CN102702898A - Organic-inorganic composite water-borne woodenware paint - Google Patents
Organic-inorganic composite water-borne woodenware paint Download PDFInfo
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Abstract
The invention discloses a kind of organic-inorganic composite water-borne woodenware paint, which comprises the following ingredients in percent by weight: 50 to 65 percent of acrylic emulsion, 10 to 20 percent of silicon sol, 0.1 to 1 percent of dispersing agent, 0.1 to 1 percent of silane coupling agent, 0.1 to 1 percent of leveling wetting agent, 0.1 to 1 percent of defoaming agent, 0.1 to 1 percent of thickener, 0.1 to 1 percent of multifunctional assistant, 2 to 6 percent of film formation assistant and the balance of deionized water. The water-borne woodenware paint is prepared according to a conventional paint production method used by technicians in the field. Compared with traditional acrylic single-component woodenware paint, the paint after forming a film has the characteristics of higher hardness, viscosity resistance, water resistance, adhesion and the like.
Description
Technical field
The present invention relates to a kind of coating of chemical field, particularly organic and inorganic compound aqueous woodware paint.
Background technology
In recent years, along with the continuous enhancing of whole world environmental consciousness, the environmental regulation of various countries is harsh day by day, and is severeer to the restriction of organic volatile in the coating (VOC) content.The continuous developing in woodwork coating market more requires the water-borne wood coating of low VOC to adapt with it, and the novel aqueous woodwork coating of low VOC or zero VOC discharging has become the focus of research and development.At present, use more ACRYLIC EMULSION in the mono-component aqueous wood lacquer and have fast doing, advantage such as fast light, weathering resistance, chemical resistant properties are excellent, and the transparency is good.But the acrylic ester emulsion hardness that second-order transition temperature is low is also low, occurs easily after-tacking; The then film-forming properties that second-order transition temperature is high is relatively poor, is prone to produce be full of cracks, needs to add the solubility promoter of more amount, thus do not reach the purpose of the low VOC of water-borne coatings, and snappiness is also relatively poor.
Summary of the invention
To above-mentioned technological deficiency, the technical problem that the present invention will solve provides a kind of organic and inorganic compound aqueous woodware paint with higher hardness, resistance to blocking, water tolerance, sticking power in addition.
For solving the problems of the technologies described above, the technical scheme that the present invention adopted is:
A kind of organic and inorganic compound aqueous woodware paint; Contain following component by weight percentage: ACRYLIC EMULSION 50-65%, silicon sol 10-20%, dispersion agent 0.1-1%, silane coupling agent 0.1-1%, levelling wetting agent 0.1-1%, skimmer 0.1-1%, thickening material 0.1-1%, multifunctional assistant 0.1-1%, film coalescence aid 2-6%, surplus is a deionized water.
The weighting agent or the pigment that also contain 10-20%, said weighting agent are one or more of talcum powder, silica powder, mica powder, Zinic stearas.
The matting agent that also contains 2-5%, described matting agent are one or both in aerosil or the polyethylene wax powder.
Described ACRYLIC EMULSION is one or more mixtures of pure acrylic acid emulsion, polyurethane-modified acrylic acid emulsion, self-crosslinking acrylic emulsion.
Described dispersion agent is one or more of BYK180, BYL190, BYK192, WET270, WET290.
Said levelling wetting agent is one or more among BYK333, BYK341, BYK345, the BYK346.
Described skimmer is one or more compositions among BYK022, BYK024, BYK028, the BYK044.
Described thickening material is one or more of cellulose thickener, Polyacrylate thickeners, polyurethane thickener.
Described film coalescence aid is one or more among propylene glycol monomethyl ether, Ucar 35 butyl ether, the TEXANOL.
