CN1690145A - Method for making plastic playground runway by using water-soluble resin modified polyurethane - Google Patents
Method for making plastic playground runway by using water-soluble resin modified polyurethane Download PDFInfo
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- CN1690145A CN1690145A CN 200410036772 CN200410036772A CN1690145A CN 1690145 A CN1690145 A CN 1690145A CN 200410036772 CN200410036772 CN 200410036772 CN 200410036772 A CN200410036772 A CN 200410036772A CN 1690145 A CN1690145 A CN 1690145A
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Abstract
The invention discloses a method for producing synthetic sports ground surface track by water-soluble resin modified polyurethane. It is known that heavy metal and chlorcosane, toluene diisocyanate in the traditional technique breakdown toxic substance in high temperature and high pressure, the invention takes water-soluble resin modified polyurethane adjust the property of toluene diisocyanate, and free of heavy metal and chlorcosane, so the products is non-toxic, each technical index comes up to the international standard, and the track is benefit to health and environment.
Description
Technical field
The present invention relates to the manufacture method of plastic sports ground runway, particularly a kind of method that adopts the water soluble resin modified polyurethane to make the plastic sports ground runway.
Background technology
The plastic sports ground of advanced making international standard and the method for runway; as Chinese patent application number is 01114616.8 disclosed; denomination of invention is made the method for plastic sports ground and runway for adopting nano material modified polyurethane; its shortcoming is to contain heavy metal and clorafin, tolylene diisocyanate in the product; in high temperature, highly compressed technical process, toxic substance be can decomposite, health and environment protection are unfavorable for.
Summary of the invention
The objective of the invention is at above-mentioned shortcoming; develop the method that adopts the water soluble resin modified polyurethane to make the plastic sports ground runway; in the technology of making, utilize the characteristic of water soluble resin; changed the performance of tolylene diisocyanate; adopt heavy metal free and clorafin technology; make the product nontoxicity, every technical indicator meets international standards, and athletic ground and runway more help health and environment protection.
The object of the present invention is achieved like this:
1, preparation A component:
Material mixture ratio is by A component total weight percent:
Take by weighing 15 to 40% tolylene diisocyanate, 60 to 85% polyether diols polyvalent alcohol, two kinds of above-mentioned material total weight percent are 100%, uniform mixing is made the A component.
2, preparation B component:
Material mixture ratio is by B component total weight percent:
Take by weighing 1 to 30% 3,3-two chloro-4,4-amine ditan or 4,4-methylene radical-two 2 ethyl phenylbenzene, two 6 methyldiphenylamines one of them or mixture; 0.1 trihydroxy-polyether glycol to 20%; 0.1 to 2% tetrahydroxy polyether glycol; 0 to 60% stopping composition: talcum powder, lime carbonate, kaolin; 1 to 55% polyalcohols plasticising drug: DEDB, phthalic ester di-isooctyl, phthalic ester dioctyl ester, phthalic ester dimethyl ester; 0.01 oxidation inhibitor: pentaerythritol tetrathioglycollate-1,3,5-trimethylammonium-2,4,6 triphens to 2%; 0.01 the UV light absorber UV-9 to 2%, UV-531; 0.1 pigment to 15%: red iron oxide, phthalein viridescent, phthalocyanine blue, the brilliant indigo plant in sea, chrome green, permanent bordeaux, permanent yellow, solid orange, orange forever forever, above-mentioned material total weight percent is 100%, uniform mixing is made the B component.
3, preparation water soluble resin modified polyurethane tackiness agent:
Above-mentioned A component, B component and catalyzer: superoxide, zinc naphthenate, calcium naphthenate, isocaprylic acid zinc, calcium iso-octoate, in following ratio: A component: B component: catalyzer=1: 0.5 to 8: 0.05 is to 0.13 uniform mixing, add 0.5 to 20% the water soluble resin press A component weight again: water-soluble polypropylene acid resin, water-soluble poly methacrylic resin, water-soluble epoxy resin or starch, uniform mixing are made water soluble resin modified polyurethane tackiness agent.
