CN108902137B - 一种可湿性粉剂专用助剂组合物 - Google Patents

一种可湿性粉剂专用助剂组合物 Download PDF

Info

Publication number
CN108902137B
CN108902137B CN201810829063.6A CN201810829063A CN108902137B CN 108902137 B CN108902137 B CN 108902137B CN 201810829063 A CN201810829063 A CN 201810829063A CN 108902137 B CN108902137 B CN 108902137B
Authority
CN
China
Prior art keywords
parts
wettable powder
acid diethanolamide
special auxiliary
active ingredients
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201810829063.6A
Other languages
English (en)
Other versions
CN108902137A (zh
Inventor
秦岭
吴晓嘉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yizhou Shanghai Chemical Technology Co ltd
Original Assignee
Yizhou Shanghai Chemical Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yizhou Shanghai Chemical Technology Co ltd filed Critical Yizhou Shanghai Chemical Technology Co ltd
Priority to CN201810829063.6A priority Critical patent/CN108902137B/zh
Publication of CN108902137A publication Critical patent/CN108902137A/zh
Application granted granted Critical
Publication of CN108902137B publication Critical patent/CN108902137B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A01N25/14—Powders or granules wettable
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明属于农药制剂领域，具体提供一种可用于可湿性粉剂的专用助剂组合物YZ‑01，由如下重量份的组成成分组成：椰子油脂肪酸二乙醇酰胺650110‑60份，壬基酚聚氧乙烯醚TX‑1010‑60份，十二烷基硫酸钠10‑40份，油酸二乙醇酰胺10‑30份，白炭黑10‑50份。本发明提供的专用助剂组合物YZ‑01可解决可湿性粉剂润湿性能差、悬浮率低的问题，可提高制剂的流动性、抗结块性，可增强活性成分的防治效果。

