CN108892495A - A kind of clay granular materials and preparation method thereof that can generate far infrared - Google Patents
A kind of clay granular materials and preparation method thereof that can generate far infrared Download PDFInfo
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Abstract
The invention discloses a kind of clay granular materials that can generate far infrared, are made from the following raw materials in parts by weight：37~47 parts of silica, 10~20 parts of aluminium oxide, 0.1~0.9 part of graphene, 10~12 parts of medical stone natural crystal, 3~4 parts of boron nitride, 3~4 parts of titanium oxide, 8~11 parts of zirconium oxide, 12~15 parts of magnesia, 1~2 part of active catalyst.The invention also discloses the preparation methods of above-mentioned clay granular materials.For manufactured goods of the present invention through detecting, far infrared all-wave length integrated emissivity is 91.5~99.2%, and the far infrared that release wave-length coverage is 2~18 μm, radiation peak wavelength range is 8~14 μm, and monochromatic emissivity is 90~98%.8~14 μm of frequencies of far infrared peak value are identical as the hydrone vibration frequency in biological cell, are easily absorbed, so that radiant heat energy activating cell tissue from inside to outside, has significant health-care physiotherapeutic effect.
Description
Technical field
The present invention relates to china clay material technical field, specifically a kind of clay granular materials that can generate far infrared and its system
Preparation Method.
Background technique
IR Radiation Ceramic Materials are a kind of novel optical-thermal conversion materials, are obtained in many fields such as household electrical appliances, medical treatment
To being widely applied.Infrared ceramic material be one kind with carbide, oxide, nitride etc. for raw material, using ceramic powder
Processing technology is prepared, and has the ceramic powder material compared with high radiant rate and radiation intensity in far infrared band.It is common at present
Far-infrared radiation ceramic mainly include carbonization silicon systems, the black such as iron-manganese-nickel-cobalt-copper system, negative ion powder or dark far infrared
The white far-infrared radiation ceramic such as radiation ceramic and oxidation zirconium, Al-Si-Mg-zinc-titanium-rare earth system.But present formula and
Method for making realizes that the emissivity of far infrared is to be improved, and the ceramic material application processed is inflexible.
Summary of the invention
The purpose of the present invention is to overcome the deficiency in the prior art, adapts to realistic development, and providing a kind of can generate far infrared
Clay granular materials and preparation method thereof.
A kind of clay granular materials that can generate far infrared of the present invention, is made from the following raw materials in parts by weight：Two
37~47 parts of silica, 10~20 parts of aluminium oxide, 0.1~0.9 part of graphene, 10~12 parts of medical stone natural crystal, boron nitride 3
~4 parts, 3~4 parts of titanium oxide, 8~11 parts of zirconium oxide, 12~15 parts of magnesia, 1~2 part of active catalyst.
Preferably, it is made from the following raw materials in parts by weight：42 parts of silica, 15 parts of aluminium oxide, 0.5 part of graphene, wheat
11 parts of meal stone natural crystal, 3.5 parts of boron nitride, 3.5 parts of titanium oxide, 9.5 parts of zirconium oxide, 13.5 parts of magnesia, active catalyst
1.5 part.
Preferably, the active catalyst is rare-earth oxide：In lanthana, praseodymium oxide, rubidium oxide or cerium oxide
One kind.
It is highly preferred that the active catalyst is cerium oxide.
The invention also discloses the preparation methods of above-mentioned clay granular materials, include the following steps：
(1) by the silica of the parts by weight, aluminium oxide, graphene, medical stone natural crystal, boron nitride, titanium oxide,
Superfine powder is respectively prepared in zirconium oxide, magnesia and active catalyst, is uniformly mixed, obtains mixed powder；
(2) mixed powder is added in the aqueous solution of polyvinyl alcohol and is infiltrated, obtain mixture A；
Wherein, the weight ratio of the polyvinyl alcohol and the mixed powder is 3~6:20；
(3) sticky kaolin is added in the mixture A, is uniformly mixed, obtains mixture B；
Wherein, the weight ratio of the sticky kaolin and the mixture A are 5~7:20；
(4) the mixture B is carried out dehydrating, obtains dehydration product；
(5) dehydration product is dried, then high temperature constant temperature is calcined.
