CN108911697A - A kind of production method of ship-and-galley tile - Google Patents

A kind of production method of ship-and-galley tile Download PDF

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Publication number
CN108911697A
CN108911697A CN201810828526.7A CN201810828526A CN108911697A CN 108911697 A CN108911697 A CN 108911697A CN 201810828526 A CN201810828526 A CN 201810828526A CN 108911697 A CN108911697 A CN 108911697A
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wear
glaze
resisting antiskid
ship
mixing
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谢宗宜
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Guangxi Chisheng Agricultural Technology Co Ltd
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Guangxi Chisheng Agricultural Technology Co Ltd
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Priority to CN201810828526.7A priority Critical patent/CN108911697A/en
Publication of CN108911697A publication Critical patent/CN108911697A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/24—Manufacture of porcelain or white ware
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The present invention provides a kind of production method of ship-and-galley tile, belongs to ceramic tile manufacturing field, this approach includes the following steps：Ingredient, ball milling, except iron sieving, stock tank is aging, spray drying, molding, drying, glazing, stamp, sintering and edging；The starved glaze is the mixing glaze of wear-resisting antiskid particle and cosmetic soil, and the mixing glaze is prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；Cosmetic soil glaze slip weight content is 60%-70% in the mixing glaze slip, and wear-resisting antiskid particle weight content is 30%-40%；The wear-resisting antiskid particle is made of wear-resisting antiskid particles one or more of in corundum, diamond dust, diamond, quartz sand, and the partial size of the wear-resisting antiskid particle is -150 mesh of 40 mesh；The temperature of the sintering is 1050 DEG C -1200 DEG C, and firing time is 45-90 minutes；The floor tile of this method production has good antiskid effect, and will not influence tile surface color effects.

