CN108913316A - A kind of environmentally-friendly water-based rust preventive cutting fluid and preparation method thereof - Google Patents
A kind of environmentally-friendly water-based rust preventive cutting fluid and preparation method thereof Download PDFInfo
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- CN108913316A CN108913316A CN201810749220.2A CN201810749220A CN108913316A CN 108913316 A CN108913316 A CN 108913316A CN 201810749220 A CN201810749220 A CN 201810749220A CN 108913316 A CN108913316 A CN 108913316A
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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Abstract
The invention discloses a kind of environmentally-friendly water-based rust preventive cutting fluids, including raw material below：Water, triethanolamine oleate, sodium alkyl sulfonate, polyethylene glycol, Sodium Polyacrylate, coconut acid diethanolamide, antirust agent, laureth sodium sulfovinate, vegetable oil, sulfonated oil.The invention also discloses the preparation methods of the environmentally-friendly water-based rust preventive cutting fluid.Rust preventive cutting fluid prepared by the present invention has excellent rustless property, can provide good protection for machining when being machined, use biodegradable plant oil substance proxy mineral oil as the base oil of cutting fluid, be more energy-saving and environmentally friendly；Simultaneously, by addition benzotriazole, sodium methyl silicate and dihydroxy methyl ether and assisting ultrasonic processing, synergistic effect is played, the rustless property of cutting fluid can be effectively improved under the premise of not influencing cutting fluid service performance, belong to environment-friendly type water base cutting fluid, has a vast market foreground.
Description
Technical field
The present invention relates to field of machining, specifically a kind of environmentally-friendly water-based rust preventive cutting fluid and preparation method thereof.
Background technique
With the continuous development of science and technology, modern mechanical processing also constantly develops to high speed, strength, accurate direction, superhard,
The development of the difficult-to-machine materials such as super-strength increases the difficulty of machining increasingly.In order to reduce rubbing in cutting process
Wipe power, frictional heat increases substantially, it is often necessary to use cutting fluid.
In face of the raising of mankind's environmental consciousness, requirement of the market for the environmentally protective performance of cutting fluid is higher and higher, water
Base cutting fluid also just comes into being.Water-base cutting fluid is that one kind is cut, cuts, ground in process used in metal, for cooling down and moistening
The industrial type fluid of sliding cutter and workpiece overcomes easily smelly, winter difficult diluted defect of traditional tradition soap base emulsion summer.But
It is that traditional water-soluble metalworking liquid has rust-proof effect difference, to cause a large amount of equipment in the process of running because of life
Rust corrodes and scraps, and shortens the service life of equipment.Therefore, it designs a kind of environmentally-friendly water-based anti-with excellent rust-preventing characteristic
It becomes rusty cutting fluid, the problem of becoming urgent need to resolve.
Summary of the invention
The purpose of the present invention is to provide a kind of environmentally-friendly water-based rust preventive cutting fluids and preparation method thereof, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：45-90 parts of water, oily triethylenetetraminehexaacetic acid
0.1-0.7 parts of hydramine, 0.2-1.8 parts of sodium alkyl sulfonate, 1-8 parts of polyethylene glycol, 0.2-1 parts of Sodium Polyacrylate, cocinic acid two
0.3-2.3 parts of glycollic amide, 2-8 parts of antirust agent, 0.5-2.5 parts of laureth sodium sulfovinate, 2-7 parts of vegetable oil, sulfonated oil
0.1-0.7 parts；Wherein, the antirust agent is by soybean oil, sodium methyl silicate, three nitrogen of alkyl phosphate salt, dihydroxy methyl ether and benzo
Azoles is prepared.
As a further solution of the present invention：Including below according to the raw material of parts by weight：55-75 parts of water, oleic acid triethanolamine
0.2-0.5 parts of amine, 0.6-1.2 parts of sodium alkyl sulfonate, 3-6 parts of polyethylene glycol, 0.5-0.9 parts of Sodium Polyacrylate, cocinic acid two
1-2 parts of glycollic amide, 4-7 parts of antirust agent, 1-2 parts of laureth sodium sulfovinate, 3-6 parts of vegetable oil, sulfonated oil 0.3-0.6
Part.
