CN109080372A - A kind of preparation method of antique copper aluminum alloy decoration plate - Google Patents

A kind of preparation method of antique copper aluminum alloy decoration plate Download PDF

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Publication number
CN109080372A
CN109080372A CN201810991524.XA CN201810991524A CN109080372A CN 109080372 A CN109080372 A CN 109080372A CN 201810991524 A CN201810991524 A CN 201810991524A CN 109080372 A CN109080372 A CN 109080372A
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Prior art keywords
aluminum alloy
decoration plate
preparation
copper aluminum
alloy decoration
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CN201810991524.XA
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CN109080372B (en
Inventor
张翔
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Sihui City Billion And Aluminum Co Ltd
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Sihui City Billion And Aluminum Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/10Designs imitating natural patterns of metallic or oxidised metallic surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention relates to aluminium product technical field, especially a kind of preparation method of antique copper aluminum alloy decoration plate;It the following steps are included: cut out, polish, washing, the washing of high temperature drying, solvent, vacuum drying, tin plating, hot stamping, cooling and solidifying, priming, upper finishing coat, dry solidification, semi-finished product and puerh tea leaves are put into jointly in boiling water heat 2 hours, semi-finished product taking-up is put in outdoor exposure 6 hours or be put in UV curing UV irradiate 30 minutes, repeat step 13) and 14) 20 times, white splendid achnatherum water, vacuum drying, coating UV solidified paint, be put in the solidification of UV curing, acquisition antique copper aluminum alloy decoration plate;Obtained antique copper aluminum alloy decoration plate visually with to do old brass sheet almost consistent, since crackle is formed for solarization, surface pattern on each block of plate is all unique, in addition the tea polyphenols gathered constitute the effect similar to patina, under paint, when use, will not cause to corrode its real pattern because of acid rain etc..

Description

A kind of preparation method of antique copper aluminum alloy decoration plate
Technical field
The present invention relates to aluminium product technical field, especially a kind of preparation method of antique copper aluminum alloy decoration plate.
Background technique
Aluminum alloy decoration plate be at present it is most popular, with widest ornament materials.Can by surface passivation, thermal transfer, The kinds of processes such as cold extrusion, spraying achieve the effect that client's needs.But there has been no do old to reach copper modelled after an antique by aluminium alloy plate The report of product.
It has been all made of a large amount of modelled after an antique in the creative park of many simple and unsophisticated/modelled after an antique styles or has done old copper product for filling Decorations.Such as China Guangzhou common brick factory creative park, it uses a large amount of copper carving and copper sheet modelled after an antique is (copper) as decoration.However due to Pearl River Delta regional industry is flourishing, generates acid rain, causes copper sheet modelled after an antique to generate a large amount of copper greens (basic copper carbonate), is especially carved with It since copper green is emerged at its engraving on the copper sheet modelled after an antique of pattern, or even falls off, leading to pattern becomes very fuzzy.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of make and has bronze color but not the aluminium conjunction of copper green occur The method of gold jewellery plate.
