CN109112893A - 一种喷墨专用的特种热敏纸 - Google Patents

一种喷墨专用的特种热敏纸 Download PDF

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CN109112893A
CN109112893A CN201710483764.4A CN201710483764A CN109112893A CN 109112893 A CN109112893 A CN 109112893A CN 201710483764 A CN201710483764 A CN 201710483764A CN 109112893 A CN109112893 A CN 109112893A
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王道力
亓华利
钟亚伍
唐宏磊
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Jiangsu Wanbao Ruida High-New Technology Co Ltd
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Abstract

本发明涉及一种喷墨专用的特种热敏纸,由下到上依次为原纸层、底涂层、耐温发色层、保护层、吸收层,所述底涂层、耐温发色层、保护层、吸收层均分别涂布有不同的涂布液。本发明能提升带保护层的特种热敏纸涂层对油墨的吸收速度,在保护层之上再进行一层吸收层的涂布,达到快干的目的,解决了因难干燥而造成纸面污染或文字图案不清晰的问题;另外,本发明增加吸收层来解决对打印热能隔离的影响,底涂层使用足够量的中空球,并提高涂布量,使其隔热效果得到提高;发色层满足了特种热敏纸在预制条码干燥时,不受干燥温度影响而发色;保护层不需要添加有机填料,提高传热效果;吸收层使用吸收性较强、热传递性能好的无机填料,有利热量的传递。