As further scheme of the invention：Including below according to the raw material of parts by weight：68 parts of water, triethanolamine oleate
0.4 part, 1 part of sodium alkyl sulfonate, 5 parts of polyethylene glycol, 0.7 part of Sodium Polyacrylate, 1.8 parts of coconut acid diethanolamide, antirust
6 parts of agent, 1.5 parts of laureth sodium sulfovinate, 5 parts of vegetable oil, 0.5 part of sulfonated oil.
As further scheme of the invention：The preparation method of the antirust agent is to weigh soybean oil 5- according to parts by weight
15 parts, 0.8-1.2 parts of sodium methyl silicate and 0.3-0.7 parts of alkyl phosphate salt are uniformly mixed, then with 200-500r/min's
Stirring rate carries out mechanical stirring 20-40min, then is slowly added to 0.05-0.45 parts of dihydroxy methyl ether and three nitrogen of benzo while stirring
It 0.1-0.3 parts of azoles, is sent into ultrasonic microwave composite reaction instrument and carries out processing 6-16min at 30-40 DEG C, be cooled to room temperature,
To obtain the final product；It can effectively improve the combination effect between antirust agent each component by ultrasonic microwave combined effect, and then be conducive to
Improve the rustless property of cutting fluid.
As further scheme of the invention：The treatment conditions of the ultrasonic microwave composite reaction instrument are ultrasonic wave frequency
Rate is 12-28kHz, ultrasonic power 25-45W, microwave frequency 600-1000MHz, microwave power 25-45W.
As further scheme of the invention：The vegetable oil is that palm fibre puts oil, rapeseed oil, cottonseed oil, coconut oil, rice bran
One of oil, castor oil or a variety of combinations；By using biodegradable plant oil substance proxy mineral oil as cutting
The base oil for cutting liquid, is more energy-saving and environmentally friendly.
The preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) it weighs water according to parts by weight to be fed through in double planetary power vacuum blender, according to the heating of 0.1 DEG C/min
Rate is warming up to 40 DEG C, is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol, while stirring with 50-
The stirring rate of 250r/min carries out mechanical stirring 10-20min, vegetable oil is then added, under vacuum conditions with 800-
The stirring rate of 1800r/min carries out mechanical stirring 20-50min, obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 20-26 DEG C, with the stirring speed of 100-250r/min
Rate carries out mechanical stirring 10-20min, obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with stirring for 200-400r/min
It mixes rate and carries out mechanical stirring 10-20min, obtain mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, is ultrasonically treated at normal temperature,
Stand 20-50min, 100 mesh filtering to get；By adding the antirust agent by preparations such as dihydroxy methyl ether and benzotriazole and surpassing
Sonication cooperates, and plays synergistic effect, can effectively mention under the premise of not influencing cutting fluid service performance
The rustless property of high cutting fluid.
As further scheme of the invention：In step 4), the supersonic frequency of the ultrasonic treatment is 10-20kHz；Institute
The ultrasonic power for stating ultrasonic treatment is 400-800W；The time of the ultrasonic treatment is 15-35min.
Purposes of the environmentally-friendly water-based rust preventive cutting fluid in preparation cutting liquid product.
Compared with prior art, the beneficial effects of the invention are as follows：
Rust preventive cutting fluid prepared by the present invention has excellent rustless property, can mention for machining when being machined
For good protection, mine is replaced using biodegradable plant oil substance under the premise of not influencing cutting fluid service performance
Base oil of the object oil as cutting fluid, is more energy-saving and environmentally friendly；Meanwhile passing through addition benzotriazole, sodium methyl silicate and dihydroxy
Methyl ether and assisting ultrasonic processing, play synergistic effect, can effectively improve the rustless property of cutting fluid, belong to environmental protection
Type water-base cutting fluid, has a vast market foreground.
Specific embodiment
Technical solution of the present invention is described in more detail With reference to embodiment.
