CN109082894B - 一种功能性塑料层合织物的制备方法 - Google Patents
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Abstract
本发明公开了一种功能性塑料层合织物的制备方法,包括以下步骤:首先制备含有纳米蒙脱土、鱼腥草提取物浓缩液的复合浆料,然后制得海藻酸钠溶液,加入聚丙烯酸、复合浆料,搅拌制得粘合剂组合物;将纳米氧化钛、粘合剂组合物、聚丙烯酸酯树脂混合制得母粒,并加入聚丙烯酸酯树脂、分散剂、炭黑、增稠剂、消泡剂、水、母粒混合制得改性组合物;将其对涤纶织物进行改性,最后将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用粘合剂组合物,进行轧制处理,制得层合织物。该层合织物性能优异,抗菌阻燃性能好,制备简单。
Description
技术领域:
本发明涉及织物制备领域,具体的涉及一种功能性塑料层合织物的制备方法。
背景技术:
层合织物即层压复合织物,就是使高聚物薄膜与单、多层织物粘结,形成一个织物复合体,从而表现出功能叠加性。与一般纺织品整理不同,层合后的复合物,不但具有织物的原有功能,而且增加了其他层合面料的功能。
层合织物多用于服装面料和装饰织物方面,如用于制作女士外衣、童装等。然而,随着层合织物的多样化发展,层合织物更多的是功能服装,通过微孔薄膜和织物层合得到具有防水透湿功能的织物,如户外运动所需要的登山、滑雪服等,也逐步开始涉及舒适性服装的领域,防护服装等,以及通过不同功能的面料层合而具有特定作用的防弹服、抗静电服、救生服等。装饰织物应用主要要贴墙布、层压地毯、层压窗帘、沙发布、车船内饰等。
中国专利(201410856463.8)公开了一种微孔树脂薄膜层合物及其制备方法,其包括:至少一层带有凸起形状的直通孔,孔径为10μm-1000μm,1-500μm厚的微孔树脂面膜;至少一层织物;以及位于所述微孔树脂薄膜和所述织物之间的、由胶水形成的粘合层。本发明的层合物具有优良的防风、透气、透湿差异化性能,外观平整无褶皱,手感柔软。但是其阻燃性能和抗菌性能不佳,耐久性还需进一步改善。
发明内容:
本发明的目的是针对现有技术的不足,提供一种功能性塑料层合织物的制备方法,该方法制得的层合织物耐高温性能好,阻燃性能优异,且具有一定的抗菌性能。
为实现上述目的,本发明采用以下技术方案:
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨20-40min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取1-3h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理50-160min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物。
作为上述技术方案的优选,步骤(1)中,纳米蒙脱土和无水乙醇的质量比为(1-3):1。
作为上述技术方案的优选,步骤(1)中,纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:(1-1.5)。
作为上述技术方案的优选,步骤(2)中,海藻酸钠溶液的质量浓度为10-20%。
作为上述技术方案的优选,步骤(2)中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为(0.1-0.5):1:(3-5)。
作为上述技术方案的优选,步骤(3)中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛1-2.5份,粘合剂0.5-1.5份,聚丙烯酸酯树脂4-8份。
作为上述技术方案的优选,步骤(3)中,所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂25-40份、分散剂1-3份、水30-60份、母粒3-7份、炭黑1-2份、增稠剂1-2份、消泡剂1-2份。
作为上述技术方案的优选,步骤(3)中,所述分散剂为N-羟甲基丙烯酰胺。
作为上述技术方案的优选,步骤(5)中,所述轧制时的压力为0.4-0.6MPa。
本发明具有以下有益效果:
纳米蒙脱土和乙醇混合研磨,进一步细化颗粒,制得的纳米蒙脱土浆料稳定性好;鱼腥草提取物浓缩液中含有较多的甲基壬基酮月桂酸等抗菌活性成分,其和纳米蒙脱土浆料复合研磨,有效改善了纳米蒙脱土的分散性;制得的复合浆料均一性好,与聚合物基体具有很好的相容性;
本发明制得的粘合剂组合物稳定性好,耐候性能优异,通过合理调节各组分的用量,制得了性能优异的粘合剂组合物;
本发明首先采用纳米氧化钛和粘合剂组合物混合,纳米氧化钛表面包覆一层粘合剂,加入聚丙烯酸酯树脂混合在纳米氧化钛表面包覆一层树脂材料,制得的母粒与聚合物基体具有良好的相容性,本发明制得的改性组合物与织物润湿性能佳,改性后的织物具有一定的抗菌阻燃性能。
具体实施方式:
为了更好的理解本发明,下面通过实施例对本发明进一步说明,实施例只用于解释本发明,不会对本发明构成任何的限定。
实施例1
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨20min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取1h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;其中,纳米蒙脱土和无水乙醇的质量比为1:1;纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:1;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;其中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为0.1:1:3;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;其中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛1份,粘合剂0.5份,聚丙烯酸酯树脂4份;所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂25份、分散剂1份、水30份、母粒3份、炭黑1份、增稠剂1份、消泡剂1份;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理50min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物,其中,轧制时的压力为0.4MPa。
实施例2
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨40min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取3h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;其中,纳米蒙脱土和无水乙醇的质量比为3:1;纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:1.5;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;其中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为0.5:1:5;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;其中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛2.5份,粘合剂1.5份,聚丙烯酸酯树脂8份;所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂40份、分散剂3份、水60份、母粒7份、炭黑2份、增稠剂2份、消泡剂2份;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理160min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物,其中,轧制时的压力为0.6MPa。
实施例3
