CN109046450A - 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 - Google Patents
一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 Download PDFInfo
- Publication number
- CN109046450A CN109046450A CN201810943543.5A CN201810943543A CN109046450A CN 109046450 A CN109046450 A CN 109046450A CN 201810943543 A CN201810943543 A CN 201810943543A CN 109046450 A CN109046450 A CN 109046450A
- Authority
- CN
- China
- Prior art keywords
- fibroin
- biocl
- cellulose acetate
- bio
- load
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 108010022355 Fibroins Proteins 0.000 title claims abstract description 129
- 229920002301 cellulose acetate Polymers 0.000 title claims abstract description 123
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 title claims abstract description 119
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000000243 solution Substances 0.000 claims abstract description 47
- 229910000014 Bismuth subcarbonate Inorganic materials 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000007864 aqueous solution Substances 0.000 claims abstract description 20
- 239000007790 solid phase Substances 0.000 claims abstract description 20
- 239000007787 solid Substances 0.000 claims abstract description 18
- 229910001868 water Inorganic materials 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 150000001621 bismuth Chemical class 0.000 claims abstract description 10
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 claims abstract description 9
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 230000015556 catabolic process Effects 0.000 claims description 32
- 238000006731 degradation reaction Methods 0.000 claims description 32
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- 229920006221 acetate fiber Polymers 0.000 claims description 20
- 239000001913 cellulose Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 18
- 238000000576 coating method Methods 0.000 claims description 18
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 16
- 229920002678 cellulose Polymers 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 239000011780 sodium chloride Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000006303 photolysis reaction Methods 0.000 claims description 9
- 230000015843 photosynthesis, light reaction Effects 0.000 claims description 9
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- 238000010422 painting Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 239000002957 persistent organic pollutant Substances 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- QYIGOGBGVKONDY-UHFFFAOYSA-N 1-(2-bromo-5-chlorophenyl)-3-methylpyrazole Chemical compound N1=C(C)C=CN1C1=CC(Cl)=CC=C1Br QYIGOGBGVKONDY-UHFFFAOYSA-N 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 claims description 2
- 229910000380 bismuth sulfate Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- BEQZMQXCOWIHRY-UHFFFAOYSA-H dibismuth;trisulfate Chemical compound [Bi+3].[Bi+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BEQZMQXCOWIHRY-UHFFFAOYSA-H 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 114
- 239000003054 catalyst Substances 0.000 description 18
- 239000012528 membrane Substances 0.000 description 17
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 229940043267 rhodamine b Drugs 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 238000005303 weighing Methods 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 description 8
- 238000004064 recycling Methods 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000000052 vinegar Substances 0.000 description 8
