CN106479339A - A kind of organic inorganic hybridization resistant abrasion coating material and preparation method thereof - Google Patents
A kind of organic inorganic hybridization resistant abrasion coating material and preparation method thereof Download PDFInfo
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- CN106479339A CN106479339A CN201610943602.XA CN201610943602A CN106479339A CN 106479339 A CN106479339 A CN 106479339A CN 201610943602 A CN201610943602 A CN 201610943602A CN 106479339 A CN106479339 A CN 106479339A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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Abstract
The invention discloses a kind of organic inorganic hybridization resistant abrasion coating material, it includes component A material and B component material, and by being calculated by weight as 30～50 parts of waterglass, 1～10 part of catalyst, 1～10 part of plasticizer, 1～10 part of cross-linking agent forms described component A material；Described modulus of water glass 2.4～3.6,35 °～50 ° of Baume degrees；Described B component material is to be calculated by weight as 35～50 parts of isocyanates.The solvent that it overcomes existing impact-resisting wear-resisting coating material highly volatile is high, and penetrating odor is big, constructional difficulties, is difficult to construct, pliability is poor under wet environment and water environment, easily has the shortcomings that cracking peels off with large stretch of；There is construction technology simple, green pollution-free and having no irritating odor, the good advantage of adhesive property, resistance to impact and abrasion.The invention also discloses preparing a kind of method of organic inorganic hybridization resistant abrasion coating material.
Description
Technical field
The present invention relates to building materials field, specifically refer to a kind of organic inorganic hybridization resistant abrasion coating material.The present invention also relates to
And prepare a kind of method of organic inorganic hybridization resistant abrasion coating material.
Background technology
In recent years, with the enforcement of development of the West Regions and transferring electricity from the west to the east development strategy, a large amount of water conservancy and hydropower works are built in various places
Journey project, wherein in a large number using concrete building material, yet with being washed away by current for a long time, concrete surface constantly quilt
How air slaking, erosion and carbonization, final impact engineering safety and service life, therefore improve the durability of concrete, reduce by
The loss that this brings is always problem of concern；Can be added by improving structure design, strengthening engineering management and operation
The additives such as organic nanofibers, slag, flyash improve the resistance to impact and abrasion of concrete itself, in order to realize water conservancy and hydropower
The good operation of engineering, concrete surface is carried out with reasonable protective treatment is most economical effective solution.
Research concrete surface resistant abrasion coating material the widest has epoxy resin, acrylic resin, organosilicon tree at present
Fat, unsaturated polyester resin, polyurethane resin etc., contain the molten of more highly volatile in most of impact-resisting wear-resisting coating material
Agent, irritant abnormal smells from the patient, this brings difficulty for construction；Meanwhile, it is difficult to construct under wet environment and water environment, material flexibility
Differ from, easily have the phenomenon such as cracking and large stretch of peeling.
Therefore, in order to solve concrete surface impact-resisting wear-resisting material problems present in engineering, obtain one kind and apply
Work process is simple, green pollution-free and have no irritating odor, surface drying and time of doing solid work are adjustable, in dry area and moist area bonding
Performance and the good material of resistance to impact and abrasion are extremely urgent.
Content of the invention
The first object of the present invention is the weak point in order to overcome above-mentioned background technology, and provides a kind of organic-inorganic miscellaneous
Change resistant abrasion coating material, construction technology is simple, green pollution-free has no irritating odor, surface drying and time of doing solid work are adjustable,
Good with moist area's adhesive property and resistance to impact and abrasion in dry area.
The second object of the present invention is to provide to prepare a kind of method of organic inorganic hybridization resistant abrasion coating material.
In order to realize the first object of the present invention, the technical scheme is that：A kind of organic inorganic hybridization resistant abrasion applies
Layer material it is characterised in that：Including component A material and B component material, described component A material by being calculated by weight as 30～
50 parts of waterglass, 1～10 part of catalyst, 1～10 part of plasticizer, 1～10 part of cross-linking agent composition；Described modulus of water glass 2.4～
3.6,35 °～50 ° of Baume degrees；Described B component material is to be calculated by weight as 35～50 parts of isocyanates.
