CN109181495A - A kind of environmental protection coating material and preparation method thereof - Google Patents

A kind of environmental protection coating material and preparation method thereof Download PDF

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Publication number
CN109181495A
CN109181495A CN201811152266.2A CN201811152266A CN109181495A CN 109181495 A CN109181495 A CN 109181495A CN 201811152266 A CN201811152266 A CN 201811152266A CN 109181495 A CN109181495 A CN 109181495A
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China
Prior art keywords
parts
environmental protection
coating material
protection coating
weight
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Pending
Application number
CN201811152266.2A
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Chinese (zh)
Inventor
何凌峰
杨富国
史亮
王军飞
杨国飞
胡宇晨
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Foshan University
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Foshan University
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Priority to CN201811152266.2A priority Critical patent/CN109181495A/en
Publication of CN109181495A publication Critical patent/CN109181495A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of environmental protection coating materials and preparation method thereof, are related to building material technical field.The present invention is mainly grouped as by the group of following parts by weight: fine sand, and 5 parts -10 parts;Middle sand, 3 parts -8 parts;Wood fibre, 3 parts -15 parts;Filler, 4 parts -7 parts;Water soluble acrylic acid epoxy modified resin, 50 parts -65 parts;Diatomite, 15 parts -20 parts;Pigment iron oxide red, 5 parts -8 parts;Antibacterial agent, 0.7 part -1.5 parts.The present invention passes through using fine sand, middle sand natural material and the wood fibre processed using natural reproducible timber by chemical treatment, Mechanical Method as aggregate; using water soluble acrylic acid epoxy modified resin and diatomite environment-friendly materials as base; the coating of production has many advantages, such as that film contraction is small, hardness is high, wearability is good, electrical insulation properties are excellent, pollution-free, corrosion-resistant, has preferable protecting effect.

