CN114315000B - Active hydrogen generator - Google Patents
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- CN114315000B CN114315000B CN202111667199.XA CN202111667199A CN114315000B CN 114315000 B CN114315000 B CN 114315000B CN 202111667199 A CN202111667199 A CN 202111667199A CN 114315000 B CN114315000 B CN 114315000B
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Abstract
The invention relates to an active hydrogen generator, which is provided with a supercharging device, a water activating device, a hydrogen-rich device and an electronic release device, wherein the supercharging device, the water activating device, the hydrogen-rich device and the electronic release device are sequentially connected through a water supply pipe; the water activating device comprises a first filter cylinder, and energy spar and projective natural ore are arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and a combined multifunctional health-preserving hydrogen-rich water sheet and a composite medical stone ceramic ball are arranged in the second filter cylinder; the electronic release device comprises an inner ribbed tube, and a combined material consisting of composite tourmaline ceramic balls and an electrode metal band is placed in the inner ribbed tube. The active hydrogen generator can prepare a large amount of active hydrogen in a lasting, safe and environment-friendly manner, and the content of the active hydrogen in water treated by the active hydrogen generator reaches 5-8PPm according to the detection data of a third party.
Description
Technical Field
The invention belongs to the technical field of water treatment, and particularly relates to an active hydrogen generator.
Background
The German Noerdenag is a small village in the northwest of Germany, a discarded mine pit is provided with a spring hole, spring water in the pit can improve the symptoms of children suffering from leukemia, later, patients suffering from osteoarticular diseases, diabetes, cardiovascular diseases, respiratory diseases, gallbladder and gastrointestinal tract problems are experienced by the patients, and the spring water in the mine pit is useful and has good effect no matter orally taken or externally applied.
Then, japan has conducted studies on "electrolyzed water", and a famous expert in electrolyzed water of japan has made a search for nordenau and found that "miracle water", water contains hydrogen very abundantly. Therefore, Japan walks out of the puddle for decomposing alkaline water by electrolyzed water, and finds a great breakthrough for preparing hydrogen-rich water by electrolysis.
The literature suggests that microorganisms 38 billion years ago evolved hydrogenases that produce and utilize hydrogen, and that most of the current bacteria on earth have the ability to metabolize hydrogen, either produce hydrogen or utilize hydrogen, most typically bacteria in the human intestinal tract, with about 50% of the bacteria being associated with hydrogen metabolism. Professor of mother-of-pearl, kyushu university, japan, 1997 found that electrolyzed water acts by active hydrogen, which may also be the reason why ancient microorganisms evolved hydrogenase, because the purpose of this enzyme is also to produce active hydrogen atoms to neutralize active oxygen, as in electrolyzed water, to address the effects of self-metabolism and environmental harmful factors.
In 2013, a korean scholar published a paper on Plos One to prove that active hydrogen (hydrogen atom) water can protect human skin from uv light. The research is based on a research in 2007, and then scholars propose a novel disinfection device, namely hydrate containing abundant hydrogen atoms is prepared by utilizing a planar electrode and a needle-shaped electrode, the substance has a strong killing effect on a plurality of viruses, bacteria and fungi, and animals live in the environment without harm. Korean scholars use this as a method for protecting against ultraviolet rays for the reason that this substance has a very good anti-oxidative effect, they have demonstrated the existence of this effect using human skin and tumor cell models, and have conducted intensive studies on signaling pathways of some inflammatory molecules and related molecules to propose a possible molecular pathway for this protective effect.
In 2009 japan, the technical problem that hydrogen molecules are difficult to dissolve in water was first broken through, and saturated hydrogen water, also called hydrogen-rich water, was produced. In the prior art which has been disclosed so far, hydrogen-rich water is mainly focused on research and development of hydrogen-rich gas (hydrogen molecules), and hydrogen-rich water is obtained mainly by preparing hydrogen by electrolyzing water and then forcibly dissolving hydrogen in water by a high-pressure method. This method requires electric energy and high voltage equipment, the process is complicated, and the electrodes are liable to cause metal contamination in water. Meanwhile, hydrogen molecules have extremely high permeability and volatility and are difficult to store, and four layers of aluminum foils are required for packaging, so that the cost is high and the use is inconvenient.
According to the latest research, active hydrogen really plays a role, and meanwhile, the active hydrogen has some advantages compared with hydrogen because the active hydrogen is not gas, the problem of volatilization does not exist, the packaging cost is low, and a plurality of convenient using methods can be developed.
In view of this, this patent is filed.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides an active hydrogen generator which can prepare a large amount of active hydrogen in a lasting, safe and environment-friendly manner.
The invention aims to provide an active hydrogen generator.
An active hydrogen generator according to an embodiment of the present invention includes: the device comprises a pressurizing device, a water activating device, a hydrogen-rich device and an electronic release device which are arranged between a main water inlet and a main water outlet, wherein the pressurizing device, the water activating device, the hydrogen-rich device and the electronic release device are sequentially connected through a water supply pipe; the water activating device comprises a first filter cylinder, and energy spar and projective natural ore are arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and a combined multifunctional health-preserving hydrogen-rich water sheet and a composite medical stone ceramic ball are arranged in the second filter cylinder; the electronic release device comprises an inner ribbed tube, and a material combination consisting of the composite tourmaline ceramic ball and an electrode metal band is placed in the inner ribbed tube.