Description

一种可湿性粉剂专用助剂组合物
技术领域
本发明属于农药制剂领域，具体涉及一种可湿性粉剂专用助剂组合物 YZ-01。
背景技术
在农业病虫害防治过程中，目前大多使用的常规喷施农药药液，当药液喷洒到作物表面上时，仅有20-30％药液展铺于作物叶面，其它70-80％药液因展着、内吸性能较差形成大液滴滚落于田间，因而造成农药利用率，农药亩用量增加，病虫害防效低，污染环境等问题。
农药可湿性粉剂是农药制剂中历史悠久、技术比较成熟、使用方便的一种剂型,它是由农药原药、表面活性剂(润湿剂、分散剂等)、辅助剂(稳定剂、警戒色等)、载体和填料等组成并粉碎得很细的农药制剂。可湿性粉剂用水稀释成田间使用的浓度时,能够形成一种稳定的、可供喷雾的悬浮液。可湿性粉剂用水稀释后能在防治对象上达到较大的均匀覆盖。我国生产可湿性粉剂农药已有几十年的历史，但是可湿性粉剂农药结块、悬浮率低、润湿时间长的问题一直困扰着广大农药生产企业，多数厂家往往由于上述问题的存在使得农药的稳定性差，效果并不理想，药效发挥不好，浪费了原药及助剂，增加了农业生产成本。
因此急需开发一种增效助剂组合物以解决现有技术中可湿性粉剂存在的各种问题。
发明内容
本发明提供一种增效助剂组合物YZ-01，解决可湿性粉剂润湿性能差、悬浮率低的问题，可提高制剂的流动性、抗结块性，可增强活性成分的防治效果。
一种可湿性粉剂专用助剂组合物YZ-01，由如下重量份的组成成分组成：椰子油脂肪酸二乙醇酰胺6501 10-60份，壬基酚聚氧乙烯醚TX-10 10-60 份，十二烷基硫酸钠10-40份，油酸二乙醇酰胺10-30份，白炭黑10-50份。
本发明所述的可湿性粉剂专用助剂组合物YZ-01，优选的，椰子油脂肪酸二乙醇酰胺6501 20-50份，壬基酚聚氧乙烯醚TX-10 20-40份，十二烷基硫酸钠10-30份，油酸二乙醇酰胺10-20份，白炭黑20-50份。
一种可湿性粉剂，包含活性成分1-85％，专用助剂组合物YZ-01 1-20％，填料补足100％。
本发明所述的可湿性粉剂，所述的活性成分选为吡虫啉，噻虫嗪，吡蚜酮，阿维菌素，甲基硫菌灵，多菌灵，戊唑醇，三环唑，哒螨灵，百菌清，敌草隆，苯磺隆，苄嘧磺隆，烟嘧磺隆，乙草胺，唑草酮，莠去津，啶虫咪或甲维盐中等中的一种或多种。
本发明所述的可湿性粉剂，所述的填料选为高岭土、硅藻土、膨润土、凹凸棒土、淀粉、轻质碳酸钙等中的一种或多种。
与现有技术相比，本发明具有如下有益效果：
本发明筛选出了可用于可湿性粉剂的专用助剂YZ-01，解决可湿性粉剂润湿性能差、悬浮率低的问题，可提高制剂的流动性、抗结块性，可增强活性成分的防治效果。
具体实施方式
下面结合实施例对本发明的具体实施方式进行详细描述，但应当理解本发明的保护范围并不受具体实施方式的限制。
实施例1助剂配方刷选
采用可湿性粉剂制备中常见的助剂进行组合复配
表1 助剂配方
Figure BDA0001743135640000031
表2 吡虫啉可湿性粉剂配方
Figure BDA0001743135640000032
Figure BDA0001743135640000041
可湿性粉剂制备方法：按配方各成分的质量分数称量原药、专用助剂、填料先进行预混合，再用超微气流粉碎机进行超微粉碎，过45μm试验筛，最后收集得到产品。
可湿性粉剂制剂性能测定方法：按照GB/T 5451-2001农药可湿性粉剂润湿性测定方法进行测定润湿时间，按照GB/T14825-2006农药悬浮率测定方法测其悬浮率。
表3 可湿性粉剂性能参数测定
悬浮率％ 润湿时间/s 外观
Z01 91 20 疏松粉末
Z02 69 90 团块
Z03 74 86 团块
Z04 70 70 疏松粉末
Z05 84 59 疏松粉末
Z06 81 64 疏松粉末
由表3可知，不同助剂的组合对可湿性粉剂的悬浮率、润湿率以及外观有较大的影响，Z01助剂组合可有效提高可湿性粉剂的润湿性，悬浮率；其润湿时间仅为20s，悬浮率为91％。
实施例2增效助剂配方
配方1：椰子油脂肪酸二乙醇酰胺6501 10份，壬基酚聚氧乙烯醚TX-10 20份，十二烷基硫酸钠10份，油酸二乙醇酰胺30份，白炭黑25份。
配方2：椰子油脂肪酸二乙醇酰胺6501 40份，壬基酚聚氧乙烯醚TX-10 10份，十二烷基硫酸钠30份，油酸二乙醇酰胺10份，白炭黑10份。
配方3：椰子油脂肪酸二乙醇酰胺6501 60份，壬基酚聚氧乙烯醚TX-10 30份，十二烷基硫酸钠15份，油酸二乙醇酰胺25份，白炭黑50份。
配方4：椰子油脂肪酸二乙醇酰胺6501 30份，壬基酚聚氧乙烯醚TX-10 45份，十二烷基硫酸钠25份，油酸二乙醇酰胺15份，白炭黑35份。
配方5：椰子油脂肪酸二乙醇酰胺6501 20份，壬基酚聚氧乙烯醚TX-10 10份，十二烷基硫酸钠15份，油酸二乙醇酰胺15份，白炭黑15份。
配方6：椰子油脂肪酸二乙醇酰胺6501 15份，壬基酚聚氧乙烯醚TX-10 30份，十二烷基硫酸钠10份，油酸二乙醇酰胺25份，白炭黑25份。
实施例3可湿性粉剂配方
表4 不同活性成分的可湿性粉剂配方
Figure BDA0001743135640000051
Figure BDA0001743135640000061
实施例4可湿性粉剂对稻飞虱的田间防效
测试方法：参照GB/T 17980.4-2000农药田间药效试验准则(一)杀虫剂防治水稻飞虱方法进行测定。
表5 不同配方可湿性粉剂对稻飞虱的田间防效
Figure BDA0001743135640000062
由表5可知，本发明提供的专用助剂组合物YZ-01可提高活性成分杀虫效果。
实施例5 可湿性粉剂对纹枯病的田间防效
测试方法：参照GB/T 17980.20-2000农药田间药效试验准则(一)杀菌剂防治水稻纹枯病的方法进行测定
表6 不同配方可湿性粉剂对纹枯病的田间防效
Figure BDA0001743135640000063
Figure BDA0001743135640000071
由表6可知，本发明提供的专用助剂组合物YZ-01可提高活性成分杀菌效果。
实施例6 可湿性粉剂对水稻田杂草的田间防效
参照GB/T 17980.40-2000农药田间药效试验准则(一)除草剂防治水稻田杂草方法进行测定，防除对象阔叶杂草。
表7 不同配方可湿性粉剂对杂草的田间防效
Figure BDA0001743135640000072
由表7可知，本发明提供的专用助剂组合物YZ-01可提高活性成分的除草效果。
上面结合实施例对本发明做了进一步的叙述，但本发明并不限于上述实施方式，在本领域的普通技术人员所具备的知识范围内，还可以在不脱离本发明宗旨的前提下做出各种变化。

