CN109179620B - Combined multifunctional health-preserving hydrogen-rich water sheet - Google Patents
Combined multifunctional health-preserving hydrogen-rich water sheet Download PDFInfo
- Publication number
- CN109179620B CN109179620B CN201811186592.5A CN201811186592A CN109179620B CN 109179620 B CN109179620 B CN 109179620B CN 201811186592 A CN201811186592 A CN 201811186592A CN 109179620 B CN109179620 B CN 109179620B
- Authority
- CN
- China
- Prior art keywords
- parts
- hydrogen
- oxide
- water
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a combined multifunctional nutrientRaw hydrogen-rich water tablets relate to the technical field of health care and health preservation. The hydrogen-rich water tablet comprises: the ceramic plate is made of magnesium tourmaline ceramic plate, aluminum oxide ceramic plate and medical stone ceramic plate, and the three ceramic plates are sintered at the temperature lower than 900 ℃. In use, the hydrogen (H) gas can be generated by placing the set in a drinking water device2) Active hydrogen ion (H)+1) Hydroxyl ion (H)3O2 ‑1) And other dissolved and precipitated elements beneficial to human bodies and the like can generate health-care effect and have obvious rehabilitation function on certain diseases. When the magnesium tourmaline, the alumina and the medical stone ceramic wafer are used together, the magnesium tourmaline, the alumina and the medical stone ceramic wafer have interaction, so that the duration of generating hydrogen-rich water is long, the used raw materials are less in amount in the water treatment process, and the cost is lower.
Description
Technical Field
The invention relates to the technical field of health care and health preservation, in particular to a combined multifunctional health-preserving hydrogen-rich water tablet.
Background
Hydrogen-rich water, i.e., hydrogen ion-rich water, is water (hydrorich water) rich in hydrogen ions, and is "aqueous water" in japanese.
The water was investigated in 1998 by the column group of "true phase of exploration" of the japanese sunrise television station, and it was found that the water can treat a variety of diseases, but is not a little deficient and black, and through sampling and research, it was found that the water is not very different from ordinary spring water, and the only difference is that the spring water contains abundant hydrogen, and the hydrogen is difficult to treat? Are not known under the scientific conditions at the time.
For a long time, biologists have considered that hydrogen is a physiologically inert gas, and once in the field of diving medicine, high-pressure hydrogen is used as a breathing medium, so that the technology is an advanced diving technology, and the maximum diving depth of 700 meters in the world is the diving mode adopting breathing hydrogen-oxygen mixed gas. However, this is only the practice in the field of diving medicine, i.e. there are cases where high pressure hydrogen gas is breathed at tens of atmospheres during a hybrid hydrogen-oxygen dive, the amount of gas dissolved in the liquid increases with increasing partial pressure, scientists have tried to prove that hydrogen gas reacts either with oxygen in solution or with highly reactive radicals at high pressure, but no direct evidence of the existence of this reaction has been obtained (Kayar et al.1994). Therefore, most of the research of biologists strongly suggests that hydrogen is a good antioxidant substance. However, hydrogen has a relatively low solubility in water and the like, but oxygen can bind to hemoglobin and can be smoothly absorbed in a large amount by the body through respiration, while hydrogen and nitrogen cannot be absorbed in a large amount. They considered that hydrogen gas does not exhibit reducibility in living organisms, or hydrogen gas does not react with any substance in living organisms, and that hydrogen gas is a physiologically inert gas. Early few thought that hydrogen gas had antioxidant effect, but it had to be carried out at high pressure, and in 1975, it was proved in the scientific paper that by continuously breathing 97.5% hydrogen (2.5% oxygen) at 8 atm for 14 days, high pressure hydrogen gas was effective in treating malignant tumors in animal skin and was thought to be caused by antioxidant effect (Dole et al 1975). In 2001, french medical scientists demonstrated that breathing 8 atmospheres of high pressure hydrogen can treat inflammatory reactions caused by liver parasitic infections, and that hydrogen has anti-inflammatory effects for the first time.
In 2007, 7 months, the scholars of the Japanese medical university report that animals can effectively scavenge free radicals by breathing 2% of hydrogen and remarkably improve cerebral ischemia-reperfusion injury, and the scholars adopt means such as chemical reaction, cytology and the like to prove that hydrogen can be dissolved in liquid to selectively neutralize hydroxyl free radicals and nitrite anions, and the hydroxyl free radicals and the nitrite anions are the most important media for oxidative injury, and in view of the fact that no specific scavenging way is found in vivo at present. Thus, the basis of hydrogen treatment of cerebral ischemia reperfusion injury is believed to be a selective antioxidant effect (Ohsawa et al 2007). The research of the japanese scholars rapidly draws a wide attention and has brought about a hot tide to research hydrogen treatment diseases (there are currently 11 related research works published internationally). Subsequently, this group, again in an animal model of hepatic and myocardial ischemia, demonstrated that breathing 2% hydrogen can treat hepatic and myocardial ischemia-reperfusion injury (Fukuda et al 2007; Hayashida et al 2008). Nerve damage caused by stress, drug toxicity, human type II diabetes mellitus patients and mouse gene deficiency chronic oxidative stress injury can be treated by drinking saturated hydrogen water (Ohsawa et al 2008; Kajiyama et al 2008; Sato et al 2008; Nagata et al 2008; Nakashima-Kamimura et al 2009). The university of pisburg transplantation center in the united states demonstrated that 2% hydrogen gas breathed can treat inflammatory injury caused by small intestine transplantation (Buchholz et al 2008), as well as protect against small intestine ischemia and injury after heart transplantation (conference data). The anesthesia department of Sichuan Huaxi hospital found that 2% of hydrogen can be breathed to treat renal ischemia reperfusion injury (meeting data). Their laboratory also demonstrated that neonatal cerebral ischemic and hypoxic injury can be treated by breathing 2% hydrogen (Cai et al.2008). After the treatment, saturated hydrogen saline is injected firstly, and the injection is proved to have obvious therapeutic effect on neonatal cerebral ischemia-hypoxia injury (Cai et al 2009), myocardial ischemia-reperfusion injury, renal ischemia-reperfusion injury, small intestine ischemia-reperfusion injury (Zheng et al 2009) and the like.
