CN106927724A - Heavy load anti-slip type aqueous polyurethane mortar - Google Patents
Heavy load anti-slip type aqueous polyurethane mortar Download PDFInfo
- Publication number
- CN106927724A CN106927724A CN201610435550.5A CN201610435550A CN106927724A CN 106927724 A CN106927724 A CN 106927724A CN 201610435550 A CN201610435550 A CN 201610435550A CN 106927724 A CN106927724 A CN 106927724A
- Authority
- CN
- China
- Prior art keywords
- coating
- component
- aqueous polyurethane
- polyurethane
- mortar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention is a kind of heavy load anti-slip type aqueous polyurethane mortar, is adapted to be used in the region for having particular characteristic requirement, such as the environment temperature less than 20 DEG C, there is corrosivity organic substance, high temperature difference and steam etc..The present invention coordinates high performance concrete using a kind of plant oil modified PPG aqueous dispersion solidification polyurethane, the mortar of various reactions can be carried out, using one 100% high solid of formation, the integrated thick coating with 6 12mm thickness.The coating compatibility is good, and firm wear-resisting, with excellent mechanical mechanics property and non-skid property, and construction procedure is few.The coating can be used mill base or colorful quartz sands to be decorated.Product of the invention also is suitable as architectural repairing and reinforcing material is used.
Description
Technical field
This patent belongs to coating, high-abrasive material, building or building materials, technical field of civil engineering, is a kind of aqueous polyurethane
Mortar coating, it is particularly possible to used as terrace coating.
Background technology
It is industrial to there are many regions with particular surroundings, such as the long-continued temperature in less than -20 DEG C
Under product freezer, often have higher concentration lactic acid overflow dairy products workshop, the material that is often corrosive leakage pharmacy
Factory, and it is moist, greasy, often there is the central kitchen of high temperature and steam.These regions also have very accordingly to the floor material for using
Strict requirements.Terrace is to be covered in surface of bottom material, ground is protected and is decorated, and realizes wear-resisting, high temperature resistant, low temperature ring
Border, shock resistance, resistance to heavy burden, the immersion coating of anti-skidding grade new capability.In these environment, terrace may have always a demand for less than-
20 DEG C are used, and keep function normal；Allow for resisting chemical attack；Necessary high temperature resistant, wet environment, resistance to greasy dirt,
Resistance to frequently high temperature difference etc..
Concrete floor such as diamond dust abrasion-proof terrace, has excellent mechanical performance, it is easy to construct, but structural porous, and material
Material is highly polar so that concrete body easily absorbs foreign matter, such as oiliness compound, even corrosive organic acid.Concrete
Main component silicate can not sufficiently resist the corrosion of chemicals.If be not modified by main in structure, draw
Enter a large amount of new functionalized chemical groups, acrylic resin generally only applies the place such as high resiliency acrylic carried in slight industry
Court etc..For example, US5543232 discloses a kind of acrylic resin modified varnish of photocuring, with good elasticity, it is adaptable to
General place.Epoxy resin is the matrix resin being most widely used, with outstanding anticorrosion and mechanical mechanics property.Epoxy
Contain substantial amounts of phenyl ring in resin structure, coating is hard；Alkyl and ehter bond are also there are, the adhesive force to concrete substrate is excellent
Good, alkali resistance is excellent, is resistant to most of organic solvent.Epoxy resin is always all as in anticorrosive coating and heavy corrosion environment
First-selected corrosion protection base-material.But epoxy resin curing reaction at low temperature is slow, and construction effect and coating performance are undesirable.For example,
US8133941 discloses a kind of aqueous double-component epoxy-resin systems, can adjust hardening time.