Furthermore, the active hydrogen generator is provided with a pressurizing device, four water activating devices, a hydrogen-rich device and two electron releasing devices which are connected in sequence through a water supply pipe. The device adopts stainless steel or other water supply pipes which are connected in series in sequence, wherein the four water running devices, the hydrogen-rich device and the two electronic release devices are connected in series in sequence in a mode of lower inlet and upper outlet. The water inlets of the supercharging device, the water activating device, the hydrogen-rich device and the electronic release device are all arranged at the lower end, and the water outlets are all arranged at the upper end.
Preferably, the boosting device is a pressure pump with the output pressure of 0.3-0.6 MPa. The fluid needs to be pressurized by a booster pump and flows into the water activating device, the hydrogen enriching device and the electron releasing device in sequence.
Furthermore, the active hydrogen generator is also provided with a filtering device and/or a sterilizing device; the filtration pore of filter equipment is 0.2um-5um, sterilizing equipment is 50-100 watts STREAMING ultraviolet pipe.
Preferably, the second filter cylinder is internally provided with combined multifunctional health-preserving hydrogen-rich water tablets and composite medical stone ceramic balls in an alternating manner. Energy spar and projective natural ore with antibacterial and water-activating functions are alternately arranged in the first filter cylinder. The alternate setting is specifically as follows: and (3) placing a layer of projecting natural ore on one layer of energy spar, then placing another layer of energy spar on the projecting natural ore layer, and repeatedly stacking. A layer of composite medical stone ceramic balls are arranged on one layer of combined multifunctional health-preserving hydrogen-rich water sheet, and then a layer of combined multifunctional health-preserving hydrogen-rich water sheet is arranged on the composite medical stone ceramic balls; the combined multifunctional health-preserving hydrogen-rich water sheet is wrapped by the composite medical stone ceramic ball, the physical wavelength and the frequency released by the two materials are mutually superposed to form a safe and stable energy field, and meanwhile, the collision between the combined multifunctional health-preserving hydrogen-rich water sheets can be avoided.
The energy spar can release specific far infrared energy waves, resonance is generated between the energy spar and water molecule groups by utilizing the polar molecular characteristics of water molecules, hydrogen bonds among the water molecules are cut off, large water molecule groups are split into smaller water molecule groups, and meanwhile, the high free energy of the crystal surface has a bacteriostatic action.
The projective natural ore can release energy to attract some magnetic fields, and the two materials are matched with each other to form a safe and stable energy field. Water molecules are very common polar molecules that can be bound into associated molecules by hydrogen bonding, which strongly interacts with energy waves of a specific frequency, thereby increasing the absorption of the energy waves by water.
The combined multifunctional health-preserving hydrogen-rich water sheet arranged in the second filter cylinder is a product in the patent number ZL201811186592.5 and is produced by Beijing Hydrogen science and technology Limited.
The first filter cylinder and the second filter cylinder are both made of stainless steel.
Further, the weight adding amount ratio of the energy spar to the projective natural ore is 1: 10-15; preferably, 2 tons of water are processed per hour, the total addition amount of the energy spar is 1-3KG, and the total addition amount of the projecting natural ore is 10-30 KG.
Further, the energy spar is prepared from the following raw materials in parts by weight: 60-80 parts of silicate binder, 10-20 parts of tourmaline powder, 5-10 parts of nano rare earth oxide, 5-10 parts of low-temperature fluxing agent and 2-10 parts of far infrared ceramic powder; the preparation method of the energy spar comprises the following steps: mixing all the above raw materials, mixing well, and sintering at 1500 deg.C or below.
Preferably, the silicate binder is kaolin with a particle size of more than 2000 meshes; the tourmaline powder is one or more of iron tourmaline, magnesium tourmaline and lithium tourmaline with particle size of more than 10000 meshes; the nano rare earth oxide is yttrium oxide, neodymium oxide and/or cerium oxide; the low-temperature fluxing agent is one or a mixture of more than two of CaO, MgO, K2O, Na2O and PbO.
Further, the projection natural ore is one or a combination of more of agate, flint, obsidian, agate, ruby, sunstone, alexandrite, crossed stone, chrysosporium and schlernite.
Further, the composite medical stone ceramic ball is prepared from the following raw materials in parts by weight: 30-50 parts of silicon dioxide and 20-40 parts of medical stone powder; 10-30 parts of tourmaline powder, 3-10 parts of graphene and 3-5 parts of sintering aid; the preparation method of the composite medical stone ceramic ball comprises the following steps: all the raw materials are mixed and sintered into ceramic balls with the diameter of 3-5mm at 1500 ℃ after being uniformly mixed.
Preferably, the particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is one or a mixture of more than two of iron tourmaline, magnesium tourmaline and lithium tourmaline with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90um, and the sintering aid is yttrium oxide and aluminum oxide.
The hydrogen-rich device can permanently promote the water molecules to generate the hydrogen positive ions (H) + ) And hydroxyl anion (OH) - ) Wherein water molecules adsorb hydroxyl anions to produce activated water, hydrated hydroxyl ions (i.e., H) 3 O 2 - Ions).
The main reaction equation is formula (1):
further, the first filter cylinder and the second filter cylinder are stainless steel filter cylinders.
The first and second filter cartridges may be integrally formed stainless steel cartridges.