In technique scheme, described component A material, by being calculated by weight as 35～40 parts of waterglass, is urged for 3～7 parts
Agent, 1～5 part of plasticizer, 3～5 parts of cross-linking agent compositions；Described modulus of water glass 3.4～3.6,43 °～47 ° of Baume degrees；Described
B component material is to be calculated by weight as 35～40 parts of isocyanates.
In technique scheme, described component A material is by being calculated by weight as 38 parts of waterglass, 3 parts of triethylenes two
Amine, 1 part of stannous octoate, 3 parts of dibutyl phthalates, 4 parts of triethanolamine compositions；Modulus of water glass 3.5,45 ° of Baume degrees；Institute
Stating B component material is to be calculated by weight as 38 parts of Bayer waterborne polyurethane resins 2542.
In technique scheme, described waterglass is sodium silicate；Described isocyanates are water-based isocyanate；Described
Isocyanates be selected from Bayer waterborne polyurethane resin 2695,2542, xp 2593/1,2558, A145.
In technique scheme, described catalyst is selected from tertiary amine catalyst and/or organic tin catalyst；Described uncle
Amines catalyst is selected from triethylamine, triethylenediamine (DABCO), hexadecyldimethyl benzyl ammonium tertiary amine, methyl diethanolamine, three second
Alkene diamidogen (DABCO)；Described organic tin catalyst is selected from dibutyl tin laurate (DBTD), stannous octoate.
In technique scheme, described plasticizer is selected from dioctyl phthalate (DOP), dibutyl phthalate
(DBP), diethylene glycol dibenzoate.
In technique scheme, described cross-linking agent is selected from crosslinkers and/or amine cross-linking agent；Described alcohols is crosslinked
Agent is selected from 1,4- butanediol, diethylene glycol, glycerol, trimethylolpropane；Described amine cross-linking agent is selected from triethanolamine, N, N- diformazan
Base p-phenylenediamine, trimethylolpropane (TMP), triethylene diamine (DABCO).
In order to realize the second object of the present invention, the present invention prepares a kind of side of organic inorganic hybridization resistant abrasion coating material
Method is it is characterised in that comprise the technical steps that：
Step 1：The preparation of component A material：Choose the component of component A material, and determine its consumption；The group of component A material
Divide and stir at normal temperatures and pressures, barrelling obtains component A material；
Step 2：The preparation of B component material：Choose the component of described B component material, and determine its consumption；Barrelling obtains B
Component materials；
Step 3：During use, component A material, B component material are pressed 1:1 ratio is mixed, and stirs, and is applied
Smear.
Combined with silanol base using NCO, creamy material water-based isocyanate being modified obtain can profit
With knife coating procedure, concrete surface is protected；Protective coating not only has excellent resistant abrasion performance and and concrete surface
Strong adhesive property, also has corrosion resistance, salt resistance alkali, resistance to funguses, the characteristic such as environment friendly and pollution-free；Meanwhile, crosslinked by adding
The auxiliary agents such as agent, catalyst, plasticizer, finally give have excellent comprehensive performance water-based isocyanate waterglass organic-inorganic miscellaneous
Change resistant abrasion coating material.
Because the Bayer water-based isocyanate molecular weight that B component is selected is larger, therefore isocyano and silanol in waterglass
Base reacts, and degree of crystallinity is higher, and therefore intensity height, wearability are good；Meanwhile, the incorporation of waterglass has introduced silica structure so that body
System is more stable；Additionally, a small amount of reaction of moisture on isocyanates and Wet concrete interface penetrate into concrete surface layer, accordingly
Good with damping interface adhesive property.