Because the performance of polyurethane is very prominent and superior, meet the application feature under extreme condition, thus be adapted to as
Floor material in above-mentioned environment.Polyurethane resin is typical elastomeric material, and the curing reaction of feature has polyurethane
Significant physical and mechanical properties.Polyurethane is resistant to chemical etching, including organic acid and most of solvent, can resist various soda acids and
Organic solvent corrodes, and often uses and substitutes rubber in the presence of a harsh environment.The polyurethane for introducing various elastomer structures can do
To anti-wear performance more more preferable than rubber, with the tearing strength more much better than than rubber.Exist in polyurethane molecular structure a large amount of
Hydrogen bond, to be similar to the effect of chemical crosslinking, can promote the mechanical property of polyurethane coating, such as tensile strength, tearing toughness,
Impact resistance, wearability etc., and strengthen hydrolytic resistance, oil resistivity etc..The source of the structure of polyurethane is a lot, and NCO can
Reacted with alcoholic extract hydroxyl group, amino, amide groups, allophanate, biuret groups, or even form the structures such as sulphur bridge, and ester can be introduced
Base, ether etc..For example, US5777024 discloses a kind of hydroxyl cure polyurethane system, high density solidification can be obtained, had
The coating of premium properties, material viscosity and curing rate can adjust；US7022257 discloses a kind of hydroxyl cure polyurethane floor
System, can use under heavy load, and keep outward appearance, easy cleaning and maintenance.
Polyurethane has the intensity more stronger than concrete, is mixed before resin arrival performance boundary in polyurethane floor system
Solidifying soil is first broken, therefore polyurethane resin, actually simultaneously in protection concrete, strengthens the mechanics of concrete when in use
Performance, while preventing concrete from suffering various corrosion.
It is to compare with certain thickness coating when in the environment with various special characteristics using under extreme conditions
Preferably.Enough thickness is subject to the premise of heavy load first, it is also possible to strengthen that resistance to surface is scratch resistance, will not be in relatively low lotus
Lower coating is carried with regard to excess compression, and is easily damaged.Enough thickness can ensure coating with the attachment of base material not by heavy load, weight
The influence of mechanical shock.The coating for occurring on this basis is damaged after can be and repaired, therefore can by safeguarding
To ensure that coating is normally used for a long time.Enough thickness can also protect the adhesive force of coating under extreme difference in temperature.Painting thickness high
Degree generally also implies that sealing permeability resistance high.
Because commonly using in extreme circumstances, the integration of coating is also important.Integrative Coating can be kept away
When exempting from environmental condition acute variation, the incompatibility that different resins system, different faces interlayer occur.So also produced in construction
Require, to obtain the Integrative Coating with higher caliper, coating process needs simple, and is conveniently repeated several times coating, with
Obtain required coating layer thickness.It should be noted that much commonly using general coating system needs to use a large amount of coating, and repeatedly apply
Work obtains a larger thickness, and when the thickness of requirement is reached, substantial amounts of filler causes film again in coating film
Appearance cohesion energy density is excessive, the phenomenon of outward appearance cracking.
One 100% high solid coating system is well suited as using the terrace system in above-mentioned zone.100% high solid
Part system does not contain solvent, and all components participate in reaction, are solidified into coating.Therefore to construction environment relatively low, the application of requirement
Also without smell in journey.Step needed for the application of 100% high solid system is also fewer, easily forms last thick film layers.
The content of the invention
Aqueous polyurethane mortar terrace starts gradually to be used in the region for having particular characteristic requirement in recent years.Aqueous polyurethane
Terrace has very good mechanical performance, Acclimation temperature scope wide, and the corrosion of the product of resistance to harsh chemical can meet strict environmental protection
It is required that, many advantages, such as short construction period, long service life.The present invention is a kind of A, B, C, D, 4 component materials, the product being made
Product, are a kind of terrace coating systems for undertaking heavy industry load, resistance to extreme environmental conditions, with perfect performance, together
When with certain dicoration.