- 235000021419 vinegar Nutrition 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 206010011953 Decreased activity Diseases 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 229960000583 acetic acid Drugs 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011941 photocatalyst Substances 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 210000000498 stratum granulosum Anatomy 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 241001198704 Aurivillius Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000001018 Hibiscus sabdariffa Nutrition 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- 235000005291 Rumex acetosa Nutrition 0.000 description 1
- 240000007001 Rumex acetosella Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229940036348 bismuth carbonate Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- GMZOPRQQINFLPQ-UHFFFAOYSA-H dibismuth;tricarbonate Chemical compound [Bi+3].[Bi+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GMZOPRQQINFLPQ-UHFFFAOYSA-H 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005909 ethyl alcohol group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000002468 redox effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000003513 sheep sorrel Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000003403 water pollutant Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B01J35/39—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/08—Cellulose derivatives
- C08J2301/10—Esters of organic acids
- C08J2301/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2389/00—Characterised by the use of proteins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/10—Esters of organic acids
- C08J2401/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2489/00—Characterised by the use of proteins; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810943543.5A CN109046450B (zh) | 2018-08-17 | 2018-08-17 | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810943543.5A CN109046450B (zh) | 2018-08-17 | 2018-08-17 | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109046450A true CN109046450A (zh) | 2018-12-21 |
CN109046450B CN109046450B (zh) | 2021-05-25 |
Family
ID=64687348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810943543.5A Active CN109046450B (zh) | 2018-08-17 | 2018-08-17 | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109046450B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110106627A (zh) * | 2019-03-29 | 2019-08-09 | 上海大学 | 一种碳酸氧铋-聚环氧乙烷膜的制备方法及其应用 |
CN111282591A (zh) * | 2020-03-20 | 2020-06-16 | 桂林电子科技大学 | 土壤修复用三硫化二锑/AgI/Ag/BON光催化剂的制备方法 |
CN113019409A (zh) * | 2021-03-23 | 2021-06-25 | 四川轻化工大学 | 一种Bi2O2CO3/BiOCl催化剂的制备方法及其应用 |
CN113854315A (zh) * | 2021-10-18 | 2021-12-31 | 山东农业大学 | 一种Ag-Bi复合纳米光催化杀菌材料及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007100569A2 (en) * | 2006-02-23 | 2007-09-07 | Pentron Clinical Technologies Llc | Self etch all purpose dental composition |
CN102344685A (zh) * | 2010-08-05 | 2012-02-08 | 中国科学院化学研究所 | 一种制备纳米纤维素微纤增强聚合物复合材料的方法 |
CN104549406A (zh) * | 2014-12-19 | 2015-04-29 | 华南理工大学 | 一种g-C3N4/铋系氧化物复合可见光催化剂及其制备方法与应用 |
CN105732824A (zh) * | 2016-03-31 | 2016-07-06 | 常州创索新材料科技有限公司 | 一种乙酰丝素蛋白改性醋酸纤维素的制备方法 |
CN106732708A (zh) * | 2016-11-11 | 2017-05-31 | 湖南大学 | 石墨相氮化碳纳米片负载单层钨酸铋纳米片异质结材料及其制备方法和应用 |
CN106824213A (zh) * | 2017-02-20 | 2017-06-13 | 上海大学 | 一种钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂及其制备方法 |
-
2018
- 2018-08-17 CN CN201810943543.5A patent/CN109046450B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007100569A2 (en) * | 2006-02-23 | 2007-09-07 | Pentron Clinical Technologies Llc | Self etch all purpose dental composition |
