CN109181450A - A kind of dedicated Lacquer finish water paint of plastering and preparation method thereof - Google Patents
A kind of dedicated Lacquer finish water paint of plastering and preparation method thereof Download PDFInfo
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- CN109181450A CN109181450A CN201810999356.9A CN201810999356A CN109181450A CN 109181450 A CN109181450 A CN 109181450A CN 201810999356 A CN201810999356 A CN 201810999356A CN 109181450 A CN109181450 A CN 109181450A
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- plastering
- dedicated
- lacquer finish
- water paint
- finish water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of dedicated Lacquer finish water paints of plastering, including following components, the mass percent of each component are as follows: silica solution 40%~50%, pure-acrylic emulsion 10%~24%, additive 6%~10%, aqueous color paste 0%~10% and deionized water 10%~44%, the pH value of the silica solution is 6.5~8.0, and partial size is 8~15nm.The preparation method of the dedicated Lacquer finish water paint of the plastering is additionally provided, including mixing the silica solution of the ratio, pure-acrylic emulsion, additive, aqueous color paste and deionized water, filters after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.The dedicated Lacquer finish water paint of plastering, coating adhesion are strong, it is not easy to which cracking and simultaneously translucency are high.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of dedicated Lacquer finish water paint of plastering and its preparation sides
Method.
Background technique
Coating (paint), our usually described paint are only one such.Finger is coated on body surface certain
Under the conditions of can form film and play a class I liquid I of protection, decoration or other specific functions (insulation, antirust, mould proof, heat-resisting etc.)
Or solid material.Because the coating of early stage is mostly using vegetable oil as primary raw material, therefore also referred to as paint.Present synthetic resin has replaced
Vegetable oil, therefore referred to as coating.Coating is simultaneously non-liquid, and powdery paints is one major class of coating variety.The material applied to from coating
Divide, is divided into metallic paint, glass coating and plastering coating.From the point of view of the position of environmental protection, paint industry Ying Xiangshui
Property, Harmless, energy saving and resource direction develop, common coating is organic coating on building wall at present, by
It is that therefore its water resistance, resistance to soiling, mildew resistance are poor for organic matter in its main component, the inorganic exterior coating of silica solution is domestic close several
Year starts to grow up.Finishing varnish: being the finishing varnish of a kind of transparent, not yellowing, UV resistant and chemical attack.Purposes: have
High glaze and high gloss retention, can be used for various wear surfaces, play decoration and protective effect.Advantage: 1. high gloss retentions, not yellowing；
2. high abrasion resistance, resistant to many chemicals corrodes smooth finish surface as 3. ceramic tiles, and effective dust is antifouling.
It is long-standing to the research of silica-sol wash, but since silica solution is not easy to form a film, it is easily cracked, stability is also slightly
Difference, therefore silica-sol wash has very big defect on film forming and storage stability.And color is easy when silica-sol wash application
It is distorted, poor transparency, fidelity decline, in the coating products for especially needing to repeat to construct, the degree meeting of this decline
It becomes apparent from.It is strong that how a kind of coating adhesion is developed, it is not easy to which cracking and the simultaneously high Lacquer finish water paint of translucency become urgently
It solves the problems, such as.
Summary of the invention
It is an object of the invention to overcome the defect of the prior art, it is aqueous to provide a kind of dedicated Lacquer finish of plastering
Paint, coating adhesion are strong, it is not easy to which cracking and simultaneously translucency are high.
The present invention is implemented as follows:
It is an object of the present invention to provide a kind of dedicated Lacquer finish water paint of plastering, including following components, each groups
The mass percent divided are as follows: silica solution 40%~50%, pure-acrylic emulsion 10%~25%, additive 5%~10%, aqueous color paste
0%~10% and deionized water 10%~45%.
Preferably, the additive following components, each component account for the mass percent of Lacquer finish water paint total amount are as follows: film forming promotees
Into agent 0.8%~1%, propylene glycol 2%~2.5%, dispersing agent 0.5%~0.8%, wetting agent 0.2%~0.4%, defoaming agent
0.1%~0.3%, pH stabilizer 0.4%~0.6%, fungicide 0.1%~0.3%, thickener 0.3%~0.5%, hydrophobic
Agent 1%~1.2%.