Description

A kind of production method of ship-and-galley tile
Technical field
The present invention relates to ceramic tile manufacturing fields, and in particular to a kind of production method of ship-and-galley tile.
Background technique
With the development of economy with the raising of living standards of the people, building ground adnornment industry is increasingly taken seriously, is in It occupies in finishing and occupies major part.Floor decorative material is more in the market, and the three categories earth material of extensive utilization is wood at present Floor, stone material and ceramic tile, from the point of view of economy, practicability and dicoration etc., ceramic tile is beautiful with it, brief and easy to clean The features such as receive liking for the majority of consumers, in building such as exhibition center, hotel, supermarket, shopping center, meal The Room, gymnasium, swimming pool, the use of bathroom and residential houses are also more and more.But accompanying problem is that due to ground It is smooth cause some accidents that slip constantly to occur, with increasing for the event of slipping, the concern of the public and government department It is more and more, important indicator one of of the ceramic tile non-skid property as ceramic tile security performance evaluation.
Such as application No. is 201711306354.9 Chinese invention patent applications to disclose a kind of preparation of color brilliant anti-skid brick Method：Raw material is pressed into brick face with protrusion or smooth morph base through press, plain kiln is burnt, after surface is plasma treated, Protrusion is moulded on brick face using round cobblestone or macromolecule resin and the mixture of abrasion resistant particles, obtains the base of brick face protrusion Brick；By base brick be placed in in the consistent mold of its length and width, in base brick concave part spray on polymer resinous coat, in smooth table One layer of color crystal coating is printed in face, after the curing be complete, is sprayed at after modified epoxy and curing agent, diluent are mixed entire Brick face removes mold to get color brilliant anti-skid brick finished product after dry.Tile surface is made this method has bumps uneven Structure, improve coefficient of friction using this concaveconvex structure, although antiskid effect may be implemented, destroy the dress of floor tile Effect is adornd, while more demanding to processing method, increases the difficulty of floor tile processing.
Summary of the invention
Goal of the invention of the invention is, in view of the above-mentioned problems, a kind of production method of ship-and-galley tile is provided, this method production Floor tile there is good antiskid effect, and will not influence the ship-and-galley tile of tile surface color effects.
In order to achieve the above objectives, the technical scheme adopted by the invention is that：A kind of production method of ship-and-galley tile, including with Lower step：
(1) ingredient：By mud, sand, stone and auxiliary material, ingredient is carried out with feeder by process recipe；
(2) ball milling：Mud, sand, stone and the auxiliary material that ingredient is completed, to ball mill, pass through ball mill by Belt Conveying Rotation makes sand mud and ballstone rubs mutually, extruding, shock reach refinement；
(3) except iron is sieved：Slurry after ball milling removes the iron tramp and coarse granule of the inside by iron removing stick and sieve；
(4) stock tank is aging：Reach mixing and homogenizing for pouring into remove in rotten pond from the slurry that different ball mills is released；
(5) it is spray-dried：Heat exchange and steaming are carried out with high-temperature flue gas in spray drying tower by the aging slurry of stock tank Shampoo part, becomes moisture content in the graininess powder of 5-6%；
(6) it forms：Powder strikes out blocky adobe by brick machine；
(7) dry：Adobe of the moisture content in 5-6% is dried to moisture content in 1% drying below by roller belt drier Adobe；
(8) glazing：One layer of starved glaze is spooned on the surface of dry brick, the starved glaze is wear-resisting antiskid particle and cosmetic soil Glaze is mixed, the mixing glaze is prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；
(9) stamp：Certain pattern, decorative pattern are stamped on the adobe surface of glazing；
(10) it is sintered：Adobe after stamp is sent into sintering in high temperature kiln；
(11) edging：The semi-finished product come are burnt out of kiln, and final standard compliant finished product is reached by edging line.