Description

一种喷墨专用的特种热敏纸
技术领域
本发明涉及热敏纸技术领域,具体涉及一种喷墨专用的特种热敏纸,适用于喷码、印章印迹快速干燥,如热敏电子发票、收据凭证等。
背景技术
随着特种热敏纸技术的发展,品质日臻成熟以及其使用简单便利特点,其使用领域越来越广泛,其使用由最初的普通收据或记录一些文字图案,不需要盖章确认,当作为电子发票或收据凭证用途后则需要在票面上预制条码来识别或盖章确认。现在市场上带保护层特种热敏纸为了达到一定防护功能,保护层一般由大量的PVA或丙烯酸胶乳组成,涂层比较封闭,对水性油墨的吸收性能较弱,当作为电子发票需要在票面预制条码时由于涂层不易吸收油墨导致干燥困难带来的条码不够清晰,影响票据的识读。
发明内容
本发明的目的在于:针对目前市场上带保护层特种热敏纸涂层吸收速度不足,提供一种喷墨专用的特种热敏纸,在保护层上再增加吸收层的涂布,以提高其吸收性。
本发明是通过以下技术方案实现的:
一种喷墨专用的特种热敏纸,包括原纸层、底涂层和耐温发色层,所述原纸层的上方依次设有底涂层、耐温发色层,所述耐温发色层的上方设有保护层,保护层的上方设有吸收层。
进一步,所述底涂层、耐温发色层、保护层、吸收层均分别采用不同的涂布液涂布,以实现每层的功能。
进一步,所述底涂层的涂布液由以下重量份原料制成:中空球 65份、丁苯胶乳 10份、保水剂 2份、高岭土分散液 20份、润滑剂 3份,搅拌混合配制成固含量为35%涂布液,用刮刀进行涂布,涂布量4.0-6.5g/m2
进一步,所述耐温发色层的涂布液由以下重量份原料制成:无色染料研磨液(粒径≤0.6μm) 12份、增感剂研磨液(粒径≤0.8μm) 10份、双酚S4,4显色剂研磨液(粒径≤0.9μm) 22份、轻质碳酸钙分散液 45份、聚乙烯醇 5份、丁苯胶乳 3份、润滑剂 3份,搅拌混合配制成固含量为25%涂布液,用计量棒进行涂布,涂布量3.0-4.5g/m2
进一步,所述保护层的涂布液由以下重量份原料制成:分散剂 3份、改性聚乙烯醇胶液 70份、交联剂 15份、润滑剂 10份、消泡剂 2份,搅拌混合配制成固含量为10%涂布液,用计量棒涂布,涂布量1.5-2.0g/㎡。
进一步,所述吸收层的涂布液由以下重量份原料制成:分散剂 2份、沉淀二氧化硅研磨液(粒径≤0.6μm) 40份、硬脂酸锌乳液 8份、改性聚乙烯醇 35份、交联剂 13份、消泡剂 2份,混合搅拌配制成固含量为15%涂布液,用计量棒涂布,涂布量1.8-2.2g/㎡。
进一步,所述原纸层的涂布定量为45-60g/m2,涂布面平滑度为50-80s。
进一步,涂布完毕进行压光,放入熟化房熟化72h后可分切成品。
综上所述,由于采用了上述技术方案,本发明的有益效果是:
1、本发明能提升带保护层的特种热敏纸涂层对油墨的吸收速度,在保护层之上再进行一层吸收层的涂布,达到快干的目的,解决了因难干燥而造成纸面污染或文字图案不清晰的问题。
2、本发明增加吸收层来解决对打印热能隔离的影响,则需要在每个涂层进行改进,底涂层使用足够量的中空球,并提高涂布量,使其隔热效果得到提高;发色层使用耐热效果更好的工艺体系,满足特种热敏纸在预制条码干燥时,不受干燥温度影响而发色;保护层不需要添加有机填料,提高传热效果,一般保护层配制是使用改性PVA、丙烯酸胶乳、无机填料、润滑剂等;吸收层使用吸收性较强、热传递性能好的无机填料,有利热量的传递。
附图说明
本发明将通过例子并参照附图的方式说明,其中:
图1是本发明的结构示意图;
图中所示:1-吸收层、2-保护层、3-耐温发色层、4-底涂层、5-原纸层。
具体实施方式
本说明书中公开的所有特征,或公开的所有方法或过程中的步骤,除了互相排斥的特征和/或步骤以外,均可以以任何方式组合。
本说明书(包括任何附加权利要求、摘要和附图)中公开的任一特征,除非特别叙述,均可被其他等效或具有类似目的的替代特征加以替换。即,除非特别叙述,每个特征只是一系列等效或类似特征中的一个例子而已。
如图1所示,一种喷墨专用的特种热敏纸,由下到上依次为原纸层5、底涂层4、耐温发色层3、保护层2、吸收层1,所述底涂层4、耐温发色层3、保护层2、吸收层1均分别涂布有不同的涂布液。
本实施例中,所述原纸层5的涂布定量为45-60g/m2,涂布面平滑度为50-80s。
本实施例中,所述底涂层4的涂布液由以下重量份原料制成:中空球65份、丁苯胶乳 10份、保水剂 2份、高岭土分散液 20份、润滑剂 3份,搅拌混合配制成固含量为35%涂布液,用刮刀进行涂布,涂布量4.0-6.5g/m2。其中,底涂层4使用足够量的中空球,并提高涂布量,使其隔热效果得到提高。
本实施例中,所述耐温发色层3的涂布液由以下重量份原料制成:无色染料研磨液(粒径≤0.6μm) 12份、增感剂研磨液(粒径≤0.8μm) 10份、双酚S4,4(4-4'-二羟基二苯砜,Cas No:80-09-1)显色剂研磨液(粒径≤0.9μm) 22份、轻质碳酸钙分散液 45份、聚乙烯醇5份、丁苯胶乳 3份、润滑剂 3份,搅拌混合配制成固含量为25%涂布液,用计量棒进行涂布,涂布量3.0-4.5g/m2。耐温发色层满足特种热敏纸在预制条码干燥时不受干燥温度影响而发色。
本实施例中,所述保护层2的涂布液由以下重量份原料制成:分散剂3份、改性聚乙烯醇胶液 70份、交联剂 15份、润滑剂 10份、消泡剂 2份,搅拌混合配制成固含量为10%涂布液,用计量棒涂布,涂布量1.5-2.0g/㎡。其中,保护层不需要添加有机填料,提高了传热效果,一般保护层配制是使用改性PVA、丙烯酸胶乳、无机填料、润滑剂等。
本实施例中,所述吸收层1的涂布液由以下重量份原料制成:分散剂2份、沉淀二氧化硅研磨液(粒径≤0.6μm) 40份、硬脂酸锌乳液 8份、改性聚乙烯醇 35份、交联剂 13份、消泡剂 2份,混合搅拌配制成固含量为15%涂布液,用计量棒涂布,涂布量1.8-2.2g/㎡。其中,吸收层工艺改进,使用吸收性较强、热传递性能好的无机填料,有利热量的传递。
本发明在涂布完毕进行压光,放入熟化房熟化72h后可分切成品。本发明为提高带保护层特种热敏纸对水性油墨的吸收性,在保护层之上再进行一层吸收层的涂布。为了解决增加吸收层对打印热能隔离的影响,则需要在每各涂层功能改进。
以上所述的具体实施例,对本发明的目的、技术方案和有益效果进行了进一步详细说明,所应理解的是,以上所述仅为本发明的具体实施例而已,并不用于限制本发明。本发明扩展到任何在本说明书中披露的新特征或任何新的组合,以及披露的任一新的方法或过程的步骤或任何新的组合。

