CN109082936B - 一种纸张表面施胶剂及其制备方法 - Google Patents
一种纸张表面施胶剂及其制备方法 Download PDFInfo
- Publication number
- CN109082936B CN109082936B CN201810933960.1A CN201810933960A CN109082936B CN 109082936 B CN109082936 B CN 109082936B CN 201810933960 A CN201810933960 A CN 201810933960A CN 109082936 B CN109082936 B CN 109082936B
- Authority
- CN
- China
- Prior art keywords
- asa
- spi
- sizing agent
- solution
- paper surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims description 38
- BGXNGARHYXNGPK-UHFFFAOYSA-N 2-[1-[(4-methoxyphenyl)methylsulfanyl]cyclohexyl]acetic acid Chemical compound C1=CC(OC)=CC=C1CSC1(CC(O)=O)CCCCC1 BGXNGARHYXNGPK-UHFFFAOYSA-N 0.000 claims description 31
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 24
- 239000012153 distilled water Substances 0.000 claims description 23
- 229920000877 Melamine resin Polymers 0.000 claims description 21
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 21
- 238000004321 preservation Methods 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000008098 formaldehyde solution Substances 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 238000001694 spray drying Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 4
- 230000010933 acylation Effects 0.000 abstract description 8
- 238000005917 acylation reaction Methods 0.000 abstract description 8
- 230000004048 modification Effects 0.000 abstract description 8
- 238000012986 modification Methods 0.000 abstract description 8
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 abstract description 4
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000012467 final product Substances 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 108010073771 Soybean Proteins Proteins 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019710 soybean protein Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 3
- 239000011087 paperboard Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- -1 Alkenyl Succinic Anhydride Chemical compound 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 108010064851 Plant Proteins Proteins 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 235000021118 plant-derived protein Nutrition 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940071440 soy protein isolate Drugs 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H1/00—Macromolecular products derived from proteins
- C08H1/02—Protein-aldehyde condensates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/26—Aminoplasts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810933960.1A CN109082936B (zh) | 2018-08-16 | 2018-08-16 | 一种纸张表面施胶剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810933960.1A CN109082936B (zh) | 2018-08-16 | 2018-08-16 | 一种纸张表面施胶剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109082936A CN109082936A (zh) | 2018-12-25 |
CN109082936B true CN109082936B (zh) | 2020-11-24 |
Family
ID=64793473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810933960.1A Active CN109082936B (zh) | 2018-08-16 | 2018-08-16 | 一种纸张表面施胶剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109082936B (zh) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997007282A1 (en) * | 1995-08-16 | 1997-02-27 | Hercules Incorporated | Methods and compositions for sizing paper |
