S3、向65kg物料b中加入8kg明矾、1.5kg马来松香、8kg活性氧化钙、12kg沸石粉、18kg白土、1.3kg抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥2.8min,加热干燥温度为190℃,裁边得到高强度纸杯。
实施例4
一种高强度纸杯的制备方法,包括如下步骤:
S1、将28kg E44型环氧树脂、105kg聚乙二醇4000混合均匀,加入1.8kg聚醚胺D230、0.2kg三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度至88℃,搅拌4h,冷却,干燥,粉碎得到物料a;
S2、将28kg针叶木浆、12kg桑树木浆、7kg物料a、22kg水混合,磨浆,然后加入8kg醋酸酯纤维、2kg丙烯酸树脂、1.7kg聚酯树脂、1.3kg天然橡胶、0.8kg醚化淀粉混合均匀,采用浓度为1.4mol/L氢氧化钠溶液调节体系至中性得到物料b;
S3、向75kg物料b中加入6kg明矾、2.5kg马来松香、6kg活性氧化钙、14kg沸石粉、16kg白土、1.7kg抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥2.2min,加热干燥温度为195℃,裁边得到高强度纸杯。
实施例5
一种高强度纸杯的制备方法,包括如下步骤:
S1、将25kg E44型环氧树脂、110kg聚乙二醇4000混合均匀,加入1.5kg聚醚胺D230、0.25kg三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度至85℃,搅拌5h,冷却,干燥,粉碎得到物料a;
S2、将26kg针叶木浆、15kg桑树木浆、6kg物料a、25kg水混合,磨浆,然后加入7kg醋酸酯纤维、2.5kg丙烯酸树脂、1.5kg聚酯树脂、1.5kg天然橡胶、0.6kg醚化淀粉混合均匀,采用浓度为1.6mol/L氢氧化钠溶液调节体系至中性得到物料b;
S3、向70kg物料b中加入7kg明矾、2kg马来松香、7kg活性氧化钙、13kg沸石粉、17kg白土、1.5kg抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥2.5min,加热干燥温度为193℃,裁边得到高强度纸杯。
将实施例5所得高强度纸杯和市售普通纸杯进行性能测试,其结果如下:
实施例5 市售普通纸杯
抗张指数,N·m/g 88.46 72.87
耐折度,次 162 121
耐破指数,kPa·m<sup>2</sup>/g 7.9 6.5
撕裂指数,mN·m<sup>2</sup>/g 11.03 9.08
挺度,mN 9873 6418
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种高强度纸杯的制备方法,其特征在于,包括如下步骤:
S1、将E44型环氧树脂、聚乙二醇4000混合均匀,加入聚醚胺D230、三-(二甲胺基甲基)苯酚混合均匀,真空脱气,调节温度搅拌,冷却,干燥,粉碎得到物料a;
S2、将针叶木浆、桑树木浆、物料a、水混合,磨浆,然后加入醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉混合均匀,调节体系至中性得到物料b;
S3、向物料b中加入明矾、马来松香、活性氧化钙、沸石粉、白土、抗光氧化剂混合均匀,注入杯盖的模具中,在模具压合状态下进行加热干燥,裁边得到高强度纸杯。
2.根据权利要求1所述高强度纸杯的制备方法,其特征在于,S1中,调节温度至80-90℃,搅拌2-8h。
3.根据权利要求1或2所述高强度纸杯的制备方法,其特征在于,S1中,E44型环氧树脂、聚乙二醇4000、聚醚胺D230、三-(二甲胺基甲基)苯酚的重量比为20-30:100-120:1-2:0.1-0.4。
4.根据权利要求1-3任一项所述高强度纸杯的制备方法,其特征在于,S2中,针叶木浆、桑树木浆、物料a、水、醋酸酯纤维、丙烯酸树脂、聚酯树脂、天然橡胶、醚化淀粉的重量比为20-32:10-19:4-8:20-30:4-10:1-4:1-2:1-2:0.2-1。
5.根据权利要求1-4任一项所述高强度纸杯的制备方法,其特征在于,S3中,在模具压合状态下进行加热干燥,加热干燥时间为2-3min,加热干燥温度为185-200℃。
6.根据权利要求1-5任一项所述高强度纸杯的制备方法,其特征在于,S3中,物料b、明矾、马来松香、活性氧化钙、沸石粉、白土、抗光氧化的重量比为60-80:4-10:1-3:5-9:10-16:15-20:1-2。
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