CN110395965A - It is a kind of to remove aldehyde interior wall coating and preparation method thereof by the inorganic of filler material of conch meal - Google Patents
It is a kind of to remove aldehyde interior wall coating and preparation method thereof by the inorganic of filler material of conch meal Download PDFInfo
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- CN110395965A CN110395965A CN201910763803.5A CN201910763803A CN110395965A CN 110395965 A CN110395965 A CN 110395965A CN 201910763803 A CN201910763803 A CN 201910763803A CN 110395965 A CN110395965 A CN 110395965A
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- interior wall
- inorganic
- wall coating
- conch meal
- filler material
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- 239000000463 material Substances 0.000 title claims abstract description 114
- 238000000576 coating method Methods 0.000 title claims abstract description 98
- 239000011248 coating agent Substances 0.000 title claims abstract description 92
- 235000012054 meals Nutrition 0.000 title claims abstract description 75
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims abstract description 60
- 239000000945 filler Substances 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 114
- DIFFLMNDXWOKQJ-UHFFFAOYSA-N [K].O[Si](O)(O)O Chemical compound [K].O[Si](O)(O)O DIFFLMNDXWOKQJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 63
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 43
- 238000002156 mixing Methods 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 25
- 239000002518 antifoaming agent Substances 0.000 claims description 23
- 239000000839 emulsion Substances 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 21
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 21
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 20
- 239000003381 stabilizer Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003755 preservative agent Substances 0.000 claims description 19
- 230000002335 preservative effect Effects 0.000 claims description 19
- 235000010215 titanium dioxide Nutrition 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 17
- 229920003086 cellulose ether Polymers 0.000 claims description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 206010001497 Agitation Diseases 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 7
- -1 alcohol ester Chemical class 0.000 claims description 7
- CLSIFQGHPQDTHQ-DTWKUNHWSA-N (2s,3r)-2-[(4-carboxyphenyl)methyl]-3-hydroxybutanedioic acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC1=CC=C(C(O)=O)C=C1 CLSIFQGHPQDTHQ-DTWKUNHWSA-N 0.000 claims description 6
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 4
- 229920000142 Sodium polycarboxylate Polymers 0.000 claims description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical group O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 229940088710 antibiotic agent Drugs 0.000 claims 1
- 230000003115 biocidal effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 26
- 238000000034 method Methods 0.000 abstract description 11
- 239000003973 paint Substances 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 8
- 238000010276 construction Methods 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 7
- 239000000049 pigment Substances 0.000 abstract description 7
- 238000005299 abrasion Methods 0.000 abstract description 5
- 238000000354 decomposition reaction Methods 0.000 abstract description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 238000012856 packing Methods 0.000 abstract description 2
- 235000019256 formaldehyde Nutrition 0.000 description 33
- 239000000243 solution Substances 0.000 description 17
- 239000006185 dispersion Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 235000003140 Panax quinquefolius Nutrition 0.000 description 4
- 240000005373 Panax quinquefolius Species 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920002866 paraformaldehyde Polymers 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000002000 scavenging effect Effects 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000579895 Chlorostilbon Species 0.000 description 2
- 241000337636 Kalama Species 0.000 description 2
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910052876 emerald Inorganic materials 0.000 description 2
- 239000010976 emerald Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001312214 Epipremnum aureum Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MUCRYNWJQNHDJH-OADIDDRXSA-N Ursonic acid Chemical compound C1CC(=O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C(O)=O)CC[C@@H](C)[C@H](C)[C@H]5C4=CC[C@@H]3[C@]21C MUCRYNWJQNHDJH-OADIDDRXSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2069—Self-cleaning materials, e.g. using lotus effect
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of using conch meal as the inorganic except aldehyde interior wall coating and preparation method thereof of filler material, belongs to interior wall coating technical field.The present invention uses conch meal for main packing material, using inorganic silicic acid potassium as main film forming substance, it is auxiliary to match diatomite modified purifying formaldehyde material and antimildew and antibacterial material, pollution of the solid-state shell to environment can either be eliminated, can also free formaldehyde in adsorption-decomposition function room air well, reach unification decorative and functional；Meanwhile the present invention is by control material composition and consumption proportion, gained interior wall coating product without formaldehyde, without APEO, moderate viscosity can directly add the existing dispersible pigment color paste of collocation, and without using special pigment, when use is not required to carry out primary coat construction, time and labour saving；And this interior wall coating environmental pollution is small, paint film fast drying, alkali resistance is good, abrasion resistance is good, self-cleaning is good.The present invention also provides the preparation method of above-mentioned interior wall coating, this method is simple and easy, it is easy to accomplish industrialized production.
Description
Technical field
It is the present invention relates to interior wall coating technical field, in particular to a kind of to remove aldehyde interior wall by the inorganic of filler material of conch meal
Coating and preparation method thereof.
Background technique
Due to continuing to optimize for furniture environment, the decorative of household building materials is continuously improved, and causes indoor formaldehyde content exceeded
The phenomenon that it is commonplace.Currently, the mode of indoor removal formaldehyde mainly has adsorbent material absorption method (active carbon, silica gel etc.), plants
Object absorption method (epipremnum aureum) etc., in addition to this, except the application of methanal paint also becomes the focus of people's research.
However, it is existing except methanal paint quality is irregular in the market, it can not reach good and remove effect of formaldehyde,
Defect of both mainly having, the persistence of the respectively inefficient and purifying formaldehyde of purifying formaldehyde are too low.