Description

A kind of environmental protection coating material and preparation method thereof
Technical field
The invention belongs to building material technical fields, more particularly to a kind of environmental protection coating material and a kind of preparation of environmental protection coating material Method.
Background technique
Coating is mainly made of high molecular polymer, natural color stone sand and relevant auxiliary agent, hard after dry and hard solidification Such as stone, decorative effect exactly likes marble or granite.Imitation marble paint belongs to the texture coating in art coatings, through its decoration Building afterwards has natural true natural colour, gives graceful, serious aesthetic feeling, is suitable for the interior of all kinds of buildings External decoration and building materials and ornaments and protection.
Currently, existing building materials coating, in order to reach various protective effects, many ingredients of addition have certain harmfulness, And general more environmentally friendly aqueous latex paint water resistance, in terms of compared with oil paint there is also larger gap, In use usually occur crack, fall off, is mouldy, validity period is shorter, not acid and alkali-resistance the problems such as.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental protection coating materials and preparation method thereof, by a variety of natural materials rationally to match Than carry out processing be prepared, solve environment-friendly water-based emulsion paint water resistance, in terms of compared with oil paint There are larger gaps, in use usually occur crack, fall off, is mouldy, validity period is shorter, not acid and alkali-resistance the problem of.
The present invention is achieved by the following technical solutions:
The present invention is a kind of environmental protection coating material and preparation method thereof, is mainly grouped as by the group of following parts by weight:
Fine sand, 5 parts -10 parts;
Middle sand, 3 parts -8 parts;
Wood fibre, 3 parts -15 parts;
Filler, 4 parts -7 parts;
Water soluble acrylic acid epoxy modified resin, 50 parts -65 parts;
Diatomite, 15 parts -20 parts;
Pigment iron oxide red, 5 parts -8 parts;
Antibacterial agent, 0.7 part -1.5 parts.
Further, a kind of environmental protection coating material, is mainly grouped as by the group of following parts by weight:
Fine sand, 5.2 parts -9.5 parts;
Middle sand, 3.5 parts -7.9 parts;
Wood fibre, 3.1 parts -14 parts;
Filler, 4.2 parts -6.8 parts;
Water soluble acrylic acid epoxy modified resin, 51 parts -64 parts;
Diatomite, 15.5 parts -19 parts;
Pigment iron oxide red, 5.3 parts -7.8 parts;
Antibacterial agent, 0.8 part -1.4 parts.
Further, the method for modifying of the water soluble acrylic acid epoxy modified resin is, is 950-1000's by parts by weight The CoatOSil2287 water that parts by weight are 20-30 is added under 400-600r/min stirring condition in water-based epoxy acrylic resin Property emulsion paint auxiliary agent stir 30 minutes as modifying agent, then store 48 hours, obtain the epoxy-modified tree of the water soluble acrylic acid Rouge has film and shrinks the advantages that small, hardness is high, wearability is good, electrical insulation properties are excellent, pollution-free, corrosion-resistant.
Further, the filler is any one in calcium carbonate, talcum powder and china clay.
Further, the diatomite be the non-burning diatomite of wet concentration, dioxide-containing silica range therein be 85% with On, the mesh number range of diatomite is in 200-325 mesh.
Further, the antibacterial agent is chitosan class natural antibacterial agent.
Further, the preparation method of a kind of environmental protection coating material, comprises the following steps:
Step 1: being 3 parts -15 parts of wood fibre, 5 parts -8 parts of pigment iron oxide red, 50 parts -65 parts by parts by weight Water is added in blender and is stirred for water soluble acrylic acid epoxy modified resin, revolving speed 400-600r/min, stirs 10 minutes, Amount of water is controlled in 20%-30%, obtains mixed liquor;
Step 2: fine sand, 3 parts -8 parts of middle sand, 15 parts -20 parts of diatomite that parts by weight are 5 parts -10 parts are passed through upper Material machine sequentially adds in the mixed liquor, and revolving speed is adjusted to 1200-1500r/min, stirs 15-20 minutes;
Step 3: adding parts by weight is 4 parts -7 parts of filler and 0.7 part -1.5 parts of antibacterial agent, with 400-600r/ Min revolving speed stirs 10-30 minutes and obtains the environmental protection coating material.
The invention has the following advantages:
1, the present invention is by passing through chemical treatment, machinery with fine sand, middle sand natural material and with natural reproducible timber The wood fibre that method is processed is aggregate, raw using water soluble acrylic acid epoxy modified resin and diatomite environment-friendly materials as base The coating of production has many advantages, such as that film contraction is small, hardness is high, wearability is good, electrical insulation properties are excellent, pollution-free, corrosion-resistant, Has preferable protecting effect.
2, the present invention has good sunshade thermal insulation and anti-flammability by pigment iron oxide red and wood fibre, recycles Natural antibacterial agent, it is therefore prevented that the problems such as cracking, fall off and is mouldy occurs in coating, is conducive to the service life for improving building materials.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without creative efforts belongs to the model that the present invention protects It encloses.
Embodiment one
The group of following parts by weight is selected to be grouped as: 10 parts of fine sand;5 parts of middle sand;10 parts of wood fibre;5 parts of porcelain clay filler;Water 60 parts of modified resin of acrylic acid epoxy of property;18 parts of diatomite;7 parts of pigment iron oxide red;0.8 part of antibacterial agent.
Step 1: being 10 parts of wood fibre, 7 parts of pigment iron oxide red, 60 parts of water soluble acrylic acid ring by parts by weight Water is added in blender and is stirred for oxygen modified resin, revolving speed 400r/min, stirs 10 minutes, and amount of water control exists 25%, obtain mixed liquor;
Step 2: the fine sand, 5 parts of middle sand, 18 parts of diatomite that parts by weight are 10 parts are sequentially added by feeder In mixed liquor, revolving speed is adjusted to 1200r/min, stirs 15 minutes;
Step 3: adding parts by weight is 5 parts of porcelain clay filler and 0.8 part of antibacterial agent, with the stirring of 400r/min revolving speed Obtain environmental protection coating material within 10 minutes.
Embodiment two
The group of following parts by weight is selected to be grouped as: 8 parts of fine sand;8 parts of middle sand;5 parts of wood fibre;5 parts of pearl filler;Water 55 parts of modified resin of acrylic acid epoxy of property;15 parts of diatomite;5 parts of pigment iron oxide red;1.2 parts of antibacterial agent.
Step 1: being 5 parts of wood fibre, 5 parts of pigment iron oxide red, 55 parts of water soluble acrylic acid epoxy by parts by weight Water is added in blender and is stirred for modified resin, revolving speed 500r/min, stirs 10 minutes, amount of water control 20%, Obtain mixed liquor;
Step 2: fine sand, 8 parts of middle sand, 15 parts of diatomite that parts by weight are 8 parts are sequentially added by feeder mixed It closes in liquid, revolving speed is adjusted to 1400r/min, stirs 18 minutes;
Step 3: adding parts by weight is 5 parts of pearl filler and 1.2 parts of antibacterial agent, stirred with 500r/min revolving speed It mixes 20 minutes and obtains environmental protection coating material.
Embodiment three
The group of following parts by weight is selected to be grouped as: 5 parts of fine sand;5 parts of middle sand;15 parts of wood fibre;5 parts of talcum powder; 55 parts of water soluble acrylic acid epoxy modified resin;10 parts of diatomite;6 parts of pigment iron oxide red;1 part of antibacterial agent.
Step 1: being 15 parts of wood fibre, 6 parts of pigment iron oxide red, 55 parts of water soluble acrylic acid ring by parts by weight Water is added in blender and is stirred for oxygen modified resin, revolving speed 600r/min, stirs 10 minutes, and amount of water control exists 30%, obtain mixed liquor;
Step 2: fine sand, 5 parts of middle sand, 10 parts of diatomite that parts by weight are 5 parts are sequentially added by feeder mixed It closes in liquid, revolving speed is adjusted to 1500r/min, stirs 20 minutes;
Step 3: adding parts by weight is 5 parts of talcum powder and 1 part of antibacterial agent, with the stirring of 600r/min revolving speed Obtain environmental protection coating material within 30 minutes.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (7)