These studies all show that hydrogen, as a selective antioxidant, has therapeutic effects on many diseases, has a very broad application prospect, and suggest that hydrogen may be a new bioactive molecule.
Furthermore, professor Ohsawa, japan medical university, 2007 published a long article "Hydrogen acts as a thermal antioxidant by selective catalytic reduction cytotoxic oxidation radials" (antioxidant treatment of oxygen radicals by Hydrogen action by selectively reducing cytotoxicity) in the world's well-known journal "nature medicine". This finding formally opened the issue of research on the biological effects of hydrogen molecules and related industries: professor Ohsawa of Japan medical university in 2007 finds that hydrogen molecules can remove free radicals in human bodies, and has good treatment effect on aging and various chronic diseases caused by the free radicals. In 2008, research institutions from the united states, germany, france, sweden, korea added to the study of the medical effect of hydrogen molecules; professor taitian adult male from the university of medical science in japan published a statement that hydrogen molecules will have revolutionary effects on the medical community. In 2009 japan, the technical problem that hydrogen molecules are difficult to dissolve in water was first broken through, and saturated hydrogen water, also called hydrogen-rich water, was produced. In 2010, 30 hydrogen-rich water manufacturers appeared in japan in a short time due to the hot sales of hydrogen-rich water. The nuclear power station leakage of the Japan Fudao in 2011 brings well-injection type growth to the hydrogen-rich water market, and the network sales amount reaches 200 hundred million yen all the year. 450 papers on the effect of hydrogen molecule medicine were published by 1700 scientific researchers from 12 developed countries in the world in 2012, and it was found that 62 diseases caused by free radicals have good effect. At this time, the global hydrogen-rich water market has reached a scale of $ 220 billion. The first hydrogen-rich water industry in china was established in 2013. Meaning china also has the ability to produce hydrogen rich water. The research project of hydrogen molecular biological effect has obtained 29 projects of national science fund project at the end of 2013, and 170 doctors and researchers from 11 hospitals in China are added to the research of hydrogen molecular biological effect.
In the prior art, hydrogen is obtained mainly by dissolving hydrogen in water by a high pressure method or electrolyzing water to generate hydrogen ions (cathode) and hydroxyl ions (anode). The first method requires high-voltage equipment and is complicated. The second method requires that the water must be electrolyzed with electrical energy and the electrodes are prone to metal contamination in the water. In addition, the fine metal powder of magnesium, aluminum, etc. may be added into water in the form of spheres by a chemical reaction method to produce hydrogen through a chemical reaction, but in this method, the activity of the fine powder is too high to cause explosion hazard, and the chemical reaction speed in this method is extremely high, and the process of producing hydrogen is terminated in a short time, so that hydrogen cannot be produced for a long time. Therefore, a raw material and a method for preparing hydrogen-rich water, which are durable, safe and environmentally friendly, are urgently needed.
Disclosure of Invention
The invention aims to provide a combined multifunctional health-preserving hydrogen-rich water tablet, so as to solve the problems in the prior art.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the utility model provides a modular multi-functional health preserving hydrogen-rich water piece, includes following three kinds of potsherds: the magnesium tourmaline ceramic wafer is formed by sintering at the temperature of 750-900 ℃, the aluminum oxide ceramic wafer is formed by sintering at the temperature of 800-900 ℃, and the medical stone ceramic wafer is formed by sintering at the temperature of 800-900 ℃.
Preferably, the magnesium tourmaline ceramic wafer comprises the following components in parts by weight: purity of 98-99%, granularity of 200 meshes50-60 parts of the above magnesium tourmaline, 20-30 parts of silicate binder, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 1-2 parts of silicon oxide, and less than or equal to 0.1-0.5 part of iron oxide impurities; wherein the molecular formula of the magnesium tourmaline is as follows: NaMg3Al6(BO3)3(Si6O18)(OH)4。
Preferably, the alumina ceramic sheet comprises the following components in parts by weight: 50-60 parts of gamma-alumina with the purity of 99.9% and the granularity of more than 200 meshes, 20-22 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 0.2 part of ferric oxide and 1-2 parts of pure aluminum powder.
Preferably, the medical stone ceramic sheet comprises the following components in parts by weight: 50-70 parts of medical stone powder with purity of more than 95.0% and granularity of more than 200 meshes, 10-30 parts of silicate binder, 10-20 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide and 1-2 parts of ferric oxide impurity.
5. The combined multifunctional health preserving hydrogen-rich water tablet as claimed in claim 1, wherein the ceramic tablet is in a shape of a circular tablet or a square block.
