CN107312368A - A kind of automobile engine oil pan energy-saving and environment-friendly paint - Google Patents
A kind of automobile engine oil pan energy-saving and environment-friendly paint Download PDFInfo
- Publication number
- CN107312368A CN107312368A CN201610278064.7A CN201610278064A CN107312368A CN 107312368 A CN107312368 A CN 107312368A CN 201610278064 A CN201610278064 A CN 201610278064A CN 107312368 A CN107312368 A CN 107312368A
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- Prior art keywords
- parts
- engine oil
- oil pan
- automobile engine
- saving
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of automobile engine oil pan energy-saving and environment-friendly paint, the coating includes according to the raw material of parts by weight:90 100 parts of waterborne epoxy modified acrylic resin, 20 30 parts of silver powder, 6 10 parts of glass fibre powder, 5 10 parts of amino resins, 10 18 parts of silver oxide, 28 parts of titanium dioxide, 10 15 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, 59 parts of diaminodiphenyl-methane, 6 12 parts of cetyl benzenesulfonic acid sodium, 16 parts of dioctyl succinate disulfonate acid, 10 18 parts of kaolin, 15 parts of PSI, 26 parts of silicone emulsion, 6 10 parts of aluminum phosphate, 6 10 parts of diatomite, 5 10 parts of polyamide wax liquor, 25 45 parts of styrene, 100 120 parts of water.The present invention has excellent fire-retardant and anti-wear performance, and curing rate is fast, with good hardness, adhesive force, water resistance, high temperature resistant, environmental protection, service life are long, reduce the VOC emission of solvent-thinned paint, concentrate and complete roller coat processing, simplify machining clearance, without being separately provided painting workshop.
Description
Technical field
The present invention relates to automobile engine oil pan Material Field, specifically a kind of automobile engine oil pan is applied with energy-conserving and environment-protective
Material.
Background technology
Acrylic resin is the resin being made up of propylene vinegar and methacrylate and other olefinic type monomers copolymerization, with other
Synthetic macromolecule resin is compared, and acrylic resin has the advantages that many protrusions, such as excellent fast light, weatherability, resistance to ultraviolet
Light irradiation is not easily decomposed and turned yellow, and original gloss and color and luster can be kept for a long time, heat-resist, have preferable acid and alkali resistance,
The chemicals such as salt, grease and detergent stain and corrosive nature, fabulous pliability and minimum pigment reactivity.Therefore, exist
Automobile, household electrical appliances, metal furniture, coiled material industry, instrument and meter, building, textile, woodwork, papermaking and plastic products
Deng industrially having a wide range of applications.
However, the shortcomings of heat sticks cold short, anti-after-tackiness and not good heat resistance caused by the linear structure of acrylic resin should to it
Had certain limitations with scope.The equal phase structure of acrylic resin causes its cold tolerance and heat resistance to be difficult to take into account, and such as
Increase resistance to low temperature, then can lose resistance to elevated temperatures, vice versa, thus common acrylic compounds coating material just can not
There is disadvantages mentioned above with avoiding.
Therefore, by with other monomers, resin altogether poly and modified, the various aspects of performance of coating can be changed, be made it is a variety of not
With the environmental protection coating material of performance and application field, be such as surface-treated, electroplated with meeting the use of engine sump tank, process,
The need for gold stamping, plated film etc..
The content of the invention
It is an object of the invention to provide a kind of automobile engine oil pan energy-saving and environment-friendly paint, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme:
A kind of automobile engine oil pan energy-saving and environment-friendly paint, the coating includes according to the raw material of parts by weight:Water-base epoxy
Acrylic resin modified 90-100 parts, 20-30 parts of silver powder, 6-10 parts of glass fibre powder, 5-10 parts of amino resins,
10-18 parts of silver oxide, 2-8 parts of titanium dioxide, 10-15 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, diaminodiphenyl-methane 5-9
Part, 6-12 parts of cetyl benzenesulfonic acid sodium, 1-6 parts of dioctyl succinate disulfonate acid, 10-18 parts of kaolin, poly- methyl
1-5 parts of phenyl siloxane, 2-6 parts of silicone emulsion, 6-10 parts of aluminum phosphate, 6-10 parts of diatomite, polyamide wax liquor 5-10
Part, 25-45 parts of styrene, 100-120 parts of water.