Claims (2)

1.一种可湿性粉剂，其特征在于，包含活性成分1-85％，专用助剂组合物YZ-01 1-20％，填料补足100％; 所述专用助剂组合物YZ-01由 如下重量份的组成成分组成：椰子油脂肪酸二乙醇酰胺6501 20-50份，壬基酚聚氧乙烯醚TX-10 20-40份，十二烷基硫酸钠10-30份，油酸二乙醇酰胺10-20份，白炭黑20-50份; 所述的活性成分选为吡虫啉，吡蚜酮，甲基硫菌灵，百菌清，烟嘧磺隆，乙草胺 中的一种或多种。
2.根据权利要求1所述的可湿性粉剂，其特征在于，所述的填料选为高岭土、硅藻土、膨润土、凹凸棒土、淀粉、轻质碳酸钙中的一种或多种。
CN201810829063.6A 2018-07-25 2018-07-25 一种可湿性粉剂专用助剂组合物 Expired - Fee Related CN108902137B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810829063.6A CN108902137B (zh) 2018-07-25 2018-07-25 一种可湿性粉剂专用助剂组合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810829063.6A CN108902137B (zh) 2018-07-25 2018-07-25 一种可湿性粉剂专用助剂组合物

Publications (2)

Publication Number Publication Date
CN108902137A CN108902137A (zh) 2018-11-30
CN108902137B true CN108902137B (zh) 2021-01-29

Family

ID=64416448

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810829063.6A Expired - Fee Related CN108902137B (zh) 2018-07-25 2018-07-25 一种可湿性粉剂专用助剂组合物

Country Status (1)