The invention has the beneficial effects that: the embodiment of the invention provides a combined multifunctional health-preserving hydrogen-rich water tablet, which comprises: the magnesium tourmaline ceramic wafer is formed by sintering at the temperature of 750-plus 800 ℃, the aluminum oxide ceramic wafer is formed by sintering at the temperature of 800-plus 900 ℃, and the medical stone ceramic wafer is formed by sintering at the temperature of 800-plus 900 ℃. In use, the hydrogen (H) gas can be generated by placing the set in a drinking water device2) Active hydrogen ion (H)+1) Hydroxyl ion (H)3O2 -1) And other dissolved and precipitated elements beneficial to the human body and the like can generate obvious health preserving and health care effects on the human health, improve the health level of people and have obvious rehabilitation function on certain diseases. When the magnesium tourmaline, the alumina and the medical stone ceramic sheet are used together, the interaction between the magnesium tourmaline, the alumina and the medical stone ceramic sheet can be generated, and the interaction can lead to theThe combined ceramic wafer has long duration of generating hydrogen-rich water, and the ceramic wafer does not need to be continuously updated in the water treatment process, so that the used raw material amount is less in the whole water treatment process, and the cost is lower.
Drawings
FIG. 1 is a schematic view of a use method of the combined multifunctional health-preserving hydrogen-rich water tablet provided by the invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the accompanying drawings. It should be understood that the detailed description and specific examples, while indicating the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention.
The embodiment of the invention provides a combined multifunctional health-preserving hydrogen-rich water sheet, which comprises the following three ceramic sheets: the magnesium tourmaline ceramic wafer is formed by sintering at the temperature of 750-900 ℃, the aluminum oxide ceramic wafer is formed by sintering at the temperature of 800-900 ℃, and the medical stone ceramic wafer is formed by sintering at the temperature of 800-900 ℃.
The combined multifunctional health-preserving hydrogen-rich water tablet can be placed in drinking water equipment such as a water cup or a water dispenser in a set in the using process. The three ceramic sheets can produce different reactions after contacting with water to produce hydrogen (H)2) Active hydrogen ion (H)+1) Hydroxyl ion (H)3O2 -1) And other dissolved and precipitated elements beneficial to the human body, and the like, and the substances can generate obvious health preserving and health care effects on the human health after being introduced into the human body, improve the health level of people, and have obvious rehabilitation function on certain diseases.
The magnesium tourmaline, the alumina or the medical stone can generate hydrogen and elements beneficial to human bodies when being contacted with water independently, and has the effects of health care and health preservation. However, it has a short duration of being able to produce hydrogen and beneficial elements, i.e. a short effectiveness in producing hydrogen rich water. Therefore, to extend the duration of the hydrogen-rich water, the raw materials need to be continuously renewed during the water treatment process, and more raw materials need to be used throughout the water treatment process.
When the magnesium tourmaline ceramic wafer, the aluminum oxide ceramic wafer and the medical stone ceramic wafer are used in a combined mode and are placed into water, the magnesium tourmaline, the aluminum oxide and the medical stone can interact with each other, the duration of hydrogen-rich water generated by the combined ceramic wafer is long due to the interaction, the ceramic wafer does not need to be continuously updated in the water treatment process, the used raw material amount is small in the whole water treatment process, and the cost is low.
Therefore, the combined multifunctional health-preserving hydrogen-rich water sheet provided by the embodiment of the invention can be used for water treatment, so that hydrogen-rich water can be generated for a long time, raw materials do not need to be continuously updated, the raw material cost is reduced, and the water treatment capacity is improved.
The specific analysis is as follows:
professor of the grand society of military science from the second military medical university was first exposed to hydrogen molecular biology in China and was known as "the first person in hydrogen molecular biology in China" in the industry. Grand professor tells the reporter: the modern medicine considers that the decomposition of substances is an acidification (oxidation) process, and a large amount of peroxy radicals are generated in human bodies due to respiration oxygen, smoking, drinking, environmental pollution and the like, and can arbitrarily destroy cell tissues to cause gene diseases and body aging. Active hydrogen can effectively remove free radicals in vivo, and the hydrogen-rich water has oxidation resistance exceeding that of all known human antioxidants such as vitamin C, carrot, lecithin and the like, and has strong protective effect on various symptoms caused by free radicals such as allergic dermatitis, constipation, hypertension, diabetes, cancer and the like. Frequent drinking of hydrogen-rich water can promote metabolism, keep each cell in a healthy state, remove rust and delay aging. "
Hydrogen-rich water (actually hydrogen-rich ionized water), which is an industry established on the biological effect of hydrogen molecules, is undoubtedly the best way from clinic to daily by means of daily drinking. Hydrogen, due to its chemical nature, which is poorly soluble in water, imposes a very high technical threshold for the production of hydrogen-rich water.
In the invention, the three ceramic plates are combined and put into water in a complete set to produce the hydrogen-rich water, so that the process is simple and easy to realize, the duration of the hydrogen-rich water production is long, and the ceramic plates are not required to be continuously updated in the water treatment process, so that the used raw material amount is less in the whole water treatment process, and the cost is lower.
The magnesium tourmaline belongs to a natural silicate mineral, and has been found to have a pyroelectric effect, namely, when the temperature of a mineral crystal changes, two ends of the crystal along the three-time symmetrical axis of the crystal are charged with positive and negative static charges, so that the magnesium tourmaline is named as tourmaline.
Tourmaline can spontaneously react with water to generate hydrogen when being put in water, and the principle is as follows: when the surface of the tourmaline is immersed in water and contacts with water molecules, the water molecules H2O is a polar molecule and can be adsorbed by the surface of tourmaline (also a polar molecule).
