CN108998190A - 一种金属加工防锈水性切削液及其制备方法 - Google Patents

一种金属加工防锈水性切削液及其制备方法 Download PDF

Info

Publication number
CN108998190A
CN108998190A CN201811077999.4A CN201811077999A CN108998190A CN 108998190 A CN108998190 A CN 108998190A CN 201811077999 A CN201811077999 A CN 201811077999A CN 108998190 A CN108998190 A CN 108998190A
Authority
CN
China
Prior art keywords
parts
cutting fluid
composite coating
intermetallic composite
aqueous cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811077999.4A
Other languages
English (en)
Inventor
秦波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Baoji Numerical Control Technology Co Ltd
Original Assignee
Jiangsu Baoji Numerical Control Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Baoji Numerical Control Technology Co Ltd filed Critical Jiangsu Baoji Numerical Control Technology Co Ltd
Priority to CN201811077999.4A priority Critical patent/CN108998190A/zh
Publication of CN108998190A publication Critical patent/CN108998190A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

一种金属加工防锈水性切削液及其制备方法，涉及机械加工技术领域，由以下质量份数的各个组分组成：三羟甲基丙烷聚醚10‑22份、2,6‑二叔丁基混合酯2‑6份、硼酸酯1‑2份、聚甲基丙烯酸酯1‑2份、烷基水杨酸钙2‑5份、硼化油酰胺2‑5份、去离子水60‑90份、抗氧抗腐剂0.5‑1.5份、防锈剂0.5‑1.8份。本发明提供的金属加工防锈水性切削液，制备工艺较为便捷，具有优良的防锈和耐腐蚀性能，不仅润滑效果优良，而且冷却性能也较为理想，非常利于机床加工切削之用。

