CN103820008A - One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof - Google Patents
One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof Download PDFInfo
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- CN103820008A CN103820008A CN201410058848.XA CN201410058848A CN103820008A CN 103820008 A CN103820008 A CN 103820008A CN 201410058848 A CN201410058848 A CN 201410058848A CN 103820008 A CN103820008 A CN 103820008A
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Abstract
The invention relates to a one-component acrylic acid epoxy modified waterborne environment-friendly coating, and a production method thereof. The waterborne environment-friendly coating comprises, by weight, 50-60 parts of a waterborne acrylic acid epoxy modified resin, 5-10 parts of a pigment iron oxide red, 20-30 parts of a rust-proof material aluminium triphosphate, 2-5 parts of hydropalat100 dispersant, 0.5-1 part of Alex F-252 anti-corrosion and mould-proof bactericide, 1-5 parts of PE100 wetting agent, 5-10 parts of dispersant hydropalat3275, 1-5 parts of LS4110 organic tin drying catalyst and 1-5 parts of a waterborne coating bubble-control agent. An object of the invention is to provide the one-component acrylic acid epoxy modified waterborne environment-friendly coating which has very good coating corrosion resistance and water resistance, can be normally applied in an environment with a temperature ten degrees below zero, and has a long service life, and has no toxicity, no taste and no organic volatile matter discharge. Besides, a production method of the coating is provided.
Description
Technical field
The present invention relates to a kind of single-component acrylic acid epoxy modified water-soluble environmental protection coating material and and production method.
Background technology
Existing water-based anticorrosive paint is in the larger gap of the aspect such as water tolerance, preservative property existence compared with oil paint, in use usually occur ftractureing, coming off, mouldy, the usage period is shorter, the problem such as acid and alkali-resistance not, and water-borne coatings Celsiusly more than 0 ℃ could constructing, lower temperature resistance is poor, is difficult to meet the service requirements under many occasions.
Summary of the invention
The object of the present invention is to provide that a kind of coating is corrosion-resistant, water tolerance is very good; can under subzero ten degree environment Celsius, use by normal construction; long service life; nontoxic, tasteless, without organic volatile discharge, can effectively protect working-yard not contaminated single-component acrylic acid epoxy modified water-soluble environmental protection coating material and production method.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, comprise that weight part is the water soluble acrylic acid epoxy modified resin of 50-60, weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the Alex F-252 anticorrosive mildewproof sterilant of 0.5-1, weight part is the PE100 wetting agent of 1-5, weight part is the dispersion agent Hydropakat3275 of 5-10, weight part is the LS4110 organotin siccative of 1-5, weight part is the water-borne coatings foam control agent of 1-5, weight part is the water of 10-15, weight part is the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1, weight part is the nano silicon Hardening agent of 5-10, weight part is the adhesion promoter F4011 of 1-5, weight part is the strong thixotropic thickening agent DSX3290 of 1-5,
Described water soluble acrylic acid epoxy modified resin adopts following methods to make:
It is that 20 CoatOSi 12287 aqueous latex paint auxiliary agents are as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain described water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, the weight part of wherein said water soluble acrylic acid epoxy modified resin is 52-58, the weight part of described pigment red iron oxide is 6-8, the weight part of described antirust material aluminium triphosphate is 22-28, the weight part of described Hydropalat100 dispersion agent is 3-4, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.6-0.8, the weight part of described PE100 wetting agent is 2-4, the weight part of described dispersion agent Hydropalat3275 is 6-8, the weight part of described LS4110 organotin siccative is 2-4, the weight part of described water-borne coatings foam control agent is 2-4, the weight part of described water is 12-14, the weight part of described water-soluble multifunctional pH value conditioning agent AMP-95 is 0.6-0.8, the weight part of described nano silicon Hardening agent is 6-8, the weight part of described adhesion promoter F4011 is 2-4, the weight part of described strong thixotropic thickening agent DSX3290 is 2-4.
The water that is 12-14 by weight part, weight part is 34 Hydropalat100 dispersion agent, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the LS4110 organotin siccative that 2228 antirust material aluminium triphosphate and weight part are 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, the weight part of wherein said water soluble acrylic acid epoxy modified resin is 54-56, the weight part of described pigment red iron oxide is 7, the weight part of described antirust material aluminium triphosphate is 24-26, the weight part of described Hydropalat100 dispersion agent is 3.5, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.7, the weight part of described PE100 wetting agent is 3, the weight part of described dispersion agent Hydropalat3275 is 7, the weight part of described LS4110 organotin siccative is 3, the weight part of described water-borne coatings foam control agent is 3, the weight part of described water is 13, the weight part of described water-soluble multifunctional pH value conditioning agent AMP-95 is 0.7, the weight part of described nano silicon Hardening agent is 7, the weight part of described adhesion promoter F40011 is 3, the weight part of described strong thixotropic thickening agent DSX3290 is 3.