The technical solution of the present invention is as follows:
A kind of preparation method of antique copper aluminum alloy decoration plate, which is characterized in that it the following steps are included:
1) it cuts out, aluminum alloy plate materials is cut out to the shape of client's needs by cutting implement or stamping equipment, obtain Substrate;
2) it polishes, removes flash removed, surface impurity;
3) it washes;
4) high temperature drying;
5) solvent washs, and removes grease, organic matter etc. by solvent;
6) it is dried in vacuo;Dehumidifying is vacuumized, prevents high temperature from solvent being caused to explode;
7) tin plating, in substrate surface, one layer of metallic tin is set;
8) hot stamping;When metallic tin is not fully cured, passes through die marks on metallic tin or manually carve various patterns Decorative pattern;
9) it cools and solidifies;
10) priming coats imitative copper paint using brush;
11) finishing coat on coats emulation copper paint using brush;
12) dry solidification obtains semi-finished product;
13) semi-finished product and puerh tea leaves are put into jointly in boiling water and are heated 2 hours, so that paint Adsorption of Tea Polyphenols, and it is logical The high temperature crossed close to 100 degrees Celsius to paint by rough degree amplification originally under the front never degenerated, so that table Face has concave-convex texture, in addition also has the function of taking out paint-like flavour;
14) semi-finished product taking-up is put in outdoor exposure 6 hours or is put in UV curing UV and irradiated 30 minutes, pass through the sun Exposure makes painted surface generate a large amount of irregular fine cracks, and tea polyphenols can constantly be accumulated in cracks, visually be formed In addition bronze texture true to nature also has the function of removing paint-like flavour;
15) step 13) and 14) 20 times are repeated, by repeating so that bronze texture is deepened;
16) white splendid achnatherum water so that accumulation tea stain (tea polyphenols) from it is greyish black deepen it is black, in addition can be by the tea of not cracks Stain washes away;
17) it is dried in vacuo;
18) UV solidified paint is coated;
19) it is put in the solidification of UV curing, obtains antique copper aluminum alloy decoration plate.
Specifically, melting metallic tin using small intermediate frequency induction melting furnace in the step 7), substrate monolith is inserted into tin It then takes out, solidifies, it is tin plating for being in water.
Specifically, carrying out deburring to substrate after the completion of tin plating in the step 7).To meet the size requirements, certainly, if Product itself does not have size to require then without deburring.
Specifically, the step 10) -12) completed in superclean bench, since priming paint and finishing coat need to bear time-out Between exposure and boiling, therefore need to guarantee that paint and the junction of substrate will not be mixed into a large amount of dust impurity.
Specifically, imitating copper paint in the step 10) with a thickness of 0.5 millimeter.
Specifically, emulation copper paint is in the step 11) with a thickness of 0.1 millimeter.
Specifically, the weight ratio of semi-finished product and puerh tea leaves is 17: 1 in the step 13), since Pu'er tea price is high Expensive, millet paste is not allowed perishable again, therefore tealeaves, millet paste do not have to generally replace, until completing this batch of preparation.
Specifically, puerh tea leaves mixing dried orange peel, Chinese prickly ash and corter pseudolaricis boil jointly in the step 13), weight ratio is 50:7:6:7.It since millet paste needs Reusability, can seriously affect dark brown, therefore use a variety of anti-if growing fungi in millet paste Fungi medicinal material, further promote millet paste uses the time, in addition, being found surprisingly that: can have after dried orange peel, Chinese prickly ash and corter pseudolaricis mixing Effect inhibits the fragrance in Pu'er, and the smell of millet paste is similar to iron rust taste.
Specifically, bletilla striata water brush surface of semi-finished is stained with using writing brush in the step 16), since writing brush does not have brush rule Then, thus the less trace for leaving manual manufacture.
Specifically, the writing brush uses block letters and milli round end centre forward's wolf writing brush.Namely having a size of block letters, hardness is nib And milli, written shape are round end, vigour of style in writing length is centre forward, and material is the writing brush of wolf hair.
Specifically, boiling 1 hour the preparation method comprises the following steps: 0.5 kilogram of the bletilla striata is put into 30 liters of water for the bletilla striata water, is then filtered It is kept the temperature after slag spare.Because the bletilla striata water of heat is easier to remove the tea stain of painted surface.
Specifically, the UV solidified paint is with a thickness of 80 microns.
The invention has the benefit that obtained antique copper aluminum alloy decoration plate visually with do old brass sheet almost one It causes, since crackle is formed for solarization, the surface pattern on each block of plate is all unique, in addition the tea polyphenols gathered are constituted Similar to the effect of patina, under paint, when use, will not cause real pattern because of acid rain etc. Corrosion.
Detailed description of the invention
Fig. 1 is the scanning figure of substrate of the invention;
Fig. 2 is the scanning figure of semi-finished product of the invention;
Fig. 3 is the scanning figure of finished product of the invention.
