CN111620670A

CN111620670A - Argil particle material capable of generating terahertz waves and preparation method thereof

Info

Publication number: CN111620670A
Application number: CN202010578722.0A
Authority: CN
Inventors: 雷建忠
Original assignee: Shaanxi Xinrongkang Medical Equipment Co ltd
Current assignee: Shaanxi Xinrongkang Medical Equipment Co ltd
Priority date: 2020-06-23
Filing date: 2020-06-23
Publication date: 2020-09-04

Abstract

The invention relates to a pottery clay particle material capable of generating terahertz waves and a preparation method thereof, wherein the pottery clay particle material is prepared from the following raw materials in parts by weight: 65-75 parts of silicon dioxide, 4-8 parts of aluminum oxide, 3-6 parts of ferric oxide, 0.5-1.5 parts of calcium oxide, 0.9-2.1 parts of magnesium oxide, 1-3 parts of boron nitride, 1-2 parts of titanium oxide, 1-2 parts of zirconium oxide, 2.5-4.5 parts of medical stone natural ore, 4-6 parts of graphene, 1-3 parts of black quartz and 1-2 parts of active catalyst. According to the invention, on the basis of the traditional formula, a large amount of graphene, black quartz and medical stone natural ores are added, and low-aluminum-containing clay is selected for firing, so that the terahertz wave particle material capable of generating terahertz waves is not only obviously improved in a far infrared band of 4-14 microns, but also extends to a 28-micron terahertz wave band of light of the moon life. Meanwhile, the low sintering temperature is adopted, and the activity of each ingredient of the pottery clay particles is improved, so that the transmitting capacity of the terahertz wave band is greatly improved.

Description

Argil particle material capable of generating terahertz waves and preparation method thereof

Technical Field

The invention belongs to the field of argil particles, and particularly relates to an argil particle material capable of generating terahertz waves and a preparation method thereof.

Background

Terahertz waves are classified into interference terahertz waves (artificial waves, single waves) and non-interference terahertz waves (natural light, complex waves) according to a transmission source and a transmission method, and can be applied to a human body and mainly to non-interference terahertz waves. The temperature of the dark space is 270 ℃ below zero, and calculation is carried out according to the Vienna displacement rule, so that the wavelength is about 1000 um. This wavelength domain belongs to the terahertz wave range. In other words, terahertz waves are electromagnetic waves emitted from the universe to the earth. The night temperature of the moon is 170 ℃ below zero, and the peak wavelength of the electromagnetic waves emitted from the moon is 28um and also falls within the terahertz wave band range. Every month of the new moon, the moon gives people a feeling of sinking of the yin-qi, but in this time, the moon emits terahertz waves extremely astonishingly, the seeds deeply buried in the soil can germinate by the strength, and the reinforced concrete acts on the human body entering deep sleep to promote the growth and metabolism of the human body, deeply restore the functions of viscera and relieve fatigue.

Terahertz waves are electromagnetic waves between infrared rays and microwaves, and have both properties due to their specific location in the electromagnetic spectrum. Terahertz waves have optical straightness and radio wave transparency. Therefore, compared with far infrared rays, the far infrared rays have stronger ability of penetrating living bodies and substances; compared with X-ray, the terahertz energy is very small, and can not damage substances. There are many unique advantages over radiation in other wavelength bands. In addition, terahertz wave can penetrate most nonpolar materials, and the resonance frequency of vibration and rotation frequency of biological macromolecules also falls within the terahertz wave band.

Due to the characteristics of the terahertz waves, the terahertz waves have wide application prospects in various fields such as spectral imaging, nondestructive testing, safety inspection, biomedical treatment, secret radar, radio astronomy, broadband communication and the like.

The infrared radiation ceramic material is a photo-thermal conversion material and has been widely applied to a plurality of fields such as household appliances, medical treatment and the like. The far infrared radiation ceramics commonly used at present mainly comprise black or dark far infrared radiation ceramics such as silicon carbide series, iron-manganese-nickel-cobalt-copper series, negative ion powder and the like, and white far infrared radiation ceramics such as zirconia series, aluminum-magnesium-silicon-zinc-titanium-rare earth series and the like. However, the existing formula and the preparation method realize that far infrared spectral lines are all in a band of 4-14 um, do not cover a terahertz wave band, and cannot realize the health-care physiotherapy effect of the terahertz wave band on people.