Further, the sintering temperature of step (5) the high temperature calcining at constant temperature is 1030~1050 DEG C, constant temperature time 30
Minute or more.
The invention also discloses the applications of above-mentioned clay granular materials, are applied on physiotherapy couch or electric heating product, to
Improve microcirculation in human body, improve the immunity of the human body.
The advantages and positive effects of the present invention：
It can be generated when graphene material, room temperature and high temperature is added in the present invention on the basis of traditional far-infrared ceramic is formulated
Far infrared, and 8~14 μm of monochromatic emissivities of far infrared band that far infrared all-wave length integrated emissivity and human body most easily absorb
It is substantially improved；Medical stone natural crystal is additionally incorporated, the granular absorption impurity finally burnt out made and purification air
Effect significantly improve；The barium monoxide in traditional ceramics formula is removed, the content of harmful substance is reduced；The clay particle of firing
Size is flexible, various informative, convenient for applying in a variety of medical treatment and health-care physical therapy product；Powder is increased using ultra-fine ball mill grinding method
Surface area per unit volume product, reduces sintering temperature, improves the far infrared radiation ability of clay particle.
For manufactured goods of the present invention through detecting, far infrared all-wave length integrated emissivity is 91.5~99.2%, discharges far infrared,
Its far infrared wave-length coverage is 2~18 μm, and radiation peak wavelength range is 8~14 μm, and monochromatic emissivity is 90~98%.It is remote red
Outside line have stronger permeability, it can penetrate into human body subcutaneously about 2~6cm locate, 8~14 μm of frequencies of far infrared peak value and
Hydrone vibration frequency in biological cell is identical, is easily absorbed, thus radiant heat energy activating cell tissue from inside to outside, tool
There is significant health-care physiotherapeutic effect.By the products application on medical rehabilitation and health-related product after, it is big to the beneficial effect of human body
It is big to be promoted.
Clay granular materials preparation process of the present invention is simple, can be applied on physiotherapy couch or electric heating product, and tool rises
The advantages that warm temperature not poly- rapidly, absolutely not electromagenetic wave radiation, high thermal conversion efficiency largely discharges far infrared, while people can be improved
Body microcirculation improves the immunity of the human body.
Specific embodiment
It elaborates below to specific embodiments of the present invention.
Embodiment 1
A kind of clay granular materials that can generate far infrared, is made from the following raw materials in parts by weight：42 parts of silica, oxygen
15 parts of aluminium of change, 0.5 part of graphene, 11 parts of medical stone natural crystal, 3.5 parts of boron nitride, 3.5 parts of titanium oxide, 9.5 parts of zirconium oxide,
13.5 parts of magnesia, 1.5 parts of active catalyst-cerium oxide；
The preparation method of above-mentioned clay granular materials, includes the following steps：
(1) by the silica of the parts by weight, aluminium oxide, graphene, medical stone natural crystal, boron nitride, titanium oxide,
Superfine powder is respectively prepared in zirconium oxide, magnesia and active catalyst, is uniformly mixed, obtains mixed powder；
(2) mixed powder is added in the aqueous solution of polyvinyl alcohol and is infiltrated, obtain mixture A；
Wherein, the weight ratio of the polyvinyl alcohol and the mixed powder is 2:10；
(3) sticky kaolin is added in the mixture A, is uniformly mixed, obtains mixture B；
Wherein, the weight ratio of the sticky kaolin and the mixture A are 3:10；
(4) the mixture B is carried out dehydrating, obtains dehydration product；
(5) dehydration product is dried, then high temperature constant temperature is calcined, and sintering temperature is 1040 DEG C, constant temperature time
It is 1.5 hours.