It is used as further scheme of the invention:The coating includes according to the raw material of parts by weight:Waterborne epoxy modified acrylic tree
95 parts of fat, 25 parts of silver powder, 8 parts of glass fibre powder, 7.5 parts of amino resins, 14 parts of silver oxide, titanium dioxide 5
It is part, 12.5 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, 7 parts of diaminodiphenyl-methane, 9 parts of cetyl benzenesulfonic acid sodium, two pungent
3.5 parts of base sodium sulfosuccinate, 14 parts of kaolin, 3 parts of PSI, 4 parts of silicone emulsion, aluminum phosphate 8
Part, 8 parts of diatomite, 7.5 parts of polyamide wax liquor, 35 parts of styrene, 110 parts of water.
It is used as further scheme of the invention:The waterborne epoxy modified acrylic resin includes according to the raw material of parts by weight:
5-20 parts of epoxy resin, 30-50 parts of solvent, 3-6 parts of acrylic compounds carboxylic monomer, 6-12 parts of acrylic compounds carboxylic monomer,
10-20 parts of styrene, 10-20 parts of isobornyl methacrylate, 1-5 parts of initiator.
It is used as further scheme of the invention:The waterborne epoxy modified acrylic resin includes according to the raw material of parts by weight:
12.5 parts of epoxy resin, 40 parts of solvent, 4.5 parts of acrylic compounds carboxylic monomer, 9 parts of acrylic compounds carboxylic monomer, benzene second
15 parts of alkene, 15 parts of isobornyl methacrylate, 3 parts of initiator.
It is used as further scheme of the invention:The epoxy resin is epoxide equivalent 500-3000 bisphenol type epoxy tree
Fat.
It is used as further scheme of the invention:The solvent is butyl glycol ether, butanol, butyl, propane diols
One or more in butyl ether, dipropylene, propylene glycol monomethyl ether, isopropanol, sec-butyl alcohol and ethanol.
It is used as further scheme of the invention:The preparation method of the waterborne epoxy modified acrylic resin, including following step
Suddenly:
(1) epoxy resin and 90% stirring solvent is added by formula to dissolve and be warming up to 110-160 DEG C;
(2) be at the uniform velocity added dropwise with 3-4hr according to formula ratio acrylic compounds carboxylic monomer, acrylic compounds carboxylic monomer, styrene,
The mixture of isobornyl methacrylate and 70% initiator, is divided into 3 parts after dripping by the initiator of residue 30%,
It is per hour plus a, finally continue to react 3hr;
(3) 80 DEG C are cooled to, remaining solvent is added, stirs, obtain waterborne epoxy modified acrylic resin.
It is used as further scheme of the invention:The coating is coated to automobile engine oil pan slab table by roll coating model
Face, 200-250 DEG C of roller coat temperature, roller coat number of times is 1-2 times.
Compared with prior art, the beneficial effects of the invention are as follows:The coating uses epoxide equivalent 500-3000 bisphenol-A
Type epoxy resin modified acrylic resin, with excellent fire-retardant and anti-wear performance, and curing rate is fast, with good hard
Degree, adhesive force, water resistance, high temperature resistant, environmental protection, service life is long, reduces the VOC emission of solvent-thinned paint, also has
Preferable mechanical property, ageing-resistant performance and resistance to chemical corrosion, concentrate on automobile engine oil pan slab and complete roller
Painting is handled, and simplifies machining clearance, without being separately provided painting workshop.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, shown
So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of automobile engine oil pan energy-saving and environment-friendly paint, the coating according to parts by weight original
Material includes:90 parts of waterborne epoxy modified acrylic resin, 20 parts of silver powder, 6 parts of glass fibre powder, 5 parts of amino resins,
10 parts of silver oxide, 2 parts of titanium dioxide, 10 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, 5 parts of diaminodiphenyl-methane, hexadecane
6 parts of base benzene sulfonic acid sodium salt, 1 part of dioctyl succinate disulfonate acid, 10 parts of kaolin, 1 part of PSI, breast
2 parts of SiClx oil, 6 parts of aluminum phosphate, 6 parts of diatomite, 5 parts of polyamide wax liquor, 25 parts of styrene, 100 parts of water.
