CN109137545A - 一种玻璃纤维网格布的制备方法 - Google Patents
一种玻璃纤维网格布的制备方法 Download PDFInfo
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Abstract
本发明公开了一种玻璃纤维网格布的制备方法,包括玻璃纤维纱捻制、将玻璃纤维纱编织成玻璃纤维网格布、酸化处理、蒸馏水冲洗、加热处理和涂覆涂层浆料六个步骤;本发明制备工艺生产的玻璃纤维网格布,组织结构紧密、布面平整光洁,厚度和平方米克重变异系数小,耐高温性能优异,具有良好的耐温和抗冲击性能,柔韧性好,服帖性好且成本低廉,可广泛用于建筑物内外墙体保温、防水、抗裂等。
Description
技术领域
本发明涉及网格布制备工艺技术领域,具体是一种玻璃纤维网格布的制备方法。
背景技术
玻璃纤维网格布是以玻璃纤维机织物为基材,经高分子抗乳液浸泡涂层的物质,由 于玻璃纤维网格布所用的丙烯酸酯乳液作为涂层存在着“热粘冷脆”强度及耐碱保留率不高的特点,在实际生产应用中都受到了限制,耐高温、抗碱性和抗冲刷性能较差;且 玻璃纤维网格布作为增强材料已经被广泛地应用于建筑墙面中,但现有的网格布其强度 无法满足建筑业的需要,如果采用较粗的纤维,网格布表面凹凸不平,服帖性差,不容 易施工,强度不够,且质量不易控制。
发明内容
本发明的目的在于提供一种玻璃纤维网格布的制备方法,以解决上述背景技术中提出 的问题。
为实现上述目的,本发明提供如下技术方案:
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.2-0.7mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为1-2mol/L的盐酸注入酸沥滤槽中,在70℃-85℃下处理1-2小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在45℃-55℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为700℃-800℃,处理时间为1-2小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品;
作为本发明进一步的方案:在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰90-97份,弹力胶3-10份,分散剂1-3份,润滑剂1-4份,光稳定剂1-3 份,抗氧剂1-3份;面粉20-30份,阻燃剂2-6份,乳化剂5-8份。
作为本发明进一步的方案:过氧化苯甲酰92份,弹力胶4份,分散剂2份,润滑剂3份,光稳定剂3份,抗氧剂1份;面粉25份,阻燃剂2份,乳化剂8份。
作为本发明再进一步的方案:乳化剂为辛基酚聚氧乙烯醚、磺化蓖麻油、十二烷基硫 酸钠、十二烷基苯磺酸钠中的一种或几种;所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为羟基官能羧酸、不饱和羧酸聚合物、多元胺酰胺溶液、 碱性氨基甲酸酯共聚物和改性聚醚中的一种或多种,所述弹力胶包括10-35份重量的固体 含量为60-75%的丙烯酸树脂乳液、10-15份水性聚氨酯、5-8份重量的丙烯酸树脂粉末、 2-6份重量的固体含量为20-35%的EVA乳液以及1-4份重量的氯化聚丙烯。
与现有技术相比,本发明的有益效果是:本发明制备工艺生产的玻璃纤维网格布,组 织结构紧密、布面平整光洁,厚度和平方米克重变异系数小,耐高温性能优异,具有良好的耐温和抗冲击性能,柔韧性好,服帖性好且成本低廉,可广泛用于建筑物内外墙体 保温、防水、抗裂等。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.3m;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为1.2mol/L的盐酸注入酸沥滤槽中,在71℃下处理1.5小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在55℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为750℃,处理时间为1.2小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰97份,弹力胶3份,分散剂1份,润滑剂1份,光稳定剂1份,抗氧剂1份;面粉20份,阻燃剂2份, 乳化剂5份。
乳化剂为辛基酚聚氧乙烯醚。
所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为羟基官能羧酸。
所述弹力胶包括15份重量的固体含量为60-75%的丙烯酸树脂乳液、10份水性聚氨酯、 5份重量的丙烯酸树脂粉末、2份重量的固体含量为25%的EVA乳液以及1份重量的氯化聚 丙烯。
实施例2
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.4mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为1.3mol/L的盐酸注入酸沥滤槽中,在78℃下处理1.3小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在47℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为710℃,处理时间为1.3小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰92份,弹力胶4份,分散剂1份,润滑剂2份,光稳定剂1份,抗氧剂1份;面粉22份,阻燃剂3份, 乳化剂6份。
乳化剂为十二烷基硫酸钠。
所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为羟基官能羧酸。
所述弹力胶包括10份重量的固体含量为65%的丙烯酸树脂乳液、11份水性聚氨酯、5 份重量的丙烯酸树脂粉末、4份重量的固体含量为25%的EVA乳液以及3份重量的氯化聚 丙烯.