Description

一种金属加工防锈水性切削液及其制备方法
技术领域
本发明属于机械化工领域，特别涉及一种金属加工过程中使用的防锈水性切削液。
背景技术
切削液是一种用在金属切削、磨加工过程中，用来冷却和润滑刀具和加工件的工业用液体，切削液由多种超强功能助剂经科学复合配合而成，同时具备良好的冷却性能、润滑性能、防锈性能、除油清洗功能、防腐功能、易稀释特点。
切削液不同于传统的皂基乳化液，不存在皂基乳化液夏天易臭、冬天难稀释、防锈效果差等问题，因而保存和利用更为便利。
金属在切削加工过程中，其加工面暴露在空气中，易发生腐蚀生锈现象，尤其是使用水性切削液，腐蚀现象更为严重，因此，如何保护切削过程中的金属工件，不仅能够及时清除碎屑，而且防止金属生锈，是水性切削液面临的较大问题。
发明内容
本发明解决的技术问题：针对上述不足，克服现有技术的缺陷，本发明的目的是提供一种具有优良的冷却性能和防锈性能的金属加工防锈水性切削液及其制备方法。
本发明的技术方案：
一种金属加工防锈水性切削液，由以下质量份数的各个组分组成：
三羟甲基丙烷聚醚10-22份、2,6-二叔丁基混合酯2-6份、硼酸酯1-2份、聚甲基丙烯酸酯1-2份、烷基水杨酸钙2-5份、硼化油酰胺2-5份、去离子水60-90份、抗氧抗腐剂0.5-1.5份、防锈剂0.5-1.8份。
作为优选，所述抗氧抗腐剂为硫代二丙酸二月桂酯、叔丁基羟基茴香醚或二丁基羟基甲苯。
更优地，所述抗氧抗腐剂为硫代二丙酸二月桂酯。
作为优选，所述防锈剂为环烷酸锌、合成磺酸镁或烯基丁二酸酯。
一种金属加工防锈水性切削液的制备方法，包括以下步骤：
（1）称量：按照各个组分的质量份数称取各个组分；
（2）混合：将各个组分依次放入搅拌器中进行搅拌；
（3）真空静置：将搅拌好的混合液放入容器中，放置在真空室温环境下静置8-12h；
（4）封装：真空静置后，进行包装封装，即得到金属加工防锈水性切削液。
有益效果：本发明提供的金属加工防锈耐腐蚀切削液，制备工艺较为便捷，具有优良的防锈和耐腐蚀性能，不仅润滑效果优良，而且冷却性能也较为理想，非常利于机床加工切削之用。
具体实施方式
为了进一步理解本发明，下面结合实施例对本发明优选实施方案进行描述，但是应当理解，这些描述只是为进一步说明本发明的特征和优点，而不是对本发明权利要求的限制。
实施例 1：
一种金属加工防锈水性切削液，由以下质量份数的各个组分组成：
三羟甲基丙烷聚醚10份、2,6-二叔丁基混合酯2份、硼酸酯1份、聚甲基丙烯酸酯1份、烷基水杨酸钙2份、硼化油酰胺2份、去离子水60份、叔丁基羟基茴香醚0.5份和环烷酸0.5份。
一种金属加工防锈水性切削液的制备方法，包括以下步骤：
（1）称量：按照各个组分的质量份数称取各个组分；
（2）混合：将各个组分依次放入搅拌器中进行搅拌；
（3）真空静置：将搅拌好的混合液放入容器中，放置在真空室温环境下静置12h；
（4）封装：真空静置后，进行包装封装，即得到上述金属加工防锈水性切削液。
根据以上制备方法得到的金属加工防锈水性切削液，为均匀液态，无分层沉淀现象，测定的导热系数为： 0.61 w/（m*k）；测定防锈等级为优良。
实施例 2：
一种金属加工防锈水性切削液，由以下质量份数的各个组分组成：
三羟甲基丙烷聚醚22份、2,6-二叔丁基混合酯6份、硼酸酯2份、聚甲基丙烯酸酯2份、烷基水杨酸钙5份、硼化油酰胺5份、去离子水90份、二丁基羟基甲苯1.5份、合成磺酸镁1.8份。
一种金属加工防锈水性切削液的制备方法，包括以下步骤：
（1）称量：按照各个组分的质量份数称取各个组分；
（2）混合：将各个组分依次放入搅拌器中进行搅拌；
（3）真空静置：将搅拌好的混合液放入容器中，放置在真空室温环境下静12h；
（4）封装：真空静置后，进行包装封装，即得到上述金属加工防锈水性切削液
根据以上制备方法得到的金属加工防锈水性切削液，为均匀液态，无分层沉淀现象，测定的导热系数为： 0.62 w/（m*k）；测定防锈等级为优良。
实施例 3：
一种金属加工防锈水性切削液，由以下质量份数的各个组分组成：
三羟甲基丙烷聚醚21份、2,6-二叔丁基混合酯5份、硼酸酯2份、聚甲基丙烯酸酯1份、烷基水杨酸钙4份、硼化油酰胺4份、去离子水83份、硫代二丙酸二月桂酯0.7份和烯基丁二酸酯防锈剂1.1份。
一种金属加工防锈水性切削液的制备方法，包括以下步骤：
（1）称量：按照各个组分的质量份数称取各个组分；
（2）混合：将各个组分依次放入搅拌器中进行搅拌；
（3）真空静置：将搅拌好的混合液放入容器中，放置在真空室温环境下静置12h；
（4）封装：真空静置后，进行包装封装，即得到上述金属加工防锈水性切削液。
根据以上制备方法得到的金属加工防锈水性切削液，为均匀液态，无分层沉淀现象，测定的导热系数为： 0.64 w/（m*k）；测定防锈等级为优良。
对所公开的实施例的上述说明，使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的，本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下，在其它实施例中实现。因此，本发明将不会被限制于本文所示的这些实施例，而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。

Claims (5)