Summary of the invention
In view of this, it is an object of that present invention to provide it is a kind of using conch meal as filler material it is inorganic except aldehyde interior wall coating and its
Preparation method.It is provided by the invention it is inorganic except aldehyde interior wall coating can free formaldehyde effectively in adsorption-decomposition function room air, to first
Aldehyde purifying rate is high, and the good combination property of paint film.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
Aldehyde interior wall coating, the group including following mass parts are removed by the inorganic of filler material of conch meal the present invention provides a kind of
Point:
Preferably, described using conch meal as the inorganic except aldehyde interior wall coating includes the component of following mass parts of filler material:
Preferably, the conch meal is low temperature calcination conch meal, and partial size is 10~18 μm.
Preferably, the antifreezing agent is ethylene glycol and/or propylene glycol；
The cellulose ether is hydroxyethyl ether cellulose；
The stabilizer is 2-amino-2-methyl-1-propanol；
The coalescing agent is alcohol ester 12；
The defoaming agent is mineral oil antifoam agent.
Preferably, the dispersing agent is sodium polycarboxylate；
The preservative is isothiazolinone and its derivative, benzisothiazole-3-ketone and 2- methyl -4- isothiazoline -
One or more of 3- ketone；
The partial size of the rutile type titanium white is 6~8 μm；
The partial size of the talcum powder is 10~13 μm.
Preferably, the diatomite modified purifying formaldehyde material be the net aldehyde agent of CBMA, 10 μm of partial size <；
The antimildew and antibacterial material is CBMA mould inhibitor.
Preferably, the solid content of the styrene-acrylic emulsion is 48 ± 1%；
The modulus of the inorganic silicic acid potassium solution is 3.8~4.2, and Baume degrees is 30~35%, and pH value is 10 ± 0.5.
The present invention provides above-mentioned using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material, including following
Step:
(1) first 19~22 parts of water are mixed with antifreezing agent, cellulose ether, are once stirred, sequentially add stabilizer,
Defoaming agent, coalescing agent and dispersing agent carry out secondary agitation, obtain premix；
(2) by the premix and rutile titanium white powder, talcum powder, conch meal, diatomite modified purifying formaldehyde material,
The mixing of antimildew and antibacterial material, carries out triple mixing, obtains mixed liquor；
(3) after the fineness of the mixed liquor is lower than 50 μm, the mixed liquor and styrene-acrylic emulsion, inorganic silicic acid potassium is molten
Liquid, preservative, levelling agent and remaining water mixing, carry out four stirrings, obtain using conch meal as the inorganic except aldehyde interior wall of filler material
Coating.
Preferably, the fineness of mixed liquor is lower than 50 μm in the step (2).
Preferably, the speed once stirred in the step (1) is 700~800rpm, and the time is 8~15min；Described two
The speed of secondary stirring is 700~800rpm, and the time is 10~15min；The temperature of triple mixing is 40~60 in the step (2)
DEG C, speed is 1400~1600rpm, and the time is 25~30min；In the step (3) four times stirring speed be 700~
800rpm, time are 10~15min.
The present invention provides it is a kind of using conch meal as filler material it is inorganic remove aldehyde interior wall coating, the present invention use conch meal for
It is filled primarily with material, it is auxiliary to match diatomite modified purifying formaldehyde material and antimildew and antibacterial using inorganic silicic acid potassium as main film forming substance
Material can either eliminate pollution of the solid-state shell to environment, additionally it is possible to which free formaldehyde in adsorption-decomposition function room air well reaches
To unification decorative and functional；Meanwhile the present invention passes through control material composition and consumption proportion, gained interior wall coating product
Without formaldehyde, without APEO, moderate viscosity can directly add the existing dispersible pigment color paste of collocation, without using special pigment, when use not
It need to carry out primary coat construction, time and labour saving；And this interior wall coating environmental pollution is small, paint film fast drying, alkali resistance are good, abrasion resistance
Well, self-cleaning is good.Embodiment the result shows that, it is provided by the invention using conch meal be filler material it is inorganic except aldehyde interior wall coating to first
The removal rate of aldehyde is up to 90% or more, is higher than country JC/T 1074-2008 " function of purifying indoor air coating material purification property
Can " purification efficiency requirement；Pigment contrast ratio is 0.96, surface drying time 1.5h, and abrasion resistance is 1200 times, is above JG/
T26-2002 " exterior wall inorganic architectural coatings " standard.
Aldehyde interior wall coating is removed by the inorganic of filler material of conch meal the present invention provides above-mentioned, this method is simple and easy, is easy to
Realize industrialized production.