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing:
Embodiment 1
As shown in Figure 1-3, a kind of preparation method of antique copper aluminum alloy decoration plate, it the following steps are included:
1) it cuts out, aluminum alloy plate materials is cut out to the shape of client's needs by stamping equipment, obtain substrate;
2) it polishes, removes flash removed, surface impurity;
3) it washes;
4) high temperature drying;
5) solvent washs, and removes grease, organic matter etc. by solvent;
6) it is dried in vacuo;Dehumidifying is vacuumized, prevents high temperature from solvent being caused to explode;
7) tin plating, in substrate surface, one layer of metallic tin is set;
8) hot stamping;When metallic tin is not fully cured, by manually carving various patterns decorative pattern on metallic tin;
9) it cools and solidifies;
10) priming coats imitative copper paint using brush;
11) finishing coat on coats emulation copper paint using brush;
12) dry solidification obtains semi-finished product;
13) semi-finished product and puerh tea leaves are put into jointly in boiling water and are heated 2 hours, so that paint Adsorption of Tea Polyphenols, and it is logical The high temperature crossed close to 100 degrees Celsius to paint by rough degree amplification originally under the front never degenerated, so that table Face has concave-convex texture, in addition also has the function of taking out paint-like flavour;
14) semi-finished product are taken out and is put in outdoor exposure 6 hours (fine day progress of the selection in November in May-as far as possible, guarantee temperature Degree and intensity of illumination), make painted surface generate a large amount of irregular fine cracks by sun exposure, tea polyphenols can be accumulated constantly In cracks, bronze texture true to nature is visually formed, in addition also has the function of removing paint-like flavour;
15) step 13) and 14) 20 times are repeated, by repeating so that bronze texture is deepened;
16) white splendid achnatherum water so that accumulation tea stain (tea polyphenols) from it is greyish black deepen it is black, in addition can be by the tea of not cracks Stain washes away;
17) it is dried in vacuo;Use vacuum oven;
18) UV solidified paint is coated;
19) it is put in the solidification of UV curing, obtains antique copper aluminum alloy decoration plate.
In the step 7), using small intermediate frequency induction melting furnace melt metallic tin, by substrate monolith be inserted into tin water in and After take out, solidify, it is tin plating for being.
In the step 7), deburring is carried out to substrate after the completion of tin plating.To meet the size requirements, certainly, such as fruit product sheet Body does not have size to require then without deburring.
The step 10) -12) completed in superclean bench, due to exposure between priming paint and finishing coat needs receiving time-out And boiling, therefore need to guarantee that paint and the junction of substrate will not be mixed into a large amount of dust impurity.
Copper paint is imitated in the step 10) with a thickness of 0.5 millimeter.
Emulation copper paint is in the step 11) with a thickness of 0.1 millimeter.
The weight ratio of semi-finished product and puerh tea leaves is 17: 1 in the step 13).
Puerh tea leaves mixing dried orange peel, Chinese prickly ash and corter pseudolaricis boil jointly in the step 13), weight ratio 50: 7: 6: 7。
Bletilla striata water brush surface of semi-finished is stained with using writing brush in the step 16).
The writing brush uses block letters and milli round end centre forward's wolf writing brush.
Boiling 1 hour the preparation method comprises the following steps: 0.5 kilogram of the bletilla striata is put into 30 liters of water for the bletilla striata water, is then protected after filter residue Warm standby is used.
The UV solidified paint is with a thickness of 80 microns.
