CN109046450B - 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 - Google Patents
一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 Download PDFInfo
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- CN109046450B CN109046450B CN201810943543.5A CN201810943543A CN109046450B CN 109046450 B CN109046450 B CN 109046450B CN 201810943543 A CN201810943543 A CN 201810943543A CN 109046450 B CN109046450 B CN 109046450B
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- cellulose acetate
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- 229920002301 cellulose acetate Polymers 0.000 title claims abstract description 162
- 108010022355 Fibroins Proteins 0.000 title claims abstract description 133
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000012528 membrane Substances 0.000 title claims abstract description 101
- 238000000034 method Methods 0.000 title description 21
- 229910000014 Bismuth subcarbonate Inorganic materials 0.000 claims abstract description 68
- 239000000243 solution Substances 0.000 claims abstract description 46
- 239000002243 precursor Substances 0.000 claims abstract description 44
- 239000011259 mixed solution Substances 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
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- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 150000001621 bismuth Chemical class 0.000 claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 claims abstract description 9
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- 239000000843 powder Substances 0.000 claims description 10
- 230000000593 degrading effect Effects 0.000 claims description 8
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 8
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- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 239000002957 persistent organic pollutant Substances 0.000 claims description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 3
- QYIGOGBGVKONDY-UHFFFAOYSA-N 1-(2-bromo-5-chlorophenyl)-3-methylpyrazole Chemical compound N1=C(C)C=CN1C1=CC(Cl)=CC=C1Br QYIGOGBGVKONDY-UHFFFAOYSA-N 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
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- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 claims description 2
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- BEQZMQXCOWIHRY-UHFFFAOYSA-H dibismuth;trisulfate Chemical compound [Bi+3].[Bi+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BEQZMQXCOWIHRY-UHFFFAOYSA-H 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
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- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract description 4
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- 230000015556 catabolic process Effects 0.000 description 18
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- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 14
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 11
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- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
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- 239000000126 substance Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- FWIZHMQARNODNX-UHFFFAOYSA-L dibismuth;oxygen(2-);carbonate Chemical compound [O-2].[O-2].[Bi+3].[Bi+3].[O-]C([O-])=O FWIZHMQARNODNX-UHFFFAOYSA-L 0.000 description 4
- 238000002791 soaking Methods 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 3
- 229940036358 bismuth subcarbonate Drugs 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
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- 241001198704 Aurivillius Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- 230000003197 catalytic effect Effects 0.000 description 1
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- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
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- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
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- 150000007522 mineralic acids Chemical class 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
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- 238000012827 research and development Methods 0.000 description 1
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- 150000003568 thioethers Chemical class 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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Abstract
Description
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CN201810943543.5A CN109046450B (zh) | 2018-08-17 | 2018-08-17 | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 |
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CN201810943543.5A CN109046450B (zh) | 2018-08-17 | 2018-08-17 | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 |
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CN109046450A CN109046450A (zh) | 2018-12-21 |
CN109046450B true CN109046450B (zh) | 2021-05-25 |
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CN110106627B (zh) * | 2019-03-29 | 2021-10-22 | 上海大学 | 一种碳酸氧铋-聚环氧乙烷膜的制备方法及其应用 |
CN111282591A (zh) * | 2020-03-20 | 2020-06-16 | 桂林电子科技大学 | 土壤修复用三硫化二锑/AgI/Ag/BON光催化剂的制备方法 |
CN113019409B (zh) * | 2021-03-23 | 2022-07-29 | 四川轻化工大学 | 一种Bi2O2CO3/BiOCl催化剂的制备方法及其应用 |
CN113854315B (zh) * | 2021-10-18 | 2022-03-08 | 山东农业大学 | 一种Ag-Bi复合纳米光催化杀菌材料及其制备方法 |
Citations (6)
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WO2007100569A2 (en) * | 2006-02-23 | 2007-09-07 | Pentron Clinical Technologies Llc | Self etch all purpose dental composition |
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