Specific embodiment
Aldehyde interior wall coating, the group including following mass parts are removed by the inorganic of filler material of conch meal the present invention provides a kind of
Point:
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 16~25 of filler material in terms of mass fraction
The conch meal of part, preferably 18~20 parts, more preferably 21.5 parts.In the present invention, the conch meal is preferably low temperature calcination
Conch meal, partial size are preferably 10~18 μm, and more preferably 12~16 μm.It is special that the present invention does not have the source of the conch meal
It is required that in the specific embodiment of the invention, the conch meal is Shandong Binzhou using the conch meal of this field conventional commercial
The oyster shell powder of the model RT73116 of Rui Tai aquaculture Co., Ltd production.The present invention is using conch meal as filler, Ke Yizeng
Add the specific surface area of powder in coating, increases contact of the coating with air to effective adsorption-decomposition function formaldehyde.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 0.6~1 of filler material in terms of mass fraction
The antifreezing agent of part, preferably 0.7~0.9 part, more preferably 0.8 part.In the present invention, the antifreezing agent is preferably ethylene glycol
And/or propylene glycol.The present invention does not have special requirement to the source of the antifreezing agent, uses the antifreezing agent of this field conventional commercial
.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.3~
0.5 part of cellulose ether, preferably 0.4 part.In the present invention, the cellulose ether is preferably hydroxyethyl ether cellulose.This hair
The bright source to the cellulose ether does not have special requirement, using the cellulose ether of this field conventional commercial, in this hair
In bright specific embodiment, the cellulose ether is the 100000H hydroxyethyl ether cellulose of Shandong Yin Ying joint-stock company production.At this
In invention, the cellulose ether plays thickening, suspension, bonding, dispersion, moisture and protecting colloid etc. is kept to improve storage stability
The effect of energy.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 0.8~1 of filler material in terms of mass fraction
The stabilizer of part, preferably 0.9 part.In the present invention, the stabilizer is preferably 2-amino-2-methyl-1-propanol.The present invention
There is no special requirement to the source of the stabilizer, using the stabilizer of this field conventional commercial, of the invention specific
In embodiment, the stabilizer is 955 model stabilizers of Guangdong Zhong Xiu foreign trade Co., Ltd production.In the present invention
In, the 2-amino-2-methyl-1-propanol stabilizer can well control the pH value of coating between 10~11, and with
Inorganic silicic acid potassium and styrene-acrylic emulsion have good compatibility.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.3~
0.5 part of coalescing agent, preferably 0.4 part.In the present invention, the coalescing agent is preferably alcohol ester 12.The present invention is to institute
The source for stating coalescing agent does not have special requirement, using the coalescing agent of this field conventional commercial, of the invention specific
In embodiment, the coalescing agent be Europe Emerald Kalama chemical company produce model K-FLEX975P at
Film auxiliary agent.In the present invention, the coalescing agent can reduce the minimum film formation temperature of coating, assign the good hydrophobicity of paint film
Energy.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.2~
0.5 part of defoaming agent.In the present invention, the defoaming agent is preferably mineral oil antifoam agent.The present invention carrys out the defoaming agent
Source does not have special requirement, using the defoaming agent of this field conventional commercial, in the specific embodiment of the invention, and the defoaming
Agent is the defoaming agent of the model SN-154 of Sheng Nuopu company, Japan production, this defoaming agent has excellent lasting defoaming capacity, can
To prevent coating from blistering for a long time；With excellent foam inhibition ability, film is without residual bubble；It is small on the toning of coating influence, it is not easy to produce
Raw shrinkage cavity.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.2~
0.4 part of dispersing agent, preferably 0.3 part.In the present invention, the dispersing agent is preferably sodium polycarboxylate aqueous solution, and quality is dense
Degree preferably 38.5~43%.The present invention does not have special requirement to the source of the dispersing agent, uses this field conventional commercial
Dispersing agent, in the specific embodiment of the invention, the dispersing agent be Sheng Nuopuke company, Japan produce model SN-
5040 dispersing agent.In the present invention, the dispersing agent can reduce the bubble of coating, and shorten the brokenly bubble time of coating, mention
The water resistance of high paint film.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.2~
0.4 part of preservative, preferably 0.3 part.In the present invention, the preservative is isothiazolinone and its derivative, benzisoxa
One of thiazole -3- ketone and 2-methyl-4-isothiazolin-3-one.It is special that the present invention does not have the source of the preservative
It is required that in a specific embodiment of the present invention, the preservative is Guangdong enlightening using the preservative of this field conventional commercial
The preservative of the model MBT-35 of U.S. Bioisystech Co., Ltd production, active constituent content 7%, pH value 8.5.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 14~18 of filler material in terms of mass fraction
The rutile type titanium white of part, preferably 14.5~16 parts.In the present invention, the partial size of the rutile type titanium white is preferably
6~8 μm.The present invention does not have special requirement to the source of the rutile type titanium white, uses the gold of this field conventional commercial
Red stone-type titanium dioxide, in a specific embodiment of the present invention, the rutile type titanium white are that the new good fortune titanium dioxide in Ningbo has
The rutile type titanium white of the model NTR-606 of limit company production.In the present invention, the titanium dioxide can be improved interior wall painting
Resistance to chalking, gloss retention, colour retention and the whiteness of material, and then interior wall coating is improved to the reflective insulation performance of sunlight.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 8~10 of filler material in terms of mass fraction
The talcum powder of part, preferably 9 parts.In the present invention, the partial size of the talcum powder is preferably 10~13 μm, more preferably 11~12
μm.The present invention does not have special requirement to the source of the talcum powder, using the talcum powder of this field conventional commercial, at this