The magnesium tourmaline has a compact structure, and metal ions are not easy to enter the crystal structure of the magnesium tourmaline, so that the adsorption of the magnesium tourmaline is surface adsorption, and the adsorption type is equal to that of simple oxides such as quartz, corundum and the like.
In the relationship between the amount adsorbed and the concentration of the solution, adsorption follows the Freundlich equation and works mainly by surface complexation.
The adsorption mechanism of tourmaline comprises polar adsorption and mineral surface adsorption (including electrostatic action, surface bonding, hydrogen bonding, etc.). Polar adsorption is due to the attraction of its dipolar charge to charged ions in solution. Mainly characterized in that positive and negative ions are gathered around the tourmaline under the action of an electric field, and crystallized and separated out after reaching a certain concentration. This is different from other minerals. Surface adsorption means that the adsorbed ions do not enter the crystal lattice. Through surface adsorption, adsorbed anions and cations can be concentrated on the surface of the tourmaline, and after reaching a certain concentration at the cathode, metal ions form insoluble substances to be crystallized and separated out, so that the tourmaline is convenient to recycle. While hydrogen ions escape in the form of hydrogen gas. The anode is rich in a large amount of hydroxyl (OH)-1) Ions. Unlike silicate minerals, tourmaline adsorbs anions and cations in solution without being limited by the ion exchange capacity of tourmaline,this generation and adsorption of hydroxyl ions (OH) may be present at all times-1) The function of (c).
The tourmaline can adsorb anions and cations simultaneously in the adsorption process. Due to the heteropolar symmetrical structure of the tourmaline, polarized charges at two ends of the crystal are generated, and an electrostatic field taking the axial plane of the C axis as two poles appears around the tourmaline and can spontaneously attract charged particles in a solution. Based on the principle, when tourmaline, especially magnesium tourmaline meets water, certain hydrogen can be spontaneously separated out and H can be generated3O2 -1Ions. And can adsorb metal ions in water to increase their concentration, so as to enhance the health-preserving activity of water.
It is well known that when water meets pure aluminum powder, a violent reaction occurs to generate hydrogen gas.
The chemical reaction formula is as follows:
2Al+6H2O＝2Al(OH)3+3H2↑
therefore, the hydrogen can be obtained only by adding aluminum powder, aluminum sheet or alloy powder and sheet thereof into water, but in the actual production process, the pure aluminum or alloy powder and sheet thereof can be quickly consumed due to the high reaction speed, or the aluminum sheet is passivated due to the generation of an oxide film on the surface to stop the reaction, the hydrogen supply is interrupted, and the required hydrogen can not be continuously generated in the water for a long time.
When the aluminum oxide ceramic wafer prepared by mixing pure magnesium or aluminum powder and aluminum oxide is used together with a magnesium tourmaline ceramic wafer and put into water, hydrogen can be gradually released in the reaction process of the aluminum oxide ceramic wafer prepared by mixing pure magnesium or aluminum powder and aluminum oxide, hydrogen ions can be generated for a long time, and the gamma-aluminum oxide has a catalytic reaction function, so that the activity of water can be increased, and the reaction speed is accelerated.
The magnesium tourmaline is mainly used for permanently promoting the water molecules to generate H+1And OH-1And adsorbing hydroxyl (OH-1) Post-production of activated water (Japanese called "creation water", i.e. H)3O2-1Ions).
At present, medical stone is a well-known natural mineral for health care and health preservation. The medical stone is used for soaking water, and has a plurality of benefits for human bodies.
China has two thousand years of history of applying medical stones to body building, and medical stones and longevity stones are known as medical stones and longevity stones from ancient times. Later on, the Chinese medicinal herb is known as a cell detergent in Japan and Korea, and according to history records, the medical stone is used for treating diseases because the famous medical science in spring and autumn warring countries depends on the magpie; maifanitum is listed in prescription of the famous doctor of Tang Dynasty, Sun Simiao, and Qianjin prescriptions, and Leishizhen of the great pharmacologist of Ming Dynasty has detailed records on Maifanitum in Bencao compendium: "Maifan Shi is sweet, warm and non-toxic, and is mainly used for all carbuncles, deep-rooted carbuncles and back injuries.
The reasons why these effects and functions are obtained are found according to modern science:
1. contains rich minerals: according to analysis, the medical stone contains more than 30 macroelements and microelements, which are necessary for human body. Drinking medical stone water is one source from which natural inorganic salts are obtained. Maifanitum water is an excellent mineral water, and has effects in improving and regulating metabolism, promoting blood circulation and endocrine function. The medical stone is in a spot structure, and the crystal surface of the medical stone is a porous sponge-like tissue, so that the medical stone has strong biological activity. The medical stone has a two-way regulating effect on water, and can absorb minerals when the minerals in the water are excessive and release the minerals when the minerals are too low, so that the minerals in the water are kept at a proper level.
2. Medicinal stone: the medical stone water is water obtained by soaking medical stone in water for several hours, and is alkalescent. The pH value of normal human body fluid should be 7.35-7.45, and the pH value of body fluid is below 7.35, and is medically called as acid sub-health state. People with acidic constitution often feel fatigue, memory decline, inattention, waist soreness and leg pain, and diseases can not be detected in hospital examination, and diseases can be caused if the sub-health state is improved carelessly and continues to develop. Medical experts point out that improving this sub-health of the body is far from sufficient simply by improving dietary nutrition and eating health care products. Thus, some diseases and conditions are associated with unhealthy water drinking. Scientists have found that weakly alkaline water can be used to improve physical fitness, improve sub-health status, and prevent and treat these diseases.