Preferably, cosmetic soil glaze slip weight content is 60%-70% in the mixing glaze slip, and wear-resisting antiskid particle weight contains Amount is 30%-40%.
Preferably, the cosmetic soil glaze slip is prepared by cosmetic soil glaze, and the cosmetic soil glaze contains following weight The component of content：Si02:50%-53%, Al203:19%-21%, Fe203:0.1%-0.3%, CaO+Mg0:2.5%-3%, K20+Na20:5%-6.5%, Zn0:0.5%-2%, Ba0:7%-10%, Zr02:4%-8% and Ti02:0.1%-0.5%.
Preferably, the wear-resisting antiskid particle is by one or more of wear-resisting anti-in corundum, diamond dust, diamond, quartz sand Sliding particle composition, the partial size of the wear-resisting antiskid particle are -150 mesh of 40 mesh.
Preferably, each component of following weight content is contained in the wear-resisting antiskid particle：SiO2:54%-64%, AL203:22%-26%, Fe203:0-0.3%, Ca0:0.5%-1.5%, Mg0:1%-5%, K20:2%-6%, Na0:1- 3%, Zn0:0.5%-1.5%, Ba0:3%-5%, ZrO2:0-10%, CO2O3:0-5%, Pr6O11:0-5% and V205:0- 5%.
Preferably, the temperature of the sintering is 1050 DEG C -1200 DEG C, and firing time is 45-90 minutes.
Due to the adoption of the above technical scheme, the invention has the advantages that：Ship-and-galley tile of the invention, due to anti-skidding Grain is embedded in cosmetic soil glaze layer, is located under ceramic tile patterns printed layer, particle components, transparency all do not interfere with product figure Case color effects, while being not easy to be worn away or wipe off in practice, and since its particle diameter compares larger, make product table Face generates better antiskid effect.
Specific embodiment
Present invention will be further explained below with reference to specific examples, it should be understood that specific embodiment described herein is only To explain the present invention, it is not intended to limit the present invention.
Embodiment 1：
A kind of production method of ship-and-galley tile of the present embodiment, includes the following steps：
(1) ingredient：By mud, sand, stone and auxiliary material, ingredient is carried out with feeder by process recipe；
(2) ball milling：Mud, sand, stone and the auxiliary material that ingredient is completed, to ball mill, pass through ball mill by Belt Conveying Rotation makes sand mud and ballstone rubs mutually, extruding, shock reach refinement；
(3) except iron is sieved：Slurry after ball milling removes the iron tramp and coarse granule of the inside by iron removing stick and sieve；
(4) stock tank is aging：Reach mixing and homogenizing for pouring into remove in rotten pond from the slurry that different ball mills is released；
(5) it is spray-dried：Heat exchange and steaming are carried out with high-temperature flue gas in spray drying tower by the aging slurry of stock tank Shampoo part, becomes moisture content in the graininess powder of 5-6%；
(6) it forms：Powder strikes out blocky adobe by brick machine；
(7) dry：Adobe of the moisture content in 5-6% is dried to moisture content in 1% drying below by roller belt drier Adobe；
(8) glazing：One layer of starved glaze is spooned on the surface of dry brick, the starved glaze is wear-resisting antiskid particle and cosmetic soil Glaze is mixed, the mixing glaze is prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；The mixing glaze Cosmetic soil glaze slip weight content is 60% in slurry, and wear-resisting antiskid particle weight content is 40%；The cosmetic soil glaze slip is by making up Clay glaze material is prepared, and the cosmetic soil glaze contains the component of following weight content：Si02:53%, Al203:20%, Fe203: 0.2%, CaO+Mg0:3%, K20+Na20:6%, Zn0:0.5%, Ba0:10%, Zr02:7% and Ti02:0.3%；It is described resistance to Mill anti-slip particles are made of corundum, diamond dust, and the partial size of particle is 40 mesh, contain following weight in the wear-resisting antiskid particle The each component of content：SiO2:61%, AL203:22%, Fe203:0.1%, Ca0:1.3%, Mg0:1.5%, K20:2.2%, Na0:2.5%, Zn0:0.8%, Ba0:5%, ZrO2:1%, CO2O3:1.2%, Pr6O11:0.6% and V205:0.8%；
(9) stamp：Certain pattern, decorative pattern are stamped on the adobe surface of glazing；
(10) it is sintered：Adobe after stamp is sent into sintering in high temperature kiln, and the temperature of the sintering is 1050 DEG C, firing Time is 45 minutes；
(11) edging：The semi-finished product come are burnt out of kiln, and final standard compliant finished product is reached by edging line.
Embodiment 2：
(1) ingredient：By mud, sand, stone and auxiliary material, ingredient is carried out with feeder by process recipe；
(2) ball milling：Mud, sand, stone and the auxiliary material that ingredient is completed, to ball mill, pass through ball mill by Belt Conveying Rotation makes sand mud and ballstone rubs mutually, extruding, shock reach refinement；
