CN108821726A - A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization - Google Patents
A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization Download PDFInfo
- Publication number
- CN108821726A CN108821726A CN201810483985.6A CN201810483985A CN108821726A CN 108821726 A CN108821726 A CN 108821726A CN 201810483985 A CN201810483985 A CN 201810483985A CN 108821726 A CN108821726 A CN 108821726A
- Authority
- CN
- China
- Prior art keywords
- aqueous polyurethane
- floor material
- inorganic
- water
- organic inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00508—Cement paints
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/50—Flexible or elastic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Abstract
The invention discloses a kind of aqueous polyurethane mortar floor materials of organic inorganic hybridization, are made of four components, are respectively:The aqueous polyalcohol of modifying water glass, sulfamate modified isocyanate, inorganic active aggregate, water-base inorganic pigment dispersion liquid.Four components are formulated by weight physical agitation.Product by organic inorganic hybridization, not only had aqueous polyurethane high-performance, low VOC the advantages of, but also have the characteristics that weather-proof, the wear-resisting and impact resistance of inorganic mixture.It can be widely applied to the floor treatment of the extreme environments such as high temperature and humidity, chemical attack, it is also possible to be used for the high requests such as heavily loaded, wear-resisting ground, the advantage for having traditional floor coatings incomparable.
Description
Technical field
The present invention relates to a kind of water-base polyurethane material, the aqueous polyurethane mortar of specifically a kind of organic inorganic hybridization
Terrace material.
Background technique
Floor coatings refer to the coating for being applied to the non-wood ground such as cement basic layer, belong to one kind of floor coating.
Floor coatings can be divided by film forming matter classification:Epoxy flooring coating, polyurethane floor coatings, Spray Polyurea Elastomer terrace apply
Material and other floor coatings etc..It but is essentially all when construction and after construction, to there is a large amount of VOC based on oleaginous system
Discharge, it is unfriendly to environment.The maximum kind of dosage is epoxy flooring coating, the current institute of polyurethane floor coatings currently on the market
The ratio accounted for is also smaller, but for opposite epoxy flooring coating, the advantages such as flexibility, low VOC that polyurethane floor coatings have,
To be able to satisfy different customer demands.In Europe, polyurethanes technology has accounted for 25% share in floor coatings system, because
This, polyurethane floor coatings have biggish development space in China.
But organic polymer is in the side such as technical performances such as heat resistance, surface hardness, ageing-resistant and minimum film formation temperature
It is superior that face is then not so good as inorganic coating.
The representative film forming matter of inorganic coating has alkali silicate system, phosphate-based, silicone-based and cement system etc..And liquid
Body waterglass is typical alkali metal silicate aqueous solution, its yield is high, at low cost, uses simplicity.And the net of curing molding
Shape silicon oxygen bond is because property is close with cement basic layer, it is possible to significantly improve the adhesive force on cement matrix.
Summary of the invention
The purpose of the present invention is:A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization is provided, had it both
There are chemical resistance, flexibility, dicoration and the feature of environmental protection of high molecular material, and high-intensitive, wear-resisting, heat-resisting etc. with inorganic matter
Excellent performance meets various use environments.
In order to achieve the above object, the present invention provides the following technical solutions:
A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization, is made of four components, is respectively:1. modifying water glass
Aqueous polyalcohol, 2. sulfamate modified isocyanates, 3. inorganic active aggregates, 4. water-base inorganic pigment dispersion liquids.Four groups
Part is by weight 10-13: 13-16 : 71 :3 mixed preparings form, and before gel, with the side of roller coating and airless spraying
Formula is constructed on the cement matrix handled well.Wherein, component 1 and 2 is the film forming matter of two-component, and component 3 is as terrace
The filler of coating, component 4 are to improve the pigment of decorative effect.
Specific embodiment
Technical solution of the present invention is further illustrated below by specific embodiment.
Component 1:Prepare the aqueous polyalcohol of modifying water glass
In the case where stirring at low speed(80-100 revs/min), the hydroxymethyl cellulose of 400 viscosity is selected, 0.1% aqueous solution is configured to;
Then the potassium water glass for selecting 2.68-3.40 modulus, is added in above-mentioned aqueous solution, is configured to 10% mixed liquor.
The 941# modified polyalcohol for selecting ALBERDINGK, by 1:1 volume ratio, in the case where stirring at low speed, average rate is added dropwise to
It in the hydroxymethyl cellulose aqueous solution of 10% potassium water glass of above-mentioned preparation, is added dropwise to complete within 3 hours, and is stirred for 3 hours.
Component 2:Sulfamate modified isocyanate
Selecting the trade mark is the sulfamate modified isocyanate of BayhydurXP2547.
Component 3:Inorganic active aggregate
By 40 mesh quartz sands, the quartz sand of 80 mesh, high strength cement, by 30:35:35 ratio is mixed with Horizontal helical mixer
Uniformly, sealed package.
Component 4:Water-base inorganic pigment dispersion liquid
Water-base inorganic pigment(It can according to need selection color, such as red, green, yellow), inorganic pigment dispersing aid platform
The gulf Central Asia 5040,941# modified polyalcohol, with 60:1:39 ratios are prepared, mill base made of ball milling 5 hours.
Above-mentioned four component is by weight 10-13: 13-16 : 71 :3 mixed preparings form, and before gel, with nothing
The mode that gas blowout applies carries out single apply on the cement matrix handled well and constructs, and the standard singly applied is to cover original cement base
Matter, and reach surface wettability and be advisable.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field
Personnel, which do not need to pay for creative labor, can associate other specific embodiments of the invention, these modes are fallen within
Within protection scope of the present invention.