Embodiment 1
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：45 parts of water, triethanolamine oleate
0.1 part, it is 0.2 part of sodium alkyl sulfonate, 1 part of polyethylene glycol, 0.2 part of Sodium Polyacrylate, 0.3 part of coconut acid diethanolamide, anti-
Rust 2 parts of agent, 0.5 part of laureth sodium sulfovinate, 2 parts of vegetable oil, 0.1 part of sulfonated oil.Wherein, the vegetable oil is that palm fibre puts oil
With rapeseed oil according to weight ratio be 1:1 ratio mixes；By with biodegradable plant oil substance proxy mineral
Base oil of the oil as cutting fluid, is more energy-saving and environmentally friendly；The preparation method of the antirust agent is to weigh soybean oil according to parts by weight
10 parts, 1 part of sodium methyl silicate and 0.5 part of alkyl phosphate salt are uniformly mixed, and then carry out machine with the stirring rate of 300r/min
Tool stirs 30min, then is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, is sent into ultrasonic microwave group
Close reaction instrument in processing 10min is carried out at 37 DEG C, be cooled to room temperature to get；The place of the ultrasonic microwave composite reaction instrument
Manage bar part is that ultrasonic frequency is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, microwave power 35W；By super
Sound wave microwave combination effect can effectively improve the combination effect between antirust agent each component, and then be conducive to improve cutting fluid
Rustless property.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 2
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：90 parts of water, triethanolamine oleate
0.7 part, 1.8 parts of sodium alkyl sulfonate, 8 parts of polyethylene glycol, 1 part of Sodium Polyacrylate, 2.3 parts of coconut acid diethanolamide, antirust
8 parts of agent, 2.5 parts of laureth sodium sulfovinate, 7 parts of vegetable oil, 0.7 part of sulfonated oil.Wherein, the vegetable oil be palm fibre put oil and
Rapeseed oil is 1 according to weight ratio:1 ratio mixes；By oily with biodegradable plant oil substance proxy mineral
As the base oil of cutting fluid, it is more energy-saving and environmentally friendly；The preparation method of the antirust agent is to weigh soybean oil 10 according to parts by weight
Part, 1 part of sodium methyl silicate and 0.5 part of alkyl phosphate salt are uniformly mixed, and are then carried out with the stirring rate of 300r/min mechanical
30min is stirred, then is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, is sent into ultrasonic microwave combination
Reaction instrument in processing 10min is carried out at 37 DEG C, be cooled to room temperature to get；The processing of the ultrasonic microwave composite reaction instrument
Condition is that ultrasonic frequency is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, microwave power 35W；Pass through ultrasound
Wave microwave combination effect can effectively improve the combination effect between antirust agent each component, and then be conducive to improve the anti-of cutting fluid
Rust performance.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 3
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：67.5 parts of water, oleic acid triethanolamine
0.4 part of amine, 1.1 parts of sodium alkyl sulfonate, 4.5 parts of polyethylene glycol, 0.6 part of Sodium Polyacrylate, coconut acid diethanolamide 1.3
Part, 5 parts of antirust agent, 1.5 parts of laureth sodium sulfovinate, 4.5 parts of vegetable oil, 0.4 part of sulfonated oil.Wherein, the vegetable oil
Putting oil and rapeseed oil according to weight ratio for palm fibre is 1:1 ratio mixes；By with biodegradable plant oil substance
Base oil of the proxy mineral oil as cutting fluid, is more energy-saving and environmentally friendly；The preparation method of the antirust agent is to claim according to parts by weight
Take 10 parts of soybean oil, 1 part of sodium methyl silicate and 0.5 part of alkyl phosphate salt uniformly mixed, then with the stirring speed of 300r/min
Rate carries out mechanical stirring 30min, then is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, is sent into ultrasound
Wave microwave combination reaction instrument in processing 10min is carried out at 37 DEG C, be cooled to room temperature to get；The ultrasonic microwave combination is anti-
The treatment conditions of Ying Yi are that ultrasonic frequency is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, and microwave power is
35W；It can effectively improve the combination effect between antirust agent each component by ultrasonic microwave combined effect, and then be conducive to mention
The rustless property of high cutting fluid.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 4
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：55 parts of water, triethanolamine oleate
0.2 part, 0.6 part of sodium alkyl sulfonate, 3 parts of polyethylene glycol, 0.5 part of Sodium Polyacrylate, 1 part of coconut acid diethanolamide, antirust
4 parts of agent, 1 part of laureth sodium sulfovinate, 3 parts of vegetable oil, 0.3 part of sulfonated oil.Wherein, the vegetable oil is that palm fibre puts oil and dish
Seed oil is 1 according to weight ratio:1 ratio mixes；By being made with biodegradable plant oil substance proxy mineral oil
For the base oil of cutting fluid, it is more energy-saving and environmentally friendly；The preparation method of the antirust agent be according to parts by weight weigh 10 parts of soybean oil,
1 part and 0.5 part of alkyl phosphate salt of sodium methyl silicate is uniformly mixed, and then carries out mechanical stirring with the stirring rate of 300r/min