The water that is 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 PE100 wetting agent, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydropalat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F-252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, it is that 20 CoatOSil2287 aqueous latex paint auxiliary agent is as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, the water that is preferably wherein 12-14 by weight part, weight part is the Hydropalat100 dispersion agent of 3-4, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the antirust material aluminium triphosphate of 22-28 and the LS4110 organotin siccative that weight part is 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, the water that is preferably further wherein 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 PE100 wetting agent, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydropalat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention and production method, by the distinctive formula of the present invention, adopt unique processing step, the water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, add again weight part be the water-based of 0.5-1 help more can pH value conditioning agent AMP-95 and weight part be 0.5-1 Alex F-252 anticorrosive mildewproof sterilant stirs 5-20 minute with the rotating speed of 400-600 rev/min, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.The single-component acrylic acid epoxy modified water-soluble environmental protection coating material of making, the water tolerance of its coating, preservative property, lower temperature resistance are good, and do not ftracture, and do not come off, not mouldy, roll painting, not sagging of spraying wet film 300 μ m; Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention can be constructed under-10 ℃ of environment, change the requirement that water-borne coatings more than 0 ℃ could be constructed: single-component acrylic acid epoxy modified water-soluble environmental protection coating material long service life of the present invention, can reach 15 years, exceeding existing oil paint and make the more than a times of the time limit, is the substitute products of oil paint.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention is a kind of water quality product; there is nontoxic, tasteless, reactive organometal compound volatile emission, without catching fire, without features such as blast, single-component easy construction, fast dryings; and easy construction; can effectively protect working-yard not contaminated, be the Green Product in a kind of real view meaning.
Below in conjunction with single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention and production method are described further.
Embodiment
Embodiment 1
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, comprise that weight part is the water soluble acrylic acid epoxy modified resin of 50-60, weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the Alox F-252 anticorrosive mildewproof sterilant of 0.5-1, weight part is the PE100 wetting agent of 1-5, weight part is the dispersion agent Hydropalat3275 of 5-10, weight part is the LS4110 organotin siccative of 1-5, weight part is the water-borne coatings foam control agent of 1-5, weight part is the water of 10-15, weight part is the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1, weight part is the nano silicon Hardening agent of 5-10, weight part is the adhesion promoter F4011 of 1-5, weight part is the strong thixotropic thickening agent DSX3290 of 1-5,
Described water soluble acrylic acid epoxy modified resin adopts following methods to make:
It is that 20 CoatOSil2287 aqueous latex paint auxiliary agent is as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain described water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400--600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy and change part Environmental Protective Water-paint.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, the weight part of preferred described water soluble acrylic acid epoxy modified resin is 52-58, the weight part of described pigment red iron oxide is 6-8, the weight part of described antirust material aluminium triphosphate is 22-28, the weight part of described Hydropalat100 dispersion agent is 3-4, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.6-0.8, the weight part of described PE100 wetting agent is 2-4, the weight part of described dispersion agent Hydropalat3275 is 6-8, the weight part of described LS4110 organotin siccative is 2-4, the weight part of described water-borne coatings foam control agent is 2-4, the weight part of described water is 12-14, the weight part of described water-soluble multifunctional pH value conditioning agent AMP-95 is 0.6-0.8, the weight part of described nano silicon Hardening agent is 6-8, the weight part of described adhesion promoter F4011 is 2-4, the weight part of described strong thixotropic thickening agent DSX3290 is 2-4.
The water that is 12-14 by weight part, weight part is the Hydropalat100 dispersion agent of 3-4, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the antirust material aluminium triphosphate of 22-28 and the LS4110 organotin siccative that weight part is 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
Single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention, more preferably the weight part of described water soluble acrylic acid epoxy modified resin is 54-56, the weight part of described pigment red iron oxide is 7, the weight part of described antirust material aluminium triphosphate is 24-26, the weight part of described Hydropalat100 dispersion agent is 3.5, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.7, the weight part of described PE100 wetting agent is 3, the weight part of described dispersion agent Hydropalat3275 is 7, the weight part of described LS4110 organotin siccative is 3, the weight part of described water-borne coatings foam control agent is 3, the weight part of described water is 13, the weight part of described water-soluble multifunctional pH value conditioning agent AMP-95 is 0.7, the weight part of described nano silicon Hardening agent is 7, the weight part of described adhesion promoter F4011 is 3, the weight part of described strong thixotropic thickening agent DSX3290 is 3.