The waterborne epoxy modified acrylic resin includes according to the raw material of parts by weight:5 parts of epoxy resin, 30 parts of solvent,
3 parts of acrylic compounds carboxylic monomer, 6 parts of acrylic compounds carboxylic monomer, 10 parts of styrene, isobornyl methacrylate 10
Part, 1 part of initiator.
The epoxy resin is epoxide equivalent 500-3000 bisphenol A type epoxy resin.
The solvent is sec-butyl alcohol and ethanol.
The preparation method of the waterborne epoxy modified acrylic resin, comprises the following steps:
(1) epoxy resin and 90% stirring solvent is added by formula to dissolve and be warming up to 110 DEG C;
(2) be at the uniform velocity added dropwise with 3hr according to formula ratio acrylic compounds carboxylic monomer, acrylic compounds carboxylic monomer, styrene,
The mixture of isobornyl methacrylate and 70% initiator, is divided into 3 parts after dripping by the initiator of residue 30%,
It is per hour plus a, finally continue to react 3hr;
(3) 80 DEG C are cooled to, remaining solvent is added, stirs, obtain waterborne epoxy modified acrylic resin.
The coating is coated to automobile engine oil pan steel slab surface, 200 DEG C of roller coat temperature, roller coat by roll coating model
Number is 2 times.
Embodiment 2
In the embodiment of the present invention, a kind of automobile engine oil pan energy-saving and environment-friendly paint, the coating according to parts by weight original
Material includes:95 parts of waterborne epoxy modified acrylic resin, 25 parts of silver powder, 8 parts of glass fibre powder, amino resins 7.5
Part, 14 parts of silver oxide, 5 parts of titanium dioxide, 12.5 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, 7 parts of diaminodiphenyl-methane,
9 parts of cetyl benzenesulfonic acid sodium, 3.5 parts of dioctyl succinate disulfonate acid, 14 parts of kaolin, PSI 3
Part, 4 parts of silicone emulsion, 8 parts of aluminum phosphate, 8 parts of diatomite, 7.5 parts of polyamide wax liquor, 35 parts of styrene, water 110
Part.
The waterborne epoxy modified acrylic resin includes according to the raw material of parts by weight:12.5 parts of epoxy resin, 40 parts of solvent,
4.5 parts of acrylic compounds carboxylic monomer, 9 parts of acrylic compounds carboxylic monomer, 15 parts of styrene, isobornyl methacrylate
15 parts, 3 parts of initiator.
The epoxy resin is epoxide equivalent 500-3000 bisphenol A type epoxy resin.
The solvent is butyl, propandiol butyl ether, dipropylene and propylene glycol monomethyl ether.
The preparation method of the waterborne epoxy modified acrylic resin, comprises the following steps:
(1) epoxy resin and 90% stirring solvent is added by formula to dissolve and be warming up to 140 DEG C;
(2) be at the uniform velocity added dropwise with 3.5hr according to formula ratio acrylic compounds carboxylic monomer, acrylic compounds carboxylic monomer, styrene,
The mixture of isobornyl methacrylate and 70% initiator, is divided into 3 parts after dripping by the initiator of residue 30%,
It is per hour plus a, finally continue to react 3hr;
(3) 80 DEG C are cooled to, remaining solvent is added, stirs, obtain waterborne epoxy modified acrylic resin.
The coating is coated to automobile engine oil pan steel slab surface, 220 DEG C of roller coat temperature, roller coat by roll coating model
Number is 2 times.
Embodiment 3
In the embodiment of the present invention, a kind of automobile engine oil pan energy-saving and environment-friendly paint, the coating according to parts by weight original
Material includes:100 parts of waterborne epoxy modified acrylic resin, 30 parts of silver powder, 10 parts of glass fibre powder, amino resins 10
Part, 18 parts of silver oxide, 8 parts of titanium dioxide, 15 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, 9 parts of diaminodiphenyl-methane, ten
Six 12 parts of sodium alkyl benzene sulfonates, 6 parts of dioctyl succinate disulfonate acid, 18 parts of kaolin, 5 parts of PSI,
6 parts of silicone emulsion, 10 parts of aluminum phosphate, 10 parts of diatomite, 10 parts of polyamide wax liquor, 45 parts of styrene, 120 parts of water.