A kind of above-mentioned organic inorganic hybridization resistant abrasion coating material construction technology step, comprises the steps：
Step 1：Basal plane is processed：With the discrete particles of angle grinder or steel wire polishing concrete surface, until exposing concrete
New face；Blow away the surface dirt grains of sand, if necessary concrete surface is carried out with clear water flushing, air-dries；
Step 2：Material brushing：Brushed according to order from top to bottom, from left to right, start energetic painting and scrape, return and scrape
When notice that surfacing is smooth；Painting requires firmly during scraping uniformly, to form the homogeneous coating of thickness；In addition painting is avoided to scrape as possible
During linking tool marks, when the larger basal plane of hole is repaired, be first firmly applied to hole larger part, point repeatedly apply on a small quantity
Smear, until smooth surface, smooth, the phenomenon such as no sag, foaming, depression；
Step 3：Coating maintenance：At least maintenance 24h after the completion of brushing, when material is not fully cured, avoid being subject to water
Soak, drench with rain, be exposed to the sun and clash into, the mechanical damage such as people steps on.
It is an advantage of the invention that：
(1) present invention is combined with silanol base using NCO and forms cancellated copolymer, and mechanical property is excellent
Different, resistant abrasion performance is good；
(2) creamy material obtaining can be protected to concrete surface using the method for blade coating, and constructing operation is simple；
(3) surface drying time is adjustable to a few houres in dozens of minutes, does solid work several hours adjustable；
(4) this product course of reaction has a small amount of carbon dioxide release, and no other toxic gas produce, environmental protection；
(5) concrete surfaces such as dangerously weak reseroirs, dam effectively can be protected.
Specific embodiment
Describe the performance of the present invention below in conjunction with specific embodiment in detail, but they do not constitute the limit to the present invention
Fixed, only for example.Make advantages of the present invention more clear and easy to understand by explanation simultaneously.
A kind of organic inorganic hybridization resistant abrasion coating material it is characterised in that：Including component A material and B component material, institute
State component A material by being calculated by weight as 30～50 parts of waterglass, 1～10 part of catalyst, 1～10 part of plasticizer, 1～10 part
Cross-linking agent forms；Described modulus of water glass 2.4～3.6,35 °～50 ° of Baume degrees；Described B component material is to count by weight
For 35～50 parts of isocyanates.
Described component A material is by being calculated by weight as 35～40 parts of waterglass, 3～7 parts of catalyst, 1～5 part of plasticising
Agent, 3～5 parts of cross-linking agent compositions；Described modulus of water glass 3.4～3.6,43 °～47 ° of Baume degrees；Described B component material is by weight
Amount number is calculated as 35～40 parts of isocyanates.
Described component A material by being calculated by weight as 38 parts of waterglass, 3 parts of triethylene diamines, 1 part of stannous octoate, 3 parts
Dibutyl phthalate, 4 parts of triethanolamine compositions；Modulus of water glass 3.5,45 ° of Baume degrees；Described B component material is by weight
Amount number is calculated as 38 parts of Bayer waterborne polyurethane resins 2542.
Described waterglass is sodium silicate；Described isocyanates are water-based isocyanate；Described isocyanates are selected from Bayer
Waterborne polyurethane resin 2695,2542, xp 2593/1,2558, A145.
Described catalyst is selected from tertiary amine catalyst and/or organic tin catalyst；Described tertiary amine catalyst is selected from three
Ethamine, triethylenediamine, hexadecyldimethyl benzyl ammonium tertiary amine, methyl diethanolamine, triethylene diamine；Described organic tin catalysis
Agent is selected from dibutyl tin laurate, stannous octoate.
Described plasticizer is selected from dioctyl phthalate, dibutyl phthalate, diethylene glycol dibenzoate.
Described cross-linking agent is selected from crosslinkers and/or amine cross-linking agent；Described crosslinkers be selected from 1,4- butanediol,
Diethylene glycol, glycerol, trimethylolpropane；Described amine cross-linking agent is selected from triethanolamine, N, N- dimethyl-p-phenylenediamine, three hydroxyl first
Base propane, triethylene diamine.
Prepare a kind of method of organic inorganic hybridization resistant abrasion coating material described above it is characterised in that：Including as follows
Processing step：
Step 1：The preparation of component A material：Choose the component of component A material, and determine its consumption；The group of component A material
Divide and stir at normal temperatures and pressures, barrelling obtains component A material；
Step 2：The preparation of B component material：Choose the component of described B component material, and determine its consumption；Barrelling obtains B
Component materials；
Step 3：During use, component A material, B component material are pressed 1:1 ratio is mixed, and stirs, and is applied
Smear.