Use under extreme conditions, polyurethane exists relative to concrete system and acrylatcs systems, or even epoxy systems
It is very superior in performance.In order to reach optimal performance, requirement of the acrylatcs systems to construction environment is higher, by
In polarity in permeability, and molecular structure and the difference of intensity, acrylatcs systems need to fully ensure that the viscosity of flowing and apply
The solid content of layer, and a preferable substrate surface for the treatment of.Acrylatcs systems can not bear high temperature difference environment and undergo chemistry
Product corrode, and anti-wear performance is simultaneously also not good enough.Polyurethane has reactivity very high, and excellent adhesive force, polyurethane system
Can a small range tolerate construct when minor defect, without influence coating overall performance.Advantage in this construction is caused
Polyurethane body ties up to the replacement epoxy-resin systems of general industry or commercial field positive part.Concrete system can not overcome easily to be opened
Split, bubble, mechanical tenacity is poor, it is poor to be unable to high temperature resistant, it is impossible to which the shortcomings such as chemicals-resistant, polyurethane system is but in these performances
Upper performance is excellent, is such as resistant to up to 130 DEG C of temperature, phosphoramidite chemical corrosion is subjected to for a long time and is normally used, with than epoxy
The ability of the stronger adaptation application feature of resin.
Product of the invention is a kind of thickness high, and 100% high solid aqueous polyurethane mortar terrace is obtained after
Be one be tightly combined with base material, the Integrative Coating of superior performance, coating overall compatibility is very good, and mechanical performance is protruded,
With hardness very high, and toughness well.
Product of the invention uses aromatic series or aliphatic isocyanates, plant oil modified polyol curing with one kind, together
When be sufficiently mixed with concrete, various curing reactions are carried out in system, the coating of generation is very firm wear-resisting.Product of the invention
Epoxy resin color mortar coatings system is overcome to bear high temperature difference in particular place and undergo chemicals corrosion, humidity, wear-resisting etc.
The performance of aspect is not enough.
It is a reaction system for complexity during products application of the invention, the reaction of generation includes：Polyethers is more in component A
First alcohol can occur the curing reaction of polyurethane with the isocyanates in B component；The OH bases and B component of modified vegetable oil in component A
There is curing reaction in middle isocyanates；The water contained in component A PPG is generated with the isocyanates reaction in B component
CO2And urea；There is curing reaction with isocyanates in B component in the OH bases in D component botanical oil-based materials；The cementation solidifying of concrete
Reaction；CO2With CO2The reaction of absorbent, reduces gas release；SiO2Reaction between alkali.The component of product four is mixed under normal temperature
Close and start reaction, be swift in response, solidification is uniform, and reacted product shows good Miscibility.Appearance of coat one
Cause, with reference to densification, in the absence of cracking, the bad filling phenomenons such as flocculation of reuniting, coating is complete, very firm wear-resisting.It is of the invention
Product is a 100% high solid coating system, during there is no solvent to volatilize, can once construct the painting obtained more than 6mm
Layer, and step is simple.
Product of the invention is a kind of thick coated type coating system, and thickness can reach 12mm, between 6-12mm thickness, can be by
Design and use need painting to be filled to required thickness.On the basis of such thickness, Integrative Coating not only has very to base material
Good adhesive force, can also increase coating new functional coating, such as increase floating coat, to strengthen sealing permeability resistance；Increase
Elastic layer, with obvious elasticity.Thick coated type coating equally also implies that validity period very long.Although being used in harsh
In extreme environment, the basis of thick coated type coating is difficult to be destroyed, and various damages all occur the top section in coating in use,
Therefore can be repaired.