Preferably, the pure-acrylic emulsion selects anionic, minimum film formation temperature≤20 DEG C, glass transition temperature 23
DEG C, brookfield viscosity is at 25 DEG C, No. 3 rotors, 200~8000mPa.s under 30 revs/min, and solid content is 49~51%.
Preferably, the dispersing agent meets following performance indicators: solid content 45%, pH value 7, density 1.31g/
Cm3, wherein the density is measured at 20 DEG C, brookfield viscosity is at 25 DEG C, No. 2 rotors, is less than 1400mPa.s under 60 revs/min.
Preferably, the defoaming agent is non-ionic paraffin class, density 0.88g/cm3, wherein the density is at 25 DEG C
When measure.
The second object of the present invention is to provide a kind of preparation method of dedicated Lacquer finish water paint of plastering, the side
Method includes mixing the silica solution of the ratio, pure-acrylic emulsion, additive, aqueous color paste and deionized water, after mixing evenly mistake
Filter, obtains the dedicated Lacquer finish water paint of the plastering.
The key technical indexes of the dedicated Lacquer finish water paint raw materials of plastering is as follows:
1, silica solution: it is purchased from Zhejiang Province Yuda Chemical Co., Ltd
Table 1
| Product type | SiO2Content | Na2O content | PH value | Viscosity mPas | Partial size nm |
| Neutral ZS | 30 | ≤0.2 | 6.5-8.0 | ≤10 | 8-15 |
2, pure-acrylic emulsion: the AC-261C model selected from the Dow Chemical Company
Table 2
3, film forming accelerating: film forming accelerating be selected from Eastman company 12 model film forming accelerating of alcohol ester, appearance without
The transparent liquid of color, no insoluble substance；Purity >=99；280 DEG C of boiling point；Flash-point >=150.
4, dispersing agent；Dispersing agent is selected from the fast easy model dispersing agent of the Dow Chemical Company
Table 3
5, wetting agent: the BD-109 model wetting agent selected from the Dow Chemical Company
Table 4
| Apparently | Weak yellow liquid |
| Effective solid content, % | 90 |
| Cloud point | 64 |
| Hydrophilic lipophilic balance (HLB) | 12.5 |
| Pour point, DEG C | 5 |
| PH, 1% aqueous solution | 6.2 |
| Viscosity, 40 DEG C, cSt (centistoke) | 61.8 |
| Density, 40 DEG C, g/ml | 1.0157 |
| Close flash point, ASTMD93 | 288℃ |
| Surface tension | 31 |
6, pH stabilizer: for the AMP-95 of Dow Chemical Company.
Table 5
7, defoaming agent: model: SN-DEFOAMER1340 is purchased from Sheng Nuopuke company of Japan；Appearance: lark is opaque
Liquid；Specific gravity: 0.88 (25 DEG C)；It is ionic: nonionic；Dispersibility: disperse in water；Flash-point: 174；Viscosity: 400；Ingredient:
Paraffin class.
8, fungicide: fungicide is selected from the A26 model fungicide of Shu Mei company, appearance: yellowish transparency liquid；Effectively at
Point: >=17%；PH value: 3.0~5.0；Viscosity (20 degrees Celsius): 10~20 centipoises；Density (20 degrees Celsius): 1.08~1.16g/
cm3；Dissolubility (20 degrees Celsius): miscible with water；Stability: stablize when light is stable, temperature is lower than 50 degrees Celsius；PH compatibility
Property: stablize when pH value 2~10.
9, hydrophober: selection organosilicon moisture repellent is Germany watt gram BS1306, appearance milky white；Active matter content 55%；
Density (25 DEG C of g/cm3) 0.99；PH is 7.