Or the second filter cylinder is divided into a plurality of sections, and two adjacent sections are connected through sealing rubber rings and clamping hoops. As water flows through the first cartridge, the energetic spar and the projecting natural ore utilize specific far infrared energy waves to break large clusters of water molecules into smaller clusters of water molecules.
Furthermore, the electronic release device comprises five sections of inner ribbed pipes, and two adjacent sections of inner ribbed pipes are connected through a sealing rubber ring and a clamping hoop; stainless steel filter screens are arranged between two adjacent sections of inner ribbed pipes for separation, the rib height of each section of inner ribbed pipe is 1-10mm, the thread pitch is 2-20mm, and the helical angle is 10-70 degrees. The diameter of the stainless steel filter screen is equal to the inner diameter of the two ends of the inner ribbed pipe, and the stainless steel filter screen is just abutted to the inner walls of the two ends of the inner ribbed pipe. The stainless steel filter screen is placed in parallel with the cross section of the inner ribbed tube.
The inner ribbed tube is made of aluminum alloy, and the electrode metal band is one or a combination of nickel-aluminum band or other electrode metal bands. The inner ribbed tube of aluminum alloy, the composite tourmaline ceramic ball and the nickel-aluminum belt (nickel-aluminum sheet) form the electrode.
When fluid flows in the inner ribbed pipe, the fluid in the pipe is forced to generate periodic rotating turbulence under the action of the approximately axial periodic rib protrusions. The larger the rib height is, the smaller the flow cross section area in the pipe is, and the larger the volume of the fluid promoting turbulent flow is, the stronger the turbulent flow is forced, the stronger the turbulent motion degree is, and meanwhile, the larger the required pumping work is; the smaller the pitch, the shorter the period of the rotational flow of the fluid in the pipe, and the more intense the turbulence, the more demanding the pumping work. Therefore, the inner ribbed tube is preferably manufactured by adopting the parameters of rib height of 1-10mm, thread pitch of 2-20mm and helix angle of 10-70 degrees.
Preferably, the thickness of the electrode metal strip is 0.1-0.5mm, and the width of the electrode metal strip is 10-50 mm; the electrode metal band is in a hollow spiral shape with the length of 20-50 mm. The electrode metal strip is made into a hollow spiral body shape with the length of 20-50mm in order to increase the disturbance effect.
Furthermore, 3/1 volumes of combined materials are added into each section of inner ribbed tube, the electrode metal band is a nickel-aluminum band or an aluminum band, and the weight adding amount ratio of the composite tourmaline ceramic ball to the electrode metal band is 10-20: 1.
Preferably, the ratio of the content of nickel to the content of aluminum in the nickel-aluminum strip is 1: 1.
Further, the composite tourmaline ceramic ball is prepared from the following raw materials in parts by weight: 50-60 parts of aluminum oxide, 5-20 parts of tourmaline powder, 5-15 parts of silicon oxide, 5-10 parts of an oxidation auxiliary agent, 3-10 parts of an organic binder, 3-10 parts of a pore-forming agent and 0.1-0.5 part of a nano noble metal; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at the temperature of over 900 ℃.
Preferably, the oxidation auxiliary agent is magnesium oxide, calcium oxide, potassium oxide and sodium oxide, the organic binder is hydroxymethyl cellulose and polyvinyl alcohol, the pore-forming agent is sodium bicarbonate and bamboo charcoal powder, and the nano noble metal is platinum oxide or palladium oxide.
Preferably, the purity of the aluminum oxide is below 99%, the particle fineness of the aluminum oxide is below 1um, the purity of the tourmaline powder is below 99%, the particle fineness of the tourmaline powder is above 6000 meshes, and the particle fineness of the silicon oxide is above 2000 meshes.
The composite tourmaline crystal structure in the electronic release device has the characteristics of permanent electrification and permanent maintenance of the anode and the cathode, composite tourmaline ceramic balls occupying one third of the volume of the inner ribbed tube and an electrode metal band are filled in the metal inner ribbed tube, and the vortex theory and the characteristics of an alloy electrode plate are utilized to strengthen the piezoelectric characteristic and release electrons permanently. The electrons released in the electron releasing device are combined with the positive hydrogen ions generated by the hydrogen enriching device to generate hydrogen atoms, namely active hydrogen.
The material combination filled in the water activating device, the hydrogen enriching device and the electron releasing device can release energy with specific frequency and wavelength, water molecules are very common polar molecules, the absorption of water to energy waves is increased through an energy field which is superposed layer by utilizing the physical characteristic of the water molecule polar molecules, and the construction of the energy field enables active hydrogen to be stably stored in water. And water flows out from the main water inlet through the supercharging device, the water activating device, the hydrogen-rich device and the electronic release device and then flows out from the main water outlet, and the active hydrogen content in the flowing-out water reaches 5-8PPm according to the detection data of a third party.
Compared with the prior art, the invention has the following beneficial effects:
(1) the active hydrogen generator adopts the water activating device, the hydrogen enriching device and the electronic releasing device to treat water to prepare active hydrogen, can prepare a large amount of active hydrogen in a lasting, safe and environment-friendly way, and shows that the content of the active hydrogen in the water treated by the active hydrogen generator reaches 5-8PPm according to third-party detection data.