Product of the invention, it is different according to application target, the quartz sand and colorful quartz sands of varying number, or stone can be used
Sand layer.A coarse texture is kept in coating surface, there can be extraordinary antiskid function.Realize such surface effect
Really, quartz sand can be integrally mixed in system so that quartzy sand grains exposes terrace surface, curing molding.Coating sand grains
It is evenly distributed, flocculation is not settled, is very effective non skid matting.Surface roughness can be true using density by quartz sand
It is fixed.In paint coating, surface increases a ramming surface layer for densification, it is also possible to realize such surface texture and anti-skidding effect
Really.The use of another benefit of quartz sand can be have enhanced effect to coating, quartz sand can be improved as coating ingredients
The mechanical property of coating.Dicoration is the characteristics of using colorful quartz sands, and the color of colorful quartz sands is intrinsic color, not with ring
Border changes, and is not migrated in colorful quartz sands terrace system after hardening, does not ooze out, therefore color is more stable, even if
In hot humid region, it is nonetheless possible to use, keep color complete with terrace texture, terrace is kept attractive in appearance.
Product of the invention is a kind of aqueous polyurethane mortar for being capable of achieving various functions, with excellent mechanical force
Performance is learned, resistant to chemical etching, high temperature resistant is anti-skidding, heavy industry load use condition can be met, with certain dicoration.This
The product of invention can be applied on the various known humidity processing environments of industrial and business, such as -40 DEG C~130 DEG C high temperature difference rings
Border, hot water cleaning ambient, it is allowed to use general cleaning agent and degreaser, it is possible to carry out steam clean.Product of the invention can
To undergo strong machinery heavy duty and impact again, without producing influence to terrace system.Product of the invention has excellent resistance toization
Moral character energy, including part organic acid and most of organic solvent, such as acetic acid, tartaric acid and acetone, alcohols, alkane, gasoline, can
To use safely in commercial kitchen, prefabricated food, meat-packing plant, fruit drink processing industry, the place such as laboratory.Above-mentioned
After the wetting of one class material, do not interfere with the performance of terrace and use.
The polyurethane floor system of product of the invention, can not be very dry concrete base layer（Moisture content ＜
10%）Upper construction；Can be constructed on the novel concrete of maintenance 7 days；Can be solidified and be constructed in as little as 5 DEG C of environment.This hair
Bright product has excellent adhesive force to base material, can not application priming coat, construction procedure is simple, can shorten the duration, and
So that the terrace repairing under wet environment becomes simple, therefore work progress has rapid curing and bigger environment tolerance
Feature.Product of the invention is an aqueous Self-leveling system, with suitable viscosity, substantially without smell, is not also had substantially
Organic volatile.
Specific embodiment
The present invention provides a kind of four components A, B, C, D aqueous polyurethane mortar material, such as high for preparing extreme condition
Temperature, high temperature difference, heavy industry load impacts again, the industry ground slab for frequently being used in the environment such as chemical contact, and with certain
Dicoration.
Present invention employs following technical scheme.
Component A：It is plant oil modified PPG aqueous dispersion.There are 2~6 in suitable vegetable oil molecule structure
Hydroxyl, it is possible to use by carrying out epoxidation to the unsaturated double-bond in molecular structure, then again with active hydrogen group
Compound reacts, and introduces the vegetable oil after hydroxyl.Can also using the vegetable oil in molecular structure per se with hydroxyl, or
By carrying out the vegetable oil after ester exchange reaction introduces hydroxyl with polyalcohol.The vegetable oil that be can be used in preparation includes but not only limits
In such as soybean oil, castor oil, palm oil, linseed oil etc..
Satisfactory modified vegetable oil polyols can serve as the curing agent of polyurethane system.Meet the A of use requirement
The molecular weight of component between 200 to 1000, with particular functional group such as hydroxyl, carboxyl, hydroxyl value 100-160.
B component：Be the material of active isocyanate functional group, it is possible to use isocyanates include but not only limit
In such as toluene di-isocyanate(TDI) (TDI), methyl diphenylene diisocyanate (MDI), 1, hexamethylene-diisocyanate (HDI), benzene two
Methylene diisocyanate (XDI), IPDI (IPDI), 3,3 '-dimethyl -4,4 ' biphenyl diisocyanates
(TODI), cyclohexanedimethyleterephthalate diisocyanate (H6XDI), HMDI (H12MDI) is right
Phenylene diisocyanate (PPPDI), 3,3 '-dimethyl -4,4 '-methyl diphenylene diisocyanate (DMMDI) etc..Wherein 1,6- oneself
The species such as diisocyanate (HDI), XDI (XDI), IPDI (IPDI) it is different
Cyanate all has anti-yellowing property, is good polyurethane component during outdoor utility.