In invention specific embodiment, the talcum powder is the talcum powder that the production of scholar's chemical materials Co., Ltd is carried out in Foshan.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 0.6~1 of filler material in terms of mass fraction
The diatomite modified purifying formaldehyde material of part, preferably 0.8~1 part.In the present invention, the diatomite modified purifying formaldehyde material
Material is preferably the net aldehyde agent of CBMA of Beijing Zhongyanyi Engineering Technology Development Center Co., Ltd.'s production；The diatomite modified formaldehyde
10 μm of the preferred < of the partial size of scavenging material.In the present invention, the diatomite modified purifying formaldehyde material can quickly, in large quantities
The formaldehyde pollutants in air are removed, it is especially good to the formaldehyde removal effect of low concentration；And diatomite modified purifying formaldehyde material
Material is free of heavy metal, and the feature of environmental protection is good, good with the other compositions safety compatibility in coating.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.5~
0.8 part of antimildew and antibacterial material, preferably 0.6~0.7 part.In the present invention, the antimildew and antibacterial material is preferably in Beijing
Grind the CBMA mould inhibitor of beneficial engineering development centered finite company production.The material is with appropriate pore volume and Large ratio surface
Long-pending porous environment mineral material loads organic mould proof component and metal ion antimicrobial component, realizes material by slow release method
Excellent antibacterial and mouldproof performance and antibacterial and mouldproof persistence, and the biological safety of the material and antibacterial and mouldproof long-term effect are better than
Traditional organic anti-fungus material；And the material has broad spectrum activity, can persistently press down and kill the harmful microorganisms such as most bacteriums, mould,
Applicable pH range is extensive, and pH6~13 can be used, and VOC, free formaldehyde and heavy metal are free of in ingredient.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 8~12 of filler material in terms of mass fraction
The styrene-acrylic emulsion of part, preferably 10 parts.In the present invention, the solid content of the styrene-acrylic emulsion is preferably 48 ± 1%.The present invention couple
The source of the styrene-acrylic emulsion does not have special requirement, using the styrene-acrylic emulsion of this field conventional commercial, of the invention
In specific embodiment, the styrene-acrylic emulsion is Wanhua Chemical Group Co., Ltd.'s production, and the trade mark is
8169 styrene-acrylic emulsion, this styrene-acrylic emulsion have ordor removing, low VOC performance, and the formaldehyde etc. that can be effectively reduced in room air has
Evil substance, can assign the performances such as the excellent washability of paint film and early stage anti-powdering in the lower situation of additive amount.
It is provided by the invention using conch meal as the inorganic except aldehyde interior wall coating includes 18~20 of filler material in terms of mass fraction
The inorganic silicic acid potassium solution of part, preferably 19 parts.In the present invention, the modulus of the inorganic silicic acid potassium solution be preferably 3.8~
4.2, Baume degrees is preferably 30~35%, and pH value is preferably 10 ± 0.5.The present invention does not have the source of the inorganic silicic acid potassium solution
There is special requirement, uses the inorganic silicic acid potassium solution of this field conventional commercial, in a specific embodiment of the present invention, institute
State the inorganic silicic acid potassium solution for 966 models that inorganic silicic acid potassium solution is the production of Guangdong Zhong Xiu foreign trade Co., Ltd.In
In the present invention, the high mould potassium silicate plays function served as bridge in linear styrene-acrylic emulsion film forming procedure, wherein linear phenylpropyl alcohol cream
" net hole " shape solid mesh-like structure is formed between liquid and potassium silicate molecule, this " net hole " is with excellent ventilative and water penetration
Can, diatomite modified purifying formaldehyde material can be increased and capture the probability of formaldehyde, and prevent metope from condensing.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 0.2~
0.5 part of levelling agent, preferably 0.3~0.4 part.The present invention does not have special requirement to the source of the levelling agent, uses this
The levelling agent of field conventional commercial, in a specific embodiment of the present invention, the levelling agent are Rhom and Hass, the U.S.
The levelling agent of the model RM-2020 of production.
In terms of mass fraction, it is provided by the invention using conch meal as filler material it is inorganic except aldehyde interior wall coating include 19.5~
23.3 parts of water, preferably 20~22 parts.In the present invention, the water is preferably deionized water.
The present invention uses conch meal for main packing material, auxiliary to match diatomite using inorganic silicic acid potassium as main film forming substance
Modified formaldehyde scavenging material and antimildew and antibacterial material can either eliminate pollution of the solid-state shell to environment, additionally it is possible to inhale well
Free formaldehyde in Fufen solution room air, reaches unification decorative and functional；Meanwhile the present invention passes through control material composition
And consumption proportion, gained interior wall coating product are free of formaldehyde, no APEO, moderate viscosity can directly add the existing pigment colour of collocation
Slurry, without using special pigment；And this interior wall coating environmental pollution is small, paint film fast drying, alkali resistance is good, abrasion resistance is good,
Self-cleaning is good.
Present invention preferably uses brushing, spraying or roll coating process to described using conch meal as the inorganic except aldehyde interior wall applies of filler material
Material carries out construction coating, and the construction spreading rate is preferably 4m2/ kg, the working viscosity of the interior wall coating is preferably 65~
70KU.Before carrying out construction coating, the present invention preferably clears up metope, greasy dirt, dust on removal metope, and metope
Moisture content is preferably 3~5%, and pH value is preferably 8~9；Carry out construction coating when, air humidity preferably≤85%, temperature it is excellent
>=5 DEG C of choosing.It is provided by the invention to be not required to progress bottom when constructing and being coated with except aldehyde interior wall coating by the inorganic of filler material of conch meal
Apply construction, it is only necessary to it constructs twice on smooth putty, time and labour saving；Also be not required to again overlay treatment can be solved it is self-cleaning
Problem has good electric transfer performance, will not generate electrostatic because it is inorganic product.