(2) The active water device in the active hydrogen generator adopts energy spar with bacteriostatic and active water functions and natural ore which is insoluble in water, so that the absorption of water to energy waves is increased, hydrogen bonds among water molecules are cut off, and large water molecule groups are split into smaller water molecule groups; the hydrogen-rich device promotes water molecules to generate a polarization reaction to generate hydrogen positive ions (H) + ) And hydroxyl anion (OH) - ) Wherein water molecules adsorb hydroxyl anions to produce activated water, hydrated hydroxyl ions (i.e., H) 3 O 2 - Ions); the electron releasing device strengthens the piezoelectric property to release electrons and permanently releases the electrons; and combines with positive hydrogen ions generated by the hydrogen enrichment device to generate active hydrogen.
(3) The wavelength range of the combined energy field covers the range of 3000-30 μm. Research shows that the substance which is most likely to resonate (absorb) with the combined micro energy wave is water molecule, and meanwhile, the substance which is likely to resonate has better radiation effect. Therefore, the water molecules have physical properties of absorbing and storing the water molecules as lattice vibration (hydrogen bonding vibration) and rotational vibration in the molecular structure. The combined micro-energy wave band contains the rotation or vibration energy level of most molecules, and particularly, many organic molecules show strong absorption, so that the organic molecules are easily absorbed by objects or animals and plants, and have good influence on cells of the animals and plants including human beings. Meanwhile, the energy of the combined micro energy field is very small, is a wave contained in natural light, cannot damage substances, and does not have any side effect.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
Fig. 1 is a flowchart of a process for producing active hydrogen by an active hydrogen generator according to example 1 of the present invention;
fig. 2 is a flowchart of a process for generating active hydrogen by the active hydrogen generator of example 2 of the present invention;
FIG. 3 is a schematic view of the structure of the internally ribbed tube of the present invention;
FIG. 4 is a second schematic view of the structure of the internally ribbed tube of the present invention.
Reference numerals
1-a supercharging device; 2-a water activating device; 3-hydrogen enrichment device; 4-electron release means; 5-a filtering device; 6, a sterilizing device; 7-inner ribbed tube; 8, clamping a hoop; 9-a filter screen.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
In some more specific embodiments, the active hydrogen generator includes: the device comprises a pressurizing device, a water activating device, a hydrogen-rich device and an electronic release device which are arranged between a main water inlet and a main water outlet, wherein the pressurizing device, the water activating device, the hydrogen-rich device and the electronic release device are sequentially connected through a water supply pipe; the water activating device comprises a first filter cylinder, and energy spar and projective natural ore are arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and a combined multifunctional health-preserving hydrogen-rich water sheet and a composite medical stone ceramic ball are arranged in the second filter cylinder; the electronic release device comprises an inner ribbed tube, and a material combination consisting of the composite tourmaline ceramic ball and an electrode metal band is placed in the inner ribbed tube.
Furthermore, the active hydrogen generator is provided with a pressurizing device, four water activating devices, a hydrogen-rich device and two electron releasing devices which are connected in sequence through a water supply pipe. The device adopts stainless steel or other water supply pipes which are connected in series in sequence, wherein the four water running devices, the hydrogen-rich device and the two electronic release devices are connected in series in sequence in a mode of lower inlet and upper outlet.
Furthermore, the water inlets of the supercharging device, the water activating device, the hydrogen-rich device and the electronic release device are all arranged at the lower end, and the water outlets are all arranged at the upper end.
Preferably, the boosting device is a pressure pump with the output pressure within 0.3-0.6 MPa. The fluid needs to be pressurized by a booster pump and flows into the water activating device, the hydrogen enriching device and the electron releasing device in sequence.
Furthermore, the active hydrogen generator is also provided with a filtering device and/or a sterilizing device; the filtration pore of filter equipment is 0.2um-5um, sterilizing equipment is 50-100 watts STREAMING ultraviolet pipe.
Preferably, the second filter cylinder is internally provided with combined multifunctional health-preserving hydrogen-rich water tablets and composite medical stone ceramic balls in an alternating manner. Energy spar and projective natural ore with antibacterial and water-activating functions are alternately arranged in the first filter cylinder. The alternate setting is specifically as follows: and (3) placing a layer of projecting natural ore on one layer of energy spar, then placing another layer of energy spar on the projecting natural ore layer, and repeatedly stacking. A layer of composite medical stone ceramic balls are arranged on one layer of combined multifunctional health-preserving hydrogen-rich water sheet, and then a layer of combined multifunctional health-preserving hydrogen-rich water sheet is arranged on the composite medical stone ceramic balls; the combined multifunctional health-preserving hydrogen-rich water sheet is wrapped by the composite medical stone ceramic ball, the physical wavelength and the frequency released by the two materials are mutually superposed to form a safe and stable energy field, and meanwhile, the collision between the combined multifunctional health-preserving hydrogen-rich water sheets can be avoided.
The combined multifunctional health-preserving hydrogen-rich water sheet arranged in the second filter cylinder is a product in the patent number ZL201811186592.5 and is produced by Beijing Hydrogen technologies Limited.
Furthermore, the weight adding amount ratio of the energy spar to the projective natural ore is 1: 10-15; preferably, 2 tons of water are processed per hour, the total addition amount of the energy spar is 1-3KG, and the total addition amount of the projecting natural ore is 10-30 KG.