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨25min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取1h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;其中,纳米蒙脱土和无水乙醇的质量比为1.5:1;纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:1.1;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;其中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为0.2:1:3;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;其中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛1.4份,粘合剂0.7份,聚丙烯酸酯树脂5份;所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂28份、分散剂1.5份、水35份、母粒4份、炭黑1.5份、增稠剂1.2份、消泡剂1.2份;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理70min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物,其中,轧制时的压力为0.45MPa。
实施例4
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨25min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取2h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;其中,纳米蒙脱土和无水乙醇的质量比为0:1;纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:1.2;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;其中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为0.3:1:3.5;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;其中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛1.8份,粘合剂0.9份,聚丙烯酸酯树脂6份;所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂33份、分散剂2份、水40份、母粒5份、炭黑1.7份、增稠剂1.6份、消泡剂1.5份;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理90min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物,其中,轧制时的压力为0.5MPa。
实施例5
一种功能性塑料层合织物的制备方法,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨35min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取2h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;其中,纳米蒙脱土和无水乙醇的质量比为2.5:1;纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:1.4;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;其中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为0.4:1:4.5;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;将聚丙烯酸酯树脂、分散剂和水混合搅拌,然后加入制得的母粒,搅拌,加入炭黑、增稠剂、消泡剂,搅拌混合制得改性组合物;其中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛2.2份,粘合剂1.3份,聚丙烯酸酯树脂7份;所述改性组合物各组分用量以重量份计,分别为:聚丙烯酸酯树脂37份、分散剂2.5份、水55份、母粒6份、炭黑1.8份、增稠剂1.7份、消泡剂1.5份;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理120min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物,其中,轧制时的压力为0.55MPa。
上述制得的层合织物柔软舒适,对大肠杆菌、金黄色葡萄球菌的抑菌率高达97.5%以上,极限氧指数为39%以上。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (8)
1.一种功能性塑料层合织物的制备方法,其特征在于,包括以下步骤:
(1)将纳米蒙脱土和无水乙醇混合,研磨20-40min,制得纳米蒙脱土浆料;将鱼腥草粉碎,研磨加入到无水乙醇中进行提取1-3h,过滤,收集滤液,进行减压浓缩,制得鱼腥草提取物浓缩液,并将其加入到纳米蒙脱土浆料中,继续搅拌30min,制得复合浆料;
(2)将海藻酸钠和水混合在50-60℃下搅拌制得海藻酸钠溶液,加入聚丙烯酸继续搅拌混合,最后加入上述制得的复合浆料,搅拌制得粘合剂组合物;
(3)将纳米氧化钛和上述制得的粘合剂组合物混合搅拌,然后加入聚丙烯酸酯树脂,制得母粒;以重量份计,将25-40份聚丙烯酸酯树脂、1-3份分散剂和30-60份水混合搅拌,然后加入3-7份制得的母粒,搅拌,加入1-2份炭黑、1-2份增稠剂、1-2份消泡剂,搅拌混合制得改性组合物;
(4)将涤纶织物加入到上述制得的改性组合物中,静置处理50-160min,取出,烘干、焙烘,制得改性涤纶织物;
(5)将涤纶织物、改性涤纶织物、涤纶织物进行层合,涤纶织物和改性涤纶织物之间采用步骤(2)制得的粘合剂组合物,进行轧制处理,制得层合织物。
2.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(1)中,纳米蒙脱土和无水乙醇的质量比为(1-3):1。
3.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(1)中,纳米蒙脱土浆料、鱼腥草提取物浓缩液的质量比为1:(1-1.5)。
4.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(2)中,海藻酸钠溶液的质量浓度为10-20%。
5.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(2)中,所述海藻酸钠、聚丙烯酸、复合浆料的质量比为(0.1-0.5):1:(3-5)。
6.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(3)中,所述母粒为纳米氧化钛-粘合剂-聚丙烯酸酯树脂三层结构,三者用量以重量份计分别为:纳米氧化钛1-2.5份,粘合剂0.5-1.5份,聚丙烯酸酯树脂4-8份。
7.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(3)中,所述分散剂为N-羟甲基丙烯酰胺。
8.如权利要求1所述的一种功能性塑料层合织物的制备方法,其特征在于:步骤(5)中,所述轧制时的压力为0.4-0.6MPa。
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CN201345911Y (zh) * | 2008-11-25 | 2009-11-18 | 中国纺织科学研究院 | 一种化学品防护面料 |
CN101429727A (zh) * | 2008-12-22 | 2009-05-13 | 四川大学 | 二组分丙烯酸系聚合物/蒙脱土纳米复合纺织浆料及其制备方法 |
CN102392356A (zh) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | 耐洗涤阻燃混纺织物的生产工艺 |
JP2014029036A (ja) * | 2012-07-31 | 2014-02-13 | Teijin Ltd | 多層織編物および繊維製品 |
CN107237122A (zh) * | 2017-06-28 | 2017-10-10 | 太仓红桥服饰有限公司 | 一种棉质面料的持久抗菌免烫整理液及整理工艺 |
CN107286821A (zh) * | 2017-07-12 | 2017-10-24 | 东莞市联洲知识产权运营管理有限公司 | 一种持久高效的抗菌导热涂料的制备方法 |
CN107675481A (zh) * | 2017-09-29 | 2018-02-09 | 安徽东锦服饰有限公司 | 一种面料抗菌整理液的制备方法 |
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