CN102189598A - Water-based non-absorptive interface agent - Google Patents

Water-based non-absorptive interface agent Download PDF

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Publication number
CN102189598A
CN102189598A CN2010101187981A CN201010118798A CN102189598A CN 102189598 A CN102189598 A CN 102189598A CN 2010101187981 A CN2010101187981 A CN 2010101187981A CN 201010118798 A CN201010118798 A CN 201010118798A CN 102189598 A CN102189598 A CN 102189598A
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CN
China
Prior art keywords
water
nonabsorbable
interfacial agents
acrylic resin
emulsion
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Pending
Application number
CN2010101187981A
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Chinese (zh)
Inventor
窦钦锋
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SHANGHAI NATURE BUILDING MATERIAL CO Ltd
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SHANGHAI NATURE BUILDING MATERIAL CO Ltd
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Priority to CN2010101187981A priority Critical patent/CN102189598A/en
Publication of CN102189598A publication Critical patent/CN102189598A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a water-based non-absorptive interface agent which comprises the following components in percentage by weight: 40-60% of acrylic resin emulsion, 5-10% of natural vegetable glue, 20-40% of water and 5-10% of functional auxiliary. The water-based non-absorptive interface agent disclosed by the invention is used for bonding the cement-based self-leveling ground with the original ground, has excellent film forming property and viscosity on the non-absorptive ground of ceramic tiles, marble, waterstone and the like, is environment-friendly, and does not contain formaldehyde or other substances harmful to the environment.