In each component of the present invention, ACRYLIC EMULSION is main filmogen.Silicon sol is claimed silicic acid water glass again, is to be that the inorganic polymer of disperse phase gathers metasilicic acid colloidal solution with water, and odorless is nontoxic; Sizable specific surface area is arranged; The water white transparency of particle own does not influence the true qualities that are capped thing, and dispersiveness and perviousness are all very good when mixing with ACRYLIC EMULSION; The gained paint film can improve performances such as hardness, sticking power, resistance to blocking, water-fast and contamination resistance, is important auxiliary film forming matter.Silane coupling agent is a kind of linking agent that is used to improve water-resistance property of coating and sticking power.Multifunctional assistant is a kind of be used to transfer pH value and organic amine auxiliary agent that improves dispersiveness.
The system lacquer method of using always according to those skilled in the art; ACRYLIC EMULSION and silicon sol are put into system lacquer container by formula rate; Add dispersion agent while stirring and add pigment then; Add multifunctional assistant after high speed dispersion to fineness is qualified while stirring and regulate pH value, at last silane coupling agent, levelling wetting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer to 8-9.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.
Compared with prior art; Prescription of the present invention is ACRYLIC EMULSION 60-65%, silicon sol 10-20%, dispersion agent 0.1-1%, silane coupling agent 0.1-1%, levelling wetting agent 0.1-1%, skimmer 0.1-1%, thickening material 0.1-1%, multifunctional assistant 0.1-1%, film coalescence aid 2-6%, and surplus is a deionized water.Guaranteed that aqueous woodware paint of the present invention compares with traditional aqueous woodware paint, had same high cost performance.That selects to prepare after special emulsion and the silicon sol blend has inorganic and the composite coating organic coating characteristic concurrently, makes this paint film have performances such as better hardness, fullness ratio, resistance to blocking, water-fast and contamination resistance.Product has used silane coupling agent can make paint film that timber is had good adhesive.Product makes the levelling wetting agent can make paint film that timber is had excellent wettability, keeps excellent paint film.Can also add filler, pigment, matting agent in addition.Show through practical application: the present invention can replace traditional single-component water-based wood lacquer fully; Can be applied to the decoration application and the furniture application of family; Under the environmental-protecting performance that guarantees water-miscible paint, obtain better paint film property, can make certain contribution for country advocates environmental protection.
Embodiment
Following examples are that organic and inorganic compound aqueous woodware paint is preferably filled a prescription; These prescriptions are the indefiniteness embodiment; It is to be used to specify the present invention, and those skilled in the art can be protection scope of the present invention according to thinking of the present invention and the prescription that the proportioning of selecting materials filters out fully.
Embodiment 1
A kind of organic and inorganic compound aqueous wooden ware transparent priming; By weight percentage: pure acrylic acid emulsion 60%, silicon sol 10%, weighting agent talcum powder 10%, dispersant B YK180 0.5%, silane coupling agent 0.5%, levelling wetting agent BYK333 0.5%, skimmer BYK022 0.5%, cellulose thickener 0.5%, multifunctional assistant 0.5%, film coalescence aid propylene glycol monomethyl ether 2%, surplus is a deionized water.
The preparation method is: pure acrylic acid emulsion and silicon sol are put into system lacquer container by formula rate; Add dispersion agent while stirring and add weighting agent then; Add multifunctional assistant after high speed dispersion to fineness is qualified while stirring and regulate pH value to 8-9; At last silane coupling agent, levelling wetting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.This aqueous woodware paint has good hardness, sticking power is good, fillibility is good, grinability is good characteristics.
Embodiment 2
A kind of organic and inorganic compound aqueous wooden ware transparent suboptical finish paint; By weight percentage: polyurethane-modified acrylic acid emulsion 55%, silicon sol 15%, matting agent aerosil 2%, dispersant B YL190 0.2%, silane coupling agent 0.2%, levelling wetting agent BYK341 0.2%, skimmer BYK024 0.2%, Polyacrylate thickeners 0.2%, multifunctional assistant 0.2%, film coalescence aid Ucar 35 butyl ether 2%, surplus is a deionized water.