The water that is 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 PE100 wetting agent, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydrpalat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F-252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention is: it is that 20 CoatOSil2287 aqueous latex paint auxiliary agent is as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention: the water that to be preferably weight part be 12-14, weight part is the Hydropalat100 dispersion agent of 3-4, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the antirust material aluminium triphosphate of 22-28 and the LS4110 organotin siccative that weight part is 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
The production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material of the present invention: the water that is more preferably 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 PE100 wetting agent, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydropalat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F-252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
Embodiment recited above is described the preferred embodiment of the present invention; not scope of the present invention is limited; design under spiritual prerequisite not departing from the present invention; various distortion and improvement that the common engineering technical personnel in this area make technical solution of the present invention, all should fall in the definite protection domain of claims of the present invention.
Claims (6)
1. single-component acrylic acid epoxy modified water-soluble environmental protection coating material, it is characterized in that comprising that weight part is the water soluble acrylic acid epoxy modified resin of 50-60, weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the Alex F-252 anticorrosive mildewproof sterilant of 0.5-1, weight part is the PE100 wetting agent of 1-5, weight part is the dispersion agent Hydropalat3275 of 5-10, weight part is the LS4110 organotin siccative of 1-5, weight part is the water-borne coatings foam control agent of 1-5, weight part is the water of 10-15, weight part is the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1, weight part is the nano silicon Hardening agent of 5-10, weight part is the adhesion promoter F4011 of 1-5, weight part is the strong thixotropic thickening agent DSX3290 of 1-5,
Described water soluble acrylic acid epoxy modified resin adopts following methods to make:
It is that 20 CoatOSil2287 aqueous latex paint auxiliary agent is as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain described water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400-600 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 1400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
2. single-component acrylic acid epoxy modified water-soluble environmental protection coating material according to claim 1, it is characterized in that: the weight part of described water soluble acrylic acid epoxy modified resin is 52-58, the weight part of described pigment red iron oxide is 6-8, the weight part of described antirust material aluminium triphosphate is 22-28, the weight part of described Hydropalat100 dispersion agent is 3-4, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.6-0.8, the weight part of described PE100 wetting agent is 2-4, the weight part of described dispersion agent Hydropalat3275 is 6-8, the weight part of described LS4110 organotin siccative is 2-4, the weight part of described water-borne coatings foam control agent is 2-4, the weight part of described water is 12-14, the weight part of described water-soluble multifunctional pH value conditioning agent AMP 95 is 0.6-0.8, the weight part of described nano silicon Hardening agent is 6-8, the weight part of described adhesion promoter F4011 is 2-4, the weight part of described strong thixotropic thickening agent DSX3290 is 2-4,
The water that is 12-14 by weight part, weight part is the Hydropalat100 dispersion agent of 3-4, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the antirust material aluminium triphosphate of 22-28 and the LS4110 organotin siccative that weight part is 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
3. single-component acrylic acid epoxy modified water-soluble environmental protection coating material according to claim 2, it is characterized in that: the weight part of described water soluble acrylic acid epoxy modified resin is 54-56, the weight part of described pigment red iron oxide is 7, the weight part of described antirust material aluminium triphosphate is 24-26, the weight part of described Hydropalat100 dispersion agent is 3.5, the weight part of described Alex F-252 anticorrosive mildewproof sterilant is 0.7, the weight part of described PE100 wetting agent is 3, the weight part of described dispersion agent Hyeropalat3275 is 7, the weight part of described LS4110 organotin siccative is 3, the weight part of described water-borne coatings foam control agent is 3, the weight part of described water is 13, the weight part of described water-soluble multifunctional pH value conditioning agent AMP-95 is 0.7, the weight part of described nano silicon Hardening agent is 7, the weight part of described adhesion promoter F4011 is 3, the weight part of described strong thixotropic thickening agent DSX3290 is 3,
