CN109097988A - 抗菌织物及其制造方法 - Google Patents
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Abstract
本发明涉及一种抗菌织物以及该抗菌织物的制造方法，包括以下具体步骤：将1重量份的抗菌纳米溶液分散在150～250重量份的水中，得到处理液；将15～25重量份的棉质织物浸泡在所述处理液中30～40分钟，所述处理液的温度控制在40～60℃；取出棉质织物脱水后温度控制在120～140℃定型1～2小时。本发明的抗菌织物采用了氧化石墨烯材料进行整理，抗菌防臭，对皮肤无刺激。
Description
技术领域
本发明涉及一种织物及其制造方法，尤其是一种彩棉毛巾织物。
背景技术
毛巾组织是利用织机特殊的送经和打纬运动的共同作用或者特殊的卷取和送经的共同作用，使织物表面覆盖着经纱形成的毛圈的组织。毛巾组织由两个系统的经纱（毛经纱与地经纱）与一个系统的纬纱交织而成。地经纱与纬纱交织成毛巾组织的地组织（也称为底织物），成为毛圈附着的基础；毛经纱与纬纱织成毛巾组织的毛圈组织，在毛巾组织的地组织表面形成毛圈。
毛巾经常在潮湿的条件下使用，与人体皮肤直接接触，时间久了容易滋生细菌，随着人们的生活质量的提高，对毛巾的抗菌性提出了更高的要求。但是，传统的抗菌剂，如抗生素、季铵盐等不但会导致微生物的抗药性，还会造成严重的环境污染，不宜与人体皮肤直接接触。随着科学的发展，石墨烯及其衍生物在抗菌性方面的应用越来越受到人们的关注，但是石墨烯材料如何牢固地与织物相结合是本领域技术人员亟待解决的问题。物理吸附方法，通过压吸或浸染方式的染整法进行处理，毛巾使用时石墨烯材料容易脱落，会成为污染源，若被人体吸入肺部会危害人体健康。中国专利CN201410670057.2将石墨烯材料制成粘胶纤维。
发明内容
本发明要解决的技术问题是，提出一种抗菌防臭，对皮肤无刺激的抗菌织物，以及该抗菌织物的制造方法。
本发明为解决上述技术问题提出的一种技术方案是：一种抗菌织物的制造方法，其特征在于，包括以下具体步骤：
步骤一、将1重量份的抗菌纳米溶液分散在150～250重量份的水中，得到处理液；
步骤二、将15～25重量份的棉质织物浸泡在所述处理液中30～40分钟，所述处理液的温度控制在40～60℃；
步骤三、取出棉质织物脱水后温度控制在120～140℃定型1～2小时。
上述抗菌纳米溶液是在抗菌防臭整理剂ATB9800中加入胺类催化剂进行活化后，再加入氧化石墨烯，然后水浴加热搅拌而得。
上述氧化石墨烯与抗菌防臭整理剂ATB9800的重量比为1︰5～1︰1，所述胺类催化剂与所述氧化石墨烯的重量比为1︰500～1︰100。
上述胺类催化剂是二环己基碳二亚胺、二甲基环己胺、三乙胺或双二甲氨基乙基醚。
上述氧化石墨烯的层数小于等于八层。
上述处理液中还包括渗透剂，所述渗透剂是十二烷基硫酸钠或十二烷基苯磺酸钠，所述渗透剂在处理液中的浓度为0.1～0.5g/L的。
上述织物是毛巾。
上述毛巾的地经纱、纬纱、毛经纱均由40S的精梳彩棉纱三股并纱而成。
本发明为解决上述技术问题提出的另一种技术方案是：一种如上述的抗菌织物的制造方法所制得的织物。
本发明为解决上述技术问题提出的另一种技术方案是：一种如上述的抗菌织物的制造方法所制得的毛巾。
本发明具有积极的效果：本发明采用具有抗菌防臭作用的氧化石墨烯纳米材料，其表面具有羟基、环氧基等含氧基团，在催化剂的诱导下抗菌防臭整理剂ATB9800带有的活性基团会与含氧基团形成共价键，另外抗菌防臭整理剂ATB9800带有的活性基团也会和棉纤维上的羟基、胺基形成共价键，通过低温浸泡和高温定型，从而使得氧化石墨烯纳米材料和ATB9800被牢固的固定在棉质织物上，整理后的毛巾抗菌防臭，对革兰氏阳性菌、革兰氏阴性菌、真菌和酵母菌具有广谱抗菌活性，并且不含甲醛和重金属离子等有害物质，无毒，对皮肤无刺激。
具体实施方式
本发明所用氧化石墨烯为纳米材料，呈片状，可以是单层也可以是多层。抗菌防臭整理剂ATB9800为德国赫特公司Herst生产，本发明中所用试剂如无特殊说明浓度均为化学纯。
实施例1
本实施例的抗菌毛巾的制造方法是：取50g的抗菌防臭整理剂ATB9800，加入0.25g的二环己基碳二亚胺，静止活化15分钟后，逐渐加入50g氧化石墨烯。超声波分散10分钟，水浴50℃加热1小时后，搅拌12小时，得到抗菌纳米溶液。将抗菌纳米溶液加入20kg的纯水中，超声波分散10分钟，得到处理液。处理液中加入10g的十二烷基硫酸钠，将2kg的毛巾浸泡在处理液中30分钟，温度控制在50℃。最后取出毛巾拧干后，温度控制在130℃定型1.5小时，即得到抗菌毛巾。
实施例2