Country Link
CN (1) CN108902137B (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108902138B (zh) * 2018-07-25 2021-01-29 薏舟（上海）化工科技有限公司 一种可用于可湿性粉剂的专用助剂组合物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1121768A (zh) * 1995-08-07 1996-05-08 深圳农业科学研究中心果树技术应用研究所 杀螨利果
CN102396524A (zh) * 2010-09-14 2012-04-04 王庭林 气雾杀爬虫剂
CN105532667A (zh) * 2016-02-26 2016-05-04 江苏丰山集团股份有限公司 一种炔草酯可湿性粉剂及其制备方法
CN106386793A (zh) * 2016-09-07 2017-02-15 马鞍山纽泽科技服务有限公司 一种高效农药助剂
CN107372491A (zh) * 2017-08-15 2017-11-24 马鞍山中粮生物化学有限公司 一种水稻专用杀虫剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9578874B2 (en) * 2012-07-12 2017-02-28 Adjuvants Unlimited, LLC Methods and compositions for reducing or inhibiting spray drift and driftable fines
JP6324322B2 (ja) * 2013-08-09 2018-05-16 株式会社クラレ フィルム
CN107889827A (zh) * 2017-10-25 2018-04-10 江苏腾龙生物药业有限公司 一种50%噻虫胺可湿性粉剂
CN108902138B (zh) * 2018-07-25 2021-01-29 薏舟（上海）化工科技有限公司 一种可用于可湿性粉剂的专用助剂组合物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1121768A (zh) * 1995-08-07 1996-05-08 深圳农业科学研究中心果树技术应用研究所 杀螨利果
CN102396524A (zh) * 2010-09-14 2012-04-04 王庭林 气雾杀爬虫剂
CN105532667A (zh) * 2016-02-26 2016-05-04 江苏丰山集团股份有限公司 一种炔草酯可湿性粉剂及其制备方法
CN106386793A (zh) * 2016-09-07 2017-02-15 马鞍山纽泽科技服务有限公司 一种高效农药助剂
CN107372491A (zh) * 2017-08-15 2017-11-24 马鞍山中粮生物化学有限公司 一种水稻专用杀虫剂及其制备方法

Also Published As

Publication number Publication date
CN108902137A (zh) 2018-11-30

Similar Documents

Publication Publication Date Title
BR112020022770A2 (pt) composição de suspensão, composição granular, processos de preparação da composição e método para melhorar a saúde ou o rendimento das plantas
CN108902138B (zh) 一种可用于可湿性粉剂的专用助剂组合物
CN107318873B (zh) 一种含有甲基二磺隆和双氟磺草胺的除草组合物
CN103081937A (zh) 一种丙草胺与吡嘧磺隆的复配除草组合物及其颗粒剂
CN108902137B (zh) 一种可湿性粉剂专用助剂组合物
CN104430450A (zh) 一种氟酮磺草胺和吡嘧磺隆的除草组合物
CN106508949A (zh) 含有吡唑醚菌酯、噻呋酰胺和呋虫胺的复配种衣剂及应用
WO2020078426A1 (zh) 一种杀菌组合物及其应用
CN104273156B (zh) 一种小麦田除草剂组合物
MX2012015050A (es) Mezclas nematicidas para usarse en caña de azucar.
CN104738046A (zh) 含有吡啶喹唑啉和氯氟氰虫酰胺的杀虫组合物
CN107156163A (zh) 一种甲基二磺隆和双氟磺草胺复配可分散油悬浮剂及其制备方法
CN107232211A (zh) 一种五氟磺草胺和噁唑酰草胺复配可分散油悬浮剂及其制备方法
CN111226953A (zh) 一种含有丙炔噁草酮和西草净的除草组合物
CN102613180B (zh) 除草组合物
CN104798800A (zh) 一种玉米苗后除草组合物
CN104957131A (zh) 一种苯磺隆可溶性水份散粒剂及其制备方法
KR0149743B1 (ko) 농약 수성현탁 농축액 및 이의 제조방법
CN104351215A (zh) 一种用于马铃薯田的除草剂
RU2400068C1 (ru) Гербицидный состав и выпускная форма гербицидного состава
CN107027801A (zh) 一种溴氰虫酰胺和呋虫胺复配可分散油悬浮剂及其制备方法
CN111226954A (zh) 除草组合物及其应用
CN112021312B (zh) 一种包含氨氟乐灵和甲氧咪草烟的除草组合物
JP4280022B2 (ja) 顆粒状水和剤
CN107751226B (zh) 一种含哒草特和氟噻草胺的除草剂组合物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20210129

Termination date: 20210725