Embodiment 2
A kind of clay granular materials that can generate far infrared, is made from the following raw materials in parts by weight：37 parts of silica, oxygen
10 parts of aluminium of change, 0.1 part of graphene, 10 parts of medical stone natural crystal, 3 parts of boron nitride, 3 parts of titanium oxide, 8 parts of zirconium oxide, magnesia
12 parts, 1 part of active catalyst-lanthana.
The preparation method of above-mentioned clay granular materials, includes the following steps：
(1) by the silica of the parts by weight, aluminium oxide, graphene, medical stone natural crystal, boron nitride, titanium oxide,
Superfine powder is respectively prepared in zirconium oxide, magnesia and active catalyst, is uniformly mixed, obtains mixed powder；
(2) mixed powder is added in the aqueous solution of polyvinyl alcohol and is infiltrated, obtain mixture A；
Wherein, the weight ratio of the polyvinyl alcohol and the mixed powder is 3:20；
(3) sticky kaolin is added in the mixture A, is uniformly mixed, obtains mixture B；
Wherein, the weight ratio of the sticky kaolin and the mixture A are 5:20；
(4) the mixture B is carried out dehydrating, obtains dehydration product；
(5) dehydration product is dried, then high temperature constant temperature is calcined, and sintering temperature is 1030 DEG C, constant temperature time
It is 45 minutes.
Embodiment 3
A kind of clay granular materials that can generate far infrared, is made from the following raw materials in parts by weight：47 parts of silica, oxygen
20 parts of aluminium of change, 0.9 part of graphene, 12 parts of medical stone natural crystal, 4 parts of boron nitride, 4 parts of titanium oxide, 11 parts of zirconium oxide, magnesia
15 parts, 2 parts of active catalyst-rubidium oxide.
The preparation method of above-mentioned clay granular materials, includes the following steps：
(1) by the silica of the parts by weight, aluminium oxide, graphene, medical stone natural crystal, boron nitride, titanium oxide,
Superfine powder is respectively prepared in zirconium oxide, magnesia and active catalyst, is uniformly mixed, obtains mixed powder；
(2) mixed powder is added in the aqueous solution of polyvinyl alcohol and is infiltrated, obtain mixture A；
Wherein, the weight ratio of the polyvinyl alcohol and the mixed powder is 3:10；
(3) sticky kaolin is added in the mixture A, is uniformly mixed, obtains mixture B；
Wherein, the weight ratio of the sticky kaolin and the mixture A are 7:20；
(4) the mixture B is carried out dehydrating, obtains dehydration product；
(5) dehydration product is dried, then high temperature constant temperature is calcined, and sintering temperature is 1050 DEG C, constant temperature time
It is 2 hours.
Comparative example 1
Difference from example 1 is that：Not containing graphene, medical stone natural crystal.
As seen from the above table, the far infrared all-wave length integrated emissivity of clay granular materials prepared by the present invention and human body are most easy
8~14 μm of monochromatic emissivities of far infrared band of absorption are substantially improved；Air flux is 1495~1552L/ (m2*h) display
Excellent permeability.
Comparative example 2
Difference from example 1 is that：Active catalyst is alkaline earth oxide-calcium oxide.
As seen from the above table, the far infrared all-wave length integrated emissivity of clay granular materials prepared by the present invention and human body are most easy
8~14 μm of monochromatic emissivities of far infrared band of absorption are substantially improved；Resistivity is that 268~268 Ω/sq shows excellent lead
Hot heat resistance keeps electrical property more stable, and permanent normal use electric conductor power is unattenuated, and heating is not poly- warm rapidly, absolutely not electric
Electromagnetic wave radiation has many advantages, such as that high thermal conversion efficiency largely discharges far infrared, is applied on physiotherapy couch or electric heating product, uses
To improve microcirculation in human body, improve the immunity of the human body.
Comparative example 3
Difference from example 1 is that：The mixed powder is added in polyvinylether aqueous solution and is infiltrated.