Embodiment 2
A kind of preparation method of antique copper aluminum alloy decoration plate, it the following steps are included:
1) it cuts out, aluminum alloy plate materials is cut out to the shape of client's needs by cutting implement, obtain substrate;
2) it polishes, removes flash removed, surface impurity;
3) it washes;
4) high temperature drying;
5) solvent washs, and removes grease, organic matter etc. by solvent;
6) it is dried in vacuo;
7) tin plating, in substrate surface, one layer of metallic tin is set;
8) hot stamping;When metallic tin is not fully cured, pass through die marks various patterns decorative pattern on metallic tin;
9) it cools and solidifies;
10) priming coats imitative copper paint using brush;
11) finishing coat on coats emulation copper paint using brush;
12) dry solidification obtains semi-finished product;
13) semi-finished product and puerh tea leaves are put into jointly in boiling water and are heated 2 hours, so that paint Adsorption of Tea Polyphenols, and it is logical The high temperature crossed close to 100 degrees Celsius to paint by rough degree amplification originally under the front never degenerated, so that table Face has concave-convex texture, in addition also has the function of taking out paint-like flavour;
14) semi-finished product taking-up is put in UV curing UV to irradiate 30 minutes, intensity of illumination is arranged in 20mw/cm2, illumination wave A length of 365nm, so that painted surface generates a large amount of irregular fine cracks, tea polyphenols can constantly be accumulated in cracks, in vision It is upper to form bronze texture true to nature, in addition also have the function of removing paint-like flavour;
15) step 13) and 14) 20 times are repeated, by repeating so that bronze texture is deepened;
16) white splendid achnatherum water so that accumulation tea stain (tea polyphenols) from it is greyish black deepen it is black, in addition can be by the tea of not cracks Stain washes away;
17) it is dried in vacuo;
18) UV solidified paint is coated;
19) it is put in the solidification of UV curing, intensity of illumination setting obtains antique copper in 20mw/cm2, illumination wavelength 365nm Aluminum alloy decoration plate.
In the step 7), using small intermediate frequency induction melting furnace melt metallic tin, by substrate monolith be inserted into tin water in and After take out, solidify, it is tin plating for being.
In the step 7), deburring is carried out to substrate after the completion of tin plating.To meet the size requirements, certainly, such as fruit product sheet Body does not have size to require then without deburring.
The step 10) -12) completed in superclean bench, due to exposure between priming paint and finishing coat needs receiving time-out And boiling, therefore need to guarantee that paint and the junction of substrate will not be mixed into a large amount of dust impurity.
Copper paint is imitated in the step 10) with a thickness of 0.5 millimeter.
Emulation copper paint is in the step 11) with a thickness of 0.1 millimeter.
The weight ratio of semi-finished product and puerh tea leaves is 17: 1, since Pu'er tea is expensive, millet paste in the step 13) Do not allow again perishable, therefore tealeaves, millet paste do not have to generally replace, until completing this batch of preparation.
Puerh tea leaves mixing dried orange peel, Chinese prickly ash and corter pseudolaricis boil jointly in the step 13), weight ratio 50: 7: 6: 7.Since millet paste needs Reusability, can be seriously affected if growing fungi in millet paste it is dark brown, therefore use a variety of antifungals Material, further promote millet paste uses the time, in addition, being found surprisingly that: can effectively inhibit after dried orange peel, Chinese prickly ash and corter pseudolaricis mixing The fragrance in Pu'er, the smell of millet paste are similar to iron rust taste.
Bletilla striata water brush surface of semi-finished is stained with using writing brush in the step 16), since writing brush does not have brush rule, thus it is less Leave the trace of manual manufacture.
The writing brush uses block letters and milli round end centre forward's wolf writing brush.For namely nib having a size of block letters, hardness is simultaneous milli, pen Head shapes are round end, and vigour of style in writing length is centre forward, and material is the writing brush of wolf hair.
Boiling 1 hour the preparation method comprises the following steps: 0.5 kilogram of the bletilla striata is put into 30 liters of water for the bletilla striata water, is then protected after filter residue Warm standby is used.Because the bletilla striata water of heat is easier to remove the tea stain of painted surface.
The UV solidified paint is with a thickness of 80 microns.
For visual effect, the more aobvious nature of embodiment 1.But from quality, it has been found that the plate that embodiment 2 produces Sub- qualification rate is higher.
The above embodiments and description only illustrate the principle of the present invention and most preferred embodiment, is not departing from this Under the premise of spirit and range, various changes and improvements may be made to the invention, these changes and improvements both fall within requirement and protect In the scope of the invention of shield.