Compared with prior art, the invention has the advantages that and effect:
1, the dedicated Lacquer finish water paint of plastering provided by the invention, with the prior art (silica solution body in the prior art
The pH stable of system guarantees that silica sol particle surface is negatively charged between 8.5-10.5) unlike, we select neutral silicon molten
Glue (pH value 6.5-8.0) is to keep the stability of coating, and the applicant unexpectedly sends out in order not to allow silica solution premature set
Existing neutrality silica solution is all improved the overall performance of coating, such as glossiness, weatherability, stain resistance, water resistance etc..
2, the dedicated Lacquer finish water paint of plastering provided by the invention, selects suitable proportion, each group point of coating it
Between there is mutually synergistic effect, coating adhesion is strong, it is not easy to which cracking and simultaneously translucency are high.Coating membrane formation mechanism: silica solution
It is using water dispersion as the colloidal solution of the poly- metasilicic acid of the inorganic polymer of medium, silicon dioxide granule is mostly with spherical single or more
A coalescence dispersion, can be securely attached to substrate and filler particles surface, with the continuous evaporation of moisture, between silicon dioxide granule
The rigidity that firm Si-O key can be formed is stronger, and film forming crosslinking is again the process of a shrink, if silica solution room temperature is used alone
Often there are the critical defects such as crackle, internal capillary in film-forming, after introducing organic polymer emulsion, organic polymer film forming matter
Si-O can be evenly distributed in apply in intermembrane space, drawbacks described above can be eliminated to a certain extent.However in order to further enhance
The bonding of silica solution and lotion, the addition of auxiliary agent and the content of each component, to film forming, the adhesion for improving inorganic silica solution
And flexibility is most important, the present invention in silica solution 40%~50%, pure-acrylic emulsion 10%~25%, additive 5%~10%,
Aqueous color paste 0%~10% and deionized water 10%~45%, silica solution be neutrality ZS, pH value 6.5-8.0, each group of coating
/ there is mutually synergistic effect, coating adhesion is strong, it is not easy to which cracking and simultaneously translucency are high.
Specific embodiment
Embodiment 1
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
The pH value of glue 40%, pure-acrylic emulsion 10%, additive 7% and deionized water 44%, the silica solution is 6.5~8.0, and partial size is
8~15nm.
The additive includes 1% film forming accelerating, 2% propylene glycol, 0.8% dispersing agent, 0.4% wetting
Agent, 0.3% defoaming agent, 0.6% pH stabilizer, 0.3% fungicide, 0.5% thickener；1% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Embodiment 2
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
The pH value of glue 50%, pure-acrylic emulsion 24%, additive 6% and deionized water 20%, the silica solution is 6.5~8.0, and partial size is
8~15nm.
The additive includes 0.8% film forming accelerating, 2% propylene glycol, 0.5% dispersing agent, 0.2% wetting
Agent, 0.3% defoaming agent, 0.5% pH stabilizer, 0.2% fungicide, 0.5% thickener；1% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Embodiment 3
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
Glue 40%, pure-acrylic emulsion 10%, additive 7%, aqueous color paste 4% and deionized water 40%, the pH value of the silica solution are 6.5
~8.0, partial size is 8~15nm.
The additive includes 1% film forming accelerating, 2% propylene glycol, 0.8% dispersing agent, 0.4% wetting
Agent, 0.3% defoaming agent, 0.6% pH stabilizer, 0.3% fungicide, 0.5% thickener；1% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Embodiment 4
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
Glue 50%, pure-acrylic emulsion 24%, additive 6%, aqueous color paste 10% and deionized water 10%, the pH value of the silica solution are
6.5~8.0, partial size is 8~15nm.
The additive includes 0.8% film forming accelerating, 2% propylene glycol, 0.5% dispersing agent, 0.2% wetting
Agent, 0.3% defoaming agent, 0.5% pH stabilizer, 0.2% fungicide, 0.5% thickener；1% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Embodiment 5
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
Glue 45%, pure-acrylic emulsion 15%, additive 8%, aqueous color paste 8% and deionized water 24%, the pH value of the silica solution are 6.5
~8.0, partial size is 8~15nm.