实施例3
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.5mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为1.4mol/L的盐酸注入酸沥滤槽中,在74℃下处理1.4小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在46℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为760℃,处理时间为1.8小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰94份,弹力胶4份,分散剂2份,润滑剂2份,光稳定剂2份,抗氧剂2份;面粉25份,阻燃剂2份, 乳化剂6份。
乳化剂为辛基酚聚氧乙烯醚、磺化蓖麻油和十二烷基硫酸钠。
所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为碱性氨基甲酸酯共聚物。
所述弹力胶包括14份重量的固体含量为71%的丙烯酸树脂乳液、13份水性聚氨酯、6 份重量的丙烯酸树脂粉末、2份重量的固体含量为31%的EVA乳液以及3份重量的氯化聚 丙烯。
实施例4
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.6mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为1.6mol/L的盐酸注入酸沥滤槽中,在84℃下处理1.8小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在49℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为780℃,处理时间为1.3小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰96份,弹力胶6份,分散剂3份,润滑剂4份,光稳定剂3份,抗氧剂3份;面粉30份,阻燃剂6份, 乳化剂8份。
乳化剂为十二烷基硫酸钠。
所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为改性聚醚。
所述弹力胶包括35份重量的固体含量为75%的丙烯酸树脂乳液、15份水性聚氨酯、7 份重量的丙烯酸树脂粉末、5份重量的固体含量为35%的EVA乳液以及4份重量的氯化聚 丙烯。
实施例5
一种玻璃纤维网格布的制备方法,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所 述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的 厚度为0.5mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择 浓度为2mol/L的盐酸注入酸沥滤槽中,在85℃下处理2小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在53℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为800℃,处理时间为2小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰97份,弹力胶9份,分散剂2份,润滑剂4份,光稳定剂2份,抗氧剂1份;面粉26份,阻燃剂6份, 乳化剂8份。
乳化剂为辛基酚聚氧乙烯醚。
所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为羟基官能羧酸。
所述弹力胶包括25份重量的固体含量为70%的丙烯酸树脂乳液、14份水性聚氨酯、5 份重量的丙烯酸树脂粉末、5份重量的固体含量为28%的EVA乳液以及3份重量的氯化聚 丙烯。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含 一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将 说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可 以理解的其他实施方式。
Claims (6)
1.一种玻璃纤维网格布的制备方法,其特征在于,步骤如下:
S1、玻璃纤维纱捻制:使用连续玻璃纤维原丝加捻制成玻璃纤维纱;
S2、将玻璃纤维纱编织成玻璃纤维网格布:将玻璃纤维纱交叉编织成一个经线组,所述经线组之间等距排列,有序地将其编织成合格的网格坯布,其中所述玻璃纤维网格布的厚度为0.2-0.7mm;
S3、酸化处理:将上述坯布均匀排布在一组支撑杆上,整体放入到酸沥滤槽内,选择浓度为1-2mol/L的盐酸注入酸沥滤槽中,在70℃-85℃下处理1-2小时,同时用耐酸泵进行循环搅拌;
S4、蒸馏水冲洗:经上述步骤处理后的坯布在45℃-55℃温度下水洗,当PH值大于5时水洗完成;
S5、加热处理:水洗后将坯布置入连续式烘干炉内进行热定型处理,温度为700℃-800℃,处理时间为1-2小时;
S6、涂覆涂层浆料:在玻璃纤维网格布表层涂覆涂层浆料,制成玻璃纤维网格布成品。
2.根据权利要求1所述的玻璃纤维网格布的制备方法,其特征在于,在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰90-97份,弹力胶3-10份,分散剂1-3份,润滑剂1-4份,光稳定剂1-3份,抗氧剂1-3份;面粉20-30份,阻燃剂2-6份,乳化剂5-8份。
3.根据权利要求1所述的玻璃纤维网格布的制备方法,其特征在于,在步骤S6中,涂覆使用的涂层浆料包括以下重量组分:过氧化苯甲酰92份,弹力胶4份,分散剂2份,润滑剂3份,光稳定剂3份,抗氧剂1份;面粉25份,阻燃剂2份,乳化剂8份。
4.根据权利要求1所述的玻璃纤维网格布的制备方法,其特征在于,乳化剂为辛基酚聚氧乙烯醚、磺化蓖麻油、十二烷基硫酸钠、十二烷基苯磺酸钠中的一种或几种。
5.根据权利要求1所述的玻璃纤维网格布的制备方法,其特征在于,所述润滑剂为硬脂酸钾,所述抗氧剂为N′,N-二苯基对苯二胺;所述分散剂为羟基官能羧酸、不饱和羧酸聚合物、多元胺酰胺溶液、碱性氨基甲酸酯共聚物和改性聚醚中的一种或多种。
6.根据权利要求2所述的玻璃纤维网格布的制备方法,其特征在于,所述弹力胶包括10-35份重量的固体含量为60-75%的丙烯酸树脂乳液、10-15份水性聚氨酯、5-8份重量的丙烯酸树脂粉末、2-6份重量的固体含量为20-35%的EVA乳液以及1-4份重量的氯化聚丙烯。
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CN111912206A (zh) * | 2020-08-24 | 2020-11-10 | 江苏华跃玻璃制品有限公司 | 一种玻璃纤维网格布烘干装置 |
CN115674824A (zh) * | 2022-09-30 | 2023-02-03 | 台嘉成都玻纤有限公司 | 一种玻璃纤维布的制备方法 |
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CN111912206A (zh) * | 2020-08-24 | 2020-11-10 | 江苏华跃玻璃制品有限公司 | 一种玻璃纤维网格布烘干装置 |
CN115674824A (zh) * | 2022-09-30 | 2023-02-03 | 台嘉成都玻纤有限公司 | 一种玻璃纤维布的制备方法 |
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