本实施例的抗菌毛巾的制造方法是：取50g的抗菌防臭整理剂ATB9800，加入0.2g的二甲基环己胺，静止活化15分钟后，逐渐加入25g氧化石墨烯。超声波分散10分钟，水浴50℃加热1小时后，搅拌12小时，得到抗菌纳米溶液。将抗菌纳米溶液加入15kg的纯水中，超声波分散10分钟，得到处理液。处理液中加入5g的十二烷基苯磺酸钠，将1.5kg的毛巾浸泡在处理液中30分钟，温度控制在50℃。最后取出毛巾拧干后，温度控制在140℃定型1小时，即得到抗菌毛巾。
实施例3
本实施例的抗菌毛巾的制造方法是：取50g的抗菌防臭整理剂ATB9800，加入0.05g的双二甲氨基乙基醚，静止活化15分钟后，逐渐加入10g氧化石墨烯。超声波分散10分钟，水浴50℃加热1小时后，搅拌12小时，得到抗菌纳米溶液。将抗菌纳米溶液加入12kg的纯水中，超声波分散10分钟，得到处理液。处理液中加入3g的十二烷基硫酸钠，将1.2kg的毛巾浸泡在处理液中30分钟，温度控制在50℃。最后取出毛巾拧干后，温度控制在120℃定型2小时，即得到抗菌毛巾。
实施例4
本实施例的抗菌毛巾的制造方法是：取50g的抗菌防臭整理剂ATB9800，加入0.3g的三乙胺，静止活化15分钟后，逐渐加入30g氧化石墨烯。超声波分散10分钟，水浴50℃加热1小时后，搅拌12小时，得到抗菌纳米溶液。将抗菌纳米溶液加入16kg的纯水中，超声波分散10分钟，得到处理液。处理液中加入5g的十二烷基苯磺酸钠，将1.6kg的毛巾浸泡在处理液中30分钟，温度控制在50℃。最后取出毛巾拧干后，温度控制在130℃定型1.5小时，即得到抗菌毛巾。
实施例5
本实施例的抗菌毛巾的制造方法是：取50g的抗菌防臭整理剂ATB9800，加入0.5g的二环己基碳二亚胺，静止活化15分钟后，逐渐加入50g氧化石墨烯。超声波分散10分钟，水浴50℃加热1小时后，搅拌12小时，得到抗菌纳米溶液。将抗菌纳米溶液加入20kg的纯水中，超声波分散10分钟，得到处理液。将2kg的毛巾浸泡在处理液中30分钟，温度控制在50℃。最后取出毛巾拧干后，温度控制在130℃定型1.5小时，即得到抗菌毛巾。
本发明中的棉质织物在浸泡前必须水洗干净。
本发明中的棉质织物优选毛巾，毛巾的地经纱、纬纱、毛经纱均由40S的精梳彩棉纱三股并纱而成。彩棉采用新疆天然彩棉，地经纱与纬纱交织成毛巾组织的地组织，在地组织上通过毛经纱与纬纱织成毛巾组织的毛圈组织。由于采用天然的彩棉无需印染，牢度强，每平方重量比大，接近600g/m2。
本发明的抗菌毛巾通过扫描电镜观察，石墨烯材料吸附在棉纤维上。将本发明的抗菌毛巾用加入洗衣粉的热水反复洗涤，对洗涤过后的水取样，将水蒸发后对水中的杂质进行扫描电镜观察，未发现石墨烯材料，说明石墨烯材料与棉纤维的结合紧密，不宜分离。
显然，上述实施例仅仅是为清楚地说明本发明所作的举例，而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说，在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。而这些属于本发明的精神所引伸出的显而易见的变化或变动仍处于本发明的保护范围之中。
Claims (10)
1.一种抗菌织物的制造方法，其特征在于，包括以下具体步骤：
步骤一、将1重量份的抗菌纳米溶液分散在150～250重量份的水中，得到处理液；
步骤二、将15～25重量份的棉质织物浸泡在所述处理液中30～40分钟，所述处理液的温度控制在40～60℃；
步骤三、取出棉质织物脱水后温度控制在120～140℃定型1～2小时。
2.根据权利要求1所述的抗菌织物的制造方法，其特征在于：所述抗菌纳米溶液是在抗菌防臭整理剂ATB9800中加入胺类催化剂进行活化后，再加入氧化石墨烯，然后水浴加热搅拌而得。
3.根据权利要求2所述的抗菌织物的制造方法，其特征在于：所述氧化石墨烯与抗菌防臭整理剂ATB9800的重量比为1︰5～1︰1，所述胺类催化剂与所述氧化石墨烯的重量比为1︰500～1︰100。
4.根据权利要求2所述的抗菌织物的制造方法，其特征在于：所述胺类催化剂是二环己基碳二亚胺、二甲基环己胺、三乙胺或双二甲氨基乙基醚。
5.根据权利要求2所述的抗菌织物的制造方法，其特征在于：所述氧化石墨烯的层数小于等于八层。
6.根据权利要求1所述的抗菌织物的制造方法，其特征在于：所述处理液中还包括渗透剂，所述渗透剂是十二烷基硫酸钠或十二烷基苯磺酸钠，所述渗透剂在处理液中的浓度为0.1～0.5g/L的。
7.根据权利要求1至6中任一项所述的抗菌织物的制造方法，其特征在于：所述织物是毛巾。
8.根据权利要求7所述的抗菌织物的制造方法，其特征在于：所述毛巾的地经纱、纬纱、毛经纱均由40S的精梳彩棉纱三股并纱而成。