Description

Water-based nonabsorbable interfacial agents
Technical field
The present invention relates to the concrete interface process field, be specifically related to a kind of water-based nonabsorbable interfacial agents.
Background technology
For the construction of cement-based self-leveling, the brushing of interfacial agents is a very important link.The purpose of brushing interfacial agents mainly comprises following 4 points: the one, to basic unit's sealing, avoid too much, the too fast suction of basic unit, and prevent that cement-based self-leveling mortar from losing moisture too early; The 2nd, the adhesion strength of enhancing basic unit and cement-based self-leveling mortar layer; The 3rd, prevent the generation of bubble; The 4th, improve the flowability of cement self-leveling mortar.Chinese patent CN02148424.4 discloses a kind of water base interfacial agents, and it is solvent (as carrier) with water, with natural animal glue and the certain technology of several auxiliary agent process, makes the aqueous solution.The maximum characteristics of this invention be exactly interfacial agents when concrete surface sprays, a part of interfacial agents is penetrated into inside concrete, a part is stayed concrete surface.When smearing mortar, this part interfacial agents of concrete surface is dissolved in the mortar, and after mortar solidified, concrete just formed firm integral body with mortar like this.Yet in some fine and close basic units, as ceramic tile, marble, terrazzo, this interfacial agents just can not well penetrate into basic unit, thereby influenced its caking property greatly, some substrate surface are smooth simultaneously, and surface tension is very low, and interfacial agents can not well form continuous film in this basic unit.Because these fine and close basal planes will increase construction cost greatly with artificial removing, common interfacial agents then is not suitable for nonabsorbable basic unit (in the transformation process of level ground, many once visited places, former terrace is that materials such as ceramic tile, terrazzo, terrace lacquer are nonabsorbable basic unit usually).
Summary of the invention
This technical problem to be solved is to provide a kind of water-based nonabsorbable interfacial agents, to solve in nonabsorbable basic unit problem such as making cement based self-leveling construction difficulty.Water-based nonabsorbable interfacial agents of the present invention has aqueous, environmental protective, advantage such as good caking property and film forming in nonabsorbable basic unit.The invention solves material and technological problems in the flat construction of flowing automatically on the nonabsorbable basal plane, for the transformation of nonabsorbable terrace has solved very big technical barrier.
In order to achieve the above object, the present invention realizes by the following technical solutions:
A kind of water-based nonabsorbable interfacial agents by weight percentage, comprises following component:
Emulsion acrylic resin 40-60%
Natural plant 5-10%
Water 20-40%
Functional aid 5-10%.
Described emulsion acrylic resin is one or more in fluorine-silicon modified acrylic resin emulsion, fluorin modified crylic acid resin emulsion, the polyurethane acrylic resin emulsion, above-mentioned silicon that preferred surface tension force is low or fluorin modified crylic acid resin emulsion.
Described natural plant is a kind of in gum arabic, the peach gum powder or the mixing of the two.
Described functional aid comprises defoamer, levelling agent, wetting agent and coalescents.Wherein, defoamer is the polyethers defoamer, and levelling agent, wetting agent are the modification silicon polymer based on multiple copolymer, and coalescents is 12 carbon alcohol esters.
The mass ratio of described defoamer, levelling agent, wetting agent, coalescents is 1-2: 1-2: 1: 5-7.
Above-mentioned raw materials is fully disperseed in dispersion machine, promptly make water-based nonabsorbable interfacial agents of the present invention.
The present invention uses the emulsion acrylic resin of modification to make that the surface tension of whole water-based nonabsorbable interfacial agents formula system is well reduced, and uses natural plant not only environmentally friendly again simultaneously, but also has increased the adhesive force and the viscosity of interfacial agents.
Water-based nonabsorbable interfacial agents of the present invention is applied to the bonding of cement-based self-leveling ground and original ground, on nonabsorbable ground such as ceramic tile, marble, terrazzo, have good film forming, caking property, environmental protection, do not contain harm such as formaldehyde surrounding material fully.
The specific embodiment
Below in conjunction with the specific embodiment the present invention that further explains.
(unit: Kg)
Embodiment 1 embodiment 2 Comparative Examples 1
Modified acrylic resin emulsion 50--
Common emulsion acrylic resin-50 50
Peach gum powder 82 10
Gum arabic 2 8/
Water 30 30 30
Coalescents 777
Defoamer 111
Levelling agent 111
Wetting agent 111
According to above proportioning, all raw materials are fully disperseed in dispersion machine, promptly obtain water-based nonabsorbable interfacial agents of the present invention and Comparative Examples 1 interfacial agents.
Measure the tensile bond strength of the two respectively, specific as follows:
1. experiment utensil:
Cupping machine: measured value range 15%~85% between, indicating accuracy is not less than 1%, draw speed (5 ± 1) mm/min.
Concrete slab: performance should meet the requirement of JC/T547 appendix A, and size is 400mm X 200mmX (40~50) mm.
Ceramic Tiles: performance should meet the requirement of GB/T4100, water absorption rate=0.5%, and surfacing is smooth.
The experiment mortar: experimental water mud adopts and meets GB175 requirement, the ordinary portland cement of strength grade 42.5MPa.Requirement by the 6th of GB/T17671 prepares cement mortar, cement: medium sand=1: 2.
2. experimental procedure:
Select the experiment base material, I type water-based interfacial agents is selected concrete slab for use, and II type water-based interfacial agents is selected Ceramic Tiles for use.Two blocks of experiment base materials are adopted in every group of experiment, a brushing interfacial agents of the present invention, a brushing Comparative Examples interfacial agents.The base material of brushing interfacial agents is placed 24h under the standard test condition.
Inside dimension is placed on the experiment base material for the 50mm*50mm*2mm metal frame, fills up the type frame, use the scraper flat surface, remove the type frame with the experiment mortar.With test specimen maintenance 6d in curing box.Remove surperficial laitance and flat surface with perching knife, with suitable high-strength adhesive (as the epoxy resin binding agent) the drawing head is sticked on the experiment mortar, placed one day under standard test conditions, every group of test specimen is at least 5.
On tensile testing machine, be stretched to test specimen with the speed of 5mm/min and destroy, measure maximum pull.
3. the result calculates:
Tensile bond strength calculates by formula (1):
d=F/S ......................(1)
In the formula:
D---stretch adhesion strength, unit is MPa (MPa);
The maximum pull of F---test specimen, unit are newton (N);
The bond area of S---test specimen, 2500mm 2
Tensile bond strength is with the arithmetic average value representation of 5 test specimens, and the result is accurate to 0.01MPa.
Tensile bond strength is than calculating by formula (2):
R=d 1/d ......................(2)
In the formula:
R---tensile bond strength ratio, unit is percentage (%);
d 1---the tensile bond strength of the test specimen of brushing interfacial agents, unit are MPa (MPa);
The tensile bond strength of the test specimen of d---not brushing interfacial agents (contrast test specimen), unit are MPa (MPa).
The result is accurate to 0.1%.
The interfacial agents that makes according to embodiment 1,2 and Comparative Examples 1 prescription in order to last method test, obtains the adhesion strength ratio of these 3 kinds of interfacial agents and cement, sees table.
Embodiment 1 embodiment 2 Comparative Examples 1
Tensile bond strength is than (7d), and % 132 142 97
By above experimental result as can be known, water-based nonabsorbable interfacial agents of the present invention has good cohesive force.