The additive includes 0.9% film forming accelerating, 2.5% propylene glycol, 0.6% dispersing agent, 0.3% profit
Humectant, 0.1% defoaming agent, 0.4% pH stabilizer, 0.1% fungicide, 0.3% thickener；1.2% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Embodiment 6
1, the dedicated Lacquer finish water paint of a kind of plastering, including following components, the mass percent of each component are as follows: silicon is molten
Glue 48%, pure-acrylic emulsion 12%, additive 7%, aqueous color paste 9% and deionized water 24%, the pH value of the silica solution are 6.5
~8.0, partial size is 8~15nm.
The additive includes 0.9% film forming accelerating, 2.2% propylene glycol, 0.7% dispersing agent, 0.3% profit
Humectant, 0.2% defoaming agent, 0.4% pH stabilizer, 0.1% fungicide, 0.4% thickener；1.1% hydrophober.
2, the preparation method of the dedicated Lacquer finish water paint of the plastering, the method includes the silicon of the ratio is molten
Glue, pure-acrylic emulsion, additive, aqueous color paste and deionized water mixing are placed in Scattered Kettle stirring, and mixing speed is 500~700r/
Min, 10~30min of mixing time, is filtered after mixing evenly, obtains the dedicated Lacquer finish water paint of the plastering.
Comparative example 1
Except the pH stable of silica solution is in 8.5-10.5, remaining is consistent with embodiment 4.
Experimental example 1
Embodiment 1-2 is the dedicated colourless Lacquer finish water paint of plastering；
Embodiment 3-6 is the dedicated coloured Lacquer finish water paint of plastering；Aqueous color paste therein can be to plastering
The color of itself plays repair.
The dedicated Lacquer finish water paint of the plastering of above-described embodiment 1- embodiment 6 and comparative example 1 presses JG/T26-2002
Standard carry out the detections of various indexs, the results are shown in Table 6:
Table 6
As seen from Table 6, the service performance of the dedicated Lacquer finish water paint of plastering of the invention is good, and drying time is fast,
Water resistance, brushing resistance, stain resistance, temperature-change resistance are good, and artificial weathering ageing resistance is good, and light transmittance is high.
The dedicated Lacquer finish water paint of plastering provided by the invention, compared with the prior art, we select neutral silica solution
(pH value 6.5-8.0) is the stability of coating to be kept, by embodiment 1-6 and comparative example 1 in order not to allow silica solution premature set
Compared to it is found that the overall performance of coating is all improved, for example, glossiness, weatherability, stain resistance, water resistance etc..Present invention choosing
Suitable proportion is selected, has mutually synergistic effect, coating adhesion strong between each component of coating, it is not easy to be cracked and saturating simultaneously
Photosensitiveness is high.
Described is only presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on should all include within protection scope of the present invention.
Claims (9)
1. a kind of dedicated Lacquer finish water paint of plastering, which is characterized in that including following components, the mass percent of each component
Are as follows: it silica solution 40%~50%, pure-acrylic emulsion 10%~24%, additive 6%~10%, aqueous color paste 0%~10% and goes
Ionized water 10%~44%, the pH value of the silica solution are 6.5~8.0.
2. the dedicated Lacquer finish water paint of plastering as described in claim 1, which is characterized in that including following components, each group
The mass percent divided are as follows: silica solution 40%~50%, pure-acrylic emulsion 10%~24%, additive 6%~8%, aqueous color paste
4%~10% and deionized water 10%~40%, the pH value of the silica solution is 6.5~8.0.
3. the dedicated Lacquer finish water paint of plastering as described in claim 1, which is characterized in that the additive is with the following group
Point, each component accounts for the mass percent of Lacquer finish water paint total amount are as follows: and film forming accelerating 0.8%~1%, propylene glycol 2%~
2.5%, dispersing agent 0.5%~0.8%, wetting agent 0.2%~0.4%, defoaming agent 0.1%~0.3%, pH stabilizer 0.4%
~0.6%, fungicide 0.1%~0.3%, thickener 0.3%~0.5%, hydrophober 1%~1.2%.