Further, the energy spar is prepared from the following raw materials in parts by weight: 60-80 parts of silicate binder, 10-20 parts of tourmaline powder, 5-10 parts of nano rare earth oxide, 5-10 parts of low-temperature fluxing agent and 2-10 parts of far infrared ceramic powder; the preparation method of the energy spar comprises the following steps: mixing all the above raw materials, mixing well, and sintering at 1500 deg.C or below.
Preferably, the silicate binder is kaolin with a particle size of 2000 meshes or more; the tourmaline powder is one or more of iron tourmaline, magnesium tourmaline and lithium tourmaline with particle size of more than 10000 meshes; the nano rare earth oxide is yttrium oxide, neodymium oxide and/or cerium oxide; the low-temperature fluxing agent is CaO, MgO and K 2 O、Na 2 O, PbO and mixing one or more of them.
Further, the projection natural ore is one or a combination of more of agate, flint, obsidian, agate, ruby, sunstone, alexandrite, crossed stone, chrysosporium and schlernite.
Further, the composite medical stone ceramic ball is prepared from the following raw materials in parts by weight: 30-50 parts of silicon dioxide and 20-40 parts of medical stone powder; 10-30 parts of tourmaline powder, 3-10 parts of graphene and 3-5 parts of sintering aid; the preparation method of the composite medical stone ceramic ball comprises the following steps: all the raw materials are mixed and sintered into ceramic balls with the diameter of 3-5mm at 1500 ℃ after being uniformly mixed.
Preferably, the particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is one or a mixture of more than two of iron tourmaline, magnesium tourmaline and lithium tourmaline with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90um, and the sintering aid is yttrium oxide and aluminum oxide.
Furthermore, the first filter cylinder and the second filter cylinder are both integrally formed stainless steel cylinders.
Or the second filter cylinder is divided into a plurality of sections, and two adjacent sections are connected through sealing rubber rings and clamping hoops.
Furthermore, the electronic release device comprises five sections of inner ribbed pipes, and two adjacent sections of inner ribbed pipes are connected through a sealing rubber ring and a clamping hoop; stainless steel filter screens are arranged between two adjacent sections of inner ribbed pipes for separation, the rib height of each section of inner ribbed pipe is 1-10mm, the thread pitch is 2-20mm, and the helical angle is 10-70 degrees. The diameter of the stainless steel filter screen is equal to the inner diameter of the two ends of the inner ribbed pipe, and the stainless steel filter screen is just abutted to the inner walls of the two ends of the inner ribbed pipe. The stainless steel filter screen is placed in parallel with the cross section of the inner ribbed tube.
The inner ribbed tube is made of aluminum alloy, and the electrode metal band is one or a combination of nickel-aluminum band or other electrode metal bands.
Preferably, the thickness of the electrode metal strip is 0.1-0.5mm, and the width of the electrode metal strip is 10-50 mm; the electrode metal band is in a hollow spiral shape with the length of 20-50 mm. The electrode metal strip is made into a hollow spiral body shape with the length of 20-50mm in order to increase the disturbance effect.
Furthermore, 3/1 volumes of combined materials are added into each section of inner ribbed tube, the electrode metal band is a nickel-aluminum band or an aluminum band, and the weight adding amount ratio of the composite tourmaline ceramic ball to the electrode metal band is 10-20: 1.
Preferably, the content ratio of nickel to aluminum in the nickel-aluminum strip is 1: 1.
Further, the composite tourmaline ceramic ball is prepared from the following raw materials in parts by weight: 50-60 parts of aluminum oxide, 5-20 parts of tourmaline powder, 5-15 parts of silicon oxide, 5-10 parts of an oxidation auxiliary agent, 3-10 parts of an organic binder, 3-10 parts of a pore-forming agent and 0.1-0.5 part of a nano noble metal; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at the temperature of over 900 ℃.
Preferably, the oxidation auxiliary agent is magnesium oxide, calcium oxide, potassium oxide and sodium oxide, the organic binder is hydroxymethyl cellulose and polyvinyl alcohol, the pore-forming agent is sodium bicarbonate and bamboo charcoal powder, and the nano noble metal is platinum oxide or palladium oxide.
Preferably, the purity of the aluminum oxide is below 99%, the particle fineness of the aluminum oxide is below 1um, the purity of the tourmaline powder is below 99%, the particle fineness of the tourmaline powder is above 6000 meshes, and the particle fineness of the silicon oxide is above 2000 meshes.
When the device is used, water flows into the supercharging device from the main water inlet for supercharging and flows through the water activating device, the hydrogen-rich device and the electronic release device in sequence; when water flows through the first filter cylinder of the running water device, the energy spar and the projective natural ore utilize specific far infrared energy waves to split large water molecule groups into smaller water molecule groups; then flows into a second filter cylinder of the hydrogen enrichment device, and the combined multifunctional health-preserving hydrogen enrichment water piece and the composite medical stone ceramic ball promote water molecules to generate a polarization reaction to generate hydrogen positive ions (H +) and hydroxyl negative ions (OH-), wherein the water molecules absorb the hydroxyl negative ions to generate activated water and hydrate hydroxyl ions (namely H-) 3 O 2 -ions); then flows into the electron releasing device to strengthen the piezoelectric property and release electrons; and combines with positive hydrogen ions generated by the hydrogen enrichment device to generate active hydrogen.