Claims (7)

1. a water-based nonabsorbable interfacial agents is characterized in that, by weight percentage, comprises following component:
Emulsion acrylic resin 40-60%
Natural plant 5-10%
Water 20-40%
Functional aid 5-10%.
2. according to claims 1 described water-based nonabsorbable interfacial agents, it is characterized in that described emulsion acrylic resin is one or more in fluorine-silicon modified acrylic resin emulsion, fluorin modified crylic acid resin emulsion, the polyurethane acrylic resin emulsion.
3. according to claims 2 described water-based nonabsorbable interfacial agents, it is characterized in that the silicon modification that described emulsion acrylic resin preferred surface tension force is low or the emulsion acrylic resin of fluorine modification.
4. according to claims 1 described water-based nonabsorbable interfacial agents, it is characterized in that described natural plant is a kind of in gum arabic, the peach gum powder or the mixing of the two.
5. according to claims 1 described water-based nonabsorbable interfacial agents, it is characterized in that described functional aid comprises defoamer, levelling agent, wetting agent and coalescents.
6. according to claims 5 described water-based nonabsorbable interfacial agents, it is characterized in that described defoamer is the polyethers defoamer, described levelling agent, wetting agent are the modification silicon polymer based on multiple copolymer, and described coalescents is 12 carbon alcohol esters.
7. according to claims 5 or 6 described water-based nonabsorbable interfacial agents, it is characterized in that the mass ratio of described defoamer, levelling agent, wetting agent, coalescents is 1-2: 1-2: 1: 5-7.
CN2010101187981A 2010-03-05 2010-03-05 Water-based non-absorptive interface agent Pending CN102189598A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898069A (en) * 2012-10-25 2013-01-30 深圳广田装饰集团股份有限公司 Interface agent for bonding vitrified tiles and construction method thereof
CN104140776A (en) * 2013-05-10 2014-11-12 洛阳市科隆涂料有限公司 Aqueous environmentally-friendly wall interface processing material and preparation method thereof
CN104745012A (en) * 2015-03-28 2015-07-01 福建六建集团有限公司 Polymer emulsion interfacial agent for treating building wall and preparation method of polymer emulsion interfacial agent
CN114891408A (en) * 2022-05-24 2022-08-12 江苏佳境生态工程技术有限公司 Permeable concrete organic protective agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1468915A (en) * 2002-07-17 2004-01-21 郭保生 Radon preventing paint
CN1504308A (en) * 2002-12-03 2004-06-16 王培武 Water based interface agent
CN1632015A (en) * 2004-11-30 2005-06-29 上海梅盛企业发展有限公司 Nano self-crosslinked acrylate paint for external wall and method for making same
CN1876750A (en) * 2006-07-06 2006-12-13 北京中化科城技术研究所 High intensity elastic water-proofing material
WO2009021814A1 (en) * 2007-08-16 2009-02-19 Henkel Ag & Co. Kgaa Water re-dissolvable adhesive
CN101555305A (en) * 2009-05-19 2009-10-14 上海华凯科技贸易公司 Composite material composed by acrylic acid copolymer and glutin and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1468915A (en) * 2002-07-17 2004-01-21 郭保生 Radon preventing paint
CN1504308A (en) * 2002-12-03 2004-06-16 王培武 Water based interface agent
CN1632015A (en) * 2004-11-30 2005-06-29 上海梅盛企业发展有限公司 Nano self-crosslinked acrylate paint for external wall and method for making same
CN1876750A (en) * 2006-07-06 2006-12-13 北京中化科城技术研究所 High intensity elastic water-proofing material
WO2009021814A1 (en) * 2007-08-16 2009-02-19 Henkel Ag & Co. Kgaa Water re-dissolvable adhesive
CN101555305A (en) * 2009-05-19 2009-10-14 上海华凯科技贸易公司 Composite material composed by acrylic acid copolymer and glutin and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898069A (en) * 2012-10-25 2013-01-30 深圳广田装饰集团股份有限公司 Interface agent for bonding vitrified tiles and construction method thereof
WO2014063480A1 (en) * 2012-10-25 2014-05-01 深圳广田装饰集团股份有限公司 Interface agent for binding vitrified tiles and construction method therefor
CN102898069B (en) * 2012-10-25 2014-11-26 深圳广田装饰集团股份有限公司 Interface agent for bonding vitrified tiles and construction method thereof
CN104140776A (en) * 2013-05-10 2014-11-12 洛阳市科隆涂料有限公司 Aqueous environmentally-friendly wall interface processing material and preparation method thereof
CN104745012A (en) * 2015-03-28 2015-07-01 福建六建集团有限公司 Polymer emulsion interfacial agent for treating building wall and preparation method of polymer emulsion interfacial agent
CN114891408A (en) * 2022-05-24 2022-08-12 江苏佳境生态工程技术有限公司 Permeable concrete organic protective agent and preparation method thereof

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Application publication date: 20110921