As seen from the above table, the far infrared all-wave length integrated emissivity of clay granular materials prepared by the present invention and human body are most easy
8~14 μm of monochromatic emissivities of far infrared band of absorption are substantially improved；Clay particle size is 8.2~8.7 μm, material property
Stablize.
Above-described embodiment is only more excellent embodiment of the invention, is implemented according to the technical essence of the invention to above
Any simple modification, modification and the alternate variation that example is made, belong in the range of technical solution of the present invention.
Claims (7)
1. a kind of clay granular materials that can generate far infrared, which is characterized in that be made from the following raw materials in parts by weight：Titanium dioxide
37~47 parts of silicon, 10~20 parts of aluminium oxide, 0.1~0.9 part of graphene, 10~12 parts of medical stone natural crystal, boron nitride 3~4
Part, 3~4 parts of titanium oxide, 8~11 parts of zirconium oxide, 12~15 parts of magnesia, 1~2 part of active catalyst.
2. a kind of clay granular materials that can generate far infrared according to claim 1, which is characterized in that by following weight
The raw material of part is made：42 parts of silica, 15 parts of aluminium oxide, 0.5 part of graphene, 11 parts of medical stone natural crystal, boron nitride 3.5
Part, 3.5 parts of titanium oxide, 9.5 parts of zirconium oxide, 13.5 parts of magnesia, 1.5 parts of active catalyst.
3. a kind of clay granular materials that can generate far infrared according to claim 1, which is characterized in that the activity is urged
Agent is rare-earth oxide：One of lanthana, praseodymium oxide, rubidium oxide or cerium oxide.
4. a kind of clay granular materials that can generate far infrared according to claim 2, which is characterized in that the activity is urged
Agent is cerium oxide.
5. a kind of preparation method of clay granular materials that can generate far infrared as described in Claims 1 to 4 any one,
It is characterized in that, includes the following steps：
(1) by the silica of the parts by weight, aluminium oxide, graphene, medical stone natural crystal, boron nitride, titanium oxide, oxidation
Superfine powder is respectively prepared in zirconium, magnesia and active catalyst, is uniformly mixed, obtains mixed powder；
(2) mixed powder is added in the aqueous solution of polyvinyl alcohol and is infiltrated, obtain mixture A；
Wherein, the weight ratio of the polyvinyl alcohol and the mixed powder is 3~6:20；
(3) sticky kaolin is added in the mixture A, is uniformly mixed, obtains mixture B；
Wherein, the weight ratio of the sticky kaolin and the mixture A are 5~7:20；
(4) the mixture B is carried out dehydrating, obtains dehydration product；
(5) dehydration product is dried, then high temperature constant temperature is calcined.
6. a kind of preparation method of clay granular materials that can generate far infrared according to claim 5, which is characterized in that
The sintering temperature of step (5) the high temperature calcining at constant temperature is 1030~1050 DEG C, and constant temperature time is 30 minutes or more.