Example 1
The present embodiment provides an active hydrogen generator including: the device comprises a supercharging device 1 (a pressure pump with the output pressure of 0.5 MPa), three water activating devices 2, a hydrogen enrichment device 3 and an electronic release device 4 which are connected in sequence between a main water inlet and a main water outlet through water supply pipes, wherein the supercharging device, the water activating devices, the hydrogen enrichment device and the electronic release device are connected in sequence through the water supply pipes; the water activating device comprises a first filter cylinder, and energy spar and projective natural ore are arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and a combined multifunctional health-preserving hydrogen-rich water sheet and a composite medical stone ceramic ball are arranged in the second filter cylinder; the electronic release device comprises an inner ribbed tube, and a combined material consisting of composite tourmaline ceramic balls and an electrode metal band is placed in the inner ribbed tube.
The weight adding amount ratio of the composite tourmaline ceramic ball to the electrode metal belt is 20: 1; the weight adding amount ratio of the energy spar to the projective natural ore is 1: 15; the total addition of energy spar is 3KG and the total addition of the projected natural ore is 25KG, each hour for 2 tons of water.
The energy spar is prepared from the following raw materials: 60kg of silicate binder, 20kg of tourmaline powder, 5kg of nano rare earth oxide, 10kg of low-temperature fluxing agent and 2kg of far infrared ceramic powder; the preparation method of the energy spar comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at 1450 ℃.
The silicate binder is kaolin with the particle size of more than 2000 meshes; the tourmaline powder is magnesium tourmaline with the particle size of more than 10000 meshes; the nanometer rare earth oxide is neodymium oxide; the low-temperature fluxing agent is MgO. The projective natural ore is obsidian.
The composite medical stone ceramic ball is prepared from the following raw materials: 30kg of silicon dioxide and 20kg of medical stone powder; 30kg of tourmaline powder, 3kg of graphene and 5kg of sintering aid; the preparation method of the composite medical stone ceramic ball comprises the following steps: all the raw materials are mixed and sintered into ceramic balls with the diameter of 3-5mm at 1500 ℃ after being uniformly mixed.
The particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is magnesium tourmaline with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90 microns, and the sintering aid is yttrium oxide and aluminum oxide.
The composite tourmaline ceramic ball is prepared from the following raw materials: 60kg of aluminum oxide, 20kg of tourmaline powder, 5kg of silicon oxide, 5kg of calcium oxide, 10kg of organic binder, 3kg of pore-forming agent and 0.5kg of platinum oxide; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at the temperature of more than 900 ℃ to obtain the porous ceramic material, wherein the organic binder is hydroxymethyl cellulose and polyvinyl alcohol, and the pore-forming agent is sodium bicarbonate and bamboo charcoal powder.
The purity of alumina is below 99%, the particle fineness of alumina is below 1um, the purity of tourmaline powder is below 99%, the particle fineness of tourmaline powder is above 6000 meshes, and the particle fineness of silicon oxide is above 2000 meshes.
Example 2
The present embodiment provides an active hydrogen generator including: the device comprises a pressurizing device 1, four water activating devices 2, a hydrogen enriching device 3, two electronic releasing devices 4, a filtering device 5 and a sterilizing device 6 which are connected in sequence from a main water inlet to a main water outlet through water supply pipes, wherein each water activating device comprises a first filter cylinder, and energy crystal and projective natural ore are alternately arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and combined multifunctional health-preserving hydrogen-rich water sheets and composite medical stone ceramic balls are alternately arranged in the second filter cylinder; the electronic release device comprises an inner ribbed pipe, and composite materials consisting of composite tourmaline ceramic balls and aluminum strips are alternately arranged in the inner ribbed pipe.
The active hydrogen generator is provided with a supercharging device, four water activating devices, a hydrogen-rich device and two electron releasing devices which are sequentially connected through a water supply pipe. The water inlets of the supercharging device, the water activating device, the hydrogen-rich device and the electronic release device are all arranged at the lower end, and the water outlets are all arranged at the upper end; the boosting device is a pressure pump with the output pressure within 0.6 MPa.
The first filter cylinder and the second filter cylinder are both integrally formed stainless steel cylinders.
The electronic release device comprises five sections of inner ribbed tubes 7, and two adjacent sections of inner ribbed tubes are connected with a clamp 8 through a sealing rubber ring; stainless steel filter screens 9 are arranged between two adjacent sections of inner ribbed pipes for separation, the rib height of each section of inner ribbed pipe is 1-10mm, the thread pitch is 2-20mm, and the helical angle is 10-70 degrees. The inner ribbed tube is made of aluminum alloy, and the electrode metal belt is a nickel-aluminum belt. The thickness of the electrode metal belt is 0.1-0.5mm, and the width of the electrode metal belt is 10-50 mm; the electrode metal band is in a hollow spiral shape with the length of 20-50 mm. 3/1-volume combined materials are added into each section of inner ribbed pipe, each combined material consists of a composite tourmaline ceramic ball and a nickel-aluminum belt, and the weight adding amount ratio of the composite tourmaline ceramic ball to the nickel-aluminum belt is 10: 1; 2 tons of water per hour are treated, the total addition of energy spar is 1KG and the total addition of projected natural ore is 10 KG.
The energy spar is prepared from the following raw materials: 80kg of silicate binder, 10kg of tourmaline powder, 10kg of nano rare earth oxide, 5kg of low-temperature fluxing agent and 10kg of far infrared ceramic powder; the preparation method of the energy spar comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at 1470 ℃.