30min, then it is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, it is sent into ultrasonic microwave composite reaction
Processing 10min is carried out in instrument at 37 DEG C, be cooled to room temperature to get；The treatment conditions of the ultrasonic microwave composite reaction instrument
It is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, microwave power 35W for ultrasonic frequency；It is micro- by ultrasonic wave
Wave combined effect can effectively improve the combination effect between antirust agent each component, and then be conducive to improve the rust-preventing characteristic of cutting fluid
Energy.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 5
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：75 parts of water, triethanolamine oleate
0.5 part, 1.2 parts of sodium alkyl sulfonate, 6 parts of polyethylene glycol, 0.9 part of Sodium Polyacrylate, 2 parts of coconut acid diethanolamide, antirust
7 parts of agent, 2 parts of laureth sodium sulfovinate, 6 parts of vegetable oil, 0.6 part of sulfonated oil.Wherein, the vegetable oil is that palm fibre puts oil and dish
Seed oil is 1 according to weight ratio:1 ratio mixes；By being made with biodegradable plant oil substance proxy mineral oil
For the base oil of cutting fluid, it is more energy-saving and environmentally friendly；The preparation method of the antirust agent be according to parts by weight weigh 10 parts of soybean oil,
1 part and 0.5 part of alkyl phosphate salt of sodium methyl silicate is uniformly mixed, and then carries out mechanical stirring with the stirring rate of 300r/min
30min, then it is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, it is sent into ultrasonic microwave composite reaction
Processing 10min is carried out in instrument at 37 DEG C, be cooled to room temperature to get；The treatment conditions of the ultrasonic microwave composite reaction instrument
It is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, microwave power 35W for ultrasonic frequency；It is micro- by ultrasonic wave
Wave combined effect can effectively improve the combination effect between antirust agent each component, and then be conducive to improve the rust-preventing characteristic of cutting fluid
Energy.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 6
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：65 parts of water, triethanolamine oleate
0.35 part, 0.9 part of sodium alkyl sulfonate, 4.5 parts of polyethylene glycol, 0.7 part of Sodium Polyacrylate, 1.5 parts of coconut acid diethanolamide,
5.5 parts of antirust agent, 1.5 parts of laureth sodium sulfovinate, 4.5 parts of vegetable oil, 0.45 part of sulfonated oil.Wherein, the vegetable oil
Putting oil and rapeseed oil according to weight ratio for palm fibre is 1:1 ratio mixes；By with biodegradable plant oil substance
Base oil of the proxy mineral oil as cutting fluid, is more energy-saving and environmentally friendly；The preparation method of the antirust agent is to claim according to parts by weight
Take 10 parts of soybean oil, 1 part of sodium methyl silicate and 0.5 part of alkyl phosphate salt uniformly mixed, then with the stirring speed of 300r/min
Rate carries out mechanical stirring 30min, then is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, is sent into ultrasound
Wave microwave combination reaction instrument in processing 10min is carried out at 37 DEG C, be cooled to room temperature to get；The ultrasonic microwave combination is anti-
The treatment conditions of Ying Yi are that ultrasonic frequency is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, and microwave power is
35W；It can effectively improve the combination effect between antirust agent each component by ultrasonic microwave combined effect, and then be conducive to mention
The rustless property of high cutting fluid.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Embodiment 7
A kind of environmentally-friendly water-based rust preventive cutting fluid, including below according to the raw material of parts by weight：68 parts of water, triethanolamine oleate
0.4 part, 1 part of sodium alkyl sulfonate, 5 parts of polyethylene glycol, 0.7 part of Sodium Polyacrylate, 1.8 parts of coconut acid diethanolamide, antirust
6 parts of agent, 1.5 parts of laureth sodium sulfovinate, 5 parts of vegetable oil, 0.5 part of sulfonated oil.Wherein, the vegetable oil be palm fibre put oil and
Rapeseed oil is 1 according to weight ratio:1 ratio mixes；By oily with biodegradable plant oil substance proxy mineral
As the base oil of cutting fluid, it is more energy-saving and environmentally friendly；The preparation method of the antirust agent is to weigh soybean oil 10 according to parts by weight
Part, 1 part of sodium methyl silicate and 0.5 part of alkyl phosphate salt are uniformly mixed, and are then carried out with the stirring rate of 300r/min mechanical
30min is stirred, then is slowly added to 0.2 part and 0.2 part of benzotriazole of dihydroxy methyl ether while stirring, is sent into ultrasonic microwave combination
Reaction instrument in processing 10min is carried out at 37 DEG C, be cooled to room temperature to get；The processing of the ultrasonic microwave composite reaction instrument
Condition is that ultrasonic frequency is 18kHz, ultrasonic power 35W, microwave frequency 700MHz, microwave power 35W；Pass through ultrasound
Wave microwave combination effect can effectively improve the combination effect between antirust agent each component, and then be conducive to improve the anti-of cutting fluid
Rust performance.