The waterborne epoxy modified acrylic resin includes according to the raw material of parts by weight:20 parts of epoxy resin, 50 parts of solvent,
6 parts of acrylic compounds carboxylic monomer, 12 parts of acrylic compounds carboxylic monomer, 20 parts of styrene, isobornyl methacrylate 20
Part, 5 parts of initiator.
The epoxy resin is epoxide equivalent 500-3000 bisphenol A type epoxy resin.
The solvent is butyl glycol ether and butanol.
The preparation method of the waterborne epoxy modified acrylic resin, comprises the following steps:
(1) epoxy resin and 90% stirring solvent is added by formula to dissolve and be warming up to 160 DEG C;
(2) be at the uniform velocity added dropwise with 4hr according to formula ratio acrylic compounds carboxylic monomer, acrylic compounds carboxylic monomer, styrene,
The mixture of isobornyl methacrylate and 70% initiator, is divided into 3 parts after dripping by the initiator of residue 30%,
It is per hour plus a, finally continue to react 3hr;
(3) 80 DEG C are cooled to, remaining solvent is added, stirs, obtain waterborne epoxy modified acrylic resin.
The coating is coated to automobile engine oil pan steel slab surface, 250 DEG C of roller coat temperature, roller coat by roll coating model
Number is 1 time.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only included
One independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should be by
Specification is as an entirety, and the technical solutions in the various embodiments may also be suitably combined, and forming those skilled in the art can
With the other embodiment of understanding.
Claims (8)
1. a kind of automobile engine oil pan energy-saving and environment-friendly paint, it is characterised in that the coating according to parts by weight original
Material includes:90-100 parts of waterborne epoxy modified acrylic resin, 20-30 parts of silver powder, 6-10 parts of glass fibre powder, ammonia
5-10 parts of base resin, 10-18 parts of silver oxide, 2-8 parts of titanium dioxide, 10-15 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, diamino
5-9 parts of base diphenyl methane, 6-12 parts of cetyl benzenesulfonic acid sodium, 1-6 parts of dioctyl succinate disulfonate acid, kaolin
10-18 parts, 1-5 parts of PSI, 2-6 parts of silicone emulsion, 6-10 parts of aluminum phosphate, 6-10 parts of diatomite,
5-10 parts of polyamide wax liquor, 25-45 parts of styrene, 100-120 parts of water.
2. automobile engine oil pan energy-saving and environment-friendly paint according to claim 1, it is characterised in that the painting
Material includes according to the raw material of parts by weight:95 parts of waterborne epoxy modified acrylic resin, 25 parts of silver powder, glass fibre powder 8
Part, 7.5 parts of amino resins, 14 parts of silver oxide, 5 parts of titanium dioxide, 12.5 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamine, diaminourea
7 parts of diphenyl methane, 9 parts of cetyl benzenesulfonic acid sodium, 3.5 parts of dioctyl succinate disulfonate acid, 14 parts of kaolin,
3 parts of PSI, 4 parts of silicone emulsion, 8 parts of aluminum phosphate, 8 parts of diatomite, 7.5 parts of polyamide wax liquor,
35 parts of styrene, 110 parts of water.
3. automobile engine oil pan energy-saving and environment-friendly paint according to claim 1, it is characterised in that the water
Property epoxy modified acrylic resin includes according to the raw material of parts by weight:5-20 parts of epoxy resin, 30-50 parts of solvent, propylene
3-6 parts of acids carboxylic monomer, 6-12 parts of acrylic compounds carboxylic monomer, 10-20 parts of styrene, methacrylic acid isoborneol
10-20 parts of ester, 1-5 parts of initiator.
4. automobile engine oil pan energy-saving and environment-friendly paint according to claim 3, it is characterised in that the water
Property epoxy modified acrylic resin includes according to the raw material of parts by weight:12.5 parts of epoxy resin, 40 parts of solvent, acrylic compounds
4.5 parts of carboxylic monomer, 9 parts of acrylic compounds carboxylic monomer, 15 parts of styrene, 15 parts of isobornyl methacrylate, draw
Send out 3 parts of agent.