9.一种如权利要求1所述的抗菌织物的制造方法所制得的棉质织物。
10.一种如权利要求1所述的抗菌织物的制造方法所制得的毛巾。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111705502A (zh) * | 2020-06-13 | 2020-09-25 | 佛山市南庄恒安织造厂有限公司 | 一种石墨烯抗菌织物的制造方法 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102168370A (zh) * | 2011-01-11 | 2011-08-31 | 中国科学院上海应用物理研究所 | 一种抗菌织物及其制备方法 |
| CN102431997A (zh) * | 2011-09-07 | 2012-05-02 | 南京师范大学 | 具有抗菌、抗凝血功能的氧化石墨烯及其制备方法 |
| CN102995394A (zh) * | 2012-12-17 | 2013-03-27 | 常州大学 | 一种基于氧化石墨烯的染色、抗菌整理剂及其制备方法和应用 |
| CN104945636A (zh) * | 2015-05-13 | 2015-09-30 | 华南师范大学 | 一种复合材料、其制备方法及其用途 |
| CN105040405A (zh) * | 2015-08-22 | 2015-11-11 | 苏州正业昌智能科技有限公司 | 一种抗菌棉织物的制备方法 |
| CN105239380A (zh) * | 2015-10-30 | 2016-01-13 | 无锡市长安曙光手套厂 | 一种抗菌防霉纺织品及其制备方法 |
| CN105918319A (zh) * | 2016-05-03 | 2016-09-07 | 天津工业大学 | 功能化氧化石墨烯抑菌材料及其制备方法 |
| CN106637924A (zh) * | 2016-11-28 | 2017-05-10 | 苏州大学 | 一种抗菌纺织品及其制备方法 |
| CN106811967A (zh) * | 2016-04-01 | 2017-06-09 | 青岛大学 | 一种氧化石墨烯抗菌涂层织物的制备方法 |
-
2017
- 2017-06-20 CN CN201710467263.7A patent/CN109097988A/zh active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102168370A (zh) * | 2011-01-11 | 2011-08-31 | 中国科学院上海应用物理研究所 | 一种抗菌织物及其制备方法 |
| CN102431997A (zh) * | 2011-09-07 | 2012-05-02 | 南京师范大学 | 具有抗菌、抗凝血功能的氧化石墨烯及其制备方法 |
| CN102995394A (zh) * | 2012-12-17 | 2013-03-27 | 常州大学 | 一种基于氧化石墨烯的染色、抗菌整理剂及其制备方法和应用 |
| CN104945636A (zh) * | 2015-05-13 | 2015-09-30 | 华南师范大学 | 一种复合材料、其制备方法及其用途 |
| CN105040405A (zh) * | 2015-08-22 | 2015-11-11 | 苏州正业昌智能科技有限公司 | 一种抗菌棉织物的制备方法 |
| CN105239380A (zh) * | 2015-10-30 | 2016-01-13 | 无锡市长安曙光手套厂 | 一种抗菌防霉纺织品及其制备方法 |
| CN106811967A (zh) * | 2016-04-01 | 2017-06-09 | 青岛大学 | 一种氧化石墨烯抗菌涂层织物的制备方法 |
| CN105918319A (zh) * | 2016-05-03 | 2016-09-07 | 天津工业大学 | 功能化氧化石墨烯抑菌材料及其制备方法 |
| CN106637924A (zh) * | 2016-11-28 | 2017-05-10 | 苏州大学 | 一种抗菌纺织品及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111705502A (zh) * | 2020-06-13 | 2020-09-25 | 佛山市南庄恒安织造厂有限公司 | 一种石墨烯抗菌织物的制造方法 |
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