The present invention provides above-mentioned using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material, including following
Step:
(1) 19~22 parts of water are mixed with antifreezing agent, cellulose ether, is once stirred, sequentially adds stabilizer, disappears
Infusion, coalescing agent and dispersing agent carry out secondary agitation, obtain premix；
(2) by the premix and rutile titanium white powder, talcum powder, conch meal, diatomite modified purifying formaldehyde material
It is mixed with antimildew and antibacterial material, carries out triple mixing, obtain mixed liquor；
(3) mixed liquor is mixed with styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling agent and remaining water, into
Row four times stirrings are obtained using conch meal as the inorganic except aldehyde interior wall coating of filler material.
The present invention mixes 19~22 parts of water with antifreezing agent, cellulose ether, is once stirred, sequentially adds stabilization
Agent, defoaming agent, coalescing agent and dispersing agent carry out secondary agitation, obtain premix.In the present invention, the moisture is twice
It is added, the water being added for the first time is 19~22 parts, preferably 20~21 parts.In the present invention, the speed once stirred
Preferably 700~800rpm, more preferably 750rpm, time are preferably 8~15min, more preferably 10~12min；Described one
Secondary stirring preferably carries out at normal temperature.In the present invention, the speed of the secondary agitation is preferably 700~800rpm, more preferably
For 750rpm, the time is preferably 10~15min, more preferably 12~14min；The secondary agitation preferably carries out at normal temperature.
After obtaining the premix, the present invention by the premix and rutile titanium white powder, talcum powder, conch meal,
Diatomite modified purifying formaldehyde material and the mixing of antimildew and antibacterial material, carry out triple mixing, obtain mixed liquor.In the present invention,
The fineness of the mixed liquor is preferably shorter than 50 μm, more preferably less than 40 μm.In the present invention, the temperature of the triple mixing is preferred
It is 40~60 DEG C, more preferably 50 DEG C, speed is preferably 1400~1600rpm, more preferably 1500rpm, and the time is preferably 25
~30min, more preferably 26~28min.
After obtaining mixed liquor, the present invention is by the mixed liquor and styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling
Agent and remaining water mixing, carry out four stirrings, obtain using conch meal as the inorganic except aldehyde interior wall coating of filler material.In the present invention
In, the speed of four stirrings is preferably 700~800rpm, and more preferably 750rpm, the time is preferably 10~15min, more
Preferably 12~14min.The present invention is conducive to the evenly dispersed of each component by control charging sequence, stirring rate and time,
Making the fineness of coating reduces.
Aldehyde interior wall coating and its system are removed by the inorganic of filler material of conch meal to provided by the invention below with reference to embodiment
Preparation Method is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
It is a kind of to remove aldehyde interior wall coating, including 21.3 parts of deionized water, antifreezing agent 0.8 by the inorganic of filler material of conch meal
Part, 0.3 part of cellulose ether, 1 part of stabilizer, 0.4 part of defoaming agent, 0.5 part of coalescing agent, 0.3 part of dispersing agent, rutile titanium dioxide
14.5 parts of powder, 8.5 parts of talcum powder, 21.5 parts of conch meal, 1 part of diatomite modified purifying formaldehyde material, antimildew and antibacterial material 0.6
Part, 10 parts of styrene-acrylic emulsion, 18.5 parts of inorganic silicic acid potassium solution, 0.4 part of preservative, 0.4 part of levelling agent.
Wherein, the antifreezing agent is ethylene glycol；The cellulose ether is that Shandong Yin Ying joint-stock company 100000H ethoxy is fine
Tie up plain ether；The stabilizer is 955 model stabilizers of Guangdong Zhong Xiu foreign trade Co., Ltd production, and ingredient is 2- ammonia
Base-2- methyl-1-propyl alcohol；The defoaming agent is the mineral oil antifoam agent that the model SN-154 of Japanese Sheng Nuopu company production is；
The coalescing agent is the coalescing agent of the model K-FLEX975P of European Emerald Kalama chemical company production,
Ingredient is alcohol ester 12；The dispersing agent is the dispersing agent that Japanese Sheng Nuopuke company production model is SN-5040, and ingredient is
Sodium polycarboxylate；The rutile titanium white powder is the rutile of the model NTR-606 of Ningbo Xinfu Titanium Dioxide Co., Ltd.'s production
Titanium dioxide；The talcum powder is the talcum powder for the model 1250 that the production of scholar's chemical materials Co., Ltd is carried out in Foshan, grain
Diameter is 13 μm；The conch meal is Shandong Binzhou Rui Tai aquaculture Co., Ltd model RT73116 oyster shell powder, partial size
It is 10 μm；The diatomite modified purifying formaldehyde material is the silicon of Beijing Zhongyanyi Engineering Technology Development Center Co., Ltd.'s production
Diatomaceous earth modified formaldehyde scavenging material, partial size is less than 10 μm；The antimildew and antibacterial material is that beneficial engineering development is ground in Beijing
The antimildew and antibacterial material of centered finite company production；The styrene-acrylic emulsion is Wanhua Chemical Group Co., Ltd.'s production,
The trade mark is8169；The inorganic silicic acid potassium solution is the production of Guangdong Zhong Xiu foreign trade Co., Ltd, model
It is 966；The preservative is Guangdong Dimei Biological Technology Co., Ltd.'s production, model MBT-35；The levelling agent is
The production of Rhom and Hass, the U.S., model RM-2020.