3. Cell detergent: the water treated by the medical stone can play a role of ion exchange, and can adsorb harmful substances which are difficult to discharge in human bodies, such as tribute, lead, arsenic, cadmium and the like, and discharge the harmful substances out of the human bodies. This property is not possessed by other minerals or mineral water, and hence is known as "cell washing agent" in japan and korea.
4. Longevity stone: modern medical research finds that mineral components in the medical stone are changed into ionized state to be dissolved in water when meeting water. The mineral substance in the food is molecular and is not easy to be absorbed by human body, while the mineral substance in the water is ionic and is easy to be absorbed by human body, and the water contains proper amount of mineral substance and rich oxygen, is 'active water', and has effective health care function for human body. The Maifanitum water has effects of promoting urination, invigorating stomach, protecting liver, regulating nerve function, improving blood circulation, lowering blood pressure, reducing blood lipid, caring skin, and delaying aging.
Through years of research by modern scientific instruments, the wheat stone has been deeply understood.
The components and effects of Maifanitum will be briefly described in the following.
The medical stone is a natural silicate mineral and is non-toxic. The name learning: quartz dilongite. The medical stone is a compound mineral or medicinal rock which is nontoxic and harmless to organisms and has certain bioactivity. The main chemical component of medical stone is inorganic aluminosilicate. Including SiO2、Al2O3、Fe2O3、FeO、MgO、CaO、K2O、Na2O、TiO2、P2O5MnO, etc., and also contains all the macroelements required by the animal, such as: K. about 58 kinds of trace elements and rare earth elements such as Na, Ca, Mg, Cu, Mo, etc.
Maifanitum belongs to volcanic rock, and its main mineral is volcanic rock.
Before 5000-7550 ten thousand years, the lava sprayed from volcano is buried underground, and through the action of high humidity and heat in volcanic zone, these lava are converted into acid substance, and then through the action of pressure produced by earth crust change, finally the Chinese medicinal stone is formed. From this it can be concluded that medical stone is produced in volcanic zones.
China's medical stone resources are very rich, and the famous and developed and applied places are Shandong Mongyin, Nemantu flag of inner Mongolia, Tianjin Ji county, Liaoning Fuxin, Zhejiang Si Ming shan, Jiangxi south, Taiwan Taidong, and the like, wherein the inner Mongolia and Shandong stone are good. It is widely used because of its strong adsorption force and water purification effect, and especially the development and application to crops are being promoted.
The chemical components of the medical stone are complex, and the northern medical stone contains trace elements, such as boron, germanium, copper, zinc, tin, gallium, chromium, nickel, indium, molybdenum, vanadium, cobalt, niobium, tantalum, zirconium, selenium, beryllium, barium and strontium, rare earth elements such as lanthanum, cerium, yttrium and ytterbium and the like through spectral analysis. Other elements are below the spectral detection limit. Radioactive elements uranium and thorium and other elements harmful to human body, such as cadmium, lead, mercury and arsenic, are also within the safety detection line.
Maifanitum has adsorption, solubility, regulation, bioactivity, and mineralization effects. It can adsorb free metal ions in water. The water soaked Maifanitum can dissolve out more than 40 elements, wherein nearly 20 elements are microelements, and trace rare earth elements are also contained. The medical stone contains Al2O315 percent, which is used as a neutral oxide, reacts with alkali (OH) in aqueous solution to reduce the pH value, and reacts with acid (H) to increase the pH value, thereby having the function of adjusting the pH value in two directions.
After the Yimeng medical stone is soaked in water, nearly 20 elements and minerals which are necessary for human bodies, such as potassium, sodium, calcium, magnesium, silicon, manganese, titanium, phosphorus and the like can be contained, and the standard of mineral water can be met. It can enhance immunity and improve anti-infection ability. Meanwhile, the Yimeng medical stone has strong adsorption rate to elements and bacterial groups such as cadmium, lead and the like which are harmful to human bodies, and the adsorption rate to escherichia coli is more than 95.
Through the identification of experts at home and abroad, the medical stone is confirmed to be rich in various trace elements necessary for human bodies, can be used for water quality purification and sewage treatment, and has strong adsorption effect on bacteria. The product has effects of regulating metabolism, invigorating stomach, promoting urination, protecting liver, and resisting aging, and is beneficial for human. In addition, the method can also be applied to vegetable and fruit preservation, animal breeding, plant cultivation, refrigerator deodorization and the like. The modern technology tests and analyses show that the medical stone contains various trace elements necessary for human health, and the medical stone mineral water can supplement mineral substances and various trace elements necessary for human body, provide inorganic nutrient components for organism, regulate metabolism, and can be used for health care physical therapy bath, and can play a role in building up body by frequent bath, and is equivalent to mineral water bath. The medical stone has a certain adsorption effect, and multiple experiments prove that the medical stone has a certain purification capacity on certain viruses, harmful microorganisms, heavy metal elements and organic substances. Maifanitum is effective in sewage treatment, drinking water purification and odor removal.
However, when the medical stone is used alone and soaked in water, although beneficial elements are dissolved, the effect is not obvious when the magnesium tourmaline ceramic chip and the alumina ceramic chip which have the catalytic effect and the adsorption effect exist at the same time. A typical illustration is: the oxidation-reduction potential (ORP) value of the water used when the three materials are soaked together is much lower than that of the water of the single foam of the wheat stone, and can be reduced from the original + 150-200 mv to-200-50 mv and kept for a long time (for example, can be kept for a plurality of months). Thereby ensuring the water reduction and health care characteristics. The hydrogen separated out can reach 1-3 ppm.