Claims (10)

1. a kind of preparation method of antique copper aluminum alloy decoration plate, which is characterized in that it the following steps are included:
1) it cuts out, aluminum alloy plate materials is cut out to the shape of client's needs by cutting implement or stamping equipment, obtain substrate;
2) it polishes, removes flash removed, surface impurity;
3) it washes;
4) high temperature drying;
5) solvent washs;
6) it is dried in vacuo;
7) tin plating;
8) hot stamping;When metallic tin is not fully cured, pass through die marks or artificial engraving various patterns decorative pattern on metallic tin;
9) it cools and solidifies;
10) priming coats imitative copper paint using brush;
11) finishing coat on coats emulation copper paint using brush;
12) dry solidification obtains semi-finished product;
13) semi-finished product and puerh tea leaves are put into jointly in boiling water and are heated 2 hours;
14) semi-finished product taking-up is put in outdoor exposure 6 hours or is put in UV curing UV and irradiated 30 minutes;
15) step 13) and 14) 20 times are repeated;
16) white splendid achnatherum water;
17) it is dried in vacuo;
18) UV solidified paint is coated;
19) it is put in the solidification of UV curing, obtains antique copper aluminum alloy decoration plate.
2. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 7) In, metallic tin is melted using small intermediate frequency induction melting furnace, substrate monolith is inserted into tin water and is then taken out, is solidified.
3. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 7) In, deburring is carried out to substrate after the completion of tin plating.
4. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 10) it -12) is completed in superclean bench.
5. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 10) copper paint is imitated in a thickness of 0.5 millimeter.
6. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 11) emulation copper paint is in a thickness of 0.1 millimeter.
7. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 13) weight ratio of semi-finished product and puerh tea leaves is 17: 1 in.
8. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 13) puerh tea leaves mixing dried orange peel, Chinese prickly ash and corter pseudolaricis boil jointly in, weight ratio 50: 7: 6: 7.
9. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the step 16) bletilla striata water brush surface of semi-finished is stained with using writing brush in, the writing brush uses block letters and milli round end centre forward's wolf writing brush.
10. a kind of preparation method of antique copper aluminum alloy decoration plate according to claim 1, it is characterised in that: the bletilla striata Boiling 1 hour the preparation method comprises the following steps: 0.5 kilogram of the bletilla striata is put into 30 liters of water for water, then keeps the temperature after filter residue spare.
CN201810991524.XA 2018-08-27 2018-08-27 Preparation method of antique copper-aluminum alloy decorative plate Active CN109080372B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3955999A (en) * 1974-07-22 1976-05-11 Paul Snellgrove Cream wax and the method of preparation thereof
US4181763A (en) * 1976-01-19 1980-01-01 Shellenberger Robert L Process for producing simulated wooden articles
CN102991264A (en) * 2012-11-28 2013-03-27 屹洋(上海)金属结构件有限公司 Manufacturing method of antique copper
CN103963550A (en) * 2014-04-10 2014-08-06 安徽旌德宏聪金属制造科技有限公司 Processing technology for manufacturing antique brass through aluminum
CN105150754A (en) * 2015-08-03 2015-12-16 宁波欧依欣卫浴有限公司 Surface antiqued processing technology of antiqued product

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3955999A (en) * 1974-07-22 1976-05-11 Paul Snellgrove Cream wax and the method of preparation thereof
US4181763A (en) * 1976-01-19 1980-01-01 Shellenberger Robert L Process for producing simulated wooden articles
CN102991264A (en) * 2012-11-28 2013-03-27 屹洋(上海)金属结构件有限公司 Manufacturing method of antique copper
CN103963550A (en) * 2014-04-10 2014-08-06 安徽旌德宏聪金属制造科技有限公司 Processing technology for manufacturing antique brass through aluminum
CN105150754A (en) * 2015-08-03 2015-12-16 宁波欧依欣卫浴有限公司 Surface antiqued processing technology of antiqued product

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