Disclosure of Invention

The invention aims to overcome the defects of the prior art, provides a pottery clay particle material capable of generating terahertz waves and a preparation method thereof, and aims to solve the technical problems, the invention is realized by the following technical scheme:

a pottery clay particle material capable of generating terahertz waves and a preparation method thereof are prepared from the following raw materials in parts by weight:

65-75 parts of silicon dioxide;

4-8 parts of alumina;

3-6 parts of ferric oxide;

0.5 to 1.5 portions of calcium oxide;

0.9 to 2.1 portions of magnesium oxide;

1-3 parts of boron nitride;

1-2 parts of titanium oxide;

1-2 parts of zirconium oxide;

2.5 to 4.5 portions of medical stone natural ore;

4-6 parts of graphene;

1-3 parts of black quartz stone;

1-2 parts of an active catalyst; the active catalyst is rare earth oxide or metal oxide, and is respectively prepared into superfine powder.

Preferably, the method comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1) and uniformly mixing;

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

(4) and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature to obtain the required argil particles.

Preferably, the organic material is added in the step (1) in an amount of 10-20% by weight based on the total weight of the mixed granule.

Preferably, the small-transverse mountain silty clay in the step (2) is added in an amount of 30-60% of the total weight of the product obtained in the step (1).

Preferably, the sintering temperature in the step (4) is 990-1020 ℃, and the constant temperature is kept for more than 30 minutes.

The invention has the following beneficial effects:

according to the invention, based on the traditional far infrared pottery clay formula, a large amount of graphene, black quartz, medical stone natural ores and the like are added, and meanwhile, pottery clay particles fired by clay with low aluminum content are selected, so that the far infrared band which is most easily absorbed by a human body is obviously increased by 4-14 um and extends to the terahertz wave band about 28um of light called the moon life. The terahertz wave detector is flexible in size and various in form, can generate non-interference terahertz waves at normal temperature and high temperature, and is convenient to apply to various medical and health care physiotherapy products. The low sintering temperature is adopted, and the activity of each ingredient of the pottery clay particles is improved, so that the transmitting capacity of the terahertz wave band is greatly improved.

Drawings

Fig. 1 is a flow chart of a kaolin particle material capable of generating terahertz waves and a preparation method thereof according to the present invention.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The first embodiment is as follows:

in the specific implementation of the invention, the following components in weight percentage can be adopted: 65 parts of silicon dioxide, 4 parts of aluminum oxide, 3 parts of ferric oxide, 0.5 part of calcium oxide, 0.9 part of magnesium oxide, 1 part of boron nitride, 1 part of titanium oxide, 1 part of zirconium oxide, 2.5 parts of medical stone natural ore, 4 parts of graphene, 1 part of black quartz stone and 1 part of active catalyst; the active catalyst is rare earth oxide or metal oxide and is respectively prepared into superfine powder;

the preparation method of the argil particles comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance, wherein the addition amount of the organic substance is 10% of the total weight of the mixed particles;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1), and uniformly mixing, wherein the adding amount of the small-transverse-mountain silty clay with low aluminum content is 30% of the total weight of the product obtained in the step (1);

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

(4) and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature, wherein the sintering temperature is 990 ℃, and the constant temperature is kept for more than 30 minutes, so that the required argil particles are obtained.

Example two:

in the specific implementation of the invention, the following components by weight can be adopted: 75 parts of silicon dioxide, 8 parts of aluminum oxide, 6 parts of ferric oxide, 1.5 parts of calcium oxide, 2.1 parts of magnesium oxide, 3 parts of boron nitride, 2 parts of titanium oxide, 2 parts of zirconium oxide, 4.5 parts of medical stone natural ore, 6 parts of graphene, 3 parts of black quartz stone and 2 parts of active catalyst; the active catalyst is rare earth oxide or metal oxide and is respectively prepared into superfine powder;

the preparation method of the argil particles comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of organic matters, wherein the addition amount of the organic matters is 20% of the total weight of the mixed particles;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1), and uniformly mixing, wherein the adding amount of the small-transverse-mountain silty clay with low aluminum content is 60% of the total weight of the product obtained in the step (1);

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

(4) and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature, wherein the sintering temperature is 1020 ℃, and the constant temperature is kept for more than 30 minutes, so that the required argil particles are obtained.