C components：Inorganic active aggregate, such as strong concrete, quartz sand, colorful quartz sands, CO2Absorbent etc..In state
In family's standard GB175-2007, six usable class common Portland system strong concretes are listed.In non-standard engineering
Under the conditions of when constructing, various concrete admixtures, such as water reducer, retarder, corrosion inhibitor etc. can be added.Add CO2Absorbent can
So as to will not be foamed in course of reaction and reduce stomata.
D components：Mill base.D components are the slurries obtained after inorganic pigment is fully ground with plant oil-based material, with one during construction
The slurry and A, B, C component of certainty ratio, after being thoroughly mixed, can obtain the homogeneous stabilized mixture of color and luster.
Four components are used in mixed way by constant weight percentage, and ratio is：A:B:C:D=2.3:2.8:24.4:0.5, after mixing
Start chemical reaction.When using, there are following several curing reactions in system simultaneously：1. PPG and B groups in component A
Isocyanates in part can occur the curing reaction of polyurethane；2. isocyanic acid in the OH bases of modified vegetable oil and B component in component A
There is curing reaction in ester；3. the water for containing in component A PPG can with the isocyanates in B component reaction generation CO2 and
Urea；4. with isocyanates in B component there is curing reaction in the OH bases in D component botanicals oil-based material；5. the cementation solidifying of concrete
Reaction.Chemical reaction is simultaneously participated in after the mixing of the component of A, B, C, D tetra-, high performance urethanes product is can obtain.Reaction
During, above-mentioned several reactions produce amount of heat, the temperature of whole system is raised rapidly, and polyurethane coating can be very
Solidification, comes into operation in the short time.
Example one
Production compound method and step：
（1）The synthesis of modified vegetable oil polyols：In following ratio 45:10:5:40, by suitable vegetable oil, binary acid,
Phthalic acid and neopentyl glycol, in putting into the reaction pot equipped with reflux condenser.Gradually heat up and be heated to 225 DEG C, taken off
Water condensation reaction, is less than 8 using refluxing xylene to pH value, stops reaction.Steam backflow dimethylbenzene, be cooled to 180 DEG C with
Bottom discharge is standby.
（2）Component A is prepared：First add water in homogenizer, emulsifying agent, then under homogenizer, according to 50:15:
0.5:34.5 ratio is slowly added into step（1）The modified vegetable oil polyols of middle preparation, PPG polyethers（L-1000）, emulsifying agent,
Water prepares mixing, and mixing is dispersed into off-white color emulsion form water-borne dispersions.
（3）B component uses technical grade MDI.
（4）Component C by strong concrete, CO2 absorbents, according to 90:10 ratio mixing, further according to required use
Amount, is well mixed after quartz sand is mixed into Horizontal helical mixer, packs.
（5）D components are according to 60:39:1 ratio mixes form and aspect inorganic pigment high, polyalcohol and macromolecule dispersing agent
Stirring, it is dispersed, by fineness of grind to below 50um, packed after filtering removal large-size particles.
Application process and step：
（1）Product preparation.Product is weighed by weight：Component A:B component:Component C:D components=2.3Kg:2.8Kg:
24.4Kg:0.5Kg, common 30Kg/ sets, packaging.
（2）Model prepares.Prepare one piece of concrete substrate of 1m × 1m, meet claimed below：
1st, the concrete strength of basic unit reaches more than 30Mpa, and adhesive strength is not less than 1.5Mpa.
2nd, basic unit's moisture control is below 8%.