The silicate binder is kaolin with the particle size of more than 2000 meshes; the tourmaline powder is iron tourmaline with the particle size of more than 10000 meshes; the nano rare earth oxide is yttrium oxide; the low-temperature fluxing agent is CaO; the projective natural ore is black agate.
The composite medical stone ceramic ball is prepared from the following raw materials: 30kg of silicon dioxide and 40kg of medical stone powder; 10kg of tourmaline powder, 10kg of graphene and 3kg of sintering aid; the preparation method of the composite medical stone ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at 1500 ℃ to form ceramic balls with the diameter of 3-5 mm; the particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is ferroelectric gas with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90 microns, and the sintering aid is yttrium oxide and aluminum oxide.
The composite tourmaline ceramic ball is prepared from the following raw materials: 50kg of aluminum oxide, 5kg of tourmaline powder, 15kg of silicon oxide, 10kg of magnesium oxide, 3kg of organic binder, 10kg of pore-forming agent and 0.1kg of nano noble metal; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at the temperature of over 900 ℃ to obtain the material; the organic binder is hydroxymethyl cellulose and polyvinyl alcohol, the pore-forming agent is sodium bicarbonate and bamboo charcoal powder, and the nano noble metal is palladium oxide.
Preferably, the purity of the aluminum oxide is below 99%, the particle fineness of the aluminum oxide is below 1um, the purity of the tourmaline powder is below 99%, the particle fineness of the tourmaline powder is above 6000 meshes, and the particle fineness of the silicon oxide is above 2000 meshes.
Example 3
This example differs from example 2 in that:
the weight adding amount ratio of the composite tourmaline ceramic ball to the electrode metal belt is 15: 1; and 2 tons of water are processed per hour, the total addition amount of the energy spar is 2KG, and the total addition amount of the projected natural ore is 20 KG.
The energy spar is prepared from the following raw materials: 70kg of silicate binder, 15kg of tourmaline powder, 8kg of nano rare earth oxide, 8kg of low-temperature fluxing agent and 7kg of far infrared ceramic powder; the preparation method of the energy spar comprises the following steps: mixing all the above raw materials, mixing well, and sintering at 1480 deg.C.
The silicate binder is kaolin with the particle size of more than 2000 meshes; the tourmaline powder is lithium tourmaline with the particle size of more than 10000 meshes; the nano rare earth oxide is cerium oxide; the low-temperature fluxing agent is Na 2 And O. The projection natural ore is the combination of red agate, ruby, sunstone, alexandrite and cross stone.
The composite medical stone ceramic ball is prepared from the following raw materials: 40kg of silicon dioxide and 30kg of medical stone powder; 20kg of tourmaline powder, 6kg of graphene and 4kg of sintering aid; the preparation method of the composite medical stone ceramic ball comprises the following steps: all the raw materials are mixed and sintered into ceramic balls with the diameter of 3-5mm at 1500 ℃ after being uniformly mixed.
The particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is lithium tourmaline with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90 microns, and the sintering aid is yttrium oxide and aluminum oxide.
The composite tourmaline ceramic ball is prepared from the following raw materials: 55kg of alumina, 15kg of tourmaline powder, 10kg of silicon oxide, 7kg of potassium oxide, 3kg of hydroxymethyl cellulose and polyvinyl alcohol respectively, 3.5kg of sodium bicarbonate and bamboo charcoal powder respectively and 0.3kg of palladium oxide; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at 920 ℃.
The purity of alumina is below 99%, the particle fineness of alumina is below 1um, the purity of tourmaline powder is below 99%, the particle fineness of tourmaline powder is above 6000 meshes, and the particle fineness of silicon oxide is above 2000 meshes.
Detection test
The active hydrogen generators of examples 2 and 3 were used to treat water, which flowed in from the total water inlet, was pressurized by the pressurizing device, and then flowed out through four water activating devices, one hydrogen enriching device, two electron releasing devices, one filtering device and one sterilizing device. Please examine the water flowing out from the center for hydrogen atoms (free radicals) and oxygen-rich content.
The detection method comprises the following steps: DBNBS was added to the sample, and the color produced by the absorption characteristics of the resulting solution was detected, and hydrogen gas was blown into OPPH solution and DBNBS solution having an absorption peak near 517nm at a constant rate in the presence of platinum black, and the concentration of hydrogen radicals was determined using a calibration curve showing the relationship between the absorbance of DBNBS azo compound near 450nm and the concentration of hydrogen radicals produced.
The results are shown in Table 1 below.