In the use process of the combined multifunctional health-preserving hydrogen-rich water piece provided by the embodiment of the invention, three ceramic pieces are mixed in the metal sleeve (as shown in figure 1), the required water flows through the metal sleeve in a high-speed rotating mode and takes away the derivative products of the ceramic pieces, and the obtained effect of the water is far higher than that of the water which is singly used due to the concentration action of catalytic reaction and adsorption.
In the embodiment of the invention, the magnesium tourmaline ceramic plate, the alumina ceramic plate and the medical stone ceramic plate are used together, and the amount of the generated health-care water can be determined according to the pipe diameter of the metal sleeve through which the treated water flows and the number of the used ceramic plates.
In the embodiment of the invention, the magnesium electric wireThe stone ceramic plate comprises the following components in parts by weight: 50-60 parts of magnesium tourmaline with purity of 98-99% and granularity of more than 200 meshes, 20-30 parts of silicate binder, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 1-2 parts of silicon oxide and less than or equal to 0.1-0.5 part of ferric oxide impurities; wherein the molecular formula of the magnesium tourmaline is as follows: NaMg3Al6(BO3)3(Si6O18)(OH)4。
In the embodiment of the invention, the magnesium tourmaline micropowder is used as a base material, kaolin or other clay additives are added as a binder, a proper amount of oxide cosolvent is added for reducing the sintering temperature, the mixture is pressed into a sheet blank after being mixed, and the sheet blank is sintered into the porcelain at the temperature of 900 ℃ lower than 800-.
In the embodiment, the sintering temperature of the magnesium tourmaline ceramic wafer, the aluminum oxide ceramic wafer and the medical stone ceramic wafer is improved, the sintering temperature higher than 1200 ℃ in the field is not adopted, and the ceramic is sintered at a lower temperature, so that various raw materials for forming the ceramic wafer have the characteristics described above, and hydrogen-rich water can be continuously generated when the ceramic wafer is used together with other two ceramic wafers.
The specific manufacturing process can be as follows:
the powder with purity of 98-99% and granularity of more than 200 meshes (more than 95% is sieved) is adopted, and about 5% of organic binder is added and then is uniformly mixed in a stirrer.
Pressing the mixture into a sheet blank in a two-way press.
After drying, the ceramic is sintered at a temperature of less than 850 ℃ (750-800 ℃ is adopted in the patent).
In another embodiment of the present invention, the alumina ceramic sheet comprises the following components in parts by weight: 50-60 parts of gamma-alumina with the purity of 99.9 percent and the granularity of more than 200 meshes, 20-22 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 0.2 part of ferric oxide and 1-2 parts of pure aluminum powder.
Aluminum reacts with water to produce hydrogen gas, but the aluminum surface tends to form a dense inert oxide film, resulting in little reaction in water. If the inert oxide film on the surface of the aluminum can be eliminated, the activity of the aluminum in reaction with water can be greatly improved, and the metallic aluminum can become a very promising hydrogen production material. The key to realize the hydrogen production by aluminum hydrolysis is to destroy or eliminate the compact oxide film on the aluminum surface so that water can contact with the fresh aluminum surface for continuous reaction. The presence of aluminum and the hydrolysis environment have a great influence on the formation of an oxide film.
For this reason, in the case of a solid sheet-like aluminum material, the surface may be formed by an anodizing reaction
The protective film can prevent passivation, and the micro-powder aluminum powder can be adsorbed on the porous alumina ceramic plate to delay the reaction process, so that the hydrogen can be continuously generated for a long time.
The alumina ceramic is prepared from alumina (Al)2O3) The ceramic material as a main body, alumina ceramics have many excellent physicochemical properties such as: better thermal conductivity, mechanical strength, high temperature resistance, catalytic reaction function in chemical industry and the like. Alumina ceramic is a ceramic with wide application, and because of the superior performance, the alumina ceramic has been more and more widely applied in modern society, and meets the requirements of daily use and special performance.
The porous ceramic material is prepared by taking high-quality raw materials such as corundum (Al2O3), silicon carbide, cordierite and the like as main materials through molding and special high-temperature sintering processes, has the advantages of high temperature resistance, high pressure resistance, acid resistance, alkali resistance, organic medium corrosion resistance, good biological inertia, controllable pore structure, high open porosity, long service life, good product regeneration performance and the like, has wide application range, can be suitable for carriers of various ultrafine particles in liquid, precise filtration and separation of various media, high-pressure gas exhaust and noise reduction, gas distribution, electrolytic diaphragms and the like.
The alumina carrier is a catalyst carrier which is most widely used and takes the molded alumina solid porous ceramic as a carrier of superfine particles, for example, powder capable of generating hydrogen, such as aluminum powder, magnesium powder and other active substances, are attached to the carrier through adsorption, and account for about 70 percent of the industrial supported catalyst. Alumina has various forms, and not only has different properties in different forms, but also has different properties, such as density, pore structure, specific surface area and the like in the same form due to different sources.
These properties are of great significance for the alumina used as a catalyst support.