3rd, base material integral seamless is complete.Apply when on engineering terrace, such as have crack, then after opening " V " groove using electric pick,
Plane fracture is scraped to fill with polyurethane cement batch to stitch, repaired.
4th, concrete substrate, concrete surface not dusting, do not have efflorescence, and hardness is normal.
5th, concrete substrate does not have grease to pollute and hollowing phenomenon.
6th, base material sample block surfacing.The surface smoothness of engineering terrace is controlled in 3-5mm/2m.
（3）Material stirring mixing.Component A in proportion and B component are poured into mixing tank, with mixer in low speed
（300rpm）Lower stirring 30 seconds to 1 minute, until well mixed.Then stirred in the material for again pouring into after mixing component C
Uniformly.D components are eventually adding, stirring incorporation time is between 2-6 minutes.Stirring material it is thicker, it is necessary to time it is more long.According to
Temperature of charge determines mixing time, if temperature of charge is high, mixing time then shortens, if temperature of charge is low, extension stirring
Time.The undue temperature that improves can greatly shorten the applicable time, related working time during to solidification.
（4）Using.The mortar for stirring should immediately spread out and be coated on concrete substrate, control coating layer thickness>6mm, uses tooth
Rake or trowel are spread out, and trowel applies the polyurethane cement as primary coat, and with froth breaking roller roller coating polyurethane cement back and forth, make table
Face uniform ground.The time for stirring mixing depends on environment temperature and component temperature.The temperature of all components is maintained at 30
Extremely important below degree Celsius, otherwise stirring incorporation time and working time all will significantly shorten, and cause site operation to occur asking
The possibility increase of topic.
（5）Solidification.At 20 °C, after 24 hours, the concrete substrate being cured can just come into operation and test.
Product be can Self-leveling water-based system, the coating of the 6mm being cured or so, with hardness very high, surface is put down
It is whole seamless, it is coarse.Coating entirety uniform color, dumb light.
Coating hardness under 70 DEG C of high temperature is constant, P Passable personnel and vehicle.Boiling water is splashed in coating surface, right
Coating does not produce destructive effects, can be cleaned immediately.The coating chemicals-resistant corrodes, and citric acid solution is revealed in coating table
Face, coating hardness is constant, and volume is not shunk, coating not defect, and surface is normal after cleaning.The coating can have mechanical heavy duty and weight
Used in shock environment, anti-wear performance is superior.Non-skid property is superior.Stable performance in use, long service life, easily maintenance,
Easy cleaning.
[example two
Production process according to example one repeats the preparation of aqueous polyurethane mortar.
Application process and step：
（1）Product preparation.Product is weighed by weight：Component A:B component:Component C:D components=2.3Kg:2.8Kg:
24.4Kg:0.5Kg, common 30Kg/ sets.
（2）Model prepares.Prepare one piece of concrete substrate of 1m × 1m, for concrete substrate requirement with example one
Description.
（3）Material stirring mixing.Process is with the description in example one.
（4）Using.Process controls the thickness of coating in 12mm or so with the description in example one.
（5）Solidification.Process is with the description in example one.
The coating is the thick coating of 12mm.Product be can Self-leveling water-based system, the thick coating of the 12mm being cured, firmly
Degree is very high, is resistant to impact again, and surfacing is seamless, coarse, overall uniform color, dumb light.
The coating is constant in high temperature boiling water lower hardness of splashing, P Passable personnel and vehicle, and coating does not produce destruction, can be with
Cleaned.The coating chemicals-resistant corrodes, and citric acid solution is revealed in coating surface, and coating hardness is constant, and volume is not shunk,
Coating not defect, surface is normal after cleaning.The coating can be used in having mechanical heavy duty and weight shock environment, and anti-wear performance is excellent
More, non-skid property is superior.Stable performance in use, long service life is easily safeguarded, easy cleaning.
Example three
Production process according to example one repeats the preparation of aqueous polyurethane mortar.