It is described using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material the following steps are included:
(1) 20 parts of deionized waters are added in reactor tank, start dispersion machine；Antifreezing agent and fibre are added while agitating
Plain ether is tieed up, uniform dispersion liquid is stirred into, the speed of stirring is 700rpm, and mixing time is 10 minutes；
(2) sequentially stabilizer, defoaming agent, coalescing agent, dispersing agent are added in reactor tank while agitating, are stirred
At uniform dispersion liquid, the speed of stirring is 700rpm, and mixing time is 15 minutes；
(3) mixing speed at least reactor tank is then improved to 40 DEG C, sequentially adds rutile titanium white powder, talcum powder, shell
Powder, diatomite modified purifying formaldehyde material, antimildew and antibacterial material are dispersed with stirring uniformly, and mixing speed need to be maintained at 1400rpm, stir
Mixing the time is 25 minutes, obtains the mixed liquor that fineness is lower than 50 μm；
(4) styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling agent and residue are added sequentially in Xiang Suoshu mixed liquor
Deionized water is dispersed with stirring uniformly, mixing speed 700rpm, is stirred 10 minutes, is obtained removing by the inorganic of filler material of conch meal
Aldehyde interior wall coating.
Because country not yet puts into effect the relevant criterion of interior wall inorganic coating, in order to verify the appearance of gained coating, stability, apply
The performances such as work, contrast ratio, surface drying time, abrasion resistance, stain resistance borrow the subitem target of exterior wall inorganic architectural coatings
Standard carries out properties of product test.To 1 gained interior wall coating product of embodiment according to JG/T26-2002 " exterior wall inorganic architectural coatings "
Its performance of standard testing, acquired results are listed in Table 1 below.
The performance test results of 1 embodiment of table, 1 gained interior wall coating
The purifying formaldehyde performance of 1 gained interior wall coating of embodiment is tested, testing standard is according to JC/T1074-2008
" function of purifying indoor air coating material purifying property " is detected.
Continuous 5 times the purifying rate of 1 gained interior wall coating PARA FORMALDEHYDE PRILLS(91,95) of embodiment is tested, test result is respectively
95.32%, 95.18%, 92.66%, 91.54%, 93.08%, 5 times test result remains at 90% or more, is higher than JC/
Purification efficiency requirement in T 1074-2008.
Embodiment 2
It is a kind of to remove aldehyde interior wall coating, including 22.5 parts of deionized water, antifreezing agent 0.6 by the inorganic of filler material of conch meal
Part, 0.5 part of cellulose ether, 0.8 part of stabilizer, 0.2 part of defoaming agent, 0.3 part of coalescing agent, 0.2 part of dispersing agent, rutile type titanium
18 parts of white powder, 10 parts of talcum powder, 25 parts of conch meal, 0.6 part of diatomite modified purifying formaldehyde material, 0.8 part of antimildew and antibacterial material,
8 parts of styrene-acrylic emulsion, 20 parts of inorganic silicic acid potassium solution, 0.2 part of preservative, 0.5 part of levelling agent.
The antifreezing agent is propylene glycol；The manufacturer of remaining raw material and model are same as Example 1.
It is described using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material the following steps are included:
(1) 22 parts of deionized waters are added in reactor tank, start dispersion machine；Antifreezing agent and fibre are added while agitating
Plain ether is tieed up, uniform dispersion liquid is stirred into, the speed of stirring is 800rpm, and mixing time is 8 minutes；
(2) sequentially stabilizer, defoaming agent, coalescing agent, dispersing agent are added in reactor tank while agitating, are stirred
At uniform dispersion liquid, the speed of stirring is 800rpm, and mixing time is 10 minutes；
(3) mixing speed at least reactor tank is then improved to 60 DEG C, sequentially adds rutile titanium white powder, talcum powder, shell
Powder, diatomite modified purifying formaldehyde material, antimildew and antibacterial material are dispersed with stirring uniformly, and mixing speed need to be maintained at 1600rpm, stir
Mixing the time is 30 minutes, obtains the mixed liquor that fineness is lower than 50 μm；
(4) styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling agent and residue are added sequentially in Xiang Suoshu mixed liquor
Deionized water is dispersed with stirring uniformly, mixing speed 800rpm, is stirred 15 minutes, is obtained removing by the inorganic of filler material of conch meal
Aldehyde interior wall coating.
According to 1 method of embodiment to the stability of gained interior wall coating, application property, contrast ratio, surface drying time, washability
Property, the performances such as stain resistance tested, detected, it is " outer that the above-mentioned performance of gained interior wall coating meets JG/T 26-2002
Wall inorganic architectural coatings " requirement.
The purifying rate of 2 gained interior wall coating PARA FORMALDEHYDE PRILLS(91,95) of embodiment is tested according to 1 method of embodiment continuous 5 times, is surveyed
Test result is respectively 94.86%, 95.24%, 92.33%, 93.56%, 93.72%, and 5 times test result remains at 90%
More than, higher than the purification efficiency requirement in JC/T 1074-2008.