The invention adopts alumina powder as a carrier, adds pure aluminum powder and other additives into the powdered alumina, presses the powdered alumina into a sheet shape, and then sinters the sheet shape into ceramic at high temperature to obtain the sheet-shaped alumina composite ceramic sheet, namely a finished product, but the crystal shape of the alumina is gamma-A L2 O3., because the alumina has large specific surface area and high activity, the alumina with large specific surface area has developed pore structure, can highly disperse the loaded catalyst active component into particles, and prevents the active component particles from sintering and growing up in the using process by the barrier effect of the carrier, thus being a widely used alumina carrier.
The specific manufacturing process can be as follows:
adding about 5% of organic binder into gamma-alumina (Al2O3) powder (more than 95% is sieved) with the purity of 99.9% and the granularity of more than 200 meshes, and uniformly mixing in a stirrer.
Pressing the mixture into a sheet blank in a two-way press.
After drying, the ceramic is sintered at the temperature of less than 900 ℃ (800-900 ℃ is adopted in the patent).
In another embodiment of the invention, the medical stone ceramic sheet comprises the following components in parts by weight: 50-70 parts of medical stone powder with purity of more than 95.0% and granularity of more than 200 meshes, 10-30 parts of silicate binder, 10-20 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide and 1-2 parts of ferric oxide impurity.
The specific manufacturing process can be as follows:
by adopting the powder of the formula, about 5 percent of organic binder is added and then the mixture is uniformly mixed in a stirrer;
pressing the mixture into a sheet blank in a two-way press;
after drying, the ceramic is sintered at a temperature of less than 900 ℃ (in this example 800-900 ℃).
In the embodiment of the invention, the ceramic plate can be in a circular plate shape or a square shape.
By adopting the technical scheme disclosed by the invention, the following beneficial effects are obtained: the embodiment of the invention provides a combined multifunctional health-preserving hydrogen-rich water tablet, which comprises: the magnesium tourmaline ceramic wafer is formed by sintering at the temperature of 750-plus 800 ℃, the aluminum oxide ceramic wafer is formed by sintering at the temperature of 800-plus 900 ℃, and the medical stone ceramic wafer is formed by sintering at the temperature of 800-plus 900 ℃. In use, the hydrogen (H) gas can be generated by placing the set in a drinking water device2) Active hydrogen ion (H)+1) Hydroxyl ion (H)3O2 -1) And other dissolved and precipitated elements beneficial to the human body and the like can generate obvious health preserving and health care effects on the human health, improve the health level of people and have obvious rehabilitation function on certain diseases. When the magnesium tourmaline, the alumina and the medical stone ceramic wafer are used together, the magnesium tourmaline, the alumina and the medical stone ceramic wafer have interaction, the combined ceramic wafer can generate hydrogen-rich water for a long time due to the interaction, the ceramic wafer does not need to be continuously updated in the water treatment process, the used raw material amount is small in the whole water treatment process, and the cost is low.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and improvements can be made without departing from the principle of the present invention, and such modifications and improvements should also be considered within the scope of the present invention.
Claims (4)
1. The combined multifunctional health-preserving hydrogen-rich water tablet is characterized by comprising the following three ceramic tablets: the magnesium tourmaline ceramic wafer is formed by sintering at the temperature of 750-900 ℃, the aluminum oxide ceramic wafer is formed by sintering at the temperature of 800-900 ℃, and the medical stone ceramic wafer is formed by sintering at the temperature of 800-900 ℃;
the aluminum oxide ceramic sheet comprises the following components in parts by weight: 50-60 parts of gamma-alumina with the purity of 99.9% and the granularity of more than 200 meshes, 20-22 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 0.2 part of ferric oxide and 1-2 parts of pure aluminum powder.
2. The combined multifunctional health-preserving hydrogen-rich water tablet as claimed in claim 1, wherein the magnesium tourmaline ceramic tablet comprises the following components in parts by weight: 50-60 parts of magnesium tourmaline with purity of 98-99% and granularity of more than 200 meshes, 20-30 parts of silicate binder, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide, 1-2 parts of silicon oxide and less than or equal to 0.1-0.5 part of ferric oxide impurities; wherein the molecular formula of the magnesium tourmaline is as follows: NaMg3Al6(BO3)3(Si6O18)(OH)4。
3. The combined multifunctional health-preserving hydrogen-rich water tablet as claimed in claim 1, wherein the medical stone ceramic tablet comprises the following components in parts by weight: 50-70 parts of medical stone powder with purity of more than 95.0% and granularity of more than 200 meshes, 10-30 parts of silicate binder, 10-20 parts of silicon oxide, 5-7 parts of magnesium oxide, 4-6 parts of calcium oxide, 1-2 parts of potassium oxide, 0.5-1 part of sodium oxide and 1-2 parts of ferric oxide impurity.