Claims (8)

1.一种喷墨专用的特种热敏纸,其特征在于,包括原纸层、底涂层和耐温发色层,所述原纸层的上方依次设有底涂层、耐温发色层,所述耐温发色层的上方设有保护层,保护层的上方设有吸收层。
2.如权利要求1所述的喷墨专用的特种热敏纸,其特征在于,所述底涂层、耐温发色层、保护层、吸收层均分别采用不同的涂布液涂布,以实现每层的功能。
3.如权利要求2所述的喷墨专用的特种热敏纸,其特征在于,所述底涂层的涂布液由以下重量份原料制成:中空球 65份、丁苯胶乳 10份、保水剂 2份、高岭土分散液 20份、润滑剂 3份,搅拌混合配制成固含量为35%涂布液,用刮刀进行涂布,涂布量4.0-6.5g/m2
4.如权利要求2所述的喷墨专用的特种热敏纸,其特征在于,所述耐温发色层的涂布液由以下重量份原料制成:无色染料研磨液(粒径≤0.6μm) 12份、增感剂研磨液(粒径≤0.8μm) 10份、双酚S4,4显色剂研磨液(粒径≤0.9μm) 22份、轻质碳酸钙分散液 45份、聚乙烯醇5份、丁苯胶乳 3份、润滑剂 3份,搅拌混合配制成固含量为25%涂布液,用计量棒进行涂布,涂布量3.0-4.5g/m2
5.如权利要求2所述的喷墨专用的特种热敏纸,其特征在于,所述保护层的涂布液由以下重量份原料制成:分散剂 3份、改性聚乙烯醇胶液 70份、交联剂 15份、润滑剂 10份、消泡剂 2份,搅拌混合配制成固含量为10%涂布液,用计量棒涂布,涂布量1.5-2.0g/㎡。
6.如权利要求2所述的喷墨专用的特种热敏纸,其特征在于,所述吸收层的涂布液由以下重量份原料制成:分散剂 2份、沉淀二氧化硅研磨液(粒径≤0.6μm) 40份、硬脂酸锌乳液8份、改性聚乙烯醇 35份、交联剂 13份、消泡剂 2份,混合搅拌配制成固含量为15%涂布液,用计量棒涂布,涂布量1.8-2.2g/㎡。
7.如权利要求2所述的喷墨专用的特种热敏纸,其特征在于,所述原纸层的涂布定量为45-60g/m2,涂布面平滑度为50-80s。
8.如权利要求1—7所述的喷墨专用的特种热敏纸,其特征在于,涂布完毕进行压光,放入熟化房熟化72h后可分切成品。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110103603A (zh) * 2019-05-31 2019-08-09 江苏万宝瑞达高新技术有限公司 一种耐强湿摩擦热敏膜及其制造方法
CN111087639A (zh) * 2019-12-17 2020-05-01 河北方大包装股份有限公司 一种涂布的哑光pp碳带打印合成纸及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110103603A (zh) * 2019-05-31 2019-08-09 江苏万宝瑞达高新技术有限公司 一种耐强湿摩擦热敏膜及其制造方法
CN111087639A (zh) * 2019-12-17 2020-05-01 河北方大包装股份有限公司 一种涂布的哑光pp碳带打印合成纸及其制备方法
CN111087639B (zh) * 2019-12-17 2022-07-19 河北方大包装股份有限公司 一种涂布的哑光pp碳带打印合成纸及其制备方法

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