1. a kind of environmental protection coating material, which is characterized in that be mainly grouped as by the group of following parts by weight:
Fine sand, 5 parts -10 parts;
Middle sand, 3 parts -8 parts;
Wood fibre, 3 parts -15 parts;
Filler, 4 parts -7 parts;
Water soluble acrylic acid epoxy modified resin, 50 parts -65 parts;
Diatomite, 15 parts -20 parts;
Pigment iron oxide red, 5 parts -8 parts;
Antibacterial agent, 0.7 part -1.5 parts.
2. a kind of environmental protection coating material according to claim 1, which is characterized in that be mainly grouped as by the group of following parts by weight:
Fine sand, 5.2 parts -9.5 parts;
Middle sand, 3.5 parts -7.9 parts;
Wood fibre, 3.1 parts -14 parts;
Filler, 4.2 parts -6.8 parts;
Water soluble acrylic acid epoxy modified resin, 51 parts -64 parts;
Diatomite, 15.5 parts -19 parts;
Pigment iron oxide red, 5.3 parts -7.8 parts;
Antibacterial agent, 0.8 part -1.4 parts.
3. a kind of environmental protection coating material according to claim 1, which is characterized in that the water soluble acrylic acid epoxy modified resin Method of modifying is, by water-based epoxy acrylic resin that parts by weight are 950-1000 under 400-600r/min stirring condition, adds Enter CoatOSil2287 aqueous latex paint auxiliary agent that parts by weight are 20-30 as modifying agent, stirring 30 minutes, then to store 48 small When, obtain the water soluble acrylic acid epoxy modified resin.
4. a kind of environmental protection coating material according to claim 1, which is characterized in that the filler is calcium carbonate, talcum powder and porcelain Any one in soil.
5. a kind of environmental protection coating material according to claim 1, which is characterized in that the diatomite is the non-burning diatom of wet concentration Soil, dioxide-containing silica range therein are 85% or more, and the mesh number range of diatomite is in 200-325 mesh.
6. a kind of environmental protection coating material according to claim 1, which is characterized in that the antibacterial agent is chitosan class natural antibacterial Agent.
7. a kind of preparation method of environmental protection coating material as described in claim 1-7 any one, which is characterized in that including following several A step:
Step 1: being 3 parts -15 parts of wood fibre, 5 parts -8 parts of pigment iron oxide red, 50 parts -65 parts aqueous by parts by weight Water is added in blender and is stirred for acrylic acid epoxy modified resin, revolving speed 400-600r/min, stirs 10 minutes, adds water Amount control obtains mixed liquor in 20%-30%;
Step 2: the fine sand, 3 parts -8 parts of middle sand, 15 parts -20 parts of diatomite that parts by weight are 5 parts -10 parts are passed through feeder It sequentially adds in the mixed liquor, revolving speed is adjusted to 1200-1500r/min, stirs 15-20 minutes;
Step 3: adding parts by weight is 4 parts -7 parts of filler and 0.7 part -1.5 parts of antibacterial agent, turned with 400-600r/min Speed stirring obtains the environmental protection coating material in 10-30 minutes.
CN201811152266.2A 2018-09-29 2018-09-29 A kind of environmental protection coating material and preparation method thereof Pending CN109181495A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811152266.2A CN109181495A (en) 2018-09-29 2018-09-29 A kind of environmental protection coating material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811152266.2A CN109181495A (en) 2018-09-29 2018-09-29 A kind of environmental protection coating material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109181495A true CN109181495A (en) 2019-01-11

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103045053A (en) * 2013-01-04 2013-04-17 高文升 Water-based industrial anticorrosion paint and preparation method
CN103820008A (en) * 2014-02-21 2014-05-28 深圳市宝骏环保涂料有限公司 One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof
CN107043229A (en) * 2017-03-14 2017-08-15 厦门丽邦集团有限公司 A kind of Environmental Protective Water-paint and construction method
CN107312368A (en) * 2016-04-26 2017-11-03 芜湖艾蔓设备工程有限公司 A kind of automobile engine oil pan energy-saving and environment-friendly paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103045053A (en) * 2013-01-04 2013-04-17 高文升 Water-based industrial anticorrosion paint and preparation method
CN103820008A (en) * 2014-02-21 2014-05-28 深圳市宝骏环保涂料有限公司 One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof
CN107312368A (en) * 2016-04-26 2017-11-03 芜湖艾蔓设备工程有限公司 A kind of automobile engine oil pan energy-saving and environment-friendly paint
CN107043229A (en) * 2017-03-14 2017-08-15 厦门丽邦集团有限公司 A kind of Environmental Protective Water-paint and construction method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
任友直等: "《涂料工业用原材料技术标准手册》", 30 April 1992, 化学工业出版社 *
杨成德等: "《涂料开发与试验》", 28 February 2015, 北京:科学技术文献出版社 *

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Application publication date: 20190111