4, adopt the water soluble resin modified polyurethane to make the plastic sports ground runway:
A, make not threshing plastic sports ground runway
Material mixture ratio is by water soluble resin modified polyurethane binder wt per-cent:
Take by weighing the above-mentioned water soluble resin modified polyurethane tackiness agent of engineering project requirement; the damaged tire particle or the old rubber grain stopping composition of adding 0 to 70% with the thickness of Slicking apparatus by 3 to 22 millimeters, are laid on the basal layer; spontaneous curing forms the plastic cement race track primer layer.0.5 to 5 millimeter water soluble resin modified polyurethane tackiness agent paves on primer layer, become mesogloea, sow or spray particle diameter that the sheet material made by water soluble resin modified polyurethane tackiness agent is ground into again and be 1 to 5 millimeter particle, bonding naturally, form the runway skid resistant surface.Wipe the particle that floating of skid resistant surface off with the Slicking apparatus brute force, apply the water soluble resin modified polyurethane tackiness agent of 0.3 to 2 millimeter thickness of one deck then, not threshing plastic sports ground runway is promptly made in setting-out after the spontaneous curing.
B, making agranular type plastic cement race track
Material mixture ratio is by water soluble resin modified polyurethane binder wt per-cent:
Take by weighing the above-mentioned water soluble resin modified polyurethane tackiness agent of engineering project requirement, add 15 to 70% damaged tire particle or old rubber grain stopping composition again, be poured on the bituminous concrete basis after high-speed stirring is even, gauge control is at 5 to 20 millimeters.After treating that glue solidifies, 2 to 6 millimeters above-mentioned tackiness agents are annotated in the shop in the above, and tackiness agent during completely solidified, with the embossing steel drum that scribbles releasing agent or washing composition, was not pressed gently, and the agranular type plastic cement race track is promptly made in setting-out on request in the above after the glue completely solidified.
C, making air-permeable plastic cement motion runway
It with above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter 1 to 5 millimeter damaged tire particle, part by weight is 1: 5, by making not threshing of water soluble resin modified polyurethane plastic cement motion runway method, make thickness and be 3 to 20 millimeters primer layer, be 1 to 5 millimeter antiskid particles again with above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter, part by weight is to 1 to mix at 1: 0.3, add above-mentioned by water soluble resin modified polyurethane binder wt than being after 10 to 30% ethyl acetate or butylacetate material dilute, with spraying machine above-mentioned materials is sprayed on primer layer, thickness is 1 to 5 millimeter, form random anti-skidding pitted skin air-permeable plastic cement race track, air-permeable plastic cement motion runway is promptly made in setting-out on request.
The plastic sports ground that employing the present invention makes and the every technical indicator of product and the nontoxicity of runway all meet international standards, and make athletic ground and runway more help health and environment protection.
Embodiment
In conjunction with the embodiments, further describe the present invention:
Embodiment 1:
Make water soluble resin modified polyurethane agranular type synthetic court runway
(1), take by weighing 600 kilograms of polyether diols polyvalent alcohols and inject retort, be warming up to 120 ℃, found time to dewater 2 hours, 210 kilograms tolylene diisocyanate is injected in the cooling back, is warming up to 90 ℃ of reactions 2 hours, is cooled to 45 ℃, the blowing packing is made the first component.
(2), take by weighing 3,3-two chloro-4,14 kilograms of 4-amine ditans; 4.4-methylene radical-two 2 ethyls, 2 kilograms of two 6 methyldiphenylamines; 24 kilograms of trihydroxy-polyether glycols; 1.5 kilograms of tetrahydroxy polyether glycols; 90 kilograms of DEDB; 163.2 kilograms of talcum powder, 1 kilogram of kaolin, 3 kilograms of red iron oxides, 0.4 kilogram of antioxidant 1010-pentaerythritol tetrathioglycollate, 0.4 kilogram of UV light absorber UV-9,1 kilogram of starch.After process is ground in the above-mentioned material input high-speed grinder, in the retort of reinjecting, dewater through heating up, blowing is packed and is made component B.