4. the dedicated Lacquer finish water paint of plastering as described in claim 1, which is characterized in that the pure-acrylic emulsion is selected
Anionic, minimum film formation temperature≤20 DEG C, glass transition temperature are 23 DEG C, and brookfield viscosity is at 25 DEG C, No. 3 rotors, 30 revs/min
Lower 200~8000mPa.s, solid content are 49~51%.
5. the dedicated Lacquer finish water paint of plastering as described in claim 1, which is characterized in that under the dispersing agent meets
State performance indicator: solid content 45%, pH value 7, density 1.31g/cm3, wherein the density is measured at 20 DEG C, Bu Shi is viscous
Degree is at 25 DEG C, No. 2 rotors, and 1400mPa.s is less than under 60 revs/min.
6. the dedicated Lacquer finish water paint of plastering as described in claim 1, which is characterized in that the defoaming agent be it is non-from
Subtype paraffin class, density 0.88g/cm3, wherein the density is measured at 25 DEG C.
7. a kind of preparation method of the dedicated Lacquer finish water paint of plastering as described in claim 1-6 is any, feature exist
In, the method includes the silica solution of the ratio, pure-acrylic emulsion, additive, aqueous color paste and deionized water are mixed, stirring
Filtering, obtains the dedicated Lacquer finish water paint of the plastering after uniformly.
8. the preparation method of the dedicated Lacquer finish water paint of plastering as claimed in claim 7, which is characterized in that the stirring
When be placed in Scattered Kettle stirring.
9. the preparation method of the dedicated Lacquer finish water paint of plastering as claimed in claim 7, which is characterized in that the stirring
Speed is 500~700r/min, 10~30min of mixing time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810999356.9A CN109181450A (en) | 2018-08-30 | 2018-08-30 | A kind of dedicated Lacquer finish water paint of plastering and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810999356.9A CN109181450A (en) | 2018-08-30 | 2018-08-30 | A kind of dedicated Lacquer finish water paint of plastering and preparation method thereof |
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| CN109181450A true CN109181450A (en) | 2019-01-11 |
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ID=64916775
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128856A (en) * | 2019-05-14 | 2019-08-16 | 东南大学 | A kind of gypsum material surface passivation reinforcing agent and preparation method thereof |
| CN116463018A (en) * | 2023-05-06 | 2023-07-21 | 上海虹涂新材料科技有限公司 | High-hardness water-based fluorocarbon coating and preparation method thereof |
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| CN102702898A (en) * | 2012-06-29 | 2012-10-03 | 惠州市长润发涂料有限公司 | Organic-inorganic composite water-borne woodenware paint |
| CN103483883A (en) * | 2013-09-05 | 2014-01-01 | 鳄鱼制漆(上海)有限公司 | High-performance silica sol inorganic exterior wall coating |
| CN104530884A (en) * | 2015-01-08 | 2015-04-22 | 四川嘉宝莉涂料有限公司 | Modified nano-silica sol finishing varnish and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1898345A (en) * | 2003-12-25 | 2007-01-17 | Sk化研株式会社 | Aqueous coating composition |
| CN102702898A (en) * | 2012-06-29 | 2012-10-03 | 惠州市长润发涂料有限公司 | Organic-inorganic composite water-borne woodenware paint |
| CN103483883A (en) * | 2013-09-05 | 2014-01-01 | 鳄鱼制漆(上海)有限公司 | High-performance silica sol inorganic exterior wall coating |
| CN104530884A (en) * | 2015-01-08 | 2015-04-22 | 四川嘉宝莉涂料有限公司 | Modified nano-silica sol finishing varnish and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110128856A (en) * | 2019-05-14 | 2019-08-16 | 东南大学 | A kind of gypsum material surface passivation reinforcing agent and preparation method thereof |
| CN116463018A (en) * | 2023-05-06 | 2023-07-21 | 上海虹涂新材料科技有限公司 | High-hardness water-based fluorocarbon coating and preparation method thereof |
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Application publication date: 20190111 |