Embodiment 1
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 45 parts of waterglass, 1 part of triethylamine, 1 part of dibutyl tin laurate, 2 parts of dioctyl phthalates, 3 parts
Triethanolamine forms；Modulus of water glass 2.8,40 ° of Baume degrees；B component material is to be calculated by weight as 42 parts of Bayer aqueouss to gather
Urethane resin 2695.
Prepare a kind of method of organic inorganic hybridization resistant abrasion coating material it is characterised in that：Comprise the technical steps that：
Step 1：The preparation of component A material：Choose the component of component A material, and determine its consumption；The group of component A material
Divide and stir at normal temperatures and pressures, barrelling obtains component A material；
Step 2：The preparation of B component material：Choose the component of described B component material, and determine its consumption；Barrelling obtains B
Component materials；
Step 3：During use, component A material, B component material are pressed 1:1 ratio is mixed, and stirs, and is applied
Smear.
A kind of main performance testing results such as table 1 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 1 main performance testing results
Embodiment 2：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 38 parts of waterglass, 3 parts of triethylene diamines, 1 part of stannous octoate, 3 parts of dibutyl phthalates, 4 part of three second
Hydramine forms；Modulus of water glass 3.5,45 ° of Baume degrees；B component material is to be calculated by weight as 38 parts of Bayer aqueous polyurethanes
Resin 2542.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 2 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 2 main performance testing results
Embodiment 3：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 40 parts of waterglass, 2 parts of triethylene diamines, 2 parts of hexadecyldimethyl benzyl ammonium tertiary amines, 2 parts of dibenzoic acid diethyls two
Alcohol ester, 3 parts of trimethylolpropane compositions；Modulus of water glass 3.2,42 ° of Baume degrees；B component material is to be calculated by weight as 50
Part Bayer waterborne polyurethane resin xp 2593/1.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 3 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 3 main performance testing results
Embodiment 4：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material be by
Parts by weight are calculated as 35 parts of waterglass, 1 part of dibutyl tin laurate, 1 part of diethylene glycol dibenzoate, 2 parts of triethanolamine,
3 parts of triethylene diamine compositions；Modulus of water glass 2.4,35 ° of Baume degrees；B component material is to be calculated by weight as 35 parts of Bayer water
Property polyurethane resin 2558.Its preparation method is same as Example 1.
A kind of main performance testing results such as table 4 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 4 main performance testing results
Embodiment 5：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 50 parts of waterglass, 1 part of stannous octoate, 3 parts of dibutyl phthalates, 1 part of BDO, 2 part of three hydroxyl
Methylpropane forms；Modulus of water glass 3.6,50 ° of Baume degrees；B component material is to be calculated by weight as 50 parts of Bayer aqueouss to gather
Urethane resin 2558.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 5 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 5 main performance testing results
Embodiment 6：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 30 parts of waterglass, 1 part of triethylamine, 10 parts of dioctyl phthalates, 3 parts of triethanolamine, 2 parts of Isosorbide-5-Nitrae-fourths two
Alcohol forms；Modulus of water glass 3.4,43 ° of Baume degrees；B component material is to be calculated by weight as 40 parts of Bayer aqueous polyurethane trees
Fat 2695.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 6 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 6 main performance testing results
Embodiment 7：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 38 parts of waterglass, 10 parts of stannous octoates, 5 parts of dibutyl phthalates, 5 parts of BDOs, 5 part of three hydroxyl
Methylpropane forms；Modulus of water glass 3.5,47 ° of Baume degrees；B component material is to be calculated by weight as 45 parts of Bayer aqueouss to gather
Urethane resin 2558.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 7 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 7 main performance testing results
Embodiment 8：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material be by
Parts by weight are calculated as 35 parts of waterglass, 3 parts of dibutyl tin laurates, 4 parts of diethylene glycol dibenzoate, 2 parts of triethanolamine,
2 parts of triethylene diamine compositions；Modulus of water glass 3.0,35 ° of Baume degrees；B component material is to be calculated by weight as 35 parts of Bayer water
Property polyurethane resin 2558.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 8 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 8 main performance testing results
Embodiment 9：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 40 parts of waterglass, 2 parts of triethylene diamines, 5 parts of hexadecyldimethyl benzyl ammonium tertiary amines, 7 parts of dibenzoic acid diethyls two
Alcohol ester, 1 part of trimethylolpropane composition；Modulus of water glass 3.5,45 ° of Baume degrees；B component material is to be calculated by weight as 40
Part Bayer waterborne polyurethane resin xp 2593/1.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 9 institute of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Show.