(3), with above-mentioned first component: component B was by 1: 3 proportioning, inject the high-speed stirring jar respectively, add 2% the calcium iso-octoate catalyzer be equivalent to first component total amount then, add again 10% the water soluble resin be equivalent to first component total amount through high-speed stirring evenly after, add the 25% damaged tire particle that is equivalent to first component, component B total amount again, be poured on the bituminous concrete basis after high-speed stirring is even, gauge control is at 9 millimeters.After treating that glue solidifies, 4 millimeters above-mentioned glues are annotated in the shop in the above, and glue during completely solidified, with the embossing steel drum that scribbles releasing agent, was not pressed gently, and agranular type synthetic court runway is promptly made in setting-out on request in the above after the glue completely solidified.
Embodiment 2:
Make not threshing of water soluble resin modified polyurethane plastic cement motion runway
(1), take by weighing 600 kilograms of polyether diols polyvalent alcohols and inject retort, be warming up to 120 ℃, found time to dewater 2 hours, 180 kilograms tolylene diisocyanate is injected in the cooling back, is warming up to 90 ℃ of reactions 2 hours again, is cooled to 45 ℃, blowing packing system first component.
(2), take by weighing 11 kilograms of 3.3-chloro-4.4-methylene dianilines, 4,4-methylene radical-two 2 ethyl phenylbenzene, 1 kilogram of two 6 methyldiphenylamine, 1 kilogram of tetrahydroxy polyether glycol, 70 kilograms of DEDB, 40 kilograms of trihydroxy-polyether glycols, talcum powder 120 kg, 5 kilograms of red iron oxides, 0.6 kilogram of oxidation inhibitor-pentaerythritol tetrathioglycollate, 0.6 kilogram of UV light absorber UV-9 with grinding in the above-mentioned all material input high-speed grinder, injects retort then, after the dehydration that heats up, cooling blowing packing is made component B.
(3), with the first component: component B was by 1: 2.5 proportioning, inject the high-speed stirring jar, add then by 3% zinc naphthenate of first component content and the mixture catalyzer of isocaprylic acid zinc, 12% the water soluble resin that adds first component content again, after the stirring mixture paved into thickness and is 6 mm film, after waiting to solidify, it is 4 millimeters antiskid particles that film is ground into particle diameter.
(4), with above-mentioned in the glue that the high-speed stirring jar stirs, add 25% damaged tire particle, after stirring, pave on the pitch basis, thickness requirement is 9 millimeters.After glue solidifies; blade coating thickness is 2 millimeters glue; on glue, spray 3 millimeters above-mentioned particles of thickness again; after the glue completely solidified; the particle of not adhesion is scraped a machine with brute force remove, spray the glue of 0.6 mm thick more in the above, after glue solidifies; not threshing plastic cement motion runway is made in setting-out on request.
Embodiment 3:
Make water soluble resin modified polyurethane air-permeable plastic cement motion runway
With above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter is that 3 millimeters damaged tire particle weight ratio is 1: 5, press embodiment 2 not threshing of water soluble resin urethane plastic cement motion runway methods, make thickness and be 9 millimeters primer layer, the antiskid particles part by weight that with above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter is 1.5 millimeters again is to mix at 1: 0.5, after adding is diluted than the butylacetate material that is 20% by above-mentioned water soluble resin modified polyurethane binder wt, with spraying machine above-mentioned materials is sprayed on primer layer, thickness is 3 millimeters, form random anti-skidding pitted skin air-permeable plastic cement race track, air-permeable plastic cement motion runway is promptly made in setting-out on request.