Application process and step：
（1）Product preparation.Product is weighed by weight：Component A:B component:Component C:D components=2.3Kg:2.8Kg:
24.4Kg:0.5Kg, common 30Kg/ sets, packaging.
（2）Model prepares.Prepare one piece of concrete substrate of 1m × 1m, for concrete substrate requirement with example one
Description.
（3）Material stirring mixing.Process is with the description in example one.
（4）Using.The mortar for stirring spreads out be coated on concrete substrate immediately, controls coating layer thickness>12mm, uses tooth
Rake or trowel are spread out, and trowel applies the polyurethane cement as primary coat, and with froth breaking roller roller coating polyurethane cement back and forth, make table
Face uniform ground.
Prepare a part of fine quartz sand in addition, it is uniformly sowed in coating surface, form a 0.5mm left and right thickness
Quartz sand layer, wait it and sink to mortar, reuse froth breaking roller roller coating polyurethane cement surface back and forth, surface is presented
One ramming surface layer of densification.
（5）Solidification.Process is with the description in example one.
The coating is one has fine and close ramming surface layer, the thick coating of 12mm.The thick coating of the 12mm being cured, there is very high
Hardness, be resistant to impact again, surfacing is seamless, in fine and close coarse shape, overall uniform color, dumb light.
The coating is when high temperature boiling water is splashed on surface, and hardness is constant, personnel and open to traffic, and coating is not produced brokenly
It is bad, and can be cleaned immediately, behaviour in service is good.The coating product of resistance to harsh chemical corrode, and citric acid solution is revealed in coating table
Face, coating hardness does not change, coating not defect, and surface is normal after cleaning.The coating can have mechanical heavy duty and weight shock environment
In use, anti-wear performance is superior, and non-skid property is superior.Stable performance in use, long service life is easily safeguarded, easy cleaning.
Claims (7)
1. one kind can be applied to prepare extreme condition, and such as high temperature, high temperature difference, heavy industry load impact again, and frequently chemicals connects
The industry ground slab for waiting and being used in environment is touched, with certain ornamental aqueous polyurethane mortar, it is characterised in that：
（1）With four components A, B, C, D；Wherein
Component A is plant oil modified PPG aqueous dispersion；
B component is the material of active isocyanate functional group；
Component C is to include high performance concrete, quartz sand, CO2The inorganic active aggregate of absorbent；
D components are mill base.
2.（2）During the mixing cured application of four components, multiple curing reactions are carried out, including
1. PPG can occur the curing reaction of polyurethane with the isocyanates in B component in component A；
2. in component A there is curing reaction in the OH bases of modified vegetable oil with isocyanates in B component；
3. the water for containing in component A PPG can be with the reaction generation of the isocyanates in B component CO2And urea；
4. with isocyanates in B component there is curing reaction in the OH bases in D component botanicals oil-based material；
5. the cementation solidifying reaction of concrete.
3.（3）When coating layer thickness can be controlled in 6-12mm, the coating surface with this thickness is smooth seamless, does not ftracture,
Can bear to impact again, heavy industry carrying can be born.
4.（4）When coating layer thickness is 6-12mm, the coating with this thickness can bear 70-100 DEG C of temperature, Ke Yicheng
By the temperature difference high, can normally be used in above-mentioned environment.
5.（5）The surface of the thick coating can be moderate to slight coarse, with good skidproof effect.
6. the aqueous polyurethane mortar according to described by claim 1, it is characterised in that：Described aqueous polyurethane sand
Slurry system is gravity flowing levelling mortar system.