(3) except iron is sieved：Slurry after ball milling removes the iron tramp and coarse granule of the inside by iron removing stick and sieve；
(4) stock tank is aging：Reach mixing and homogenizing for pouring into remove in rotten pond from the slurry that different ball mills is released；
(5) it is spray-dried：Heat exchange and steaming are carried out with high-temperature flue gas in spray drying tower by the aging slurry of stock tank Shampoo part, becomes moisture content in the graininess powder of 5-6%；
(6) it forms：Powder strikes out blocky adobe by brick machine；
(7) dry：Adobe of the moisture content in 5-6% is dried to moisture content in 1% drying below by roller belt drier Adobe；
(8) glazing：One layer of starved glaze is spooned on the surface of dry brick, the starved glaze is wear-resisting antiskid particle and cosmetic soil Glaze is mixed, the mixing glaze is prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；The mixing glaze Cosmetic soil glaze slip weight content is 65% in slurry, and wear-resisting antiskid particle weight content is 35%；The cosmetic soil glaze slip is by making up Clay glaze material is prepared, and the cosmetic soil glaze contains the component of following weight content：Si02:50%, Al203:21%, Fe203: 0.3%, CaO+Mg0:2.7%, K20+Na20:6.5%, Zn0:1%, Ba0:10%, Zr02:8% and Ti02:0.5%；It is described Wear-resisting antiskid particle is made of diamond, quartz sand, and the partial size of particle is 100 mesh, is contained such as in the wear-resisting antiskid particle The each component of lower weight content：SiO2:58%, AL203:24%, Fe203:0.3%, Ca0:1%, Mg0:2%, K20:3%, Na0:1%, Zn0:1.5%, Ba0:4.5%, ZrO2:2.5%, CO2O3:1%, Pr6O11:0.9% and V205:0.3%；
(9) stamp：Certain pattern, decorative pattern are stamped on the adobe surface of glazing；
(10) it is sintered：Adobe after stamp is sent into sintering in high temperature kiln, and the temperature of the sintering is 1100 DEG C, firing Time is 75 minutes；
(11) edging：The semi-finished product come are burnt out of kiln, and final standard compliant finished product is reached by edging line.
Embodiment 3：
(1) ingredient：By mud, sand, stone and auxiliary material, ingredient is carried out with feeder by process recipe；
(2) ball milling：Mud, sand, stone and the auxiliary material that ingredient is completed, to ball mill, pass through ball mill by Belt Conveying Rotation makes sand mud and ballstone rubs mutually, extruding, shock reach refinement；
(3) except iron is sieved：Slurry after ball milling removes the iron tramp and coarse granule of the inside by iron removing stick and sieve；
(4) stock tank is aging：Reach mixing and homogenizing for pouring into remove in rotten pond from the slurry that different ball mills is released；
(5) it is spray-dried：Heat exchange and steaming are carried out with high-temperature flue gas in spray drying tower by the aging slurry of stock tank Shampoo part, becomes moisture content in the graininess powder of 5-6%；
(6) it forms：Powder strikes out blocky adobe by brick machine；
(7) dry：Adobe of the moisture content in 5-6% is dried to moisture content in 1% drying below by roller belt drier Adobe；
(8) glazing：One layer of starved glaze is spooned on the surface of dry brick, the starved glaze is wear-resisting antiskid particle and cosmetic soil Glaze is mixed, the mixing glaze is prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；The mixing glaze Cosmetic soil glaze slip weight content is 70% in slurry, and wear-resisting antiskid particle weight content is 30%；The cosmetic soil glaze slip is by making up Clay glaze material is prepared, and the cosmetic soil glaze contains the component of following weight content：Si02:52%, Al203:20%, Fe203: 0.2%, CaO+Mg0:2.8%, K20+Na20:6.3%, Zn0:1.8%, Ba0:9.5%, Zr02:7% and Ti02:0.4%；Institute It states wear-resisting antiskid particle to be made of diamond dust, the partial size of particle is 150 mesh, contains following weight in the wear-resisting antiskid particle The each component of content：SiO2:55%, AL203:23%, Fe203:0.2%, Ca0:1%, Mg0:2%, K20:5%, Na0:2%, Zn0:1%, Ba0:3%, ZrO2:2.5%, CO2O3:0.3%, Pr6O11:2% and V205:3%；
(9) stamp：Certain pattern, decorative pattern are stamped on the adobe surface of glazing；
(10) it is sintered：Adobe after stamp is sent into sintering in high temperature kiln, and the temperature of the sintering is 1200 DEG C, firing Time is 90 minutes.
(11) edging：The semi-finished product come are burnt out of kiln, and final standard compliant finished product is reached by edging line.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to In the covered the scope of the patents of the present invention.