Claims (8)
1, adopt the water soluble resin modified polyurethane to make the method for plastic sports ground runway, it is characterized in that:
Preparation A component:
Material mixture ratio is by A component total weight percent:
Take by weighing 15 to 40% tolylene diisocyanate, 60 to 85% polyether diols polyvalent alcohol, two kinds of above-mentioned material total weight percent are 100%, uniform mixing is made the A component;
Preparation B component:
Material mixture ratio is by B component total weight percent:
Take by weighing 1 to 30% 3,3-two chloro-4,4-amine ditan or 4,4-methylene radical-two 2 ethyl phenylbenzene, two 6 methyldiphenylamines one of them or mixture; 0.1 trihydroxy-polyether glycol to 20%; 0.1 to 2% tetrahydroxy polyether glycol; 0 to 60% stopping composition; 1 to 55% polyalcohols plasticising drug; 0.01 oxidation inhibitor to 2%; 0.01 UV light absorber to 2%; 0.1 the pigment to 15%, above-mentioned material total weight percent is 100%, and uniform mixing is made the B component;
Preparation water soluble resin modified polyurethane tackiness agent:
Above-mentioned A component, B component and catalyzer: superoxide, zinc naphthenate, calcium naphthenate, isocaprylic acid zinc, calcium iso-octoate, in following ratio: A component: B component: catalyzer=1: 0.5 to 8: 0.05 is to 0.13 uniform mixing, add 0.5 to 20% the water soluble resin press A component weight again, uniform mixing is made water soluble resin modified polyurethane tackiness agent;
Adopt the water soluble resin modified polyurethane to make the plastic sports ground runway: to make not threshing plastic sports ground runway, agranular type plastic cement race track or air-permeable plastic cement motion runway:
(A), make not threshing plastic sports ground runway
Material mixture ratio is by water soluble resin modified polyurethane binder wt per-cent:
Take by weighing the above-mentioned water soluble resin modified polyurethane tackiness agent of engineering project requirement; the damaged tire particle or the old rubber grain stopping composition of adding 0 to 70% with the thickness of Slicking apparatus by 3 to 22 millimeters, are laid on the basal layer; spontaneous curing forms the plastic cement race track primer layer.0.5 to 5 millimeter water soluble resin modified polyurethane tackiness agent paves on primer layer, become mesogloea, sow or spray particle diameter that the sheet material made by water soluble resin modified polyurethane tackiness agent is ground into again and be 1 to 5 millimeter particle, naturally bonding, form the runway skid resistant surface, wipe the particle that floating of skid resistant surface off with the Slicking apparatus brute force, apply the water soluble resin modified polyurethane tackiness agent of 0.3 to 2 millimeter thickness of one deck then, not threshing plastic sports ground runway is promptly made in setting-out after the spontaneous curing;
(B), make water soluble resin modified polyurethane agranular type plastic cement race track
Material mixture ratio is by water soluble resin modified polyurethane binder wt per-cent:
Take by weighing the above-mentioned water soluble resin modified polyurethane tackiness agent of engineering project requirement, add 15 to 70% damaged tire particle or old rubber grain stopping composition again, be poured on the bituminous concrete basis after high-speed stirring is even, gauge control is at 5 to 20 millimeters, after treating that glue solidifies, 2 to 6 millimeters above-mentioned tackiness agents are annotated in the shop in the above, tackiness agent is not during completely solidified, with the embossing steel drum that scribbles releasing agent or washing composition, pressed gently, the agranular type plastic cement race track is promptly made in setting-out on request in the above after the glue completely solidified;
(C), make water soluble resin modified polyurethane air-permeable plastic cement motion runway
It with above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter 1 to 5 millimeter damaged tire particle, part by weight is 1: 5, by making not threshing of water soluble resin modified polyurethane plastic cement motion runway method, make thickness and be 3 to 20 millimeters primer layer, be 1 to 5 millimeter antiskid particles again with above-mentioned water soluble resin modified polyurethane tackiness agent and particle diameter, part by weight is to 1 to mix at 1: 0.3, add above-mentioned by water soluble resin modified polyurethane binder wt than being after 10 to 30% ethyl acetate or butylacetate material dilute, with spraying machine above-mentioned materials is sprayed on primer layer, thickness is 1 to 5 millimeter, form random anti-skidding pitted skin air-permeable plastic cement race track, air-permeable plastic cement motion runway is promptly made in setting-out on request.
2, method according to claim 1 is characterized in that: above-mentioned polyalcohols plasticising drug is DEDB, phthalic ester di-isooctyl, phthalic ester dioctyl ester, phthalic ester dimethyl ester.
3, method according to claim 1 is characterized in that: above-mentioned catalyzer is zinc naphthenate, calcium naphthenate, isocaprylic acid zinc, calcium iso-octoate.
4, method according to claim 1 is characterized in that: above-mentioned stopping composition is talcum powder, lime carbonate, kaolin.
5, method according to claim 1 is characterized in that: above-mentioned water soluble resin is water-soluble polypropylene acid resin, water-soluble poly methacrylic resin, water-soluble epoxy resin or starch.