7. the aqueous polyurethane mortar according to described by claim 2, it is characterised in that：Described aqueous polyurethane sand
Slurry system, in use, ramming can be carried out on surface, forms a ramming surface layer；One can also be constructed with same process
Individual middle ramming layer, positioned at coating middle part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610435550.5A CN106927724A (en) | 2016-06-16 | 2016-06-16 | Heavy load anti-slip type aqueous polyurethane mortar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610435550.5A CN106927724A (en) | 2016-06-16 | 2016-06-16 | Heavy load anti-slip type aqueous polyurethane mortar |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106927724A true CN106927724A (en) | 2017-07-07 |
Family
ID=59444447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610435550.5A Pending CN106927724A (en) | 2016-06-16 | 2016-06-16 | Heavy load anti-slip type aqueous polyurethane mortar |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106927724A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN111996861A (en) * | 2020-07-21 | 2020-11-27 | 湖南砼艺市政工程建设有限公司 | Construction process of anti-skid pavement structure constructed by MMA (methyl methacrylate) |
| CN112456938A (en) * | 2020-12-10 | 2021-03-09 | 上海阳森精细化工有限公司 | High-fluidity long-operation-period polyurethane urea cement concrete mortar terrace |
-
2016
- 2016-06-16 CN CN201610435550.5A patent/CN106927724A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN111996861A (en) * | 2020-07-21 | 2020-11-27 | 湖南砼艺市政工程建设有限公司 | Construction process of anti-skid pavement structure constructed by MMA (methyl methacrylate) |
| CN112456938A (en) * | 2020-12-10 | 2021-03-09 | 上海阳森精细化工有限公司 | High-fluidity long-operation-period polyurethane urea cement concrete mortar terrace |
| CN112456938B (en) * | 2020-12-10 | 2022-08-26 | 上海阳森精细化工有限公司 | High-fluidity long-operation-period polyurethane urea cement concrete mortar terrace |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102770599B (en) | Composite road surface structure | |
| CN106927725A (en) | Aqueous color sand Self-leveling polyurethane cement | |
| KR100947460B1 (en) | Waterproofing method using polyurea and surfacepreparation compound | |
| JP2007254179A (en) | Coated floor material and polyurethane-based cement composition used therein | |
| KR100706636B1 (en) | High speed hardening epoxy resin concrete for the use of a paving bridge | |
| CN106927724A (en) | Heavy load anti-slip type aqueous polyurethane mortar | |
| CN106414363A (en) | Polyurethane hybrid system combining high compressive strength and early water resistance | |
| US4559239A (en) | Method for repairing cementitious substrate | |
| KR20210034816A (en) | Polyurethane resin mortar and its construction method | |
| KR102243728B1 (en) | Flooring composition with multi-functions of lyphophilic and hydrophilic properties and construction method of concrete flooring using the same | |
| KR101801833B1 (en) | Inorganic-based Paint Composition for Spraying and Method for Preparing Floor Finish Structure Using the Same | |
| US9221996B2 (en) | Process for repairing road surfacing systems, in particular for open-pore asphalts | |
| AU2012344079B2 (en) | Repair method for road surfacings, in particular for open-pored asphalts | |
| KR101009743B1 (en) | Repairing agent for reinforcing the concrete | |
| KR102145949B1 (en) | Polyurea coatings for quick-curing water treatment and a coating method using the same | |
| JP5008267B2 (en) | Urethane resin composition for inner surface resin lining of centrifugal reinforced concrete pipe | |
| US8617346B2 (en) | Process for coating, adhesive bonding and binding of mineral surfaces | |
| JP2012510008A (en) | Recycling road paving materials | |
| JP3793709B2 (en) | Coating floor and its construction method | |
| JP3924699B2 (en) | Floor structure and its construction method | |
| KR101783943B1 (en) | Three-component water dispered polyurethane-cement mortar flooring material composition using eoc-friendly bio-based resin and flooring construction method using the same | |
| JP6731838B2 (en) | Hydraulic polymer cement composition | |
| JP3796153B2 (en) | Repair floor and its construction method | |
| JP4140682B2 (en) | Formation method of coating layer | |
| KR100772483B1 (en) | Block with water permeability and method of fabrication thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170707 |