TABLE 1 analysis results of hydrogen atoms of treated water samples
| Sample name | Item | Analysis results |
| Example 2 Water sample | Hydrogen atom (radical), ppm | 7.41 |
| Example 3 Water sample | Hydrogen atom (free radical)，ppm | 7.82 |
| Example 2 Water sample | Half-height peak width (oxygen-rich content) of small molecular group 17ONMR signal, Hz | 41 |
| Example 3 Water sample | Half-height peak width (oxygen-rich content) of small molecular group 17ONMR signal, Hz | 54 |
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. An active hydrogen generator, comprising: the device comprises a pressurizing device, a water activating device, a hydrogen-rich device and an electronic release device which are arranged between a main water inlet and a main water outlet, wherein the pressurizing device, the water activating device, the hydrogen-rich device and the electronic release device are sequentially connected through a water supply pipe; the water activating device comprises a first filter cylinder, and energy spar and projective natural ore are arranged in the first filter cylinder; the hydrogen-rich device comprises a second filter cylinder, and a combined multifunctional health-preserving hydrogen-rich water sheet and a composite medical stone ceramic ball are arranged in the second filter cylinder; the electronic release device comprises an inner ribbed tube, and a composite material consisting of composite tourmaline ceramic balls and an electrode metal band is placed in the inner ribbed tube; the energy spar is prepared from the following raw materials in parts by weight: 60-80 parts of silicate binder, 10-20 parts of tourmaline powder, 5-10 parts of nano rare earth oxide, 5-10 parts of low-temperature fluxing agent and 2-10 parts of far infrared ceramic powder; the composite tourmaline ceramic ball is prepared from the following raw materials in parts by weight: 50-60 parts of aluminum oxide, 5-20 parts of tourmaline powder, 5-15 parts of silicon oxide, 5-10 parts of an oxidation auxiliary agent, 3-10 parts of an organic binder, 3-10 parts of a pore-forming agent and 0.1-0.5 part of a nano noble metal; the composite medical stone ceramic ball is prepared from the following raw materials in parts by weight: 30-50 parts of silicon dioxide and 20-40 parts of medical stone powder; 10-30 parts of tourmaline powder, 3-10 parts of graphene and 3-5 parts of sintering aid.
2. The active hydrogen generator according to claim 1, wherein the active hydrogen generator is provided with one pressure boosting device, four water activating devices, one hydrogen rich device and two electron releasing devices which are connected in sequence through water supply pipes; the boosting device is a pressure pump with the output pressure of 0.3-0.6 MPa.
3. An active hydrogen generator according to claim 1 or 2, characterized in that the active hydrogen generator is further provided with a filtering device and/or a sterilizing device; the filtering holes of the filtering device are 0.2-5 um, and the sterilizing device is a 50-100 watt flow type ultraviolet tube; energy spar and projective natural ore are alternately arranged in the first filter cylinder, and combined multifunctional health-preserving hydrogen-rich water tablets and composite medical stone ceramic balls are alternately arranged in the second filter cylinder.
4. The active hydrogen generator of claim 1 or 2, wherein the ratio of the weight addition of the energy spar to the projected natural ore is 1: 10-15.
5. The active hydrogen generator of claim 1, wherein the energy spar is prepared by: mixing all the raw materials, uniformly mixing, and sintering at the temperature of below 1500 ℃; the silicate binder is kaolin with the particle size of more than 2000 meshes; the tourmaline powder is one or more of iron tourmaline, magnesium tourmaline and lithium tourmaline with particle size of more than 10000 meshes; the above-mentioned The nanometer rare earth oxide is yttrium oxide, neodymium oxide and/or cerium oxide; the low-temperature fluxing agent is CaO, MgO and K 2 O、Na 2 O, PbO and mixing above two materials.
6. The active hydrogen generator according to claim 1, wherein the projecting natural ore is one or more of black agate, flint, obsidian, red agate, ruby, sunstone, alexandrite, crossed stone, gold crystals, and black crystals; the preparation method of the composite tourmaline ceramic ball comprises the following steps: mixing all the raw materials, uniformly mixing, and sintering at the temperature of over 900 ℃; the oxidation auxiliary agent is magnesium oxide, calcium oxide, potassium oxide and sodium oxide, the organic binder is hydroxymethyl cellulose and polyvinyl alcohol, the pore-forming agent is sodium bicarbonate and bamboo charcoal powder, and the nano noble metal is platinum oxide or palladium oxide.
7. The active hydrogen generator according to claim 1, wherein the composite medical stone ceramic ball is prepared by a method comprising: mixing all the raw materials, uniformly mixing, and sintering at 1500 ℃ to form ceramic balls with the diameter of 3-5 mm; the particle size of the silicon dioxide is more than 2000 meshes, the purity of the medical stone powder is more than 95%, the particle size of the medical stone powder is more than 1250 meshes, the tourmaline powder is one or more of iron tourmaline, magnesium tourmaline and lithium tourmaline with the particle size of more than 10000 meshes, the particle fineness of the graphene is 70-90um, and the sintering aid is yttrium oxide and aluminum oxide.
8. The active hydrogen generator of claim 1, wherein the first and second filter cartridges are stainless steel filter cartridges.
9. The active hydrogen generator according to claim 1, wherein the electron release device comprises five sections of inner ribbed tubes, and two adjacent sections of inner ribbed tubes are connected through a sealing rubber ring and a clamping hoop; a stainless steel filter screen is arranged between two adjacent sections of inner ribbed tubes, the rib height of each inner ribbed tube is 1-10mm, the thread pitch is 2-20mm, and the helical angle is 10-70 degrees; the thickness of the electrode metal belt is 0.1-0.5mm, and the width of the electrode metal belt is 10-50 mm; the electrode metal band is in a hollow spiral shape with the length of 20-50 mm.
10. The active hydrogen generator according to claim 9, wherein 3/1 volumes of combined materials are added into each section of inner ribbed tube, the electrode metal band is a nickel-aluminum band or an aluminum band, and the weight addition ratio of the composite tourmaline ceramic balls to the electrode metal band is 10-20: 1; the content ratio of nickel to aluminum in the nickel-aluminum strip is 1: 1.
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