Table 9 main performance testing results
Embodiment 10：
A kind of organic inorganic hybridization resistant abrasion coating material, including component A material and B component material, component A material is by pressing
Parts by weight are calculated as 38 parts of waterglass, 3 parts of triethylene diamines, 3 parts of dioctyl phthalates, 5 parts of triethanolamine compositions；Water glass
Glass modulus 3.5,45 ° of Baume degrees；B component material is to be calculated by weight as 38 parts of Bayer waterborne polyurethane resins 2542.
Its preparation method is same as Example 1.
A kind of main performance testing results such as table 10 of organic inorganic hybridization resistant abrasion coating material that the present embodiment is obtained
Shown.
Table 10 main performance testing results
A kind of organic inorganic hybridization resistant abrasion coating material mechanical property and resistant abrasion performance that above-described embodiment is obtained
Relatively：Embodiment 2 ＞ embodiment, 10 ＞ embodiment, 1 ＞ embodiment, 6 ＞ embodiment, 4 ＞ embodiment, 8 ＞ embodiment 7 ＞ embodiment 5
Preferably, embodiment 3 effect is relatively poor for ＞ embodiment 9 ＞ embodiment 3, the wherein effect of embodiment 2.
Below by contrast test, a kind of organic inorganic hybridization anti-impact that the embodiment of the present invention 2, embodiment 3 are obtained to be described
Mill coating material mechanical property and resistant abrasion performance, main performance testing results are as shown in table 11.
Table 11 contrast test main performance testing results
As can be known from the above table：A kind of prepared organic inorganic hybridization resistant abrasion coating material mechanical property of the embodiment of the present invention 2,
Resistant abrasion performance is substantially better than embodiment 3, a kind of organic inorganic hybridization resistant abrasion coating material mechanical property that embodiment 3 is obtained
Energy, resistant abrasion performance are substantially better than concrete building material, existing impact-resisting wear-resisting coating material.
Other unaccounted parts belong to prior art.
Claims (8)
1. a kind of organic inorganic hybridization resistant abrasion coating material it is characterised in that：Including component A material and B component material, described
Component A material, by being calculated by weight as 30～50 parts of waterglass, 1～10 part of catalyst, 1～10 part of plasticizer, is handed over for 1～10 part
Connection agent composition；Described modulus of water glass 2.4～3.6,35 °～50 ° of Baume degrees；Described B component material is to be calculated by weight as
35～50 parts of isocyanates.
2. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 1 it is characterised in that：Described component A
Material is by being calculated by weight as 35～40 parts of waterglass, 3～7 parts of catalyst, 1～5 part of plasticizer, 3～5 parts of cross-linking agent groups
Become；Described modulus of water glass 3.4～3.6,43 °～47 ° of Baume degrees；Described B component material is to be calculated by weight as 35～40
Part isocyanates.
3. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 1 and 2 it is characterised in that：Described A group
Point material is by being calculated by weight as 38 parts of waterglass, 3 parts of triethylene diamines, 1 part of stannous octoate, 3 parts of phthalic acid two fourths
Ester, 4 parts of triethanolamine compositions；Modulus of water glass 3.5,45 ° of Baume degrees；Described B component material is to be calculated by weight as 38 parts
Bayer waterborne polyurethane resin 2542.
4. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 3 it is characterised in that：Described waterglass
For sodium silicate；Described isocyanates are water-based isocyanate；Described isocyanates be selected from Bayer waterborne polyurethane resin 2695,
2542、xp 2593/1、2558、A145.
5. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 4 it is characterised in that：Described catalyst
Selected from tertiary amine catalyst and/or organic tin catalyst；Described tertiary amine catalyst be selected from triethylamine, triethylenediamine,
Hexadecyldimethyl benzyl ammonium tertiary amine, methyl diethanolamine, triethylene diamine；Described organic tin catalyst is selected from tin dilaurate two fourth
Ji Xi, stannous octoate.
6. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 5 it is characterised in that：Described plasticizer
Selected from dioctyl phthalate, dibutyl phthalate, diethylene glycol dibenzoate.
7. a kind of organic inorganic hybridization resistant abrasion coating material according to claim 6 it is characterised in that：Described cross-linking agent
Selected from crosslinkers and/or amine cross-linking agent；Described crosslinkers are selected from 1,4- butanediol, diethylene glycol, glycerol, three hydroxyl first
Base propane；Described amine cross-linking agent is selected from triethanolamine, N, N- dimethyl-p-phenylenediamine, trimethylolpropane, triethylene diamine.
8. a kind of side of organic inorganic hybridization resistant abrasion coating material described in any claim in preparation the claims 1-7
Method it is characterised in that：Comprise the technical steps that：
Step 1：The preparation of component A material：Choose the component of component A material, and determine its consumption；The component of component A material exists
Stir under normal temperature and pressure, barrelling obtains component A material；
Step 2：The preparation of B component material：Choose the component of described B component material, and determine its consumption；Barrelling obtains B component
Material；
Step 3：During use, component A material, B component material are pressed 1:1 ratio is mixed, and stirs, and is smeared.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892868A (en) * | 2017-11-03 | 2018-04-10 | 洛阳双瑞防腐工程技术有限公司 | A kind of double-composition polyurethane waterproof paint and preparation method thereof |
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN113214635A (en) * | 2021-04-28 | 2021-08-06 | 汾阳市绿健塑胶材料制造有限公司 | Silicate/isocyanate composite polyurethane plastic track material and preparation method thereof |
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| CN102718462A (en) * | 2012-07-09 | 2012-10-10 | 杭州国电大坝安全工程有限公司 | Chemical grouting material for reinforcing loose and broken bedrock |
| CN104498004A (en) * | 2014-11-27 | 2015-04-08 | 山东一诺威新材料有限公司 | Chemical grouting material for coal-rock mass water shutoff and reinforcement and preparation method thereof |
| CN104910790A (en) * | 2015-06-11 | 2015-09-16 | 山东一诺威新材料有限公司 | Inorganic modified polyurethane spraying seal material and preparation method thereof |
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| CN102718462A (en) * | 2012-07-09 | 2012-10-10 | 杭州国电大坝安全工程有限公司 | Chemical grouting material for reinforcing loose and broken bedrock |
| CN104498004A (en) * | 2014-11-27 | 2015-04-08 | 山东一诺威新材料有限公司 | Chemical grouting material for coal-rock mass water shutoff and reinforcement and preparation method thereof |
| CN104910790A (en) * | 2015-06-11 | 2015-09-16 | 山东一诺威新材料有限公司 | Inorganic modified polyurethane spraying seal material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892868A (en) * | 2017-11-03 | 2018-04-10 | 洛阳双瑞防腐工程技术有限公司 | A kind of double-composition polyurethane waterproof paint and preparation method thereof |
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN113214635A (en) * | 2021-04-28 | 2021-08-06 | 汾阳市绿健塑胶材料制造有限公司 | Silicate/isocyanate composite polyurethane plastic track material and preparation method thereof |
| CN113214635B (en) * | 2021-04-28 | 2022-08-30 | 汾阳市绿健塑胶材料制造有限公司 | Silicate/isocyanate composite polyurethane plastic track material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106479339B (en) | 2019-05-28 |
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