5. automobile engine oil pan energy-saving and environment-friendly paint according to claim 3, it is characterised in that the ring
Oxygen tree fat is epoxide equivalent 500-3000 bisphenol A type epoxy resin.
6. automobile engine oil pan energy-saving and environment-friendly paint according to claim 3, it is characterised in that described molten
Agent is butyl glycol ether, butanol, butyl, propandiol butyl ether, dipropylene, propylene glycol monomethyl ether, isopropyl
One or more in alcohol, sec-butyl alcohol and ethanol.
7. automobile engine oil pan energy-saving and environment-friendly paint according to claim 3, it is characterised in that the water
The preparation method of property epoxy modified acrylic resin, comprises the following steps:
(1) epoxy resin and 90% stirring solvent is added by formula to dissolve and be warming up to 110-160 DEG C;
(2) be at the uniform velocity added dropwise with 3-4hr according to formula ratio acrylic compounds carboxylic monomer, acrylic compounds carboxylic monomer, styrene,
The mixture of isobornyl methacrylate and 70% initiator, is divided into 3 parts after dripping by the initiator of residue 30%,
It is per hour plus a, finally continue to react 3hr;
(3) 80 DEG C are cooled to, remaining solvent is added, stirs, obtain waterborne epoxy modified acrylic resin.
8. according to any described automobile engine oil pan energy-saving and environment-friendly paints of claim 1-7, it is characterised in that
The coating is coated to automobile engine oil pan steel slab surface, 200-250 DEG C of roller coat temperature, roller coat by roll coating model
Number is 1-2 times.
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CN201610278064.7A CN107312368A (en) | 2016-04-26 | 2016-04-26 | A kind of automobile engine oil pan energy-saving and environment-friendly paint |
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CN201610278064.7A CN107312368A (en) | 2016-04-26 | 2016-04-26 | A kind of automobile engine oil pan energy-saving and environment-friendly paint |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108976970A (en) * | 2018-07-30 | 2018-12-11 | 合肥铭佑高温技术有限公司 | A kind of high-temperature service heat-resisting paint and preparation method thereof |
CN109181495A (en) * | 2018-09-29 | 2019-01-11 | 佛山科学技术学院 | A kind of environmental protection coating material and preparation method thereof |
CN109777242A (en) * | 2019-02-21 | 2019-05-21 | 上海振华重工(集团)常州油漆有限公司 | A kind of water-base resin and preparation method thereof suitable for aqueous quick-drying anti-corrosive primer |
CN113845810A (en) * | 2021-09-07 | 2021-12-28 | 湖州玖丰新材料科技有限公司 | Preparation process of explosion-proof flexible paint |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104513344A (en) * | 2014-12-04 | 2015-04-15 | 北京金汇利应用化工制品有限公司 | Waterborne epoxy modified acrylic resin and aqueous dispersion thereof |
CN105038344A (en) * | 2015-09-02 | 2015-11-11 | 太仓市金新涂料有限公司 | Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator |
-
2016
- 2016-04-26 CN CN201610278064.7A patent/CN107312368A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104513344A (en) * | 2014-12-04 | 2015-04-15 | 北京金汇利应用化工制品有限公司 | Waterborne epoxy modified acrylic resin and aqueous dispersion thereof |
CN105038344A (en) * | 2015-09-02 | 2015-11-11 | 太仓市金新涂料有限公司 | Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108976970A (en) * | 2018-07-30 | 2018-12-11 | 合肥铭佑高温技术有限公司 | A kind of high-temperature service heat-resisting paint and preparation method thereof |
CN109181495A (en) * | 2018-09-29 | 2019-01-11 | 佛山科学技术学院 | A kind of environmental protection coating material and preparation method thereof |
CN109777242A (en) * | 2019-02-21 | 2019-05-21 | 上海振华重工(集团)常州油漆有限公司 | A kind of water-base resin and preparation method thereof suitable for aqueous quick-drying anti-corrosive primer |
CN113845810A (en) * | 2021-09-07 | 2021-12-28 | 湖州玖丰新材料科技有限公司 | Preparation process of explosion-proof flexible paint |
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Application publication date: 20171103 |