7. a kind of application of clay granular materials that can generate far infrared as described in Claims 1 to 4 any one, feature
It is, is applied on physiotherapy couch or electric heating product, to improve microcirculation in human body, improve the immunity of the human body.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109626540A (en) * | 2018-12-29 | 2019-04-16 | 福建金源泉科技发展有限公司 | A kind of minerals sustained-release microspheres and device with service life prompting function |
| CN110436904A (en) * | 2019-08-22 | 2019-11-12 | 陕西新容康医疗器械有限公司 | A kind of anion functional clay particle and preparation method thereof |
| CN110721414A (en) * | 2019-11-19 | 2020-01-24 | 冼光 | Rare earth material capable of continuously emitting far infrared rays and preparation method thereof |
| CN111253146A (en) * | 2020-01-21 | 2020-06-09 | 江南大学 | Medium-far infrared ceramic powder and preparation method thereof |
| CN111423224A (en) * | 2020-04-17 | 2020-07-17 | 汪平南 | Red interior line ceramic material, ceramic product, preparation method and application thereof |
| CN111620670A (en) * | 2020-06-23 | 2020-09-04 | 陕西新容康医疗器械有限公司 | Argil particle material capable of generating terahertz waves and preparation method thereof |
| CN112142451A (en) * | 2020-09-27 | 2020-12-29 | 陈彩霞 | Antibacterial environment-friendly domestic ceramic and preparation method thereof |
| CN112225549A (en) * | 2020-08-25 | 2021-01-15 | 深圳京鲁计算科学应用研究院 | Bionic far infrared ceramic powder material and preparation method thereof |
| CN113174750A (en) * | 2021-04-21 | 2021-07-27 | 罗莱生活科技股份有限公司 | Far infrared ceramic powder and preparation method and application thereof |
| CN113603468A (en) * | 2021-06-25 | 2021-11-05 | 北京中和澄明环境科技有限公司 | Composition of multi-element high-efficiency far infrared mineral base material and its manufacturing method |
| CN113893460A (en) * | 2021-07-19 | 2022-01-07 | 秦琳 | Magnetic far infrared physiotherapy bag for prostate and manufacturing method |
| CN117210196A (en) * | 2023-08-01 | 2023-12-12 | 佛山松和宏量健康科技有限公司 | Material capable of stably emitting far infrared rays and negative ions and application thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HK1060344A1 (en) * | 2002-07-23 | 2004-08-06 | Firbest Co Ltd | Far infrared radiation emitting material |
| CN103641462A (en) * | 2013-12-13 | 2014-03-19 | 卢烨 | Preparation method of far infrared ceramic material |
| CN103755329A (en) * | 2013-12-13 | 2014-04-30 | 吴冰心 | Far-infrared ceramic material used for manufacturing of boiler body and preparation method thereof |
| CN105244117A (en) * | 2015-09-29 | 2016-01-13 | 无锡同创石墨烯应用科技有限公司 | Preparation method of graphene-modified reinforced far infrared conductive paste |
| CN105645899A (en) * | 2016-01-23 | 2016-06-08 | 王秋芹 | Graphene oxide silicon based far infrared heating coating and preparation method thereof |
| CN106362294A (en) * | 2016-08-31 | 2017-02-01 | 青岛大学 | Preparation method of graphene-based multifunctional physiotherapy magnet |
| CN206420028U (en) * | 2017-01-05 | 2017-08-18 | 肖议 | A kind of electric heating porcelain plate based on graphene technology is drawn |
| CN107541207A (en) * | 2017-05-08 | 2018-01-05 | 墨烯材料科技有限公司 | A kind of high IR emissivity graphene/MnO2The preparation method of porous material |
| KR20180013044A (en) * | 2016-07-28 | 2018-02-07 | (주)싸이언스텐 | Functional material and articles comprising the material |
-
2018
- 2018-08-08 CN CN201810898565.4A patent/CN108892495A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HK1060344A1 (en) * | 2002-07-23 | 2004-08-06 | Firbest Co Ltd | Far infrared radiation emitting material |
| CN103641462A (en) * | 2013-12-13 | 2014-03-19 | 卢烨 | Preparation method of far infrared ceramic material |
| CN103755329A (en) * | 2013-12-13 | 2014-04-30 | 吴冰心 | Far-infrared ceramic material used for manufacturing of boiler body and preparation method thereof |