Claims (6)

1. a kind of production method of ship-and-galley tile, it is characterised in that：Include the following steps：
(1) ingredient：By mud, sand, stone and auxiliary material, ingredient is carried out with feeder by process recipe；
(2) ball milling：Mud, sand, stone and the auxiliary material that ingredient is completed, to ball mill, pass through the rotation of ball mill by Belt Conveying Sand mud and ballstone rubs mutually, extruding, shock is set to reach refinement；
(3) except iron is sieved：Slurry after ball milling removes the iron tramp and coarse granule of the inside by iron removing stick and sieve；
(4) stock tank is aging：Reach mixing and homogenizing for pouring into remove in rotten pond from the slurry that different ball mills is released；
(5) it is spray-dried：Heat exchange and evaporation water are carried out with high-temperature flue gas in spray drying tower by the aging slurry of stock tank Part, become moisture content in the graininess powder of 5-6%；
(6) it forms：Powder strikes out blocky adobe by brick machine；
(7) dry：Adobe of the moisture content in 5-6% is dried to moisture content in 1% dry brick below by roller belt drier；
(8) glazing：One layer of starved glaze is spooned on the surface of dry brick, the starved glaze is the mixing of wear-resisting antiskid particle and cosmetic soil Glaze, the mixing glaze are prepared by cosmetic soil glaze slip and the molecular mixing glaze slip of wear-resisting antiskid grain；
(9) stamp：Certain pattern, decorative pattern are stamped on the adobe surface of glazing；
(10) it is sintered：Adobe after stamp is sent into sintering in high temperature kiln；
(11) edging：The semi-finished product come are burnt out of kiln, and final standard compliant finished product is reached by edging line.
2. a kind of production method of ship-and-galley tile according to claim 1, it is characterised in that：It makes up in the mixing glaze slip It is 60%-70% that clay glaze, which starches weight content, and wear-resisting antiskid particle weight content is 30%-40%.
3. a kind of production method of ship-and-galley tile according to claim 2, it is characterised in that：The cosmetic soil glaze slip is by changing Adornment clay glaze material is prepared, and the cosmetic soil glaze contains the component of following weight content：Si02:50%-53%, Al203: 19%-21%, Fe203:0.1%-0.3%, CaO+Mg0:2.5%-3%, K20+Na20:5%-6.5%, Zn0:0.5%- 2%, Ba0:7%-10%, Zr02:4%-8% and Ti02:0.1%-0.5%.
4. a kind of production method of ship-and-galley tile according to claim 1, it is characterised in that：The wear-resisting antiskid particle by Corundum, diamond dust, diamond, one or more of wear-resisting antiskid particles compositions in quartz sand, the partial size of the wear-resisting antiskid particle For -150 mesh of 40 mesh.
5. a kind of production method of ship-and-galley tile according to claim 4, it is characterised in that：In the wear-resisting antiskid particle Each component containing following weight content：SiO2:54%-64%, AL203:22%-26%, Fe203:0-0.3%, Ca0: 0.5%-1.5%, Mg0:1%-5%, K20:2%-6%, Na0:1-3%, Zn0:0.5%-1.5%, Ba0:3%-5%, ZrO2:0-10%, CO2O3:0-5%, Pr6O11:0-5% and V205:0-5%.
6. a kind of production method of ship-and-galley tile according to claim 1, it is characterised in that：The temperature of the sintering is 1050 DEG C -1200 DEG C, firing time is 45-90 minutes.
CN201810828526.7A 2018-07-25 2018-07-25 A kind of production method of ship-and-galley tile Withdrawn CN108911697A (en)

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Publication number Priority date Publication date Assignee Title
CN110746204A (en) * 2019-03-13 2020-02-04 李长松 Marble ceramic tile with anti-skid layer and preparation method thereof
CN111172835A (en) * 2020-02-18 2020-05-19 深圳市科建建设集团有限公司 Manufacturing and mounting method of building energy-saving floor tile
IT202100028466A1 (en) * 2021-11-09 2023-05-09 Gruppo Concorde Spa METHOD FOR OBTAINING PORCELAIN STONEWARE TILES WITH NON-SLIP SURFACE

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CN110746204A (en) * 2019-03-13 2020-02-04 李长松 Marble ceramic tile with anti-skid layer and preparation method thereof
CN111172835A (en) * 2020-02-18 2020-05-19 深圳市科建建设集团有限公司 Manufacturing and mounting method of building energy-saving floor tile
IT202100028466A1 (en) * 2021-11-09 2023-05-09 Gruppo Concorde Spa METHOD FOR OBTAINING PORCELAIN STONEWARE TILES WITH NON-SLIP SURFACE
EP4177236A1 (en) * 2021-11-09 2023-05-10 Gruppo Concorde S.p.a. Method for obtaining porcelain stoneware tiles with anti-slip surface

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Application publication date: 20181130