4. The combined multifunctional health preserving hydrogen-rich water tablet as claimed in claim 1, wherein the ceramic tablet is in a shape of a circular tablet or a square block.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811186592.5A CN109179620B (en) | 2018-10-12 | 2018-10-12 | Combined multifunctional health-preserving hydrogen-rich water sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811186592.5A CN109179620B (en) | 2018-10-12 | 2018-10-12 | Combined multifunctional health-preserving hydrogen-rich water sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109179620A CN109179620A (en) | 2019-01-11 |
| CN109179620B true CN109179620B (en) | 2020-07-28 |
Family
ID=64948090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811186592.5A Active CN109179620B (en) | 2018-10-12 | 2018-10-12 | Combined multifunctional health-preserving hydrogen-rich water sheet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109179620B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114315000B (en) * | 2021-12-31 | 2022-07-29 | 北京氢润科技有限公司 | Active hydrogen generator |
| CN116656451A (en) * | 2023-05-30 | 2023-08-29 | 北京氢润科技有限公司 | Preparation equipment and method of active hydrogen atom wine |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557728A (en) * | 2004-02-09 | 2004-12-29 | 苍风波 | Antimicrobial compound for anion water purifying and activating, its pelletized product and preparation method |
| CN106006911A (en) * | 2016-04-27 | 2016-10-12 | 昆山超猛生物科技有限公司 | Composite mineralized ceramic material capable of producing activated hydrogen health-care water |
| CN106115621A (en) * | 2016-06-24 | 2016-11-16 | 山东木齐健康科技有限公司 | Graphene activates hydrogen manufacturing material and its preparation method and application |
| CN106756399A (en) * | 2016-12-21 | 2017-05-31 | 刘维良 | A kind of hydrogen rich water porous metalloceramic composite and its preparation method and application processed |
| CN206375716U (en) * | 2016-05-25 | 2017-08-04 | 广州弘皓电子科技有限公司 | Hydrogen rod |
| WO2017146487A2 (en) * | 2016-02-24 | 2017-08-31 | 지병욱 | Hydrogen water and magnetic water generating water bottle |
| CN107573047A (en) * | 2017-08-22 | 2018-01-12 | 深圳市和之科技有限公司 | Hydrogen manufacturing ceramic water material and its preparation method and application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170267563A1 (en) * | 2016-03-20 | 2017-09-21 | Mega Sun Biomedical Corp. | Negative hydrogen ion intellegrnt filtration system for curing cancer, cardiovascular disease, diabetes, hypertension, nephrotic syndrome, gout, dysautonomia and atopic dermatitis |
-
2018
- 2018-10-12 CN CN201811186592.5A patent/CN109179620B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557728A (en) * | 2004-02-09 | 2004-12-29 | 苍风波 | Antimicrobial compound for anion water purifying and activating, its pelletized product and preparation method |
| WO2017146487A2 (en) * | 2016-02-24 | 2017-08-31 | 지병욱 | Hydrogen water and magnetic water generating water bottle |
| CN106006911A (en) * | 2016-04-27 | 2016-10-12 | 昆山超猛生物科技有限公司 | Composite mineralized ceramic material capable of producing activated hydrogen health-care water |
| CN206375716U (en) * | 2016-05-25 | 2017-08-04 | 广州弘皓电子科技有限公司 | Hydrogen rod |
| CN106115621A (en) * | 2016-06-24 | 2016-11-16 | 山东木齐健康科技有限公司 | Graphene activates hydrogen manufacturing material and its preparation method and application |
| CN106756399A (en) * | 2016-12-21 | 2017-05-31 | 刘维良 | A kind of hydrogen rich water porous metalloceramic composite and its preparation method and application processed |
| CN107573047A (en) * | 2017-08-22 | 2018-01-12 | 深圳市和之科技有限公司 | Hydrogen manufacturing ceramic water material and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109179620A (en) | 2019-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108727007A (en) | More effect water purification ceramic materials and its preparation method and application | |
| CN103922666A (en) | Silver selenium and germanium-enriched sintering-free pottery with sterilizing and poison filtering functions | |
| CN109179620B (en) | Combined multifunctional health-preserving hydrogen-rich water sheet | |
| JP2017196611A (en) | Composite ore ceramic material capable of generating health care active hydrogen water | |
| CN107381731A (en) | Water and method and the application for handling water | |
| CN101891264A (en) | Multi-dimensional composite energy active material and preparation method thereof | |
| CN102795737A (en) | Preparation method of weakly alkaline drinking water | |
| CN102805973A (en) | Water filter material, producing process of water filter material and corresponding water filter device | |
| KR20150012595A (en) | apparatus and method for producing alkaline water | |
| CN104305595B (en) | A kind of health-care physiotherapeutic clothing | |
| CN203595255U (en) | Hot spring water heater | |
| CN203653375U (en) | Manufacturing equipment of negative hydrogen ionized water for improving cancer, diabetes, cholesterol, high blood pressure and kidney disease | |
| CN104291794B (en) | A kind of anionic particle material that can produce micro-electric current | |
| CN101643255A (en) | Micro-electrolysis water-activating material and preparation method thereof | |
| CN103948281B (en) | A kind of warm balance cup | |
| WO2013008061A2 (en) | Novel nano gold and process for preparation | |
| CN106419388A (en) | Portable [Sihua] (activating, purifying, benefiting and energizing) water cup | |
| CN102898120A (en) | Water filter material and preparation process thereof as well as corresponding water filter device | |
| CN109264842A (en) | A kind of health care cup sleeve | |
| CN108294960A (en) | A kind of hydrogen-rich beauty mask and preparation method thereof | |
| CN104278543A (en) | Dye comprising negative ion particles | |
| TWI574922B (en) | Composite Mineralized-Ceramic Material | |
| CN1810677A (en) | Prepn process of alkali ion water | |
| TWM520408U (en) | Ultrahigh concentration hydrogen water machine | |
| CN108658039B (en) | Water hydrogen production material and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200928 Address after: 101149 2521, 25th floor, building 5, yard 1, jiangmidian street, Tongzhou District, Beijing Patentee after: Beijing Hydrogen Technology Co., Ltd Address before: 102206 Room 808, Unit 2, Building 6, No. 1 Beiqing Road, Changping District, Beijing Patentee before: BEIJING HUIBOYUAN BIOTECHNOLOGY Co.,Ltd. |