Example three:

in the specific implementation of the invention, the following components by weight can be adopted: 70 parts of silicon dioxide, 6 parts of aluminum oxide, 4.5 parts of ferric oxide, 1 part of calcium oxide, 1.5 parts of magnesium oxide, 2 parts of boron nitride, 1.5 parts of titanium oxide, 1.5 parts of zirconium oxide, 3.5 parts of medical stone natural ore, 5 parts of graphene, 2 parts of black quartz stone and 1.5 parts of active catalyst; the active catalyst is rare earth oxide or metal oxide and is respectively prepared into superfine powder;

the preparation method of the argil particles comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance, wherein the addition amount of the organic substance is 15% of the total weight of the mixed particles;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1), and uniformly mixing, wherein the adding amount of the small-transverse-mountain silty clay with low aluminum content is 45% of the total weight of the product obtained in the step (1);

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

(4) and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature, wherein the sintering temperature is 1000 ℃, and the constant temperature is kept for more than 30 minutes, so that the required argil particles are obtained.

Example four:

in the specific implementation of the invention, the following components by weight can be adopted: 68 parts of silicon dioxide, 5 parts of aluminum oxide, 3.8 parts of ferric oxide, 0.8 part of calcium oxide, 1.2 parts of magnesium oxide, 1.5 parts of boron nitride, 1.2 parts of titanium oxide, 1.2 parts of zirconium oxide, 3 parts of medical stone natural ore, 4.5 parts of graphene, 1.2 parts of black quartz and 1.2 parts of active catalyst; the active catalyst is rare earth oxide or metal oxide and is respectively prepared into superfine powder;

the preparation method of the argil particles comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance, wherein the addition amount of the organic substance is 12% of the total weight of the mixed particles;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1), and uniformly mixing, wherein the adding amount of the small-transverse-mountain silty clay with low aluminum content is 38% of the total weight of the product obtained in the step (1);

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

Example five:

in the specific implementation of the invention, the following components by weight can be adopted: 72 parts of silicon dioxide, 7 parts of aluminum oxide, 5 parts of ferric oxide, 1.4 parts of calcium oxide, 1.8 parts of magnesium oxide, 2.5 parts of boron nitride, 1.8 parts of titanium oxide, 1.8 parts of zirconium oxide, 4 parts of medical stone natural ore, 5.5 parts of graphene, 2.5 parts of black quartz and 1.8 parts of active catalyst; the active catalyst is rare earth oxide or metal oxide and is respectively prepared into superfine powder;

the preparation method of the argil particles comprises the following steps:

(1) organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance, wherein the addition amount of the organic substance is 18% of the total weight of the mixed particles;

(2) viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1), and uniformly mixing, wherein the adding amount of the small-transverse-mountain silty clay with low aluminum content is 55% of the total weight of the product obtained in the step (1);

(3) and (3) dehydrating: dehydrating the mixture obtained in the step (2);

(4) and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature, wherein the sintering temperature is 1010 ℃, and the constant temperature is kept for more than 30 minutes, so that the required argil particles are obtained.

The action mechanism of the terahertz waves generated by the argil particles is as follows:

terahertz waves are one kind of energy waves in the universe, are common motive power of universe life, are called life light waves, are sources of electromagnetic waves and light waves, and have double functions of the electromagnetic waves and the light waves.

For human body, the terahertz wave is close to original qi in traditional Chinese medicine, and all life is from life to old to ill to death, which is caused by continuous attenuation of the terahertz wave.

The life is characterized by possessing terahertz waves, whether animals or plants.

The secret of keeping the body of a family for a long life is the terahertz waves for ensuring that the viscera are normal and not diseased, so that many people with long life die from old rather than sick.

Research by Japanese and American scientists finds that the body is aged and ill due to attenuation and insufficiency of terahertz waves of the human body.

The terahertz waves have a lot of benefits on a human body, can activate the activity of biological macromolecules, so that the molecules of the human body can be excited to be in a high vibration state, and the activity of nucleic acid, protein and other human macromolecules is activated, so that the functions of regulating activities of organism metabolism and the like by the human macromolecules are exerted, the recovery and balance of the organism are facilitated, and the purposes of preventing and treating diseases are achieved.

The terahertz wave has the following effects on human body health care physiotherapy:

(1) promoting and improving blood circulation

After the terahertz waves act on the skin, most energy is absorbed by the skin and converted into heat energy, the temperature of the skin is raised, thermal receptors in the skin are stimulated, vascular smooth muscle is relaxed and vascular dilation and blood circulation is accelerated through thalamus reflection, and on the other hand, due to the thermal action, vasoactive substances are released, the vascular tension is reduced, superficial capillaries, superficial arterioles and superficial arteries are dilated and the blood circulation is accelerated.