Embodiment 3
It is a kind of using conch meal as filler material it is inorganic remove aldehyde interior wall coating, including 19.5 parts of deionized water, 1 part of antifreezing agent,
0.4 part of cellulose ether, 0.9 part of stabilizer, 0.5 part of defoaming agent, 0.4 part of coalescing agent, 0.4 part of dispersing agent, rutile titanium dioxide
16 parts of powder, 9 parts of talcum powder, 16 parts of conch meal, 0.8 part of diatomite modified purifying formaldehyde material, 0.5 part of antimildew and antibacterial material, benzene
12 parts of acrylic emulsion, 18 parts of inorganic silicic acid potassium solution, 0.3 part of preservative, 0.2 part of levelling agent.
The antifreezing agent is propylene glycol；The manufacturer of remaining raw material and model are same as Example 1.
It is described using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material the following steps are included:
(1) 19 parts of deionized waters are added in reactor tank, start dispersion machine；Antifreezing agent and fibre are added while agitating
Plain ether is tieed up, uniform dispersion liquid is stirred into, the speed of stirring is 750rpm, and mixing time is 10 minutes；
(2) sequentially stabilizer, defoaming agent, coalescing agent, dispersing agent are added in reactor tank while agitating, are stirred
At uniform dispersion liquid, the speed of stirring is 750rpm, and mixing time is 13 minutes；
(3) mixing speed at least reactor tank is then improved to 60 DEG C, sequentially adds rutile titanium white powder, talcum powder, shell
Powder, diatomite modified purifying formaldehyde material, antimildew and antibacterial material are dispersed with stirring uniformly, and mixing speed need to be maintained at 1500rpm, stir
Mixing the time is 28 minutes, obtains the mixed liquor that fineness is lower than 50 μm；
(4) styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling agent and residue are added sequentially in Xiang Suoshu mixed liquor
Deionized water is dispersed with stirring uniformly, mixing speed 750rpm, is stirred 12 minutes, is obtained removing by the inorganic of filler material of conch meal
Aldehyde interior wall coating.
According to 1 method of embodiment to the stability of gained interior wall coating, application property, contrast ratio, surface drying time, washability
Property, the performances such as stain resistance tested, detected, it is " outer that the above-mentioned performance of gained interior wall coating meets JG/T 26-2002
Wall inorganic architectural coatings " requirement.
The purifying rate of 3 gained interior wall coating PARA FORMALDEHYDE PRILLS(91,95) of embodiment is tested according to 1 method of embodiment continuous 5 times, is surveyed
Test result is respectively 93.22%, 95.45%, 95.87%, 94.43%, 94.82%, and 5 times test result remains at 90%
More than, higher than the purification efficiency requirement in JC/T 1074-2008.
It is according to above embodiments it is found that provided by the invention inorganic except aldehyde interior wall coating being capable of effective adsorption-decomposition function Interior Space
Free formaldehyde in gas, PARA FORMALDEHYDE PRILLS(91,95) purifying rate is high, and the good combination property of paint film.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that the component including following mass parts:
2. it is according to claim 1 using conch meal as filler material it is inorganic remove aldehyde interior wall coating, which is characterized in that including with
The component of lower mass parts:
3. according to claim 1 or 2 remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that institute
Stating conch meal is low temperature calcination conch meal, and partial size is 10~18 μm.
4. according to claim 1 or 2 remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that institute
Stating antifreezing agent is ethylene glycol and/or propylene glycol；
The cellulose ether is hydroxyethyl ether cellulose；
The stabilizer is 2-amino-2-methyl-1-propanol；
The coalescing agent is alcohol ester 12；
The defoaming agent is mineral oil antifoam agent.
5. according to claim 1 or 2 remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that institute
Stating dispersing agent is sodium polycarboxylate；
The preservative is isothiazolinone and its derivative, benzisothiazole-3-ketone and 2-methyl-4-isothiazolin-3-one
One or more of；
The partial size of the rutile type titanium white is 6~8 μm；
The partial size of the talcum powder is 10~13 μm.
6. according to claim 1 or 2 remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that institute
State diatomite modified purifying formaldehyde material be the net aldehyde agent of CBMA, 10 μm of partial size <；
The antimildew and antibacterial material is CBMA mould inhibitor.
7. according to claim 1 or 2 remove aldehyde interior wall coating by the inorganic of filler material of conch meal, which is characterized in that institute
The solid content for stating styrene-acrylic emulsion is 48 ± 1%；
The modulus of the inorganic silicic acid potassium solution is 3.8~4.2, and Baume degrees is 30~35%, and pH value is 10 ± 0.5.
8. using conch meal as the inorganic preparation method except aldehyde interior wall coating of filler material described in claim 1~7 any one,
Characterized by comprising the following steps:
(1) first 19~22 parts of water are mixed with antifreezing agent, cellulose ether, is once stirred, sequentially add stabilizer, defoaming
Agent, coalescing agent and dispersing agent carry out secondary agitation, obtain premix；
(2) by the premix and rutile titanium white powder, talcum powder, conch meal, diatomite modified purifying formaldehyde material, mould proof
Anti-biotic material mixing, carries out triple mixing, obtains mixed liquor；
(3) mixed liquor is mixed with styrene-acrylic emulsion, inorganic silicic acid potassium solution, preservative, levelling agent and remaining water, carries out four
Secondary stirring is obtained using conch meal as the inorganic except aldehyde interior wall coating of filler material.