6, method according to claim 1 is characterized in that: above-mentioned oxidation inhibitor is pentaerythritol tetrathioglycollate-1,3,5-trimethylammonium-2,4,6 triphens.
7, method according to claim 1 is characterized in that: above-mentioned UV light absorber is UV-9, UV-531.
8, method according to claim 1 is characterized in that: above-mentioned pigment is red iron oxide, phthalein viridescent, phthalocyanine blue, the brilliant indigo plant in sea, chrome green, permanent bordeaux, permanent yellow, solid orange, orange forever forever.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410036772 CN1690145A (en) | 2004-04-24 | 2004-04-24 | Method for making plastic playground runway by using water-soluble resin modified polyurethane |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410036772 CN1690145A (en) | 2004-04-24 | 2004-04-24 | Method for making plastic playground runway by using water-soluble resin modified polyurethane |
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| CN1690145A true CN1690145A (en) | 2005-11-02 |
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| CN 200410036772 Pending CN1690145A (en) | 2004-04-24 | 2004-04-24 | Method for making plastic playground runway by using water-soluble resin modified polyurethane |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302415B (en) * | 2008-06-27 | 2011-11-09 | 上海黎众木业有限公司 | Foaming floor glue |
| CN102250542A (en) * | 2011-04-25 | 2011-11-23 | 广州市合工大实力新材料研究院有限公司 | Polyurethane anti-slip finish material as well as preparation method and application thereof |
| CN102741480A (en) * | 2009-12-15 | 2012-10-17 | 拜尔材料科学股份公司 | Method for manufacturing outdoor facility pavement, finishing material used therein, and outdoor facility pavement obtained thereby |
| CN105949750A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Environment-friendly slide-proof abrasion-resistant high-elasticity composite plastic material applied to tracks |
| CN106084166A (en) * | 2016-07-29 | 2016-11-09 | 无锡龙盈环保科技有限公司 | A kind of fire resistant environment-friendly polyurethane plastic track material and preparation method thereof |
| CN107245296A (en) * | 2017-07-28 | 2017-10-13 | 陈两 | Full-plastic bears water ripple runway and preparation method thereof certainly |
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN109265638A (en) * | 2018-09-07 | 2019-01-25 | 江苏叙然信息科技有限公司 | A kind of environment-friendly type athletic ground surface material and application method |
-
2004
- 2004-04-24 CN CN 200410036772 patent/CN1690145A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302415B (en) * | 2008-06-27 | 2011-11-09 | 上海黎众木业有限公司 | Foaming floor glue |
| CN102741480A (en) * | 2009-12-15 | 2012-10-17 | 拜尔材料科学股份公司 | Method for manufacturing outdoor facility pavement, finishing material used therein, and outdoor facility pavement obtained thereby |
| CN102741480B (en) * | 2009-12-15 | 2015-04-22 | 拜尔材料科学股份公司 | Method for manufacturing outdoor facility pavement, finishing material used therein, and outdoor facility pavement obtained thereby |
| CN102250542A (en) * | 2011-04-25 | 2011-11-23 | 广州市合工大实力新材料研究院有限公司 | Polyurethane anti-slip finish material as well as preparation method and application thereof |
| CN102250542B (en) * | 2011-04-25 | 2013-09-18 | 广州市合工大实力新材料研究院有限公司 | Polyurethane anti-slip finish material as well as preparation method and application thereof |
| CN105949750A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Environment-friendly slide-proof abrasion-resistant high-elasticity composite plastic material applied to tracks |
| CN106084166A (en) * | 2016-07-29 | 2016-11-09 | 无锡龙盈环保科技有限公司 | A kind of fire resistant environment-friendly polyurethane plastic track material and preparation method thereof |
| CN107245296A (en) * | 2017-07-28 | 2017-10-13 | 陈两 | Full-plastic bears water ripple runway and preparation method thereof certainly |
| CN108821726A (en) * | 2018-05-19 | 2018-11-16 | 邵俊轩 | A kind of aqueous polyurethane mortar floor material of organic inorganic hybridization |
| CN109265638A (en) * | 2018-09-07 | 2019-01-25 | 江苏叙然信息科技有限公司 | A kind of environment-friendly type athletic ground surface material and application method |
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