The water that is 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 property 100 wetting agents, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydroaplat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F-252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
4. the production method of single-component acrylic acid epoxy modified water-soluble environmental protection coating material, it is characterized in that: it is that 20 CoatOSil2287 aqueous latex paint auxiliary agent is as properties-correcting agent that the water-based epoxy acrylic resin that is 980 using weight part adds weight part under 400-600 rev/min of agitation condition, stir 30 minutes, deposit again 48 hours, obtain water soluble acrylic acid epoxy modified resin;
The water that is 10-15 by weight part, weight part is the Hydropalat100 dispersion agent of 2-5, weight part is the PE100 wetting agent of 1-5, weight part is that the water-borne coatings foam control agent of 1-5 stirs 5-20 minute with the rotating speed of 400-600 rev/min, then adding weight part is the pigment red iron oxide of 5-10, weight part is the antirust material aluminium triphosphate of 20-30 and the LS4110 organotin siccative that weight part is 1-5, and raise speed to the rotating speed stirring 20-40 minute of 1000-1400 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and to add weight part to reactor third be that the water soluble acrylic acid epoxy modified resin of 50-60 stirs 10-30 minute with the rotating speed of 400--600 rev/min, adding weight part is that the nano silicon Hardening agent of 5-10 is stirred 10-30 minute with the rotating speed of 1000-1400 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 5-10 stirs 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.5-1 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.5-1 stir 5-20 minute with the rotating speed of 400-600 rev/min again, adding weight part is that the adhesion promoter F4011 of 1-5 and strong thixotropic thickening agent DSX3290 that weight part is 1-5 stir 10-30 minute with the rotating speed of 400-600 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
5. according to the production method of weighing and require the single-component acrylic acid epoxy modified water-soluble environmental protection coating material described in 4, it is characterized in that: the water that is 12-14 by weight part, weight part is the Hydropalat100 dispersion agent of 3-4, weight part is the PE100 wetting agent of 2-4, weight part is that the water-borne coatings foam control agent of 2-4 stirs 8-15 minute with the rotating speed of 450-550 rev/min, then adding weight part is the pigment red iron oxide of 6-8, weight part is the antirust material aluminium triphosphate of 22-28 and the LS4110 organotin siccative that weight part is 2-4, and raise speed to the rotating speed stirring 25-35 minute of 1100-1300 rev/min, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 52-58 stirs 15-25 minute with the rotating speed of 450-550 rev/min to adding weight part in reactor, adding weight part is that the nano silicon Hardening agent of 6-8 is stirred 15-25 minute with the rotating speed of 1100-1300 rev/min again, adding weight part is that the dispersion agent Hydropalat3275 of 6-8 stirs 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the water-soluble multifunctional pH value conditioning agent AMP-95 of 0.6-0.8 and Alex F-252 anticorrosive mildewproof sterilant that weight part is 0.6-0.8 stir 8-15 minute with the rotating speed of 450-550 rev/min again, adding weight part is that the adhesion promoter F4011 of 2-4 and strong thixotropic thickening agent DSX3290 that weight part is 2-4 stir 15-25 minute with the rotating speed of 450-550 rev/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
6. according to the production method of weighing and require the single-component acrylic acid epoxy modified water-soluble environmental protection coating material described in 5, it is characterized in that: the water that is 13 by weight part, weight part is 3.5 Hydropalat100 dispersion agent, weight part is 3 PE100 wetting agent, weight part is that 3 water-borne coatings foam control agent stirs 10 minutes with the rotating speed of 500 revs/min, then adding weight part is 7 pigment red iron oxide, weight part is the antirust material aluminium triphosphate of 24-26 and the LS4110 organotin siccative that weight part is 3, and speed-raising to the rotating speed of 1200 revs/min stirs 30 minutes, obtain mixed solution, then allow mixed solution carry out levigate by sand mill to it, again levigate mixed solution is added in reactor, and be that the water soluble acrylic acid epoxy modified resin of 54-56 stirs 20 minutes with the rotating speed of 500 revs/min to adding weight part in reactor, adding weight part is that 7 nano silicon Hardening agent is stirred 20 minutes with the rotating speed of 1200 revs/min again, adding weight part is that 7 dispersion agent Hydropalat3275 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the Alex F-252 anticorrosive mildewproof sterilant that 0.7 water-soluble multifunctional pH value conditioning agent AMP-95 and weight part are 0.7 stirs 10 minutes with the rotating speed of 500 revs/min again, adding weight part is that the strong thixotropic thickening agent DSX3290 that 3 adhesion promoter F4011 and weight part are 3 stirs 20 minutes with the rotating speed of 500 revs/min again, obtain single-component acrylic acid epoxy modified water-soluble environmental protection coating material.
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