CN1089742C - 制备1,6－己二醇和己内酯的方法 - Google Patents

制备1,6－己二醇和己内酯的方法 Download PDF

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Publication number
CN1089742C
CN1089742C CN97192521A CN97192521A CN1089742C CN 1089742 C CN1089742 C CN 1089742C CN 97192521 A CN97192521 A CN 97192521A CN 97192521 A CN97192521 A CN 97192521A CN 1089742 C CN1089742 C CN 1089742C
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CN
China
Prior art keywords
ester
esterification
cut
cyclohexanediol
caprolactone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN97192521A
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English (en)
Chinese (zh)
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CN1211969A (zh
Inventor
K·G·保尔
R·费舍尔
R·宾克斯
F·斯坦恩
B·布里特施德尔
H·鲁斯特
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BASF SE
Original Assignee
BASF SE
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Filing date
Publication date
Priority claimed from DE1996107954 external-priority patent/DE19607954A1/de
Priority claimed from DE1996147349 external-priority patent/DE19647349A1/de
Application filed by BASF SE filed Critical BASF SE
Publication of CN1211969A publication Critical patent/CN1211969A/zh
Application granted granted Critical
Publication of CN1089742C publication Critical patent/CN1089742C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Pyrane Compounds (AREA)
CN97192521A 1996-03-01 1997-02-28 制备1,6－己二醇和己内酯的方法 Expired - Lifetime CN1089742C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19607954.3 1996-03-01
DE1996107954 DE19607954A1 (de) 1996-03-01 1996-03-01 Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
DE1996147349 DE19647349A1 (de) 1996-11-15 1996-11-15 Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
DE19647349.7 1996-11-15

Publications (2)

Publication Number Publication Date
CN1211969A CN1211969A (zh) 1999-03-24
CN1089742C true CN1089742C (zh) 2002-08-28

Family

ID=26023397

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97192521A Expired - Lifetime CN1089742C (zh) 1996-03-01 1997-02-28 制备1,6－己二醇和己内酯的方法

Country Status (13)

Country Link
US (1) US5981769A (cg-RX-API-DMAC7.html)
EP (1) EP0883591B1 (cg-RX-API-DMAC7.html)
JP (1) JP4107396B2 (cg-RX-API-DMAC7.html)
KR (1) KR100468182B1 (cg-RX-API-DMAC7.html)
CN (1) CN1089742C (cg-RX-API-DMAC7.html)
AT (1) ATE192730T1 (cg-RX-API-DMAC7.html)
CA (1) CA2248004C (cg-RX-API-DMAC7.html)
DE (1) DE59701646D1 (cg-RX-API-DMAC7.html)
ES (1) ES2147435T3 (cg-RX-API-DMAC7.html)
GR (1) GR3033955T3 (cg-RX-API-DMAC7.html)
MY (1) MY118128A (cg-RX-API-DMAC7.html)
PT (1) PT883591E (cg-RX-API-DMAC7.html)
WO (1) WO1997031883A1 (cg-RX-API-DMAC7.html)

Families Citing this family (43)