In the present embodiment, the preparation method of the environmentally-friendly water-based rust preventive cutting fluid, steps are as follows：
1) water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, in the present embodiment, the duplicate rows
Planetary power vacuum blender is triumphant SXJ vacuum double-planet mixing and blending machine of anticipating, then according to the heating rate liter of 0.1 DEG C/min
Temperature is respectively added slowly to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol to 40 DEG C while stirring, with stirring for 150r/min
It mixes rate and carries out mechanical stirring 14min, vegetable oil is then added, carried out under vacuum conditions with the stirring rate of 1300r/min
Mechanical stirring 35min obtains mixture A；
2) mixture A obtained in step 1) is fed through in container, Sodium Polyacrylate, coconut oil is added according to parts by weight
Sour diglycollic amide and laureth sodium sulfovinate, keeping system temperature is 23 DEG C, is carried out with the stirring rate of 175r/min
Mechanical stirring 15min obtains mixture B；
3) antirust agent and sulfonated oil will be sequentially added in mixture B obtained in step 2), with the stirring speed of 300r/min
Rate carries out mechanical stirring 15min, obtains mixture C；
4) mixture C obtained in step 3) is sent into ultrasonic cell disruptor, in the present embodiment, the ultrasonic wave
Cell disruptor is the KF-1800W ultrasonic cell disruptor of Nanjing Ken Fan Electronic Science and Technology Co., Ltd., is surpassed at normal temperature
Sonication 25min, wherein the supersonic frequency of the ultrasonic treatment is 15kHz, and the ultrasonic power of the ultrasonic treatment is 600W,
Stand 35min after ultrasonic treatment, the filtering of 100 mesh to get；By adding the antirust by preparations such as dihydroxy methyl ether and benzotriazole
Agent and ultrasonic treatment cooperate, and play synergistic effect, can under the premise of not influencing cutting fluid service performance
Effectively improve the rustless property of cutting fluid.
Comparative example 1
Compared with Example 7, benzotriazole is free of, other are same as Example 7.
Comparative example 2
Compared with Example 7, sodium methyl silicate and dihydroxy methyl ether are free of, other are same as Example 7.
Comparative example 3
Compared with Example 7, benzotriazole, sodium methyl silicate and dihydroxy methyl ether are free of, other are same as Example 7.
Performance test
Rust preventive cutting fluid obtained by embodiment 7 and comparative example 1-3 is subjected to the test of monolithic test for rust preventing ability, specific method is
The water for being 6000ppm with hardness in no mouth flat bottom beaker prepares the dilution 200mL that cutting fluid volumetric concentration is 2%, with circle
Head glass bar stirs 2min, emulsifies it all, the dilution that oneself prepares is dipped with round end glass bar, in the test piece that oneself handles well
Upper 5 drop of drop, every drop diameter is 4-5mm, should maintain a certain distance, must not connect between each drop, and test piece is placed in wetting slot
On porcelain plate, wetting slot is covered, is stood under the conditions of 35 ± 2 DEG C, is stood after a certain period of time, is carried out test piece visual examination, will dilute
Drop is wiped, then is dipped in ethyl alcohol with cotton and gently wiped raffinate, observe test piece situation and grade, wherein five drops are A completely without rust
Grade, rustless four drops are B grades, and rustless three drops are C grades, and the full rust of four-five drops is D grades.Specific testing result is as shown in table 1.