1.一种金属加工防锈水性切削液，其特征在于，由以下质量份数的各个组分组成：三羟甲基丙烷聚醚，10-22份；2,6-二叔丁基混合酯，2-6份；硼酸酯，1-2份；聚甲基丙烯酸酯，1-2份；烷基水杨酸钙，2-5份；硼化油酰胺，2-5份；去离子水，60-90份；抗氧抗腐剂，0.5-1.5份；防锈剂，0.5-1.8份。
2.根据权利要求1所述的金属加工防锈水性切削液，其特征在于：所述抗氧抗腐剂为硫代二丙酸二月桂酯、叔丁基羟基茴香醚或二丁基羟基甲苯。
3.根据权利要求2所述的金属加工防锈水性切削液，其特征在于：所述抗氧抗腐剂为硫代二丙酸二月桂酯。
4.根据权利要求1所述的金属加工防锈水性切削液，其特征在于：所述防锈剂为环烷酸锌、合成磺酸镁或烯基丁二酸酯。
5.一种制备权利要求1所述的金属加工防锈水性切削液的方法，其特征在于，包括以下步骤：
（1）称量：按照各个组分的质量份数称取各个组分；
（2）混合：将各个组分依次放入搅拌器中进行搅拌；
（3）真空静置：将搅拌好的混合液放入容器中，放置在真空室温环境下静置8-12h；
（4）封装:真空静置后，进行包装封装，即得到金属加工防锈水性切削液。
CN201811077999.4A 2018-09-16 2018-09-16 一种金属加工防锈水性切削液及其制备方法 Pending CN108998190A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811077999.4A CN108998190A (zh) 2018-09-16 2018-09-16 一种金属加工防锈水性切削液及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811077999.4A CN108998190A (zh) 2018-09-16 2018-09-16 一种金属加工防锈水性切削液及其制备方法

Publications (1)

Publication Number Publication Date
CN108998190A true CN108998190A (zh) 2018-12-14

Family

ID=64591775

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811077999.4A Pending CN108998190A (zh) 2018-09-16 2018-09-16 一种金属加工防锈水性切削液及其制备方法

Country Status (1)

Country Link
CN (1) CN108998190A (zh)

Similar Documents

Publication Publication Date Title
CN102787007A (zh) 一种绿色环保可溶性冲压拉伸油及其制备方法
CN106479654A (zh) 水基金属切削液
CN104263476B (zh) 生物可降解微量润滑油及其制备方法
CN103113970B (zh) 一种水溶性准干切削液及其制备方法和用途
CN103443254A (zh) 高润滑性固体润滑剂
CN111423928A (zh) 一种铸铁和铝合金混合件加工用切削液及其制备方法
CN105001966B (zh) 一种铝及铝合金切削液
CN102952610A (zh) 一种铝合金轮毂专用切削液
TW200932898A (en) Dry-film, anti-corrosive cold forming lubricant
CN101104829A (zh) 一种冲压油及其制备方法
CN108998190A (zh) 一种金属加工防锈水性切削液及其制备方法
CN108998178A (zh) 一种金属加工水性切削液及其制备方法
JPH0244878B2 (zh)
CN104120002B (zh) 一种具有抗菌防霉效果的切削液及其制备方法
CN109135903A (zh) 一种铸铁加工防锈切削液及其制备方法
JP5204625B2 (ja) ホウ酸塩非含有の乾式伸線用潤滑剤
CN101811173A (zh) 无石墨高性能环境友好型热锻加工液
CN109722331A (zh) 一种全合成切削液的制备工艺
WO2001004241A1 (en) Improved process and product for lubricating metal prior to cold forming
CN109207242A (zh) 一种机床加工防锈耐腐蚀切削液及其制备方法
CN103589481B (zh) 一种金属加工清洗皂化液
CN108998172A (zh) 一种高冷却性能机械加工切削液及其制备方法
CN109810749A (zh) 一种全合成切削液
CN108998170A (zh) 一种耐腐蚀金属切削液及其制备方法
CN104388171A (zh) 一种高性价比的新型水基切削液及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181214

WD01 Invention patent application deemed withdrawn after publication