CN103201428A (zh) * | 2010-11-17 | 2013-07-10 | 惠普发展公司,有限责任合伙企业 | 数字打印中的打印介质用的表面施胶组合物 |
CN103437244A (zh) * | 2013-09-02 | 2013-12-11 | 齐鲁工业大学 | 一种三聚氰胺改性锂皂石稳定的asa施胶乳液及其制备方法 |
CN105358765A (zh) * | 2013-07-10 | 2016-02-24 | 艺康美国股份有限公司 | 使用大豆粉或大豆蛋白增强纸张脱水 |
CN106758542A (zh) * | 2016-12-30 | 2017-05-31 | 李宗飞 | 一种改性大豆蛋白增强纸张强度的可降解薄膜防水纸 |
CN107674170A (zh) * | 2017-10-27 | 2018-02-09 | 张园 | 水解大豆分离蛋白改性尿醛树脂及其制备方法和胶合板 |
-
2018
- 2018-08-16 CN CN201810933960.1A patent/CN109082936B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997007282A1 (en) * | 1995-08-16 | 1997-02-27 | Hercules Incorporated | Methods and compositions for sizing paper |
CN103201428A (zh) * | 2010-11-17 | 2013-07-10 | 惠普发展公司,有限责任合伙企业 | 数字打印中的打印介质用的表面施胶组合物 |
CN105358765A (zh) * | 2013-07-10 | 2016-02-24 | 艺康美国股份有限公司 | 使用大豆粉或大豆蛋白增强纸张脱水 |
CN103437244A (zh) * | 2013-09-02 | 2013-12-11 | 齐鲁工业大学 | 一种三聚氰胺改性锂皂石稳定的asa施胶乳液及其制备方法 |
CN106758542A (zh) * | 2016-12-30 | 2017-05-31 | 李宗飞 | 一种改性大豆蛋白增强纸张强度的可降解薄膜防水纸 |
CN107674170A (zh) * | 2017-10-27 | 2018-02-09 | 张园 | 水解大豆分离蛋白改性尿醛树脂及其制备方法和胶合板 |
Also Published As
Publication number | Publication date |
---|---|
CN109082936A (zh) | 2018-12-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109811587B (zh) | 一种瓦楞原纸表面施胶液及其制备方法和应用 | |
CN105599085A (zh) | 木材及棉纤维处理剂、其制备方法及应用 | |
CN110982487B (zh) | 一种多重网络结构的无醛大豆蛋白胶黏剂及其制备方法 | |
Yang et al. | Development of biomass adhesives based on aminated cellulose and oxidized sucrose reinforced with epoxy functionalized wood interface | |
Bismark et al. | Phosphorylation and Octenylsuccinylation of Acid‐Thinned Starch for Enhancing Adhesion on Cotton/Polyester Blend Fibers at Varied Temperature Sizing | |
CN109082936B (zh) | 一种纸张表面施胶剂及其制备方法 | |
CN110964478B (zh) | 一种超支化聚酯和硼酸盐改性的高强度防腐大豆蛋白胶黏剂及其制备方法 | |
CN109294516B (zh) | 贻贝仿生高分子粘附材料及其制备方法 | |
JP3924612B2 (ja) | 絹タンパク質とキトサンとの複合体およびその製造方法 | |
CN102719208A (zh) | 高分子粘结剂及其制备方法 | |
CN110437397A (zh) | 一种高分子竹纤维、制备方法及其应用 | |
CN114163762A (zh) | 一种疏水改性的聚乙烯醇薄膜及其制备方法与应用 | |
CN112779815A (zh) | 一种多功能造纸用复合增强剂及其制备方法 | |
JP6093947B2 (ja) | β−1,3−グルカンナノファイバー及びその製造方法 | |
CN112225829A (zh) | 一种末端带电荷多糖及其制备方法 | |
CN110483810A (zh) | 一种纳米纤维素抗菌水凝胶的制备方法 | |
CN110330900A (zh) | 一种低成本共混改性水玻璃木材胶粘剂及其制备方法 | |
CN111925453B (zh) | 一种造纸用生态型阳离子表面施胶增强剂及制备方法 | |
CN108395869A (zh) | 一种淀粉与大豆蛋白共混胶粘剂的制备方法 | |
CN104877610B (zh) | 一种间苯二酚‑双醛淀粉‑甲醛共缩聚树脂胶黏剂及其制备方法 | |
CN110437766B (zh) | 一种无醛低成本多糖胶黏剂及其制备方法 | |
CN112538185A (zh) | 一种聚乳酸气体阻隔复合膜的制备方法 | |
CN106833455A (zh) | 一种改性明胶‑丙烯酸树脂粘合剂制备方法 | |
CN114672055B (zh) | 一种以末端阳离子淀粉为基料的可降解疏水薄膜的制备 | |
Sadanandan | An eco‐friendly molecular imprinting technique for the selective recognition and controlled release of bovine serum albumin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231123 Address after: 310000, Room 302, Building 17, Nanyue Mansion, Jinnan Street, Lin'an District, Hangzhou City, Zhejiang Province Patentee after: Hangzhou Jinyuan Decoration Material Co.,Ltd. Address before: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee before: Dragon totem Technology (Hefei) Co.,Ltd. Effective date of registration: 20231123 Address after: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Dragon totem Technology (Hefei) Co.,Ltd. Address before: 641112 No. 705, Dongtong Road, Neijiang City, Sichuan Province Patentee before: NEIJIANG NORMAL University |