1 monolithic test for rust preventing ability result table of table
It, can from can be seen that the present invention in the data comparison of embodiment 7 and comparative example 1 by addition benzotriazole
Effectively improve the rustless property of cutting fluid；From can be seen that the present invention in the data comparison of embodiment 7 and comparative example 2 by adding
Methylate sodium metasilicate and dihydroxy methyl ether, can effectively improve the rustless property of cutting fluid；In addition, from embodiment 7 and comparative example 1-3
Data comparison in as can be seen that the present invention is cooperated by benzotriazole, sodium methyl silicate and dihydroxy methyl ether, play
Synergistic effect, can further effectively improve the rustless property of cutting fluid.
As can be seen from the above results, rust preventive cutting fluid prepared by the present invention has excellent rustless property, can be to cut
It cuts processing and good protection is provided, biodegradable plant oil object is used under the premise of not influencing cutting fluid service performance
Base oil of the matter proxy mineral oil as cutting fluid, is more energy-saving and environmentally friendly；Meanwhile by adding benzotriazole, methane-siliconic acid
Sodium and dihydroxy methyl ether and assisting ultrasonic processing, play synergistic effect, can effectively improve the rustless property of cutting fluid.
Rust preventive cutting fluid prepared by the present invention has excellent rustless property, can mention for the machining in machining
For good protection, belong to environment-friendly type water base cutting fluid；Meanwhile passing through addition benzotriazole, sodium methyl silicate and dihydroxy first
Ether and assisting ultrasonic processing, play synergistic effect, can be effective under the premise of not influencing cutting fluid service performance
Improve cutting fluid rustless property, can large-scale industrial production, have a vast market foreground.
Better embodiment of the invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be without departing from the purpose of the present invention
Various changes can be made.There is no necessity and possibility to exhaust all the enbodiments.And it thus amplifies out apparent
Variation or variation be still in the protection scope of this invention.
Claims (10)
1. a kind of environmentally-friendly water-based rust preventive cutting fluid, which is characterized in that including below according to the raw material of parts by weight：45-90 parts of water,
0.1-0.7 parts of triethanolamine oleate, 0.2-1.8 parts of sodium alkyl sulfonate, 1-8 parts of polyethylene glycol, 0.2-1 parts of Sodium Polyacrylate, coconut palm
Sub- oleic acid diethyl amide 0.3-2.3 parts, 2-8 parts of antirust agent, 0.5-2.5 parts of laureth sodium sulfovinate, vegetable oil 2-7
Part, 0.1-0.7 parts of sulfonated oil；Wherein, the antirust agent by soybean oil, sodium methyl silicate, alkyl phosphate salt, dihydroxy methyl ether and
Benzotriazole is prepared.
2. environmentally-friendly water-based rust preventive cutting fluid according to claim 1, which is characterized in that including below according to parts by weight
Raw material：55-75 parts of water, 0.2-0.5 parts of triethanolamine oleate, 0.6-1.2 parts of sodium alkyl sulfonate, 3-6 parts of polyethylene glycol, polypropylene
Sour sodium 0.5-0.9 parts, 1-2 parts of coconut acid diethanolamide, 4-7 parts of antirust agent, 1-2 parts of laureth sodium sulfovinate, plant
3-6 parts of object oil, 0.3-0.6 parts of sulfonated oil.
3. environmentally-friendly water-based rust preventive cutting fluid according to claim 2, which is characterized in that including below according to parts by weight
Raw material：68 parts of water, 0.4 part of triethanolamine oleate, 1 part of sodium alkyl sulfonate, 5 parts of polyethylene glycol, 0.7 part of Sodium Polyacrylate, coconut
1.8 parts of oleic acid diethyl amide, 6 parts of antirust agent, 1.5 parts of laureth sodium sulfovinate, 5 parts of vegetable oil, 0.5 part of sulfonated oil.
4. environmentally-friendly water-based rust preventive cutting fluid according to claim 1 or 2 or 3, which is characterized in that the system of the antirust agent
Preparation Method is to weigh soybean oil, sodium methyl silicate and alkyl phosphate salt to be uniformly mixed, and then carries out mechanical stirring 20-40min,
It is slowly added to dihydroxy methyl ether and benzotriazole while stirring again, is sent into ultrasonic microwave composite reaction instrument at 30-40 DEG C
Carry out processing 6-16min, be cooled to room temperature to get.