(2) Enhancing metabolism

If the metabolism of the human body is disturbed to cause abnormal exchange of substances in and out of the body, various diseases such as: water and electrolyte metabolism disorders, which can bring danger to life; diabetes mellitus due to disturbances of sugar metabolism; hyperlipidemia and obesity caused by lipid metabolism disorder; ventilation caused by disturbances in protein metabolism, etc.

(3) The terahertz wave heat effect can increase the activity of cells, adjust nerves and body fluid, strengthen metabolism and enable the exchange of internal and external substances of the organism to be in a balanced state.

(4) Improving human body function

The health-care product can improve the functions of human body and enhance the physiological protection response of human body, comprises cells and body fluid, has the functions of human body defense, human body cell immunity enhancement and human body fluid regulation, and is beneficial to human health.

(5) Analgesic, anti-inflammatory and repercussive functions

The thermal effect of the terahertz wave reduces excitability of nerve endings, improves blood circulation and eliminates edema, and relieves chemical and mechanical stimulation of the nerve endings. All the reasons play a role in relieving pain.

(6) Regulating autonomic nerve, activating the activity of biological molecular chain, and effectively increasing the microcirculation at the tail end.

(7) The skin care and beauty treatment are realized, the skin can breathe smoothly, the toxin in the skin can be effectively discharged, the color spots can be slowed down, and the sub-health state of the skin such as whelk and the like can be prevented.

(8) The female mammary gland patient can accelerate microcirculation and obviously improve the discomfort of distending pain, hyperplasia of mammary glands and the like caused by unsmooth stasis and blockage.

According to the terahertz wave pottery clay particles, on the basis of a traditional far infrared pottery clay particle formula, a large amount of graphene, black quartz, medical stone natural ores and other materials are added, so that the integral emissivity of far infrared rays is obviously improved, the far infrared band which is most easily absorbed by a human body is obviously improved in a range of 4-14 um, the radiation band extends to the terahertz band, and the emission amount of light in the moon life is greatly improved in a range of about 28 um. Meanwhile, the argil particles have obvious functions of adsorbing impurities and purifying air. The product has greatly improved beneficial effect on human body after being applied to medical rehabilitation and health care products.

The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims

1. The pottery clay particle material capable of generating terahertz waves and the preparation method thereof are characterized by being prepared from the following raw materials in parts by weight:

65-75 parts of silicon dioxide;

4-8 parts of alumina;

3-6 parts of ferric oxide;

0.5 to 1.5 portions of calcium oxide;

0.9 to 2.1 portions of magnesium oxide;

1-3 parts of boron nitride;

1-2 parts of titanium oxide;

1-2 parts of zirconium oxide;

2.5 to 4.5 portions of medical stone natural ore;

4-6 parts of graphene;

1-3 parts of black quartz stone;

2. The kaolin particle material capable of generating terahertz waves and the preparation method thereof according to claim 1 are characterized by comprising the following steps:

organic mixing: uniformly mixing silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide, boron nitride, titanium oxide, zirconium oxide, medical stone natural ore, graphene, black quartz stone and active catalyst superfine powder, and adding the mixture into an aqueous solution of an organic substance;

viscosity mixing: adding a small-transverse-mountain silty clay mixture with low aluminum content into the product obtained in the step (1) and uniformly mixing;

and (3) dehydrating: dehydrating the mixture obtained in the step (2);

and (3) calcining: and (4) drying the product subjected to dehydration treatment in the step (3), and calcining at a high temperature and a constant temperature to obtain the required argil particles.

3. The kaolin particle material capable of generating terahertz waves and the preparation method thereof according to claim 2, wherein the organic matter is added in the step (1) in an amount of 10-20% of the total weight of the mixed particles.

4. The kaolin particle material capable of generating terahertz waves and the preparation method thereof as claimed in claim 2, wherein the small-mount-mountain silty clay with low aluminum content of the step (2) is added in an amount of 30-60% by weight based on the total weight of the product obtained in the step (1).

5. The kaolin particle material capable of generating terahertz waves and the preparation method thereof according to claim 2, wherein the sintering temperature in the step (4) is 990-1020 ℃, and the temperature is kept for more than 30 minutes.