Claims (6)
1. a kind of aqueous polyurethane mortar floor material of organic inorganic hybridization, it is characterised in that:It is made of four components, respectively
It is:The aqueous polyalcohol of modifying water glass, sulfamate modified isocyanate, inorganic active aggregate, water-base inorganic pigment dispersion
Liquid.
2. the aqueous polyurethane mortar floor material of organic inorganic hybridization according to claim 1, it is characterised in that:Water glass
The preparation method of glass modified water-soluble polyalcohol is, in the case where stirring at low speed(80-100 revs/min), the modified multicomponent of same volume
Alcohol is added drop-wise in 10% waterglass hydroxymethyl cellulose aqueous solution, is dripped off within 3 hours, and stirring 3-5 hours is continued.
3. the aqueous polyurethane mortar floor material of organic inorganic hybridization according to claim 1, it is characterised in that:Isocyanide
Acid esters is modified using sulfamate, by internal emulsification method, obtains stable water-based isocyanate.
4. the aqueous polyurethane mortar floor material of organic inorganic hybridization according to claim 1, it is characterised in that:Four groups
Part mixed preparing uniform by weight percentage forms, and ratio is:10-13 : 13-16 : 71 : 3.
5. the aqueous polyurethane mortar floor material of organic inorganic hybridization according to claim 1, it is characterised in that:It is described
Inorganic active aggregate refers to the existing cement in market, the mortar of quartz sand mixed.
6. the aqueous polyurethane mortar floor material of organic inorganic hybridization according to claim 1, it is characterised in that:It is described
Water-base inorganic pigment dispersion liquid be by water-base inorganic pigment, inorganic pigment dispersing aid, modified polyalcohol, with 60:1:39 ratios
Example is prepared, mill base made of the technique grinding by ball milling.
Priority Applications (1)
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CN201810483985.6A CN108821726A (en) | 2018-05-19 | 2018-05-19 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
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CN201810483985.6A CN108821726A (en) | 2018-05-19 | 2018-05-19 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
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Citations (11)
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CN1285364A (en) * | 2000-09-25 | 2001-02-28 | 四川省和光高技术开发有限责任公司 | Process for preparation of high strength polyurethane aqueous dispersion |
CN1690145A (en) * | 2004-04-24 | 2005-11-02 | 师永昌 | Method for making plastic playground runway by using water-soluble resin modified polyurethane |
CN101734885A (en) * | 2009-12-22 | 2010-06-16 | 康可睿建筑材料(上海)有限公司 | Polyurethane elastic self-leveling mortar |
CN101798484A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Dendritic organic-inorganic hybrid water-borne nano polyurethane-epoxy anticorrosive coating and preparation method thereof |
CN101798483A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Normal-temperature multiple curing organic-inorganic hybridized aqueous nano polyurethane woodware coating and preparation method thereof |
CN103173179A (en) * | 2013-03-07 | 2013-06-26 | 常州大学 | Preparation method of aqueous polyurethane adhesive for laminated composite fabrics |
CN104364225A (en) * | 2012-06-06 | 2015-02-18 | 格雷斯公司 | Polyurethane-based waterproofing composition for the water-proofing of concrete structures |
CN105753379A (en) * | 2014-12-17 | 2016-07-13 | 广州市领科化工有限公司 | Four-component aqueous polyurethane mortar floor material |
CN106479339A (en) * | 2016-08-31 | 2017-03-08 | 武汉长江科创科技发展有限公司 | A kind of organic inorganic hybridization resistant abrasion coating material and preparation method thereof |
CN106927725A (en) * | 2016-06-16 | 2017-07-07 | 广州固耐特化工有限公司 | Aqueous color sand Self-leveling polyurethane cement |
CN106927724A (en) * | 2016-06-16 | 2017-07-07 | 广州固耐特化工有限公司 | Heavy load anti-slip type aqueous polyurethane mortar |
-
2018
- 2018-05-19 CN CN201810483985.6A patent/CN108821726A/en active Pending
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1285364A (en) * | 2000-09-25 | 2001-02-28 | 四川省和光高技术开发有限责任公司 | Process for preparation of high strength polyurethane aqueous dispersion |
CN1690145A (en) * | 2004-04-24 | 2005-11-02 | 师永昌 | Method for making plastic playground runway by using water-soluble resin modified polyurethane |
CN101734885A (en) * | 2009-12-22 | 2010-06-16 | 康可睿建筑材料(上海)有限公司 | Polyurethane elastic self-leveling mortar |
CN101798484A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Dendritic organic-inorganic hybrid water-borne nano polyurethane-epoxy anticorrosive coating and preparation method thereof |
CN101798483A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Normal-temperature multiple curing organic-inorganic hybridized aqueous nano polyurethane woodware coating and preparation method thereof |
CN104364225A (en) * | 2012-06-06 | 2015-02-18 | 格雷斯公司 | Polyurethane-based waterproofing composition for the water-proofing of concrete structures |
CN103173179A (en) * | 2013-03-07 | 2013-06-26 | 常州大学 | Preparation method of aqueous polyurethane adhesive for laminated composite fabrics |
CN105753379A (en) * | 2014-12-17 | 2016-07-13 | 广州市领科化工有限公司 | Four-component aqueous polyurethane mortar floor material |
CN106927725A (en) * | 2016-06-16 | 2017-07-07 | 广州固耐特化工有限公司 | Aqueous color sand Self-leveling polyurethane cement |
CN106927724A (en) * | 2016-06-16 | 2017-07-07 | 广州固耐特化工有限公司 | Heavy load anti-slip type aqueous polyurethane mortar |
CN106479339A (en) * | 2016-08-31 | 2017-03-08 | 武汉长江科创科技发展有限公司 | A kind of organic inorganic hybridization resistant abrasion coating material and preparation method thereof |
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