| CN105244117A (en) * | 2015-09-29 | 2016-01-13 | 无锡同创石墨烯应用科技有限公司 | Preparation method of graphene-modified reinforced far infrared conductive paste |
| CN105645899A (en) * | 2016-01-23 | 2016-06-08 | 王秋芹 | Graphene oxide silicon based far infrared heating coating and preparation method thereof |
| KR20180013044A (en) * | 2016-07-28 | 2018-02-07 | (주)싸이언스텐 | Functional material and articles comprising the material |
| CN106362294A (en) * | 2016-08-31 | 2017-02-01 | 青岛大学 | Preparation method of graphene-based multifunctional physiotherapy magnet |
| CN206420028U (en) * | 2017-01-05 | 2017-08-18 | 肖议 | A kind of electric heating porcelain plate based on graphene technology is drawn |
| CN107541207A (en) * | 2017-05-08 | 2018-01-05 | 墨烯材料科技有限公司 | A kind of high IR emissivity graphene/MnO2The preparation method of porous material |
Non-Patent Citations (5)
| Title |
|---|
| 中国大百科全书总编辑委员会编: "《中国大百科全书 化工》", 30 September 2002, 中国大百科全书出版社 * |
| 周张健: "《无机非金属材料工艺学》", 31 January 2010, 中国轻工业出版社 * |
| 商平 等: "《环境矿物资源》", 31 January 2008, 化学工业出版社 * |
| 曾宇: "红外辐射电热技术及其在建筑供暖领域的应用", 《全国第十六届红外加热暨红外医学发展研讨会论文及论文摘要集》 * |
| 王冬利: "《电力需求侧管理实用技术》", 31 July 2005, 中国电力出版社 * |
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| CN109626540B (en) * | 2018-12-29 | 2023-10-20 | 福建金源泉科技发展有限公司 | Mineral substance slow release ball and device with life-span reminding function |
| CN109626540A (en) * | 2018-12-29 | 2019-04-16 | 福建金源泉科技发展有限公司 | A kind of minerals sustained-release microspheres and device with service life prompting function |
| CN110436904A (en) * | 2019-08-22 | 2019-11-12 | 陕西新容康医疗器械有限公司 | A kind of anion functional clay particle and preparation method thereof |
| CN110721414A (en) * | 2019-11-19 | 2020-01-24 | 冼光 | Rare earth material capable of continuously emitting far infrared rays and preparation method thereof |
| CN111253146A (en) * | 2020-01-21 | 2020-06-09 | 江南大学 | Medium-far infrared ceramic powder and preparation method thereof |
| CN111423224A (en) * | 2020-04-17 | 2020-07-17 | 汪平南 | Red interior line ceramic material, ceramic product, preparation method and application thereof |
| CN111620670A (en) * | 2020-06-23 | 2020-09-04 | 陕西新容康医疗器械有限公司 | Argil particle material capable of generating terahertz waves and preparation method thereof |
| CN112225549A (en) * | 2020-08-25 | 2021-01-15 | 深圳京鲁计算科学应用研究院 | Bionic far infrared ceramic powder material and preparation method thereof |
| CN112142451A (en) * | 2020-09-27 | 2020-12-29 | 陈彩霞 | Antibacterial environment-friendly domestic ceramic and preparation method thereof |
| CN113174750A (en) * | 2021-04-21 | 2021-07-27 | 罗莱生活科技股份有限公司 | Far infrared ceramic powder and preparation method and application thereof |
| CN113603468A (en) * | 2021-06-25 | 2021-11-05 | 北京中和澄明环境科技有限公司 | Composition of multi-element high-efficiency far infrared mineral base material and its manufacturing method |
| CN113603468B (en) * | 2021-06-25 | 2024-03-05 | 北京中和澄明环境科技有限公司 | Composition of multi-element high-efficiency far infrared mineral base material and manufacturing method thereof |
| CN113893460A (en) * | 2021-07-19 | 2022-01-07 | 秦琳 | Magnetic far infrared physiotherapy bag for prostate and manufacturing method |
| CN113893460B (en) * | 2021-07-19 | 2024-02-27 | 秦琳 | Magnetic far infrared physiotherapy bag for prostate and manufacturing method |
| CN117210196A (en) * | 2023-08-01 | 2023-12-12 | 佛山松和宏量健康科技有限公司 | Material capable of stably emitting far infrared rays and negative ions and application thereof |
| CN117210196B (en) * | 2023-08-01 | 2024-03-19 | 佛山松和虹量健康科技有限公司 | Material capable of stably emitting far infrared rays and negative ions and application thereof |
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Application publication date: 20181127 |