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DE19757554A1 (de) 1997-12-23 1999-06-24 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
DE19826614A1 (de) * 1998-05-29 1999-12-02 Basf Ag Verfahren zur Herstellung von Hexandiol-1,6
US6344586B1 (en) * 1998-07-30 2002-02-05 Sumitomo Chemical Company, Limited Process for producing adipic acid
ES2254402T3 (es) * 2000-08-24 2006-06-16 UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION Procedimientos para la fabricacion de lactonas.
DE10100552A1 (de) * 2001-01-09 2002-07-11 Basf Ag Verfahren und Vorrichtung zur destillativen Aufarbeitung von 1,6-Hexandiol, 1,5-Pentandiol ung Caprolacton
DE10128249A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Entfernung von Ameisensäure aus wässrigen Lösungen
DE10242882A1 (de) * 2002-09-16 2004-03-25 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
AU2003285106A1 (en) * 2002-11-01 2004-06-07 Cargill, Incorporated Process for preparation of 1,3-propanediol
WO2005121380A1 (en) * 2004-06-04 2005-12-22 Smithkline Beecham Corporation Predictive biomarkers in cancer therapy
DE102004033557A1 (de) 2004-07-09 2006-02-16 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol in einer Reinheit von über 99,5%
DE102004054047A1 (de) 2004-11-05 2006-05-11 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
ATE458771T1 (de) * 2005-06-03 2010-03-15 Univ Twente Verzweigte polymere, ein makromonomer, verfahren zu deren herstellungen und deren verwendungen
EP1975146B1 (en) * 2006-01-13 2018-03-14 Ube Industries, Ltd. Process for production of 1,6-hexanediol
CA2690867A1 (en) * 2007-06-14 2008-12-18 Basf Se Process for preparing .epsilon.-caprolactone
EP2217587B1 (de) * 2007-11-05 2015-09-23 Basf Se Verfahren zur herstellung von e-caprolacton
US8217186B2 (en) 2007-12-21 2012-07-10 Basf Se Process for preparing epsilon-caprolactone
ES2393838T5 (es) 2008-02-15 2016-03-02 Basf Se Procedimiento para la obtención de ésteres de ácido 6-hidroxicaprónico
KR100922998B1 (ko) * 2008-03-06 2009-10-22 한국화학연구원 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법
US8828903B2 (en) 2008-11-10 2014-09-09 Basf Corporation Copper catalyst for dehydrogenation application
US20110263907A1 (en) * 2008-12-05 2011-10-27 Basf Se Process for preparing 1,6-hexanediol
JP5651126B2 (ja) * 2008-12-18 2015-01-07 インヴィスタ テクノロジーズ エスアエルエル シクロヘキサン酸化工程副生成物の誘導体およびそれの使用方法
EP2385933B1 (de) 2009-01-12 2014-06-25 Basf Se Verfahren zur herstellung von polymethylolen
CA2755696A1 (en) * 2009-04-07 2010-10-14 Basf Se Method for producing 1,6-hexanediol
US8471042B2 (en) * 2009-04-07 2013-06-25 Basf Se Method for producing 1,6-hexanediol and caprolactone
TWI490034B (zh) 2009-11-17 2015-07-01 Basf Se 製備具有增強氫化活性之經承載氫化觸媒之方法
CA2800282A1 (en) * 2010-06-16 2011-12-22 Bioamber S.A.S. Processes for the production of hydrogenated products and derivatives thereof
KR20130041905A (ko) 2010-06-16 2013-04-25 바이오엠버, 에스.아.에스. 수소화 생성물 및 이의 유도체를 제조하는 방법
EP2404889A1 (de) * 2010-07-06 2012-01-11 LANXESS Deutschland GmbH Verfahren zur Herstellung von Alpha, Omega-Diolen
US20120059174A1 (en) * 2010-09-08 2012-03-08 Basf Se Process for preparing epsilon-caprolactone and 1,6-hexanediol
CN103080098B (zh) * 2010-09-08 2014-11-05 巴斯夫欧洲公司 制备ε-己内酯和1,6-己二醇的方法
WO2013101969A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Process for preparing 1, 6-hexanediol
US8865940B2 (en) 2011-12-30 2014-10-21 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8889912B2 (en) 2011-12-30 2014-11-18 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8884036B2 (en) 2011-12-30 2014-11-11 E I Du Pont De Nemours And Company Production of hydroxymethylfurfural from levoglucosenone
WO2013101977A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Production of tetrahydrofuran-2, 5-dimethanol from isosorbide
EP2797868A4 (en) 2011-12-30 2015-08-12 Du Pont PROCESS FOR PRODUCING HEXANEDIOLS
CN102603446B (zh) * 2012-02-13 2014-08-06 湖南大学 一种以碳材料催化氧化有机酮制备有机内酯的方法
CN102603447B (zh) * 2012-02-13 2014-09-03 湖南大学 一种制备有机内酯的方法
US8846984B2 (en) 2012-04-27 2014-09-30 E I Du Pont De Nemours And Company Production of α,ω-diols
US8859826B2 (en) 2012-04-27 2014-10-14 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US9018423B2 (en) 2012-04-27 2015-04-28 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US11208394B2 (en) 2018-09-17 2021-12-28 Regents Of The University Of Minnesota Chemical process to manufacture branched-caprolactone
GB202109710D0 (en) 2021-07-05 2021-08-18 Johnson Matthey Davy Technologies Ltd Separation process for the production of C5 or C6 alkanediol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2819593A1 (de) * 1978-05-05 1979-11-08 Basf Ag Verfahren zur herstellung von diolen
EP0661255A1 (en) * 1993-12-28 1995-07-05 Ube Industries, Ltd. Process for producing diol compounds

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DE1618143C3 (de) * 1967-04-27 1975-08-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von epsilon-Hydroxycapronsäurelacton und von Alkandicarbonsäuren
DE2060548C3 (de) * 1970-12-09 1979-10-11 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von sehr reinem 1,6-Hexandiol durch Kristallisation
DE2321101C2 (de) * 1973-04-26 1982-07-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung im wesentlichen trägerfreier Kobaltkatalysatoren
US3933930A (en) * 1975-03-06 1976-01-20 Celanese Corporation Hexanediol from cyclohexane
DE3823213A1 (de) * 1988-07-08 1990-01-11 Basf Ag Verfahren zur herstellung von caprolacton
US5710349A (en) * 1993-10-08 1998-01-20 Ube Industries, Ltd. Process for producing diol compounds

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
DE2819593A1 (de) * 1978-05-05 1979-11-08 Basf Ag Verfahren zur herstellung von diolen
EP0661255A1 (en) * 1993-12-28 1995-07-05 Ube Industries, Ltd. Process for producing diol compounds

Also Published As

Publication number Publication date
DE59701646D1 (de) 2000-06-15
KR100468182B1 (ko) 2005-03-16
PT883591E (pt) 2000-10-31
CA2248004C (en) 2006-04-11
JP2000506134A (ja) 2000-05-23
ES2147435T3 (es) 2000-09-01
CN1211969A (zh) 1999-03-24
MY118128A (en) 2004-09-30
US5981769A (en) 1999-11-09
EP0883591B1 (de) 2000-05-10
WO1997031883A1 (de) 1997-09-04
CA2248004A1 (en) 1997-09-04
KR19990087422A (ko) 1999-12-27
ATE192730T1 (de) 2000-05-15
JP4107396B2 (ja) 2008-06-25
EP0883591A1 (de) 1998-12-16
GR3033955T3 (en) 2000-11-30

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Granted publication date: 20020828