5. environmentally-friendly water-based rust preventive cutting fluid according to claim 4, which is characterized in that the ultrasonic microwave combination is anti-
It is 12-28kHz, ultrasonic power 25-45W, microwave frequency 600-1000MHz that the treatment conditions of Ying Yi, which are ultrasonic frequency,
Microwave power is 25-45W.
6. environmentally-friendly water-based rust preventive cutting fluid according to claim 4, which is characterized in that the vegetable oil be palm fibre put oil,
One of rapeseed oil, cottonseed oil, coconut oil, rice bran oil, castor oil or a variety of combinations.
7. a kind of preparation method of the environmentally-friendly water-based rust preventive cutting fluid as described in claim 1-6 is any, which is characterized in that step
It is rapid as follows：
1）Water is weighed according to parts by weight to be fed through in double planetary power vacuum blender, is warming up to 40 DEG C, is distinguished while stirring
It is slowly added to triethanolamine oleate, sodium alkyl sulfonate and polyethylene glycol, mechanical stirring 10-20min is carried out, plant is then added
Oil carries out mechanical stirring 20-50min under vacuum conditions, obtains mixture A；
2）By step 1）Obtained in mixture A be fed through in container, according to parts by weight be added Sodium Polyacrylate, cocinic acid two
Glycollic amide and laureth sodium sulfovinate, keeping system temperature is 20-26 DEG C, carries out mechanical stirring 10-20min, obtains mixed
Close material B；
3）By step 2）Obtained in sequentially add antirust agent and sulfonated oil in mixture B, with the stirring speed of 200-400r/min
Rate carries out mechanical stirring 10-20min, obtains mixture C；
4）By step 3）Obtained in mixture C be sent into ultrasonic cell disruptor in, be ultrasonically treated at normal temperature, stand
20-50min, 100 mesh filtering to get.
8. the preparation method of environmentally-friendly water-based rust preventive cutting fluid according to claim 7, which is characterized in that step 4）In,
The supersonic frequency of the ultrasonic treatment is 10-20kHz；The ultrasonic power of the ultrasonic treatment is 400-800W.
9. the preparation method of environmentally-friendly water-based rust preventive cutting fluid according to claim 8, which is characterized in that step 4）In,
The time of the ultrasonic treatment is 15-35min.
10. a kind of use of environmentally-friendly water-based rust preventive cutting fluid as described in claim 1-6 is any in preparation cutting liquid product
On the way.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61149489A (en) * | 1984-12-25 | 1986-07-08 | Tatsuta Electric Wire & Cable Co Ltd | Corrosion inhibitor composition |
| CN104017636A (en) * | 2014-06-06 | 2014-09-03 | 清华大学 | Water soluble full-alloy metal grinding fluid |
| CN105296126A (en) * | 2015-12-02 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | Environment-friendly water-based antirust cutting fluid and preparation method thereof |
| CN105802702A (en) * | 2014-12-30 | 2016-07-27 | 比亚迪股份有限公司 | Metal working fluid composition, metal working fluid, preparation method and application thereof |
| CN107488494A (en) * | 2017-07-28 | 2017-12-19 | 清华大学天津高端装备研究院 | A kind of water base full synthetic aluminum alloy working fluid of dynamic corrosion inhibition type |
-
2018
- 2018-07-10 CN CN201810749220.2A patent/CN108913316B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61149489A (en) * | 1984-12-25 | 1986-07-08 | Tatsuta Electric Wire & Cable Co Ltd | Corrosion inhibitor composition |
| CN104017636A (en) * | 2014-06-06 | 2014-09-03 | 清华大学 | Water soluble full-alloy metal grinding fluid |
| CN105802702A (en) * | 2014-12-30 | 2016-07-27 | 比亚迪股份有限公司 | Metal working fluid composition, metal working fluid, preparation method and application thereof |
| CN105296126A (en) * | 2015-12-02 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | Environment-friendly water-based antirust cutting fluid and preparation method thereof |
| CN107488494A (en) * | 2017-07-28 | 2017-12-19 | 清华大学天津高端装备研究院 | A kind of water base full synthetic aluminum alloy working fluid of dynamic corrosion inhibition type |
Non-Patent Citations (1)
| Title |
|---|
| 陈国红: ""四合一"金属切削液的研制", 《河北化工》 * |
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