CN102344685A (zh) * | 2010-08-05 | 2012-02-08 | 中国科学院化学研究所 | 一种制备纳米纤维素微纤增强聚合物复合材料的方法 |
CN104549406A (zh) * | 2014-12-19 | 2015-04-29 | 华南理工大学 | 一种g-C3N4/铋系氧化物复合可见光催化剂及其制备方法与应用 |
CN105732824A (zh) * | 2016-03-31 | 2016-07-06 | 常州创索新材料科技有限公司 | 一种乙酰丝素蛋白改性醋酸纤维素的制备方法 |
CN106732708A (zh) * | 2016-11-11 | 2017-05-31 | 湖南大学 | 石墨相氮化碳纳米片负载单层钨酸铋纳米片异质结材料及其制备方法和应用 |
CN106824213A (zh) * | 2017-02-20 | 2017-06-13 | 上海大学 | 一种钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂及其制备方法 |
Non-Patent Citations (2)
Title |
---|
JING CAO ET AL.: "Surface acid etching of (BiO)2CO3 to construct (BiO)2CO3/BiOX (X = Cl, Br, I) heterostructure for methyl orange removal under visible light", 《APPLIED SURFACE SCIENCE》 * |
WEITAO ZHOU ET AL.: "Nanofibrous Membrane of Silk Fibroin/Cellulose Acetate Blend for Heavy Metal Ion Adsorption", 《ADVANCED MATERIALS RESEARCH VOLS》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110106627A (zh) * | 2019-03-29 | 2019-08-09 | 上海大学 | 一种碳酸氧铋-聚环氧乙烷膜的制备方法及其应用 |
CN111282591A (zh) * | 2020-03-20 | 2020-06-16 | 桂林电子科技大学 | 土壤修复用三硫化二锑/AgI/Ag/BON光催化剂的制备方法 |
CN113019409A (zh) * | 2021-03-23 | 2021-06-25 | 四川轻化工大学 | 一种Bi2O2CO3/BiOCl催化剂的制备方法及其应用 |
CN113854315A (zh) * | 2021-10-18 | 2021-12-31 | 山东农业大学 | 一种Ag-Bi复合纳米光催化杀菌材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN109046450B (zh) | 2021-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Liu et al. | The application of Zeolitic imidazolate frameworks (ZIFs) and their derivatives based materials for photocatalytic hydrogen evolution and pollutants treatment | |
Pan et al. | Recent progress in 2D metal-organic framework photocatalysts: synthesis, photocatalytic mechanism and applications | |
CN109046450A (zh) | 一种BiOCl/(BiO)2CO3负载的醋酸纤维素/丝素杂化膜的制备方法和应用 | |
CN103433060B (zh) | 核-壳型TiO2/ZnIn2S4复合光催化剂及其制备方法与应用 | |
CN101791565B (zh) | 一种TiO2@石墨相氮化碳异质结复合光催化剂及其制备方法 | |
CN102580742B (zh) | 一种活性炭负载氧化亚铜光催化剂及其制备方法 | |
CN103599800B (zh) | 玻璃纤维负载银-溴化银-氧化钛复合材料的制备方法 | |
CN102080262B (zh) | 一种可见光催化材料及其制备方法与应用 | |
CN106552651B (zh) | 一种Bi12O17Br2光催化剂的合成及应用方法 | |
CN109046473B (zh) | 一种过渡金属修饰TiO2-MOFs膜的复合电极及其制备方法与应用 | |
CN110227500A (zh) | 一种Cd1-xZnxS-Ni/MoS2复合光催化剂及其制备方法、应用 | |
CN104971720A (zh) | 一种钨酸铋纳米复合材料及其制备方法和应用 | |
CN111437884A (zh) | 一种复合光催化剂及其制备方法 | |
CN104588040A (zh) | 一种光催化剂及其制备方法 | |
CN108273528A (zh) | 一种制备纳米棒状高碘氧铋光催化剂的方法 | |
CN110589886A (zh) | 一种碳酸氧铋的制备方法 | |
CN109261188A (zh) | 一种氧空位可调的氧化亚铜-氧化铜/氮化碳复合氧化物、制备方法及其应用 | |
CN110102322A (zh) | 花状的Ag@AgBr/ZnO光催化材料的制备方法 | |
CN102125831B (zh) | 介孔Bi2O3/TiO2纳米光催化剂的制备方法 | |
CN103623823B (zh) | 一种碳球@CuO核-壳型复合微球及其制备方法和应用 | |
CN109499563A (zh) | 一种氧化锌-活性炭复合催化剂的制备方法 | |
CN105597786A (zh) | 一种锯齿状Cu2MoS4纳米片的制备方法及在电、光催化中的应用 | |
CN102744087A (zh) | 一种片状纳米氯氧化铋薄膜光催化剂的电化学制备方法 | |
CN107935043A (zh) | 光催化活性的钨酸铋空心微球的制备方法 | |
CN104689842A (zh) | 用于水二次处理的二维蜂窝状ZnO/沸石的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Fu Yongying Inventor after: Wang Yi Inventor before: Wang Yi |
|
CB03 | Change of inventor or designer information | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210430 Address after: 2 / F, Anbo Lijing garden, 6012 Shennan Avenue, Meiling community, Lianhua street, Futian District, Shenzhen, Guangdong 518000 Applicant after: Ruiliheng ecological technology (Shenzhen) Co.,Ltd. Address before: 313017 Mindang Village, Nanxun District, Huzhou City, Zhejiang Province Applicant before: Wang Yi |
|
TA01 | Transfer of patent application right | ||
GR01 | Patent grant | ||
GR01 | Patent grant |