9. preparation method according to claim 8, which is characterized in that the fineness of mixed liquor is lower than 50 μ in the step (2)
m。
10. preparation method according to claim 8, which is characterized in that the speed once stirred in the step (1) is
700~800rpm, time are 8~15min；The speed of the secondary agitation is 700~800rpm, and the time is 10~15min；Institute
The temperature for stating triple mixing in step (2) is 40~60 DEG C, and speed is 1400~1600rpm, and the time is 25~30min；It is described
The speed of four stirrings is 700~800rpm in step (3), and the time is 10~15min.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876000A (en) * | 2020-09-09 | 2020-11-03 | 贝卡乐(北京)生物科技有限公司 | Purifying antibacterial shell powder inorganic coating and preparation method thereof |
| CN112778804A (en) * | 2021-01-04 | 2021-05-11 | 安徽省瓷玛新材料技术有限公司 | Inorganic fireproof aldehyde-removing coating |
| CN114149701A (en) * | 2021-12-03 | 2022-03-08 | 广东嘉宝莉科技材料有限公司 | Antiviral and formaldehyde-resistant A-grade fireproof interior wall coating and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268211A (en) * | 2011-07-16 | 2011-12-07 | 江苏冠军涂料科技集团有限公司 | Shell powder biological environment-friendly internal wall coating |
| CN102558987A (en) * | 2012-02-17 | 2012-07-11 | 四川嘉宝莉涂料有限公司 | Reinforced formaldehyde-decomposed dope and preparation method thereof |
| CN102731052A (en) * | 2012-06-08 | 2012-10-17 | 嘉宝莉化工集团股份有限公司 | Aqueous organic-inorganic composite coating and preparation method thereof |
| CN103483935A (en) * | 2013-09-24 | 2014-01-01 | 青岛三立新源电器有限公司 | Waterproof and heat-insulating paint for external wall of building |
| CN105062242A (en) * | 2015-09-07 | 2015-11-18 | 无锡市嘉邦电力管道厂 | Formaldehyde-removing environment-friendly water-based paint and preparation method thereof |
| CN105542603A (en) * | 2016-01-27 | 2016-05-04 | 广东施彩涂料有限公司 | High-strength inorganic paint and preparation method thereof |
| CN105542525A (en) * | 2016-01-27 | 2016-05-04 | 广东施彩涂料有限公司 | Inorganic coating with good storage stability and preparation method thereof |
| CN105731977A (en) * | 2016-01-27 | 2016-07-06 | 广东施彩涂料有限公司 | Water-tolerant inorganic coating and preparation method thereof |
| CN108997854A (en) * | 2018-09-14 | 2018-12-14 | 深圳市博原实业有限公司 | Environment-friendly exterior wall thermal insulation coatings |
| CN109575728A (en) * | 2018-11-29 | 2019-04-05 | 杭州高雅涂料有限公司 | Environment-friendly interior wall coating and preparation method thereof |
-
2019
- 2019-08-19 CN CN201910763803.5A patent/CN110395965A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268211A (en) * | 2011-07-16 | 2011-12-07 | 江苏冠军涂料科技集团有限公司 | Shell powder biological environment-friendly internal wall coating |
| CN102558987A (en) * | 2012-02-17 | 2012-07-11 | 四川嘉宝莉涂料有限公司 | Reinforced formaldehyde-decomposed dope and preparation method thereof |
| CN102731052A (en) * | 2012-06-08 | 2012-10-17 | 嘉宝莉化工集团股份有限公司 | Aqueous organic-inorganic composite coating and preparation method thereof |
| CN103483935A (en) * | 2013-09-24 | 2014-01-01 | 青岛三立新源电器有限公司 | Waterproof and heat-insulating paint for external wall of building |
| CN105062242A (en) * | 2015-09-07 | 2015-11-18 | 无锡市嘉邦电力管道厂 | Formaldehyde-removing environment-friendly water-based paint and preparation method thereof |
| CN105542603A (en) * | 2016-01-27 | 2016-05-04 | 广东施彩涂料有限公司 | High-strength inorganic paint and preparation method thereof |
| CN105542525A (en) * | 2016-01-27 | 2016-05-04 | 广东施彩涂料有限公司 | Inorganic coating with good storage stability and preparation method thereof |
| CN105731977A (en) * | 2016-01-27 | 2016-07-06 | 广东施彩涂料有限公司 | Water-tolerant inorganic coating and preparation method thereof |
| CN108997854A (en) * | 2018-09-14 | 2018-12-14 | 深圳市博原实业有限公司 | Environment-friendly exterior wall thermal insulation coatings |
| CN109575728A (en) * | 2018-11-29 | 2019-04-05 | 杭州高雅涂料有限公司 | Environment-friendly interior wall coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111876000A (en) * | 2020-09-09 | 2020-11-03 | 贝卡乐(北京)生物科技有限公司 | Purifying antibacterial shell powder inorganic coating and preparation method thereof |
| CN112778804A (en) * | 2021-01-04 | 2021-05-11 | 安徽省瓷玛新材料技术有限公司 | Inorganic fireproof aldehyde-removing coating |
| CN114149701A (en) * | 2021-12-03 | 2022-03-08 | 广东嘉宝莉科技材料有限公司 | Antiviral and formaldehyde-resistant A-grade fireproof interior wall coating and preparation method thereof |
| CN114149701B (en) * | 2021-12-03 | 2023-02-28 | 广东嘉宝莉科技材料有限公司 | Antiviral and formaldehyde-resistant A-grade fireproof interior wall coating and preparation method thereof |
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Application publication date: 20191101 |