The preparation method is: polyurethane-modified acrylic acid emulsion and silicon sol are put into system lacquer container by formula rate; Add dispersion agent while stirring and add matting agent then; Add multifunctional assistant after high speed dispersion to fineness is qualified while stirring and regulate pH value to 8-9; At last silane coupling agent, levelling wetting agent, matting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.This aqueous woodware paint has performance characteristics such as good hardness, fullness ratio, resistance to blocking, water-fast and contamination resistance.
Embodiment 3
The real look dull surface lacquer of a kind of organic and inorganic compound aqueous wooden ware; By weight percentage: self-crosslinking acrylic emulsion 60%, silicon sol 10%, matting agent polyethylene wax powder 5%, pigment 10%, dispersant B YK192 0.1%, silane coupling agent 0.1%, levelling wetting agent BYK345 0.1%, skimmer BYK028 0.1%, polyurethane thickener 0.1%, multifunctional assistant 0.1%, film coalescence aid TEXANOL 6%, surplus is a deionized water.
The preparation method is: ACRYLIC EMULSION and silicon sol are put into system lacquer container by formula rate; Add dispersion agent while stirring and add pigment then; Add multifunctional assistant after high speed dispersion to fineness is qualified while stirring and regulate pH value to 8-9; At last silane coupling agent, levelling wetting agent, matting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.This aqueous woodware paint has performance characteristics such as good hardness, fullness ratio, resistance to blocking, water-fast and contamination resistance.
Embodiment 4
The transparent light top coat top coat of a kind of organic and inorganic compound aqueous wooden ware; By weight percentage: self-crosslinking acrylic emulsion 60%, silicon sol 15%, dispersion agent WET270 1%, silane coupling agent 1%, levelling wetting agent BYK346 1%, skimmer BYK044 1%, polyurethane thickener 1%, multifunctional assistant 1%, propylene glycol monomethyl ether film coalescence aid 4%, surplus is a deionized water.
The preparation method is: ACRYLIC EMULSION and silicon sol are put into system lacquer container by formula rate; Add multifunctional assistant while stirring and regulate pH value to 8-9; At last silane coupling agent, levelling wetting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.This aqueous woodware paint has performance characteristics such as good hardness, fullness ratio, resistance to blocking, water-fast and contamination resistance.
Embodiment 5
A kind of organic and inorganic compound aqueous wooden ware white primer; By weight percentage: pure acrylic acid emulsion 50%, silicon sol 10%, white pigment white titanium pigment 15%, dispersion agent WET290 0.1%, silane coupling agent 0.1%, levelling wetting agent BYK345 0.1%, skimmer BYK028 0.1%, Polyacrylate thickeners 0.1%, multifunctional assistant 0.1%, film coalescence aid propylene glycol monomethyl ether 2%, surplus is a deionized water.
The preparation method is: pure acrylic acid emulsion and silicon sol are put into system lacquer container by formula rate; Add dispersion agent while stirring and add the white pigment white titanium pigment then; Add multifunctional assistant after high speed dispersion to fineness is qualified while stirring and regulate pH value to 8-9; At last silane coupling agent, levelling wetting agent, skimmer, thickening material, film coalescence aid and deionized water are mixed in proportion the back and disperse the limit to join in the system lacquer container, be uniformly dispersed and promptly get this master's lacquer.Can add 10-30% water before the application and regulate working viscosity to obtain the best effect of filming.This aqueous woodware paint has good hardness, sticking power is good, fillibility is good, grinability is good characteristics.
Claims (9)
1. organic and inorganic compound aqueous woodware paint; It is characterized in that containing by weight percentage following component: ACRYLIC EMULSION 50-65%, silicon sol 10-20%, dispersion agent 0.1-1%, silane coupling agent 0.1-1%, levelling wetting agent 0.1-1%, skimmer 0.1-1%, thickening material 0.1-1%, multifunctional assistant 0.1-1%, film coalescence aid 2-6%, surplus is a deionized water.
2. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: also contain weighting agent or the pigment of 10-20%, said weighting agent is one or more of talcum powder, silica powder, mica powder, Zinic stearas.
3. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: also contain the matting agent of 2-5%, described matting agent is one or both in aerosil or the polyethylene wax powder.
4. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: described ACRYLIC EMULSION is one or more mixtures of pure acrylic acid emulsion, polyurethane-modified acrylic acid emulsion, self-crosslinking acrylic emulsion.
5. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: described dispersion agent is one or more of BYK180, BYL190, BYK192, WET270, WET290.
6. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: said levelling wetting agent is one or more among BYK333, BYK341, BYK345, the BYK346.
7. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: described skimmer is one or more compositions among BYK022, BYK024, BYK028, the BYK044.
8. organic nothing according to claim 1-machine compound aqueous woodware paint is characterized in that: described thickening material is one or more of cellulose thickener, Polyacrylate thickeners, polyurethane thickener.
9. organic and inorganic compound aqueous woodware paint according to claim 1 is characterized in that: described film coalescence aid is one or more among propylene glycol monomethyl ether, Ucar 35 butyl ether, the TEXANOL.
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| CN2012102194572A CN102702898A (en) | 2012-06-29 | 2012-06-29 | Organic-inorganic composite water-borne woodenware paint |
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| CN2012102194572A CN102702898A (en) | 2012-06-29 | 2012-06-29 | Organic-inorganic composite water-borne woodenware paint |
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| CN103819987A (en) * | 2014-01-07 | 2014-05-28 | 江门市制漆厂有限公司 | Waterborne organic/inorganic hybrid plastic coating and preparation method thereof |
| CN104098979A (en) * | 2013-04-15 | 2014-10-15 | 四川远见实业有限公司 | Self-crosslinked high-gloss aqueous woodware finishing coat |
| CN104098961A (en) * | 2013-04-12 | 2014-10-15 | 四川远见实业有限公司 | Self-crosslinking aqueous woodenware primer |
| CN104263141A (en) * | 2013-11-20 | 2015-01-07 | 漳州水之采环保科技有限公司 | Water-based woodenware seal primer and preparing method thereof |
| CN104327632A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Long-lasting fade-proof aqueous coating for glass doors, and its preparation method |
| CN104761992A (en) * | 2015-04-17 | 2015-07-08 | 君子兰化工（上海）有限公司 | Water-based primer for wood enamel sealing and preparation method thereof |
| CN104924388A (en) * | 2014-10-16 | 2015-09-23 | 洋浦久聚台木材科技有限公司 | Wood modification working liquid used for wet plate processing and use method thereof |
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| WO2016095200A1 (en) * | 2014-12-19 | 2016-06-23 | Dow Global Technologies Llc | Aqueous coating composition and process of making the same |
| CN105733428A (en) * | 2016-05-12 | 2016-07-06 | 武汉赫斯特涂层材料股份有限公司 | Water-based fluorine-silicon coating and preparation method thereof |
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| CN106085150A (en) * | 2016-06-10 | 2016-11-09 | 洪其祥 | A kind of aqueous high wear-resistant low luster coating and preparation method thereof |
| CN106118482A (en) * | 2016-07-12 | 2016-11-16 | 无锡市华东电力设备有限公司 | A kind of environmental protection coating material and preparation method thereof |
| CN106380974A (en) * | 2016-08-30 | 2017-02-08 | 河北晨阳工贸集团有限公司 | Nano silica sol modified acrylic acid finishing varnish and preparation method thereof |
| CN106675266A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne colored steel paint |
| CN107446458A (en) * | 2017-08-04 | 2017-12-08 | 合众（佛山）化工有限公司 | A kind of acrylic acid modified polyurethane hybrid resin water paint of enhanced water resistance |
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Application publication date: 20121003 |